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Tisinalite

A valid IMA mineral species
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About TisinaliteHide

Formula:
Na3H3(Mn,Ca,Fe)TiSi6(O,OH)18 · 2H2O
Colour:
Yellow-orange
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
2.66 - 2.69
Crystal System:
Trigonal
Name:
The name reflects its titanium (Ti), silicon (Si) and sodium (Na) content.
Lovozerite Group. A possible Fe analogue is known as 'UM1980-19-SiO:FeHNaTi'.


Unique IdentifiersHide

Mindat ID:
3976
Long-form identifier:
mindat:1:1:3976:1

IMA Classification of TisinaliteHide

Classification of TisinaliteHide

9.CJ.15a

9 : SILICATES (Germanates)
C : Cyclosilicates
J : [Si6O18]12- 6-membered single rings (sechser-Einfachringe), without insular complex anions
61.1.2a.3

61 : CYCLOSILICATES Six-Membered Rings
1 : Six-Membered Rings with [Si6O18] rings; possible (OH) and Al substitution
14.9.25

14 : Silicates not Containing Aluminum
9 : Silicates of Ti

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
TisIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TisinaliteHide

Vitreous
Transparency:
Transparent, Translucent
Colour:
Yellow-orange
Hardness:
Hardness:
VHN100=520 - 560 - Vickers
Fracture:
Irregular/Uneven, Conchoidal
Density:
2.66 - 2.69 g/cm3 (Measured)    2.682 g/cm3 (Calculated)

Optical Data of TisinaliteHide

Type:
Uniaxial (-)
RI values:
nω = 1.624 nε = 1.590 - 1.592
Max. Birefringence:
δ = 0.032 - 0.034
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.

Surface Relief:
Moderate

Chemistry of TisinaliteHide

Mindat Formula:
Na3H3(Mn,Ca,Fe)TiSi6(O,OH)18 · 2H2O
Element Weights:
Element% weight
O47.950 %
Si25.252 %
Na10.335 %
Mn8.233 %
Ti7.173 %
H1.057 %

Calculated from ideal end-member formula.
Common Impurities:
K

Crystallography of TisinaliteHide

Crystal System:
Trigonal
Class (H-M):
3m (3 2/m) - Hexagonal Scalenohedral
Cell Parameters:
a = 10.14 Å, c = 13.08 Å
Ratio:
a:c = 1 : 1.29
Unit Cell V:
1,164.70 ų (Calculated from Unit Cell)
Z:
3
Comment:
Space Group: n.d.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012385TisinaliteYamnova N A, Egorov-Tismenko Y K, Pekov I V, Shchegol'kova L V (2003) Crystal structure of tisinalite Na2(Mn,Ca)1-x(Ti,Zr,Nb,Fe3+)[Si6O8(O,OH)10] Crystallography Reports 48 551-5562003Khibiny massif, Kola Peninsula, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.19 Å(70)
3.60 Å(100)
3.26 Å(60)
3.18 Å(80)
2.590 Å(60)
2.510 Å(50)
1.802 Å(55)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of TisinaliteHide

General Appearance of Type Material:
Rough crystals up to 1 x 0.5 x 0.5 mm and granular aggregates up to 1 cm wide.
Place of Conservation of Type Material:
A. E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia.
Geological Setting of Type Material:
In alkalic pegmatites. Formed by the hydrothermal alteration of lomonosovite and barium-lamprophyllite.
Associated Minerals at Type Locality:

Synonyms of TisinaliteHide

Other Language Names for TisinaliteHide

Relationship of Tisinalite to other SpeciesHide

Other Members of Zirsinalite-Lovozerite Subgroup:
CombeiteNa4.5Ca3.5Si6O17.5(OH)0.5Trig. 3m (3 2/m) : R3m
KapustiniteNa6ZrSi6O16(OH)2Mon. 2/m : B2/m
KazakoviteNa6Mn2+Ti(Si6O18)Trig. 3m (3 2/m) : R3m
LitvinskiteNa2(◻,Na,Mn)ZrSi6O12(OH,O)6Mon. m : Bm
LovozeriteNa2Ca(Zr,Ti)(Si6O12)[(OH)4O2] · H2OTrig. 3 : R3
TownenditeNa8ZrSi6O18Trig. 3m (3 2/m) : R3m
ZirsinaliteNa6(Ca,Mn2+,Fe2+)Zr(Si6O18)Trig. 3m (3 2/m) : R3m

Common AssociatesHide

Associated Minerals Based on Photo Data:
7 photos of Tisinalite associated with AegirineNaFe3+Si2O6
1 photo of Tisinalite associated with NatroliteNa2Al2Si3O10 · 2H2O
1 photo of Tisinalite associated with ErshoviteNa4K3(Fe,Mn,Ti)2Si8O22(OH)4 · 4H2O
1 photo of Tisinalite associated with NephelineNa3K(Al4Si4O16)
1 photo of Tisinalite associated with FluorapatiteCa5(PO4)3F

