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Fransoletite

A valid IMA mineral species
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About FransoletiteHide

01962510017271923356448.jpg
André-Mathieu Fransolet
Formula:
Ca3Be2(PO4)2(PO3OH)2 · 4H2O
Colour:
Colorless to slightly whitish
Lustre:
Sub-Vitreous
Hardness:
3
Specific Gravity:
2.56
Crystal System:
Monoclinic
Name:
Named in 1983 by D.R. Peacor, P.J. Dunn, W.L. Roberts, T.J. Campbell, and D. Newbury after André-Mathieu Fransolet (8 May 1947, Verviers, Liège, Belgium - ), professor of mineralogy and crystallography at the University of Liège and specialist in phosphates.
This page provides mineralogical data about Fransoletite.


Unique IdentifiersHide

Mindat ID:
1600
Long-form identifier:
mindat:1:1:1600:7

IMA Classification of FransoletiteHide

Approved
IMA Formula:
Ca3Be2(PO4)2(PO3OH)2·4H2O
Approval year:
1982
First published:
1983

Classification of FransoletiteHide

8.CA.05

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
A : With small and large/medium cations
40.5.1.1

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
5 : AXO4·xH2O
19.3.6

19 : Phosphates
3 : Phosphates of Be and Mg

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
FslIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FransoletiteHide

Sub-Vitreous
Transparency:
Transparent, Translucent
Colour:
Colorless to slightly whitish
Streak:
White
Hardness:
Cleavage:
Imperfect/Fair
{010}, imperfect
Fracture:
Irregular/Uneven
Density:
2.56(3) g/cm3 (Measured)    2.53 g/cm3 (Calculated)

Optical Data of FransoletiteHide

Type:
Biaxial (+)
RI values:
nα = 1.560(2) nβ = 1.566(2) nγ = 1.586(2)
2V:
Measured: 25° , Calculated: 58°
Max. Birefringence:
δ = 0.026
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r < v moderate
Optical Extinction:
Y = b; Z ∧ c = 14º.
Pleochroism:
Non-pleochroic

Chemistry of FransoletiteHide

Mindat Formula:
Ca3Be2(PO4)2(PO3OH)2 · 4H2O
Element Weights:
Element% weight
O54.032 %
P20.920 %
Ca20.302 %
Be3.044 %
H1.702 %

Calculated from ideal end-member formula.
O
P
Ca
Be
H

Crystallography of FransoletiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/a
Cell Parameters:
a = 7.35 Å, b = 15.07 Å, c = 7.05 Å
β = 96.41°
Ratio:
a:b:c = 0.488 : 1 : 0.468
Unit Cell V:
776.01 ų (Calculated from Unit Cell)
Z:
2

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0001531FransoletiteKampf A R (1992) Beryllophosphate chains in the structures of fransoletite, parafransoletite, and ehrleite and some general comments on beryllophosphate linkages American Mineralogist 77 848-85619920293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.044 Å(100)
3.47 Å(90)
3.32 Å(70)
2.317 Å(50)
7.52 Å(40)
2.597 Å(40)
6.55 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47c : [Carbonates, phosphates, borates, nitrates]

Type Occurrence of FransoletiteHide

General Appearance of Type Material:
Crystals are arrow-head-shaped, curved, composed of mosaiced aggregates of minute crystallites, to 3 mm.
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 149607.
Los Angeles County Museum of Natural History, Los Angeles, California, USA.
Geological Setting of Type Material:
Altered granitic pegmatite.
Associated Minerals at Type Locality:

Synonyms of FransoletiteHide

Other Language Names for FransoletiteHide

Common AssociatesHide

Associations Based on Photo Data:
9 photos of Fransoletite associated with TiptopiteK2(Na,Ca)2Li3Be6(PO4)6(OH)2 · H2O
6 photos of Fransoletite associated with RoscheriteCa2Mn2+5Be4(PO4)6(OH)4 · 6H2O
4 photos of Fransoletite associated with MontgomeryiteCa4MgAl4(PO4)6(OH)4 · 12H2O
3 photos of Fransoletite associated with EnglishiteK3Na2Ca10Al15(PO4)21(OH)7 · 26H2O
2 photos of Fransoletite associated with HurlbutiteCaBe2(PO4)2
1 photo of Fransoletite associated with RobertsiteCa2Mn3+3(PO4)3O2 · 3H2O
1 photo of Fransoletite associated with BerylBe3Al2(Si6O18)
1 photo of Fransoletite associated with WhitlockiteCa9Mg(PO4)6(PO3OH)

