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Petarasite

A valid IMA mineral species
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About PetarasiteHide

03873380017271925895630.jpg
Peter Tarassoff
Formula:
Na5Zr2(Si6O18)(Cl,OH) · 2H2O
Colour:
Orange to brown, pink, yellow, white
Lustre:
Vitreous
Hardness:
5 - 5½
Specific Gravity:
2.88
Crystal System:
Monoclinic
Name:
Named in 1980 by George Y. Chao, T. T. Chen, and J. Baker in honor of Dr. Peter Tarassoff [b. April 11, 1934 Canada] of Beaconsfield, Quebec, considered to be “the dean” of Mont Saint-Hilaire mineral collectors, for his long (55+ years) and sustained contributions to Mont Saint-Hilaire mineralogy.
Related to the Lovozerite Group.


Unique IdentifiersHide

Mindat ID:
3172
Long-form identifier:
mindat:1:1:3172:7

Similar NamesHide

Petersita-(Ce)A synonym of Petersite-(Ce)
Petersita-(La)A synonym of Petersite-(La)
PetersiteA synonym
Petersite-(Y)A valid IMA mineral speciesYCu6(PO4)3(OH)6 · 3H2O
PietersiteA variety of 'Chalcedony' [Quartz]SiO2

IMA Classification of PetarasiteHide

Approved
IMA Formula:
Na5Zr4+2Si6O18(Cl,OH)(H2O)2
Approval year:
1979
First published:
1980

Classification of PetarasiteHide

9.CJ.40

9 : SILICATES (Germanates)
C : Cyclosilicates
J : [Si6O18]12- 6-membered single rings (sechser-Einfachringe), without insular complex anions
61.1.2b.3

61 : CYCLOSILICATES Six-Membered Rings
1 : Six-Membered Rings with [Si6O18] rings; possible (OH) and Al substitution
14.10.11

14 : Silicates not Containing Aluminum
10 : Silicates of Zr or Hf

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
PraIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PetarasiteHide

Vitreous
Transparency:
Translucent
Colour:
Orange to brown, pink, yellow, white
Streak:
White.
Hardness:
5 - 5½ on Mohs scale
Cleavage:
Very Good
Very good on {110}, plus 2 more directions distinct.
Fracture:
Sub-Conchoidal
Density:
2.88(1) g/cm3 (Measured)    2.915 g/cm3 (Calculated)
Comment:
Calculated value based on the empirical formula.

Optical Data of PetarasiteHide

Type:
Biaxial (+)
RI values:
nα = 1.595 - 1.596 nβ = 1.598 - 1.6 nγ = 1.631 - 1.632
2V:
Measured: 29° to 43°, Calculated: 36° to 40°
Max. Birefringence:
δ = 0.036
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r < v, weak.
Optical Extinction:
X = b; Z ∧ c = 41.5°.
Pleochroism:
Weak
Comments:
X = colorless; Y = Z = pale greenish yellow.
Comments:
Absorption: Y = Z > X.

Chemistry of PetarasiteHide

Mindat Formula:
Na5Zr2(Si6O18)(Cl,OH) · 2H2O
Element Weights:
Element% weight
O38.768 %
Zr22.105 %
Si20.416 %
Na13.927 %
Cl4.295 %
H0.489 %

Calculated from ideal end-member formula.
O
Zr
Si
Na
Cl
H
Common Impurities:
Ti,Ca,K

Crystallography of PetarasiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/m
Setting:
P21/m
Cell Parameters:
a = 10.79 Å, b = 14.49 Å, c = 6.62 Å
β = 113.21°
Ratio:
a:b:c = 0.745 : 1 : 0.457
Unit Cell V:
951.25 ų (Calculated from Unit Cell)

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005181PetarasiteGhose S, Wan C, Chao G Y (1980) Petarasite, Na5Zr2Si6O18(Cl,OH).2H2O, a zeolite-type zirconosilicate The Canadian Mineralogist 18 503-50919800293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.10 Å(100)
2.924 Å(100)
7.25 Å(70)
6.09 Å(40)
3.220 Å(30)
3.041 Å(30)
1.729 Å(20)
Comments:
Poudrette quarry, Mont Saint-Hilaire, Québec, Canada. The data are from Chao et al. (1980).

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of PetarasiteHide

General Appearance of Type Material:
Irregular grains up to 10 mm across.
Place of Conservation of Type Material:
Canadian Museum of Nature, Ottawa, Ontario, Canada, numbers 43721, 43630, 43631 (cotype).
Royal Ontario Museum, Toronto, Ontario, Canada, numbers M36456, M36457, M36458.
Geological Survey of Canada, Ottawa, Ontario, Canada, number 61531 (cotype).
Geological Setting of Type Material:
In a xenolith, composed mainly of coarse grained biotite and microcline, in nepheline syenite.
Associated Minerals at Type Locality:

Synonyms of PetarasiteHide

Other Language Names for PetarasiteHide

Relationship of Petarasite to other SpeciesHide

Chemically related to group(s):
Lovozerite GroupA3D3G2M(HxSi6O18) · nH2O (x = 0-6)

