Giraudite-(Zn)
A valid IMA mineral species
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About Giraudite-(Zn)
Formula:
Cu6(Cu4Zn2)As4Se12Se
Giraudite-(Zn) is re-named from "giraudite" according to the new tetrahedrite group nomenclature of Biagione et al., 2020. The IMA formula presented here has not yet been updated to reflect the observation of Zn>Fe2+ in the type material.
Lustre:
Metallic
Hardness:
3½ - 4
Specific Gravity:
5.75 (Calculated)
Crystal System:
Isometric
Member of:
Name:
Named giraudite (without the suffix) in honor of Roger Giraud (1936– ), electron microprobe laboratory, BRGM-CNRS, Orleans, France. The suffix was added by the IMA, according to the new tetrahedrite group nomenclature of Biagione et al. (2020).
This page provides mineralogical data about Giraudite-(Zn).
Unique Identifiers
Mindat ID:
1698
Long-form identifier:
mindat:1:1:1698:4
Similar Names
| Girdite | A discredited species name | H2Pb3(Te4+O3)(Te6+O6) |
IMA Classification of Giraudite-(Zn)
Approved
IMA Formula:
Cu1+6(Cu1+4Zn2+2)As3+4Se2-13
Approval year:
1980
First published:
1982
Type description reference:
Johan, Z.; Picot, P.; Ruhlmann, F. (1982) Evolution paragénétique de la minéralisation uranifère de Chaméane (Puy-de-Dôme), France: chaméanite, geffroyite et giraudite, trois séléniures nouveaux de Cu, Fe, Ag et As. TMPM Tschermaks Mineralogische und Petrographische Mitteilungen, 29 (3). 151-167 doi:10.1007/bf01084639
Classification of Giraudite-(Zn)
2.GB.05
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
B : Neso-sulfarsenites, etc. with additional S
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
B : Neso-sulfarsenites, etc. with additional S
3.3.6.5
3 : SULFOSALTS
3 : 3 <ø < 4
3 : SULFOSALTS
3 : 3 <ø < 4
5.1.11
5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
1 : Sulpharsenites etc. of Cu
5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
1 : Sulpharsenites etc. of Cu
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Gir-Zn | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Gir | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Giraudite-(Zn)
Metallic
Transparency:
Opaque
Hardness:
3½ - 4 on Mohs scale
Hardness:
VHN25=233 - 333 kg/mm2 - Vickers
Density:
5.75 g/cm3 (Calculated)
Chemistry of Giraudite-(Zn)
Mindat Formula:
Cu6(Cu4Zn2)As4Se12Se
Giraudite-(Zn) is re-named from "giraudite" according to the new tetrahedrite group nomenclature of Biagione et al., 2020. The IMA formula presented here has not yet been updated to reflect the observation of Zn>Fe2+ in the type material.
Giraudite-(Zn) is re-named from "giraudite" according to the new tetrahedrite group nomenclature of Biagione et al., 2020. The IMA formula presented here has not yet been updated to reflect the observation of Zn>Fe2+ in the type material.
Element Weights:
Elements listed:
Common Impurities:
Hg,Fe
Crystallography of Giraudite-(Zn)
Crystal System:
Isometric
Class (H-M):
43m - Hextetrahedral
Space Group:
I43m
Cell Parameters:
a = 10.578 Å
Unit Cell V:
1,183.62 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Anhedral grains to 400 microns, myrmekitic intergrowths with chameanite.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Giraudite-(Zn)
Place of Conservation of Type Material:
National School of Mines, Paris, France
Geological Setting of Type Material:
Late stage veins cutting granite.
