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Dorallcharite

A valid IMA mineral species
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About DorallchariteHide

Formula:
TlFe3+3(SO4)2(OH)6
Colour:
Golden yellow
Lustre:
Earthy
Hardness:
3 - 4
Specific Gravity:
3.85 (Calculated)
Crystal System:
Trigonal
Name:
Named by T. Balic-Žunic, Y. Moëlo, Z. Loncar, H. Micheelsen in 1994. The name is a concatenation of the French word doré, for the mineral's golden yellow color, and Allchar, the type locality in Macedonia. The discoverers wanted to honor the very important locality but 'allcharite' had already been used on a later discredited mineral.
This page provides mineralogical data about Dorallcharite.


Unique IdentifiersHide

Mindat ID:
1311
Long-form identifier:
mindat:1:1:1311:2

IMA Classification of DorallchariteHide

Approved
IMA Formula:
Tl1+Fe3+3(S6+O4)2(OH)6
Approval year:
1992
First published:
1994

Classification of DorallchariteHide

7.BC.10

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations
30.2.5.8

30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
2 : (AB)2(XO4)Zq

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
DrcIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of DorallchariteHide

Earthy
Colour:
Golden yellow
Streak:
Yellow
Hardness:
3 - 4 on Mohs scale
Density:
3.85 g/cm3 (Calculated)

Optical Data of DorallchariteHide

Type:
Uniaxial (-)
RI values:
nω = 1.822 nε = 1.768
Max. Birefringence:
δ = 0.054
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of DorallchariteHide

Mindat Formula:
TlFe3+3(SO4)2(OH)6
Element Weights:
Element% weight
O33.628 %
Tl30.684 %
Fe25.152 %
S9.628 %
H0.908 %

Calculated from ideal end-member formula.
O
Tl
Fe
S
H
Common Impurities:
H2O

Crystallography of DorallchariteHide

Crystal System:
Trigonal
Class (H-M):
3m(32/m) - Hexagonal Scalenohedral
Space Group:
R3m
Cell Parameters:
a = 7.33 Å, c = 17.66 Å
Ratio:
a:c = 1 : 2.409
Unit Cell V:
821.73 ų (Calculated from Unit Cell)
Z:
3

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0006535DorallchariteBalic-Zunic T, Moelo Y, Loncar Z, Micheelsen H (1994) Dorallcharite, Tl0.8K0.2Fe3(SO4)2(OH)6, a new member of the jarosite-alunite family European Journal of Mineralogy 6 255-26319940293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.112 Å(100)
5.974 Å(87)
3.666 Å(34)
1.991 Å(29)
1.833 Å(23)
2.988 Å(22)
2.577 Å(21)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47b : [Sulfates and sulfites]

Type Occurrence of DorallchariteHide

General Appearance of Type Material:
Fine grained and forms earthy masses.
Place of Conservation of Type Material:
Geological Museum of Copenhagen, Denmark, 1993.7.
Geological Setting of Type Material:
Epithermal As-Sb-(Au-Tl) deposit.

Synonyms of DorallchariteHide

Other Language Names for DorallchariteHide

Simplified Chinese:铁钾铊矾

Relationship of Dorallcharite to other SpeciesHide

Other Members of Alunite Group:
AluniteKAl3(SO4)2(OH)6Trig. 3m : R3m
Ammonioalunite(NH4)Al3(SO4)2(OH)6Trig.
Ammoniojarosite(NH4)Fe3+3(SO4)2(OH)6Trig. 3m : R3m
ArgentojarositeAgFe3+3(SO4)2(OH)6Trig. 3m : R3m
Beaverite-(Cu)Pb(Fe3+2Cu)(SO4)2(OH)6Trig. 3m(32/m) : R3m
Beaverite-(Zn)Pb(Fe3+2Zn)(SO4)2(OH)6Trig. 3m(32/m) : R3m
HuangiteCa0.5Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
Hydroniumjarosite(H3O)Fe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
JarositeKFe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
NatroaluniteNaAl3(SO4)2(OH)6Trig. 3m : R3m
'Natroalunite-2c'(Na,Ca0.5,K)Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
NatrojarositeNaFe3(SO4)2(OH)6Trig. 3m : R3m
OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6Trig. 3m(32/m) : R3m
PlumbojarositePb0.5Fe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
Schlossmacherite(H3O)Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
WalthieriteBa0.5Al3(SO4)2(OH)6Trig.

