Kenoargentotetrahedrite-(Fe)
A valid IMA mineral species
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About Kenoargentotetrahedrite-(Fe)
Formula:
[Ag6]4+(Cu4Fe2+2)Sb4S12◻
Ag in the M2 site consists of a [Ag6]4+ cluster that presumably exhibits metal-metal bonding; the "missing" M2 charge is compensated by a vacancy in the S2 site; thus, there are only 12 S atoms per formula unit, not 13.
Colour:
greenish grey
Lustre:
Metallic
Crystal System:
Isometric
Member of:
Name:
The name kenoargentotetrahedrite-(Fe) partially supplants the former name freibergite for Fe>Zn members. The new name follows the revised nomenclature for the tetrahedrite group (Biagioni et al 2020).
Sb analogue of Kenoargentotennantite-(Fe).
The name kenoargentotetrahedrite-(Fe) partially supplants the former name "freibergite" for Fe>Zn members.
The name kenoargentotetrahedrite-(Fe) partially supplants the former name "freibergite" for Fe>Zn members.
Unique Identifiers
Mindat ID:
53610
Long-form identifier:
mindat:1:1:53610:3
Similar Names
| Kenoargentotetrahedrite-(Zn) | A valid IMA mineral species | [Ag6]4+(Cu4Zn2)Sb4S12◻ |
IMA Classification of Kenoargentotetrahedrite-(Fe)
Approved
IMA status notes:
Redefined by the IMA, Renamed by the IMA
IMA Formula:
Ag1+6(Cu1+4Fe2+2)Sb4S2-12◻
Type description reference:
Classification of Kenoargentotetrahedrite-(Fe)
2.GB.05
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
B : Neso-sulfarsenites, etc. with additional S
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
B : Neso-sulfarsenites, etc. with additional S
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Kattr-Fe | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Kenoargentotetrahedrite-(Fe)
Chemistry of Kenoargentotetrahedrite-(Fe)
Mindat Formula:
[Ag6]4+(Cu4Fe2+2)Sb4S12◻
Ag in the M2 site consists of a [Ag6]4+ cluster that presumably exhibits metal-metal bonding; the "missing" M2 charge is compensated by a vacancy in the S2 site; thus, there are only 12 S atoms per formula unit, not 13.
Ag in the M2 site consists of a [Ag6]4+ cluster that presumably exhibits metal-metal bonding; the "missing" M2 charge is compensated by a vacancy in the S2 site; thus, there are only 12 S atoms per formula unit, not 13.
Element Weights:
Crystallography of Kenoargentotetrahedrite-(Fe)
Crystal System:
Isometric
Class (H-M):
43m - Hextetrahedral
Space Group:
I43m
Cell Parameters:
a = 10.4930(4) Å
Unit Cell V:
1155.31 ų
Z:
2
Comment:
Space group by analogy with other members of Tetrahedrite group. Cell parameters from 'freibergite' of Welch et al 2018.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Kenoargentotetrahedrite-(Fe)
Co-Type Localities:
Place of Conservation of Type Material:
Senchenberg Museum collection, Frankfurt, Germany, 2289sa.
British Museum Natural History, London, UK, BM88668.
British Museum Natural History, London, UK, BM88668.