Common AssociatesHide

Associations Based on Photo Data:
36 photos of Petarasite associated with CatapleiiteNa2Zr(Si3O9) · 2H2O
13 photos of Petarasite associated with AlbiteNa(AlSi3O8)
10 photos of Petarasite associated with AegirineNaFe3+Si2O6
5 photos of Petarasite associated with ManganoneptuniteKNa2Li(Mn2+)2Ti2[Si4O12]2
4 photos of Petarasite associated with GaidonnayiteNa2Zr(Si3O9) · 2H2O
4 photos of Petarasite associated with PolylithioniteKLi2Al(Si4O10)(F,OH)2
3 photos of Petarasite associated with Kentbrooksite(Na,REE)15(Ca,REE)6(Mn2+,Fe2+)3Zr3Nb[Si25O74]F2 · 2H2O
3 photos of Petarasite associated with GenthelviteBe3Zn4(SiO4)3S
2 photos of Petarasite associated with AnalcimeNa(AlSi2O6) · H2O
2 photos of Petarasite associated with SeranditeNaMn2+2Si3O8(OH)

Related Minerals - Strunz-mindat GroupingHide

9.CJ.ZolotareviteNa5Zr[Si6O15(OH)3] · 3H2OTrig. 3m(32/m) : R3m
9.CJ.'Avdeevite'NaAl4(Be5Li)(Si6O18)2(H2O)1-2Hex. 6/mmm(6/m2/m2/m) : P63/mmc
9.CJ.'Beryllocordierite-Na'NaMg4(Al5Be)(AlSi5O18)2 · 2H2OOrth. mmm(2/m2/m2/m) : Cccm
9.CJ.SachanbińskiiteNaMn4(Al5Be)(AlSi5O18)2 · 2H2OOrth. mmm(2/m2/m2/m) : Cccm
9.CJ.NakkaalaaqiteK2[Na3Ca]LiCa2Ti2Be4Si12O38Orth. mmm(2/m2/m2/m) : Fddd
9.CJ.05Johnkoivulaite-(Cs)Cs[Be2B]Mg2Si6O18Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CJ.05BerylBe3Al2(Si6O18)Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CJ.05BazziteBe3Sc2(Si6O18)Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CJ.05Ferroindialite(Fe2+,Mg)2Al4Si5O18Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CJ.05 va'Vorobyevite'Be3Al2(Si6O18)
9.CJ.05StoppaniiteBe3Fe3+2(Si6O18) · H2OHex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CJ.05IndialiteMg2Al3(AlSi5O18)Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.CJ.10SekaninaiteFe2+2Al4Si5O18Orth. mmm(2/m2/m2/m) : Cccm
9.CJ.10CordieriteMg2Al4Si5O18Orth. mmm(2/m2/m2/m) : Cccm
9.CJ.15aZirsinaliteNa6(Ca,Mn2+,Fe2+)Zr(Si6O18)Trig. 3m(32/m) : R3m
9.CJ.15aKapustiniteNa6ZrSi6O16(OH)2Mon. 2/m : B2/m
9.CJ.15aTownenditeNa8ZrSi6O18Trig. 3m(32/m) : R3m
9.CJ.15aCombeiteNa4.5Ca3.5Si6O17.5(OH)0.5Trig. 3m(32/m) : R3m
9.CJ.15aKazakoviteNa6Mn2+Ti(Si6O18)Trig. 3m(32/m) : R3m
9.CJ.15aTisinaliteNa3H3(Mn,Ca,Fe)TiSi6(O,OH)18 · 2H2OTrig. 3m(32/m)
9.CJ.15aLovozeriteNa2Ca(Zr,Ti)(Si6O12)[(OH)4O2] · H2OTrig. 3 : R3
9.CJ.15aLitvinskiteNa2(◻,Na,Mn)ZrSi6O12(OH,O)6Mon. m : Bm
9.CJ.15cKoashviteNa6(Ca,Mn)(Ti,Fe)Si6O18 · H2OOrth. mmm(2/m2/m2/m)
9.CJ.15bImandriteNa12Ca3Fe3+2(Si6O18)2Orth. mmm(2/m2/m2/m)
9.CJ.25BaratoviteKCa7(Ti,Zr)2Li3Si12O36F2Mon. 2/m : B2/b
9.CJ.25AleksandroviteKCa7Sn2Li3Si12O36F2Mon. 2/m : B2/b
9.CJ.25KatayamaliteKLi3Ca7Ti2(SiO3)12(OH)2Mon. 2/m : B2/b
9.CJ.30DioptaseCuSiO3 · H2OTrig. 3 : R3
9.CJ.35KostyleviteK2Zr(Si3O9) · H2OMon. 2/m : P21/b
9.CJ.45Gerenite-(Y)(Ca,Na)2(Y,REE)3Si6O18 · 2H2OTric. 1 : P1
9.CJ.50OdintsoviteK2Na4Ca3Ti2Be4Si12O38Orth. mmm(2/m2/m2/m) : Fddd
9.CJ.55MathewrogersitePb7FeAl3GeSi12O36(OH,H2O)6Trig.
9.CJ.60Pezzottaite-(Cs)Cs(Be2Li)Al2(Si6O18)Trig. 3 : R3

Fluorescence of PetarasiteHide

Not fluorescent.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for PetarasiteHide

References for PetarasiteHide

Localities for PetarasiteHide

Showing 7 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada (TL)
 
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
Chao et al. (1980) +2 other references
Norway
 
  • Vestfold
    • Larvik Commune
      • Malerød
Larsen et al. (2010) +1 other reference
Portugal
 
  • Azores
    • São Miguel
Chiappino et al. (2015)
Russia
 
  • Murmansk Oblast
    • Kukisvumchorr Mt
      • East slope
        • Tuliok River head
Pavel M. Kartashov (n.d.)
...
Хомяков А.П. et al. (1981)
USA
 
  • New Mexico
    • Otero County
      • Cornudas Mountains
Dr. W. Stoll (private communication 2001 & 2004)
 
and/or  
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