Common AssociatesHide

Associations Based on Photo Data:
5 photos of Dorallcharite associated with RealgarAs4S4
2 photos of Dorallcharite associated with LoránditeTlAsS2
1 photo of Dorallcharite associated with GypsumCaSO4 · 2H2O

Related Minerals - Strunz-mindat GroupingHide

7.BC.ViskontitePb5Cu2(SO4)3(SeO3)(OH)6Orth. mm2 : Pmn21
7.BC.ZincochenitePb4Zn(OH)6(SO4)2Tric. 1 : P1
7.BC.D'Ansite-(Mn)Na21Mn2+(SO4)10Cl3Iso. 43m : I43d
7.BC.D'Ansite-(Fe)Na21Fe2+(SO4)10Cl3Iso. 43m : I43d
7.BC.Acmonidesite(NH4,K,Pb)8NaFe2+4(SO4)5Cl8Orth. 222 : C2221
7.BC.Adranosite(NH4)4NaAl2(SO4)4Cl(OH)2Tet. 4/mmm(4/m2/m2/m) : I41/acd
7.BC.ChromviskontitePb5Cu2(CrO4)3(SeO3)(OH)6Orth. mm2 : Pmn21
7.BC.BackitePb2AlTeO6ClTrig. 32 : P312
7.BC.Adranosite-(Fe)(NH4)4NaFe3+2(SO4)4Cl(OH)2Tet. 4/mmm(4/m2/m2/m) : I41/acd
7.BC.AgaitePb3CuTeO5(OH)2(CO3) Orth. mm2 : Pca21
7.BC.WildcatiteCaFe3+Te6+O5(OH)Trig. 3m(32/m) : P31m
7.BC.HagstromitePb8Cu2+(Te6+O6)2(CO3)Cl4Orth. mmm(2/m2/m2/m) : Ibam
7.BC.05D'AnsiteNa21Mg(SO4)10Cl3Iso. 43m : I43m
7.BC.07'Apatelite'Fe3(SO4)2(OH)5 · 0.5H2O
7.BC.07'Unnamed (Ba-Fe Vanadate)'Ba, Fe, V, O, H
7.BC.10JarositeKFe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10ArgentojarositeAgFe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10NatroaluniteNaAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10NatrojarositeNaFe3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Beaverite-(Cu)Pb(Fe3+2Cu)(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Beaverite-(Zn)Pb(Fe3+2Zn)(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10WalthieriteBa0.5Al3(SO4)2(OH)6Trig.
7.BC.10HuangiteCa0.5Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10'Natroalunite-2c'(Na,Ca0.5,K)Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10AluniteKAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10PlumbojarositePb0.5Fe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Karlseifertite Pb(Ga2Ge)(AsO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Hydroniumjarosite(H3O)Fe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Ammonioalunite(NH4)Al3(SO4)2(OH)6Trig.
7.BC.10Ammoniojarosite(NH4)Fe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Schlossmacherite(H3O)Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.15Ye'elimiteCa4Al6(SO4)O12Iso. 432 : I4132