Reference:
Other Language Names for Kenoargentotetrahedrite-(Fe)
Relationship of Kenoargentotetrahedrite-(Fe) to other Species
Member of:
Other Members of Freibergite Subgroup:
| Argentotetrahedrite-(Cd) | Ag6(Cu4Cd2)Sb4S12S | Iso. 43m : I43m |
| Argentotetrahedrite-(Fe) | Ag6(Cu4Fe2)Sb4S12S | Iso. 43m : I43m |
| Argentotetrahedrite-(Hg) | Ag6(Cu4Hg2)Sb4S12S | Iso. 43m : I43m |
| Argentotetrahedrite-(Zn) | Ag6(Cu4Zn2)Sb4S12S | Iso. 43m : I43m |
| Kenoargentotetrahedrite-(Zn) | [Ag6]4+(Cu4Zn2)Sb4S12◻ | Iso. 43m : I43m |
Common Associates
Associations Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
| 2.GB. | 'Polybasite-Tac' | [Ag6Sb2S7][Ag9CuS4] |
| 2.GB. | Kenoargentotetrahedrite-(Zn) | [Ag6]4+(Cu4Zn2)Sb4S12◻ |
| 2.GB. | Argentotetrahedrite-(Hg) | Ag6(Cu4Hg2)Sb4S12S |
| 2.GB. | Annivite-(Zn) | Cu6(Cu4Zn2)Bi4S12S |
| 2.GB. | Pošepnýite | (Cu+3◻3)(Hg2+4Cu+2)Sb4Se12(Se0.5◻0.5) |
| 2.GB. | Tennantite-(Cu) | Cu6(Cu4Cu2)As4S12S |
| 2.GB. | Argentopolybasite | [Ag6Sb2S7][Ag9AgS4] |
| 2.GB. | Tennantite-(Mn) | Cu6(Cu4Mn2)As4S12S |
| 2.GB. | Argentotetrahedrite-(Cd) | Ag6(Cu4Cd2)Sb4S12S |
| 2.GB. | Stibioústalečite | (Cu4Cu2)(Cu4Cu+2)(Sb2Te2)Se12Se |
| 2.GB. | Stibiogoldfieldite | (Cu4Cu2)(Cu4Cu+2)(Sb2Te2)S12S |
| 2.GB. | Argentotetrahedrite-(Zn) | Ag6(Cu4Zn2)Sb4S12S |
| 2.GB. | Tetrahedrite-(Cd) | Cu6(Cu4Cd2)Sb4S12S |
| 2.GB. | Arsenogoldfieldite | (Cu4Cu2)(Cu4Cu+2)(As2Te2)S12S |
| 2.GB. | Arsenoústalečite | (Cu4Cu2)(Cu4Cu+2)(As2Te2)Se12Se |
| 2.GB. | Tennantite-(In) | Cu6(Cu5In)As4S13 |
| 2.GB. | Zvěstovite-(Fe) | Ag6(Ag4Fe2+2)As4S12S |
| 2.GB. | Hakite-(Fe) | Cu6(Cu4Fe2+2)Sb4Se12Se |
| 2.GB. | Tennantite-(Cd) | Cu6(Cu4Cd2)As4S12S |
| 2.GB.X | Kenorozhdestvenskayaite-(Fe) | [Ag6]4+(Ag4Fe2+2)Sb4S12◻ |
| 2.GB. | Tetrahedrite-(Cu) | Cu6(Cu4Cu2+2)Sb4S12S |
| 2.GB. | Hakite-(Zn) | Cu6(Cu4Zn2)Sb4Se12Se |
| 2.GB. | Zvěstovite-(Zn) | Ag6(Ag4Zn2)As4S12S |
| 2.GB. | Hakite-(Cd) | Cu6(Cu4Cd2)Sb4Se12Se |
| 2.GB. | Kenoargentotennantite-(Fe) | [Ag6]4+(Cu4Fe2)As4S12◻ |
| 2.GB. | Tennantite-(Hg) | Cu6(Cu4Hg2)As4S12S |
| 2.GB. | Tetrahedrite-(Mn) | Cu6(Cu4Mn2)Sb4S12S |
| 2.GB. | Tennantite-(Ni) | Cu6(Cu4Ni2)As4S12S |
| 2.GB. | Tetrahedrite-(Ni) | Cu6(Cu4Ni2)Sb4S12S |
| 2.GB.05 | Hakite-(Hg) | Cu6(Cu4Hg2)Sb4Se12Se |
| 2.GB.05 | Rozhdestvenskayaite-(Zn) | Ag6(Ag4Zn2)Sb4S12S |
| 2.GB.05 | Argentotennantite-(Zn) | Ag6(Cu4Zn2)As4S12S |
| 2.GB.05 | Argentotennantite-(Fe) | Ag6(Cu4Fe2)As4S12S |
| 2.GB.05 | Freibergite Subgroup | (Ag6,[Ag6]4+)(Cu4 C2+2)Sb4S12S0-1 |
| 2.GB.05 | Tennantite Subgroup | Cu6(Cu4C2+2)As4S12S |
