Tennantite-(In)
A valid IMA mineral species
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Formula:
Cu6(Cu5In)As4S13
The formula Cu6(Cu4(In3+Cu+))As4S12S represents a charge-balanced end-member composition consistent with one of the published analyses.
A more general formula has also been given as Cu6(Cu4(In,Cu,Zn)2)As4S12S.
A more general formula has also been given as Cu6(Cu4(In,Cu,Zn)2)As4S12S.
Colour:
black
Lustre:
Metallic
Hardness:
3½ - 4
Specific Gravity:
4.763 (Calculated)
Crystal System:
Isometric
Member of:
Name:
Named for being the In rich member of the tennantite subgroup.
A Cu-Zn-rich “tennantite-(In)” (with quotation marks in original article) is described by Voudouris et al. (2022). It grades into In-rich tennantite-(Cu). The most In-rich analysis has 6.27 wt.% In. The mineral was subsequently approved (Voudouris et al., 2026).
Unique Identifiers
Mindat ID:
55711
Long-form identifier:
mindat:1:1:55711:5
Similar Names
| Pennantite | A valid IMA mineral species - grandfathered | Mn52+Al(AlSi3O10)(OH)8 |
| Tennantit | A synonym of Tennantite Subgroup | |
| Tennantite-(Cd) | A valid IMA mineral species | Cu6(Cu4Cd2)As4S12S |
| Tennantite-(Cu) | A valid IMA mineral species | Cu6(Cu4Cu2)As4S12S |
| Tennantite-(Fe) | A valid IMA mineral species | Cu6(Cu4Fe22+)As4S12S |
| Tennantite-(Hg) | A valid IMA mineral species | Cu6(Cu4Hg2)As4S12S |
| Tennantite-(Mn) | A valid IMA mineral species - pending publication | Cu6(Cu4Mn2)As4S12S |
| Tennantite-(Ni) | A valid IMA mineral species | Cu6(Cu4Ni2)As4S12S |
| Tennantite-(Zn) | A valid IMA mineral species | Cu6(Cu4Zn2)As4S12S |
IMA Classification of Tennantite-(In)
Approved
IMA Formula:
Cu1+6(Cu1+5In3+)As3+4S2-13
Type description reference:
Classification of Tennantite-(In)
2.GB.
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
B : Neso-sulfarsenites, etc. with additional S
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
B : Neso-sulfarsenites, etc. with additional S
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Tnt-In | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Tennantite-(In)
Metallic
Transparency:
Opaque
Colour:
Black
Streak:
Black
Hardness:
3½ - 4 on Mohs scale
Comment:
estimated
Tenacity:
Brittle
Cleavage:
Poor/Indistinct
Fracture:
Conchoidal
Density:
4.763 g/cm3 (Calculated)
Optical Data of Tennantite-(In)
Reflectivity:
| Wavelength | R1 (%) |
|---|---|
| 470nm | 31.2% |
| 546nm | 30.7% |
| 589nm | 30.5% |
| 650nm | 28.8% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 31.2%.
Colour in reflected light:
pale grey
Internal Reflections:
none
Chemistry of Tennantite-(In)
Mindat Formula:
Cu6(Cu5In)As4S13
The formula Cu6(Cu4(In3+Cu+))As4S12S represents a charge-balanced end-member composition consistent with one of the published analyses.
A more general formula has also been given as Cu6(Cu4(In,Cu,Zn)2)As4S12S.
The formula Cu6(Cu4(In3+Cu+))As4S12S represents a charge-balanced end-member composition consistent with one of the published analyses.
A more general formula has also been given as Cu6(Cu4(In,Cu,Zn)2)As4S12S.
Element Weights:
Elements listed:
Common Impurities:
Fe,Zn,Sb,Te,Sn,Mn,Se
Crystallography of Tennantite-(In)
Crystal System:
Isometric
Class (H-M):
43m - Hextetrahedral
Space Group:
I43m
Cell Parameters:
a = 10.285(2) Å
Unit Cell V:
1,087.96 ų (Calculated from Unit Cell)
Z:
2
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 4.199 Å | (4) |
| 2.969 Å | (100) |
| 2.749 Å | (4) |
| 2.571 Å | (20) |
| 2.018 Å | (4) |
| 1.878 Å | (7) |
| 1.818 Å | (42) |
| 1.551 Å | (21) |
Reference:
Type Occurrence of Tennantite-(In)
General Appearance of Type Material:
anhedral grains, up to 0.1 mm in size
Place of Conservation of Type Material:
Type material is deposited in the collections of the Museo di Storia Naturale, Università di Pisa, Via Roma 79, Calci (PI), Italy, catalogue number 20029
Geological Setting of Type Material:
epithermal ore deposit
probably related to the transition from the HS to the IS stages during the evolution of the Pefka epithermal deposit.
probably related to the transition from the HS to the IS stages during the evolution of the Pefka epithermal deposit.