Related Minerals - Strunz-mindat GroupingHide

9.CJ.ZolotareviteNa5Zr[Si6O15(OH)3] · 3H2OTrig. 3m (3 2/m) : R3m
9.CJ.AvdeeviteNaAl4(Be5Li)(Si6O18)2(H2O)1-2Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.CJ.Beryllocordierite-NaNaMg4(Al5Be)(AlSi5O18)2 · 2H2OOrth. mmm (2/m 2/m 2/m) : Cccm
9.CJ.SachanbińskiiteNaMn4(Al5Be)(AlSi5O18)2 · 2H2OOrth. mmm (2/m 2/m 2/m) : Cccm
9.CJ.NakkaalaaqiteK2[Na3Ca]LiCa2Ti2Be4Si12O38Orth. mmm (2/m 2/m 2/m) : Fddd
9.CJ.05Johnkoivulaite-(Cs)Cs[Be2B]Mg2Si6O18Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CJ.05BerylBe3Al2(Si6O18)Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CJ.05BazziteBe3Sc2(Si6O18)Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CJ.05Ferroindialite(Fe2+,Mg)2Al4Si5O18Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CJ.05 vaVorobyeviteBe3Al2(Si6O18)
9.CJ.05StoppaniiteBe3Fe3+2(Si6O18) · H2OHex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CJ.05IndialiteMg2Al3(AlSi5O18)Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CJ.10SekaninaiteFe2+2Al4Si5O18Orth. mmm (2/m 2/m 2/m) : Cccm
9.CJ.10CordieriteMg2Al4Si5O18Orth. mmm (2/m 2/m 2/m) : Cccm
9.CJ.15aZirsinaliteNa6(Ca,Mn2+,Fe2+)Zr(Si6O18)Trig. 3m (3 2/m) : R3m
9.CJ.15aKapustiniteNa6ZrSi6O16(OH)2Mon. 2/m : B2/m
9.CJ.15aTownenditeNa8ZrSi6O18Trig. 3m (3 2/m) : R3m
9.CJ.15aCombeiteNa4.5Ca3.5Si6O17.5(OH)0.5Trig. 3m (3 2/m) : R3m
9.CJ.15aKazakoviteNa6Mn2+Ti(Si6O18)Trig. 3m (3 2/m) : R3m
9.CJ.15aLovozeriteNa2Ca(Zr,Ti)(Si6O12)[(OH)4O2] · H2OTrig. 3 : R3
9.CJ.15aLitvinskiteNa2(◻,Na,Mn)ZrSi6O12(OH,O)6Mon. m : Bm
9.CJ.15cKoashviteNa6(Ca,Mn)(Ti,Fe)Si6O18 · H2OOrth. mmm (2/m 2/m 2/m)
9.CJ.15bImandriteNa12Ca3Fe3+2(Si6O18)2Orth. mmm (2/m 2/m 2/m)
9.CJ.25BaratoviteKCa7(Ti,Zr)2Li3Si12O36F2Mon. 2/m : B2/b
9.CJ.25AleksandroviteKCa7Sn2Li3Si12O36F2Mon. 2/m : B2/b
9.CJ.25KatayamaliteKLi3Ca7Ti2(SiO3)12(OH)2Mon. 2/m : B2/b
9.CJ.30DioptaseCuSiO3 · H2OTrig. 3 : R3
9.CJ.35KostyleviteK2Zr(Si3O9) · H2OMon. 2/m : P21/b
9.CJ.40PetarasiteNa5Zr2(Si6O18)(Cl,OH) · 2H2OMon. 2/m : P21/m
9.CJ.45Gerenite-(Y)(Ca,Na)2(Y,REE)3Si6O18 · 2H2OTric. 1 : P1
9.CJ.50OdintsoviteK2Na4Ca3Ti2Be4Si12O38Orth. mmm (2/m 2/m 2/m) : Fddd
9.CJ.55MathewrogersitePb7FeAl3GeSi12O36(OH,H2O)6Trig.
9.CJ.60Pezzottaite-(Cs)Cs(Be2Li)Al2(Si6O18)Trig. 3 : R3

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for TisinaliteHide

References for TisinaliteHide

Localities for TisinaliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Murmansk Oblast
    • Koashva Mt
[World of Stones 95:5-6 +2 other references
    • Lovozersky District
Pekov (2000)
Pekov (1998) +1 other reference
Konopleva et al. (2008)
      • Rasvumchorr Mine
Jiri Spalek specimen. +2 other references
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