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D'Ansite-(Fe)

A valid IMA mineral species
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About D'Ansite-(Fe)Hide

Formula:
Na21Fe2+(SO4)10Cl3
Colour:
Colourless, white
Lustre:
Vitreous
Specific Gravity:
2.62
Crystal System:
Isometric
Member of:
Name:
For the mineral d'ansite and the iron content
Isostructural with:
Fe2+-dominant analogue of d’ansite and d'ansite-(Mn).

Compare the chemically similar 'Unnamed (Sodium Potassium Iron Sulfate Chloride)'.


Unique IdentifiersHide

Mindat ID:
42848
Long-form identifier:
mindat:1:1:42848:8

Similar NamesHide

D'AnsiteA valid IMA mineral species - grandfatheredNa21Mg(SO4)10Cl3
D'Ansite-(Mn)A valid IMA mineral speciesNa21Mn2+(SO4)10Cl3
DanaiteA variety of Arsenopyrite(Fe0.90Co0.10)AsS - (Fe0.65Co0.35)AsS
DownsiteA valid IMA mineral species - pending publicationK2(MoO3)3(SO4) · 4H2O
Kansite (of Meyer et al.)A synonym of Mackinawite
TunisiteA valid IMA mineral speciesNaCa2Al4(CO3)4(OH)8Cl

IMA Classification of D'Ansite-(Fe)Hide

Approved
IMA Formula:
Na21Fe2+(S6+O4)10Cl3
Approval year:
2011

Classification of D'Ansite-(Fe)Hide

7.BC.

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
D'an-FeIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of D'Ansite-(Fe)Hide

Vitreous
Colour:
Colourless, white
Streak:
White
Tenacity:
Brittle
Cleavage:
None Observed
Density:
2.62(1) g/cm3 (Measured)    2.644 g/cm3 (Calculated)

Optical Data of D'Ansite-(Fe)Hide

Type:
Isotropic
RI values:
n = 1.51(1)
Birefringence:
Isotropic minerals have no birefringence
Surface Relief:
Low

Chemistry of D'Ansite-(Fe)Hide

Mindat Formula:
Na21Fe2+(SO4)10Cl3
Element Weights:
Element% weight
O39.859 %
Na30.069 %
S19.971 %
Cl6.624 %
Fe3.478 %

Calculated from ideal end-member formula.

Crystallography of D'Ansite-(Fe)Hide

Crystal System:
Isometric
Class (H-M):
43m - Hextetrahedral
Space Group:
I43d
Cell Parameters:
a = 15.882(3) Å
Unit Cell V:
4,006.04 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Aggregates of complex isometric crystals up to 0.2 mm.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.384 Å(27)
3.113 Å(26)
2.900 Å(14)
2.807 Å(100)
2.570 Å(37)
2.161 Å(15)
2.018 Å(15)
1.714 Å(29)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
25 : Evaporites (prebiotic)
Stage 10b: Anthropogenic minerals<10 Ka
55 : Anthropogenic mine minerals

Type Occurrence of D'Ansite-(Fe)Hide

General Appearance of Type Material:
forms aggregates of colourless to white complex isometric crystals to 0.2mm
Place of Conservation of Type Material:
Holotype material is deposited in the Reference Collection of the DCSSI, University of Milan,sample number 2011-02
Geological Setting of Type Material:
In fumaroles on pyroclastic flows.
Associated Minerals at Type Locality:

Synonyms of D'Ansite-(Fe)Hide

Other Language Names for D'Ansite-(Fe)Hide

Relationship of D'Ansite-(Fe) to other SpeciesHide

Member of:
Other Members of D'Ansite Group:
D'AnsiteNa21Mg(SO4)10Cl3Iso. 43m : I43m
D'Ansite-(Mn)Na21Mn2+(SO4)10Cl3Iso. 43m : I43d

Common AssociatesHide

Associations Based on Photo Data:
3 photos of D'Ansite-(Fe) associated with Adranosite(NH4)4NaAl2(SO4)4Cl(OH)2
1 photo of D'Ansite-(Fe) associated with Adranosite-(Fe)(NH4)4NaFe3+2(SO4)4Cl(OH)2