Associated Minerals at Type Locality:
Reference:
Other Language Names for Tennantite-(In)
Dutch:Tennantiet-(In)
German:Tennantit-(In)
Relationship of Tennantite-(In) to other Species
Member of:
Other Members of Tennantite Subgroup:
| Tennantite-(Cd) | Cu6(Cu4Cd2)As4S12S | Iso. 43m : I43m |
| Tennantite-(Cu) | Cu6(Cu4Cu2)As4S12S | Iso. 43m : I43m |
| Tennantite-(Fe) | Cu6(Cu4Fe2+2)As4S12S | Iso. 43m : I43m |
| Tennantite-(Hg) | Cu6(Cu4Hg2)As4S12S | Iso. 43m : I43m |
| Tennantite-(Mn) | Cu6(Cu4Mn2)As4S12S | Iso. 43m : I43m |
| Tennantite-(Ni) | Cu6(Cu4Ni2)As4S12S | Iso. 43m : I43m |
| Tennantite-(Zn) | Cu6(Cu4Zn2)As4S12S | Iso. 43m : I43m |
Related Minerals - Strunz-mindat Grouping
| 2.GB. | 'Polybasite-Tac' | [Ag6Sb2S7][Ag9CuS4] |
| 2.GB. | Kenoargentotetrahedrite-(Zn) | [Ag6]4+(Cu4Zn2)Sb4S12◻ |
| 2.GB. | Argentotetrahedrite-(Hg) | Ag6(Cu4Hg2)Sb4S12S |
| 2.GB. | Annivite-(Zn) | Cu6(Cu4Zn2)Bi4S12S |
| 2.GB. | Pošepnýite | (Cu+3◻3)(Hg2+4Cu+2)Sb4Se12(Se0.5◻0.5) |
| 2.GB. | Tennantite-(Cu) | Cu6(Cu4Cu2)As4S12S |
| 2.GB. | Argentopolybasite | [Ag6Sb2S7][Ag9AgS4] |
| 2.GB. | Tennantite-(Mn) | Cu6(Cu4Mn2)As4S12S |
| 2.GB. | Argentotetrahedrite-(Cd) | Ag6(Cu4Cd2)Sb4S12S |
| 2.GB. | Stibioústalečite | (Cu4Cu2)(Cu4Cu+2)(Sb2Te2)Se12Se |
| 2.GB. | Stibiogoldfieldite | (Cu4Cu2)(Cu4Cu+2)(Sb2Te2)S12S |
| 2.GB. | Argentotetrahedrite-(Zn) | Ag6(Cu4Zn2)Sb4S12S |
| 2.GB. | Tetrahedrite-(Cd) | Cu6(Cu4Cd2)Sb4S12S |
| 2.GB. | Arsenogoldfieldite | (Cu4Cu2)(Cu4Cu+2)(As2Te2)S12S |
| 2.GB. | Arsenoústalečite | (Cu4Cu2)(Cu4Cu+2)(As2Te2)Se12Se |
| 2.GB. | Zvěstovite-(Fe) | Ag6(Ag4Fe2+2)As4S12S |
| 2.GB. | Hakite-(Fe) | Cu6(Cu4Fe2+2)Sb4Se12Se |
| 2.GB. | Tennantite-(Cd) | Cu6(Cu4Cd2)As4S12S |
| 2.GB.X | Kenorozhdestvenskayaite-(Fe) | [Ag6]4+(Ag4Fe2+2)Sb4S12◻ |
| 2.GB. | Tetrahedrite-(Cu) | Cu6(Cu4Cu2+2)Sb4S12S |
| 2.GB. | Hakite-(Zn) | Cu6(Cu4Zn2)Sb4Se12Se |
| 2.GB. | Zvěstovite-(Zn) | Ag6(Ag4Zn2)As4S12S |
| 2.GB. | Hakite-(Cd) | Cu6(Cu4Cd2)Sb4Se12Se |
| 2.GB. | Kenoargentotennantite-(Fe) | [Ag6]4+(Cu4Fe2)As4S12◻ |
| 2.GB. | Tennantite-(Hg) | Cu6(Cu4Hg2)As4S12S |
| 2.GB. | Tetrahedrite-(Mn) | Cu6(Cu4Mn2)Sb4S12S |
| 2.GB. | Tennantite-(Ni) | Cu6(Cu4Ni2)As4S12S |
| 2.GB. | Tetrahedrite-(Ni) | Cu6(Cu4Ni2)Sb4S12S |
| 2.GB.05 | Hakite-(Hg) | Cu6(Cu4Hg2)Sb4Se12Se |
| 2.GB.05 | Rozhdestvenskayaite-(Zn) | Ag6(Ag4Zn2)Sb4S12S |
| 2.GB.05 | Argentotennantite-(Zn) | Ag6(Cu4Zn2)As4S12S |
| 2.GB.05 | Argentotennantite-(Fe) | Ag6(Cu4Fe2)As4S12S |