Reference:
Johan, Z.; Picot, P.; Ruhlmann, F. (1982) Evolution paragénétique de la minéralisation uranifère de Chaméane (Puy-de-Dôme), France: chaméanite, geffroyite et giraudite, trois séléniures nouveaux de Cu, Fe, Ag et As. TMPM Tschermaks Mineralogische und Petrographische Mitteilungen, 29 (3). 151-167 doi:10.1007/bf01084639
Synonyms of Giraudite-(Zn)
Other Language Names for Giraudite-(Zn)
Relationship of Giraudite-(Zn) to other Species
Member of:
Common Associates
Associations Based on Photo Data:
| 1 photo of Giraudite-(Zn) associated with Eskebornite | CuFeSe2 |
| 1 photo of Giraudite-(Zn) associated with 'Pitchblende' | UO2 |
Related Minerals - Strunz-mindat Grouping
| 2.GB. | 'Polybasite-Tac' | [Ag6Sb2S7][Ag9CuS4] |
| 2.GB. | Kenoargentotetrahedrite-(Zn) | [Ag6]4+(Cu4Zn2)Sb4S12◻ |
| 2.GB. | Argentotetrahedrite-(Hg) | Ag6(Cu4Hg2)Sb4S12S |
| 2.GB. | Annivite-(Zn) | Cu6(Cu4Zn2)Bi4S12S |
| 2.GB. | Pošepnýite | (Cu+3◻3)(Hg2+4Cu+2)Sb4Se12(Se0.5◻0.5) |
| 2.GB. | Tennantite-(Cu) | Cu6(Cu4Cu2)As4S12S |
| 2.GB. | Argentopolybasite | [Ag6Sb2S7][Ag9AgS4] |
| 2.GB. | Tennantite-(Mn) | Cu6(Cu4Mn2)As4S12S |
| 2.GB. | Argentotetrahedrite-(Cd) | Ag6(Cu4Cd2)Sb4S12S |
| 2.GB. | Stibioústalečite | (Cu4Cu2)(Cu4Cu+2)(Sb2Te2)Se12Se |
| 2.GB. | Stibiogoldfieldite | (Cu4Cu2)(Cu4Cu+2)(Sb2Te2)S12S |
| 2.GB. | Argentotetrahedrite-(Zn) | Ag6(Cu4Zn2)Sb4S12S |
| 2.GB. | Tetrahedrite-(Cd) | Cu6(Cu4Cd2)Sb4S12S |
| 2.GB. | Arsenogoldfieldite | (Cu4Cu2)(Cu4Cu+2)(As2Te2)S12S |
| 2.GB. | Arsenoústalečite | (Cu4Cu2)(Cu4Cu+2)(As2Te2)Se12Se |
| 2.GB. | Tennantite-(In) | Cu6(Cu5In)As4S13 |
| 2.GB. | Zvěstovite-(Fe) | Ag6(Ag4Fe2+2)As4S12S |
| 2.GB. | Hakite-(Fe) | Cu6(Cu4Fe2+2)Sb4Se12Se |
| 2.GB. | Tennantite-(Cd) | Cu6(Cu4Cd2)As4S12S |
| 2.GB.X | Kenorozhdestvenskayaite-(Fe) | [Ag6]4+(Ag4Fe2+2)Sb4S12◻ |
| 2.GB. | Tetrahedrite-(Cu) | Cu6(Cu4Cu2+2)Sb4S12S |
| 2.GB. | Hakite-(Zn) | Cu6(Cu4Zn2)Sb4Se12Se |
| 2.GB. | Zvěstovite-(Zn) | Ag6(Ag4Zn2)As4S12S |
| 2.GB. | Hakite-(Cd) | Cu6(Cu4Cd2)Sb4Se12Se |
| 2.GB. | Kenoargentotennantite-(Fe) | [Ag6]4+(Cu4Fe2)As4S12◻ |
| 2.GB. | Tennantite-(Hg) | Cu6(Cu4Hg2)As4S12S |
| 2.GB. | Tetrahedrite-(Mn) | Cu6(Cu4Mn2)Sb4S12S |
| 2.GB. | Tennantite-(Ni) | Cu6(Cu4Ni2)As4S12S |
| 2.GB. | Tetrahedrite-(Ni) | Cu6(Cu4Ni2)Sb4S12S |
| 2.GB.05 | Hakite-(Hg) | Cu6(Cu4Hg2)Sb4Se12Se |
| 2.GB.05 | Rozhdestvenskayaite-(Zn) | Ag6(Ag4Zn2)Sb4S12S |
| 2.GB.05 | Argentotennantite-(Zn) | Ag6(Cu4Zn2)As4S12S |
| 2.GB.05 | Argentotennantite-(Fe) | Ag6(Cu4Fe2)As4S12S |
| 2.GB.05 | Freibergite Subgroup | (Ag6,[Ag6]4+)(Cu4 C2+2)Sb4S12S0-1 |
| 2.GB.05 | Tennantite Subgroup | Cu6(Cu4C2+2)As4S12S |
| 2.GB.05 | Tennantite-(Zn) | Cu6(Cu4Zn2)As4S12S |
| 2.GB.05 | Tetrahedrite-(Zn) | Cu6(Cu4Zn2)Sb4S12S |