Related Minerals - Strunz-mindat GroupingHide

7.BC.ViskontitePb5Cu2(SO4)3(SeO3)(OH)6Orth. mm2 : Pmn21
7.BC.ZincochenitePb4Zn(OH)6(SO4)2Tric. 1 : P1
7.BC.D'Ansite-(Mn)Na21Mn2+(SO4)10Cl3Iso. 43m : I43d
7.BC.Acmonidesite(NH4,K,Pb)8NaFe2+4(SO4)5Cl8Orth. 222 : C2221
7.BC.Adranosite(NH4)4NaAl2(SO4)4Cl(OH)2Tet. 4/mmm(4/m2/m2/m) : I41/acd
7.BC.ChromviskontitePb5Cu2(CrO4)3(SeO3)(OH)6Orth. mm2 : Pmn21
7.BC.BackitePb2AlTeO6ClTrig. 32 : P312
7.BC.Adranosite-(Fe)(NH4)4NaFe3+2(SO4)4Cl(OH)2Tet. 4/mmm(4/m2/m2/m) : I41/acd
7.BC.AgaitePb3CuTeO5(OH)2(CO3) Orth. mm2 : Pca21
7.BC.WildcatiteCaFe3+Te6+O5(OH)Trig. 3m(32/m) : P31m
7.BC.HagstromitePb8Cu2+(Te6+O6)2(CO3)Cl4Orth. mmm(2/m2/m2/m) : Ibam
7.BC.05D'AnsiteNa21Mg(SO4)10Cl3Iso. 43m : I43m
7.BC.07'Apatelite'Fe3(SO4)2(OH)5 · 0.5H2O
7.BC.07'Unnamed (Ba-Fe Vanadate)'Ba, Fe, V, O, H
7.BC.10JarositeKFe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10DorallchariteTlFe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10ArgentojarositeAgFe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10NatroaluniteNaAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10NatrojarositeNaFe3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Beaverite-(Cu)Pb(Fe3+2Cu)(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Beaverite-(Zn)Pb(Fe3+2Zn)(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10WalthieriteBa0.5Al3(SO4)2(OH)6Trig.
7.BC.10HuangiteCa0.5Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10'Natroalunite-2c'(Na,Ca0.5,K)Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10AluniteKAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10PlumbojarositePb0.5Fe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Karlseifertite Pb(Ga2Ge)(AsO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Hydroniumjarosite(H3O)Fe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Ammonioalunite(NH4)Al3(SO4)2(OH)6Trig.
7.BC.10Ammoniojarosite(NH4)Fe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Schlossmacherite(H3O)Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.15Ye'elimiteCa4Al6(SO4)O12Iso. 432 : I4132
7.BC.20NabokoiteKCu7(SO4)5(Te4+O3)OClTet. 4/mmm(4/m2/m2/m) : P4/ncc
7.BC.20PuniniteNa2Cu3O(SO4)3Mon. 2/m : B2/b
7.BC.20AtlasoviteK(BiO)Cu6Fe3+(SO4)5O3ClTet. 4/mmm(4/m2/m2/m) : P4/ncc
7.BC.25ChlorothioniteK2Cu(SO4)Cl2Orth. mmm(2/m2/m2/m) : Pnma
7.BC.30EuchlorineKNaCu3(SO4)3OMon. 2/m
7.BC.30FedotoviteK2Cu3(SO4)3OMon. 2/m : B2/b
7.BC.35KamchatkiteKCu3(SO4)2OClOrth. mmm(2/m2/m2/m) : Pnma
7.BC.40PiypiteK4Cu4O2(SO4)4 · (Na,Cu)ClTet. 4 : I4
7.BC.45AlumoklyuchevskiteK3Cu3(Al,Fe3+)(SO4)4O2Tric. 1 : P1
7.BC.45BelousoviteKZn(SO4)ClMon. 2/m : P21/b
7.BC.45KlyuchevskiteK3Cu3(Fe3+,Al)(SO4)4O2Mon. 2
7.BC.47MülleritePb2Fe3+(Te6+O6)ClTrig. 32 : P3112
7.BC.50CaledonitePb5Cu2(SO4)3(CO3)(OH)6Orth. mm2 : Pmn21
7.BC.50ElasmochloiteNa3Cu6BiO4(SO4)5Mon. 2/m
7.BC.52Eleomelanite(K2Pb)Cu4O2(SO4)4Mon. 2/m
7.BC.55FalgariteK4(VO)3(SO4)5Mon. 2/m : B2/b
7.BC.55WherryitePb7Cu2(SO4)4(SiO4)2(OH)2Mon. 2/m : B2/m
7.BC.57KrasheninnikoviteKNa2CaMg(SO4)3FHex. 6/mmm(6/m2/m2/m) : P63/mcm
7.BC.60WulffiteK3NaCu4O2(SO4)4Orth. mm2
7.BC.60ParawulffiteK5Na3Cu8O4(SO4)8Mon. 2/m : P2/b
7.BC.60MammothitePb6Cu4AlSb5+O2(OH)16Cl4(SO4)2Mon. 2 : B2
7.BC.62ShuvaloviteK2(Ca2Na)(SO4)3FOrth. mmm(2/m2/m2/m) : Pnma
7.BC.65SaccoiteCa2Mn3+2F(OH)8 · 0.5(SO4)Tet. 4/mmm(4/m2/m2/m) : P4/ncc
7.BC.65LinaritePbCu(SO4)(OH)2Mon. 2/m : P21/m
7.BC.65Therasiaite(NH4)3KNa2Fe2+Fe3+(SO4)3Cl5Mon. m : Bb
7.BC.65FranksousaitePbCu(Se6+O4)(OH)2Mon. 2/m : P21/m
7.BC.65MunakataitePb2Cu2(Se4+O3)(SO4)(OH)4Mon. 2/m : P21/m
7.BC.65SchmiederitePb2Cu2(Se6+O4)(Se4+O3)(OH)4Mon. 2/m : P21/m
7.BC.70ChenitePb4Cu(SO4)2(OH)6Tric. 1 : P1
7.BC.75KrivovichevitePb3Al(OH)6(SO4)(OH)Trig. 3m : R3c
7.BC.80AnhydrokainiteKMg(SO4)Cl

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for D'Ansite-(Fe)Hide

References for D'Ansite-(Fe)Hide

Localities for D'Ansite-(Fe)Hide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy (TL)
 
  • Sicily
    • Metropolitan City of Messina
      • Eolie Islands (Aeolian Islands)
        • Lipari
          • Vulcano Island
Williams et al. (2011) +1 other reference
Slovenia
 
  • Mežica
Demartin et al. (2012)
 
and/or  
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