7.BC.20NabokoiteKCu7(SO4)5(Te4+O3)OClTet. 4/mmm(4/m2/m2/m) : P4/ncc
7.BC.20PuniniteNa2Cu3O(SO4)3Mon. 2/m : B2/b
7.BC.20AtlasoviteK(BiO)Cu6Fe3+(SO4)5O3ClTet. 4/mmm(4/m2/m2/m) : P4/ncc
7.BC.25ChlorothioniteK2Cu(SO4)Cl2Orth. mmm(2/m2/m2/m) : Pnma
7.BC.30EuchlorineKNaCu3(SO4)3OMon. 2/m
7.BC.30FedotoviteK2Cu3(SO4)3OMon. 2/m : B2/b
7.BC.35KamchatkiteKCu3(SO4)2OClOrth. mmm(2/m2/m2/m) : Pnma
7.BC.40PiypiteK4Cu4O2(SO4)4 · (Na,Cu)ClTet. 4 : I4
7.BC.45AlumoklyuchevskiteK3Cu3(Al,Fe3+)(SO4)4O2Tric. 1 : P1
7.BC.45BelousoviteKZn(SO4)ClMon. 2/m : P21/b
7.BC.45KlyuchevskiteK3Cu3(Fe3+,Al)(SO4)4O2Mon. 2
7.BC.47MülleritePb2Fe3+(Te6+O6)ClTrig. 32 : P3112
7.BC.50CaledonitePb5Cu2(SO4)3(CO3)(OH)6Orth. mm2 : Pmn21
7.BC.50ElasmochloiteNa3Cu6BiO4(SO4)5Mon. 2/m
7.BC.52Eleomelanite(K2Pb)Cu4O2(SO4)4Mon. 2/m
7.BC.55FalgariteK4(VO)3(SO4)5Mon. 2/m : B2/b
7.BC.55WherryitePb7Cu2(SO4)4(SiO4)2(OH)2Mon. 2/m : B2/m
7.BC.57KrasheninnikoviteKNa2CaMg(SO4)3FHex. 6/mmm(6/m2/m2/m) : P63/mcm
7.BC.60WulffiteK3NaCu4O2(SO4)4Orth. mm2
7.BC.60ParawulffiteK5Na3Cu8O4(SO4)8Mon. 2/m : P2/b
7.BC.60MammothitePb6Cu4AlSb5+O2(OH)16Cl4(SO4)2Mon. 2 : B2
7.BC.62ShuvaloviteK2(Ca2Na)(SO4)3FOrth. mmm(2/m2/m2/m) : Pnma
7.BC.65SaccoiteCa2Mn3+2F(OH)8 · 0.5(SO4)Tet. 4/mmm(4/m2/m2/m) : P4/ncc
7.BC.65LinaritePbCu(SO4)(OH)2Mon. 2/m : P21/m
7.BC.65Therasiaite(NH4)3KNa2Fe2+Fe3+(SO4)3Cl5Mon. m : Bb
7.BC.65FranksousaitePbCu(Se6+O4)(OH)2Mon. 2/m : P21/m
7.BC.65MunakataitePb2Cu2(Se4+O3)(SO4)(OH)4Mon. 2/m : P21/m
7.BC.65SchmiederitePb2Cu2(Se6+O4)(Se4+O3)(OH)4Mon. 2/m : P21/m
7.BC.70ChenitePb4Cu(SO4)2(OH)6Tric. 1 : P1
7.BC.75KrivovichevitePb3Al(OH)6(SO4)(OH)Trig. 3m : R3c
7.BC.80AnhydrokainiteKMg(SO4)Cl

Other InformationHide

Health Risks:
very toxic

Internet Links for DorallchariteHide

References for DorallchariteHide

Localities for DorallchariteHide

Showing 5 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
France
 
  • Provence-Alpes-Côte d'Azur
    • Hautes-Alpes
      • Gap
        • La Chapelle-en-Valgaudemar
Bourgoin et al. (2011)
North Macedonia (TL)
 
  • Kavadarci Municipality
    • Ržanovo
Balić Žunić et al. (1994) +2 other references
Alois Lechner collection +4 other references
Ðorđević et al. (2020)
Switzerland
 
  • Basel-Landschaft
    • Sissach
      • Buus
Majzlan et al. (2016) +1 other reference
 
and/or  
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