Related Minerals - Strunz-mindat GroupingHide

8.CA.ApexiteNaMg(PO4) · 9H2OTric. 1 : P1
8.CA.BrandãoiteBeAl2(PO4)2(OH)2(H2O)5Tric. 1 : P1
8.CA.DavidlloyditeZn3(AsO4)2 · 4H2OTric. 1 : P1
8.CA.05ParafransoletiteCa3Be2(PO4)2(PO3OH)2 · 4H2OTric. 1 : P1
8.CA.10EhrleiteCa4Be3Zn2(PO4)6 · 9H2OTric. 1 : P1
8.CA.15FaheyiteBe2Mn2+Fe3+2(PO4)4 · 6H2OTrig. 32 : P3121
8.CA.20MccrillisiteNaCs(Be,Li)Zr2(PO4)4 · 1-2H2OTet. 4/mmm(4/m2/m2/m) : I41/amd
8.CA.20GainesiteNa(Na,K)(Be,Li)Zr2(PO4)4 · 1.5-2H2OTet. 4mm : I41md
8.CA.20SelwyniteNaK(Be,Al)Zr2(PO4)4 · 2H2OTet. 4/mmm(4/m2/m2/m) : I41/amd
8.CA.25PahasapaiteLi8(Ca,Li,K)10.5Be24(PO4)24 · 38H2OIso. 23 : I23
8.CA.30NizamoffiteMn2+Zn2(PO4)2(H2O)4Orth. mmm(2/m2/m2/m) : Pbcm
8.CA.30ArsenohopeiteZn3(AsO4)2 · 4H2OOrth. mmm(2/m2/m2/m) : Pnma
8.CA.30HopeiteZnZn2(PO4)2 · 4H2OOrth. mmm(2/m2/m2/m) : Pnma
8.CA.35WarikahniteZn3(AsO4)2 · 2H2OTric. 1 : P1
8.CA.40PhosphophylliteZn2Fe 2+(PO4)2 · 4H2OMon. 2/m : P21/b
8.CA.42SteinmetziteZn2Fe3+(PO4)2(OH) · 3H2OTric. 1 : P1
8.CA.45ParascholziteCaZn2(PO4)2 · 2H2OMon.
8.CA.45ScholziteCaZn2(PO4)2 · 2H2OOrth. mmm(2/m2/m2/m) : Pbcm
8.CA.50KeyiteCu2+3Zn4Cd2(AsO4)6 · 2H2OMon. 2/m
8.CA.55PushcharovskiteK0.6Cu18[AsO2(OH)2]4[AsO3OH]10(AsO4)(OH)9.6 · 18.6H2OTric.
8.CA.60ProsperiteCa2Zn4(AsO4)4 · H2OMon.
8.CA.65GengenbachiteKFe3+3(PO3OH)4[PO2(OH)2]2 · 6H2OTrig. 3m : P31c
8.CA.70ParahopeiteZn3(PO4)2 · 4H2OTric. 1 : P1
8.CA.70ReaphookhilliteMgZn2(PO4)2 · 4H2OTric. 1 : P1
8.CA.75StergiouiteCaZn2(AsO4)2 · 4H2OMon. m : Pb
8.CA.80LimousiniteBaCa[Be4P4O16] · 6H2OMon. 2/m : P21/b
8.CA.85MinjiangiteBaBe2(PO4)2Hex. 6/mmm(6/m2/m2/m) : P6/mmm
8.CA.85Wilancookite(Ba5Li2◻)Ba6Be24P24O96 · 26H2OIso. 23 : I23

Fluorescence of FransoletiteHide

Not fluorescent.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FransoletiteHide

References for FransoletiteHide

Localities for FransoletiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
USA (TL)
 
  • South Dakota
    • Custer County
      • Custer Mining District
        • Fourmile
Rocks & Minerals: 60: 117. +1 other reference
 
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