| 2.GB.05 | Freibergite Subgroup | (Ag6,[Ag6]4+)(Cu4 C2+2)Sb4S12S0-1 |
| 2.GB.05 | Tennantite Subgroup | Cu6(Cu4C2+2)As4S12S |
| 2.GB.05 | Tennantite-(Zn) | Cu6(Cu4Zn2)As4S12S |
| 2.GB.05 | Tetrahedrite-(Zn) | Cu6(Cu4Zn2)Sb4S12S |
| 2.GB.05 | Tetrahedrite Subgroup | Cu6(Cu4C2+2)Sb4S12S |
| 2.GB.05 | Tennantite-(Fe) | Cu6(Cu4Fe2+2)As4S12S |
| 2.GB.05 | Tetrahedrite-(Fe) | Cu6(Cu4Fe2+2)Sb4S12S |
| 2.GB.05 | Tetrahedrite-(Hg) | Cu6(Cu4Hg2)Sb4S12S |
| 2.GB.05 | Kenoargentotetrahedrite-(Fe) | [Ag6]4+(Cu4Fe2+2)Sb4S12◻ |
| 2.GB.05 | Giraudite-(Zn) | Cu6(Cu4Zn2)As4Se12Se |
| 2.GB.05 | Argentotetrahedrite-(Fe) | Ag6(Cu4Fe2)Sb4S12S |
| 2.GB.05 | Goldfieldite | (Cu4◻2)(Cu4Cu+2)Te4S12S |
| 2.GB.05 | 'UM1992-21-S:AgFeSb' | Ag6(Ag4Fe2+2)Sb4S12S |
| 2.GB.10 | Selenostephanite | Ag5SbSe4 |
| 2.GB.10 | Stephanite | Ag5SbS4 |
| 2.GB.15 | 'UM2003-14-S:AgBiFeTe' | Ag16FeBiTe3S8 |
| 2.GB.15 | 'UM1979-17-S:BiCuFe' | ~Cu18Fe4BiS16 |
| 2.GB.15 | Pearceite | [Ag6As2S7][Ag9CuS4] |
| 2.GB.15 | Argentopearceite | Ag16As2S11 |
| 2.GB.15 | Cupropolybasite | [Cu6Sb2S7][Ag9CuS4] |
| 2.GB.15 | Fengruiite | [Ag6Sb2S7][Ag9CuS2Te2] |
| 2.GB.15 | Auropearceite | [Ag9AuS4][Ag6As2S7] |
| 2.GB.15 | Selenopolybasite | [(Ag,Cu)6(Sb,As)2(S,Se)7][Ag9Cu(S,Se)2Se2] |
| 2.GB.15 | Polybasite | [Ag6Sb2S7][Ag9CuS4] |
| 2.GB.15 | Auropolybasite | [Ag9AuS4][Ag6Sb2S7] |
| 2.GB.15 | Cupropearceite | [Cu6As2S7][Ag9CuS4] |
| 2.GB.20 | Vorontsovite | (Hg5Cu)Σ6TlAs4S12 |
| 2.GB.20 | Ferrovorontsovite | (Fe5Cu)Σ6TlAs4S12 |
| 2.GB.20 | Galkhaite | (Hg5Cu)CsAs4S12 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Tennantite-(In)
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https://www.mindat.org/min-55711.html
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References for Tennantite-(In)
Reference List:
Voudouris, Panagiotis; Repstock, Alexander; Spry, Paul G.; Frenzel, Max; Mavrogonatos, Constantinos; Keith, Manuel; Tarantola, Alexandre; Melfos, Vasilios; Tombros, Stylianos; Zhai, Degao; et al. (2022) Physicochemical constraints on indium-, tin-, germanium-, gallium-, gold-, and tellurium-bearing mineralizations in the Pefka and St Philippos polymetallic vein- and breccia-type deposits, Greece. Ore Geology Reviews, 140. 104348 doi:10.1016/j.oregeorev.2021.104348
Localities for Tennantite-(In)
Showing 2 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Greece | |
| Voudouris et al. (2022) |
| Voudouris et al. (2022) +1 other reference |
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