| 2.GB.05 | Tetrahedrite Subgroup | Cu6(Cu4C2+2)Sb4S12S |
| 2.GB.05 | Tennantite-(Fe) | Cu6(Cu4Fe2+2)As4S12S |
| 2.GB.05 | Tetrahedrite-(Fe) | Cu6(Cu4Fe2+2)Sb4S12S |
| 2.GB.05 | Tetrahedrite-(Hg) | Cu6(Cu4Hg2)Sb4S12S |
| 2.GB.05 | Kenoargentotetrahedrite-(Fe) | [Ag6]4+(Cu4Fe2+2)Sb4S12◻ |
| 2.GB.05 | Argentotetrahedrite-(Fe) | Ag6(Cu4Fe2)Sb4S12S |
| 2.GB.05 | Goldfieldite | (Cu4◻2)(Cu4Cu+2)Te4S12S |
| 2.GB.05 | 'UM1992-21-S:AgFeSb' | Ag6(Ag4Fe2+2)Sb4S12S |
| 2.GB.10 | Selenostephanite | Ag5SbSe4 |
| 2.GB.10 | Stephanite | Ag5SbS4 |
| 2.GB.15 | 'UM2003-14-S:AgBiFeTe' | Ag16FeBiTe3S8 |
| 2.GB.15 | 'UM1979-17-S:BiCuFe' | ~Cu18Fe4BiS16 |
| 2.GB.15 | Pearceite | [Ag6As2S7][Ag9CuS4] |
| 2.GB.15 | Argentopearceite | Ag16As2S11 |
| 2.GB.15 | Cupropolybasite | [Cu6Sb2S7][Ag9CuS4] |
| 2.GB.15 | Fengruiite | [Ag6Sb2S7][Ag9CuS2Te2] |
| 2.GB.15 | Auropearceite | [Ag9AuS4][Ag6As2S7] |
| 2.GB.15 | Selenopolybasite | [(Ag,Cu)6(Sb,As)2(S,Se)7][Ag9Cu(S,Se)2Se2] |
| 2.GB.15 | Polybasite | [Ag6Sb2S7][Ag9CuS4] |
| 2.GB.15 | Auropolybasite | [Ag9AuS4][Ag6Sb2S7] |
| 2.GB.15 | Cupropearceite | [Cu6As2S7][Ag9CuS4] |
| 2.GB.20 | Vorontsovite | (Hg5Cu)Σ6TlAs4S12 |
| 2.GB.20 | Ferrovorontsovite | (Fe5Cu)Σ6TlAs4S12 |
| 2.GB.20 | Galkhaite | (Hg5Cu)CsAs4S12 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Giraudite-(Zn)
mindat.org URL:
https://www.mindat.org/min-1698.html
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References for Giraudite-(Zn)
Reference List:
Johan, Z.; Picot, P.; Ruhlmann, F. (1982) Evolution paragénétique de la minéralisation uranifère de Chaméane (Puy-de-Dôme), France: chaméanite, geffroyite et giraudite, trois séléniures nouveaux de Cu, Fe, Ag et As. TMPM Tschermaks Mineralogische und Petrographische Mitteilungen, 29 (3). 151-167 doi:10.1007/bf01084639
Johan, Z.; Picot, P.; Ruhlmann, F. (1982) Evolution paragénétique de la minéralisation uranifère de Chaméane (Puy-de-Dôme), France: chaméanite, geffroyite et giraudite, trois séléniures nouveaux de Cu, Fe, Ag et As. TMPM Tschermaks Mineralogische und Petrographische Mitteilungen, 29 (3). 151-167 doi:10.1007/bf01084639
Localities for Giraudite-(Zn)
Showing 10 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Czech Republic | |
| Škácha et al. (2017) |
| Škácha et al. (2017) |
| Sejkora et al. (2022) |
| Bindi et al. (2016) |
France (TL) | |
| Johan et al. (1982) +1 other reference |
Germany | |
| Can Min 40 et al. (2002) +1 other reference |
| Forster et al. (2004) |
Mexico | |
| Camprubi |
| Braith et al. (2001) |
USA | |
| Castor et al. (2004) |
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The
Chaméane Uranium Deposit, Le Vernet-Chaméane, Issoire, Puy-de-Dôme, Auvergne-Rhône-Alpes, France