| 2.GB.05 | Tennantite-(Zn) | Cu6(Cu4Zn2)As4S12S |
| 2.GB.05 | Tetrahedrite-(Zn) | Cu6(Cu4Zn2)Sb4S12S |
| 2.GB.05 | Tetrahedrite Subgroup | Cu6(Cu4C2+2)Sb4S12S |
| 2.GB.05 | Tennantite-(Fe) | Cu6(Cu4Fe2+2)As4S12S |
| 2.GB.05 | Tetrahedrite-(Fe) | Cu6(Cu4Fe2+2)Sb4S12S |
| 2.GB.05 | Tetrahedrite-(Hg) | Cu6(Cu4Hg2)Sb4S12S |
| 2.GB.05 | Giraudite-(Zn) | Cu6(Cu4Zn2)As4Se12Se |
| 2.GB.05 | Argentotetrahedrite-(Fe) | Ag6(Cu4Fe2)Sb4S12S |
| 2.GB.05 | Goldfieldite | (Cu4◻2)(Cu4Cu+2)Te4S12S |
| 2.GB.05 | 'UM1992-21-S:AgFeSb' | Ag6(Ag4Fe2+2)Sb4S12S |
| 2.GB.10 | Selenostephanite | Ag5SbSe4 |
| 2.GB.10 | Stephanite | Ag5SbS4 |
| 2.GB.15 | 'UM2003-14-S:AgBiFeTe' | Ag16FeBiTe3S8 |
| 2.GB.15 | 'UM1979-17-S:BiCuFe' | ~Cu18Fe4BiS16 |
| 2.GB.15 | Pearceite | [Ag6As2S7][Ag9CuS4] |
| 2.GB.15 | Argentopearceite | Ag16As2S11 |
| 2.GB.15 | Cupropolybasite | [Cu6Sb2S7][Ag9CuS4] |
| 2.GB.15 | Fengruiite | [Ag6Sb2S7][Ag9CuS2Te2] |
| 2.GB.15 | Auropearceite | [Ag9AuS4][Ag6As2S7] |
| 2.GB.15 | Selenopolybasite | [(Ag,Cu)6(Sb,As)2(S,Se)7][Ag9Cu(S,Se)2Se2] |
| 2.GB.15 | Polybasite | [Ag6Sb2S7][Ag9CuS4] |
| 2.GB.15 | Auropolybasite | [Ag9AuS4][Ag6Sb2S7] |
| 2.GB.15 | Cupropearceite | [Cu6As2S7][Ag9CuS4] |
| 2.GB.20 | Vorontsovite | (Hg5Cu)Σ6TlAs4S12 |
| 2.GB.20 | Ferrovorontsovite | (Fe5Cu)Σ6TlAs4S12 |
| 2.GB.20 | Galkhaite | (Hg5Cu)CsAs4S12 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Kenoargentotetrahedrite-(Fe)
mindat.org URL:
https://www.mindat.org/min-53610.html
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References for Kenoargentotetrahedrite-(Fe)
Reference List:
Welch, Mark D., Stanley, Chris J., Spratt, John, Mills, Stuart J. (2018) Rozhdestvenskayaite Ag10Zn2Sb4S13 and argentotetrahedrite Ag6Cu4(Fe2+,Zn)2Sb4S13: two Ag-dominant members of the tetrahedrite group. European Journal of Mineralogy, 30 (6) 1163-1172 doi:10.1127/ejm/2018/0030-2773
Localities for Kenoargentotetrahedrite-(Fe)
Showing 15 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Austria | |
| Auer et al. (2022) |
Bolivia | |
| Velebil et al. (2023) |
| Velebil et al. (2023) |
Canada | |
| rruff.info (n.d.) |
China | |
| Qu et al. (2024) |
| Shu et al. (2022) |
Czech Republic | |
| Sejkora et al. (2022) |
| Pažout (2025) |
| Pažout et al. (2026) | |
| Dolníček et al. (2023) |
| Pauliš et al. (2023) |
Germany (TL) | |
| Biagioni et al. (2020) |
| Biagioni et al. (2020) |
Slovakia | |
| Radvanec M. et al. (2022) |
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Khachakchan Ag-Sb-Hg deposit, Khachakchan ore cluster, Verkhoyansk Silver Province, Verkhoyansk Fold Belt, Sakha, Russia