Kazakovite
A valid IMA mineral species
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About Kazakovite
Formula:
Na6Mn2+Ti(Si6O18)
Colour:
Pale yellow
Lustre:
Vitreous, Greasy
Hardness:
4
Specific Gravity:
2.84 - 2.90
Crystal System:
Trigonal
Member of:
Name:
Named by A.P. Khomyakov, E.I. Semenov, E.M. Es´kova, and A.A. Voronkov in 1974 in honor of Maria Efimovna Kazakova (Мария Ефимовна Казакова) (1913 - 1982), analytical chemist at the Institute of Mineralogy and Geochemistry of Rare Elements, Moscow, Russia. She did the chemical analyses of many new Russian minerals.
Unique Identifiers
Mindat ID:
2172
Long-form identifier:
mindat:1:1:2172:8
Similar Names
| H-Kazakovite | A synonym of Tisinalite |
IMA Classification of Kazakovite
Approved
IMA Formula:
Na6Mn2+Ti4+Si6O18
Approval year:
1973
Classification of Kazakovite
9.CJ.15a
9 : SILICATES (Germanates)
C : Cyclosilicates
J : [Si6O18]12- 6-membered single rings (sechser-Einfachringe), without insular complex anions
9 : SILICATES (Germanates)
C : Cyclosilicates
J : [Si6O18]12- 6-membered single rings (sechser-Einfachringe), without insular complex anions
61.1.2a.2
61 : CYCLOSILICATES Six-Membered Rings
1 : Six-Membered Rings with [Si6O18] rings; possible (OH) and Al substitution
61 : CYCLOSILICATES Six-Membered Rings
1 : Six-Membered Rings with [Si6O18] rings; possible (OH) and Al substitution
14.9.5
14 : Silicates not Containing Aluminum
9 : Silicates of Ti
14 : Silicates not Containing Aluminum
9 : Silicates of Ti
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Kzk | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Kazakovite
Vitreous, Greasy
Transparency:
Translucent
Colour:
Pale yellow
Hardness:
4 on Mohs scale
Cleavage:
None Observed
Fracture:
Irregular/Uneven, Conchoidal
Density:
2.84 - 2.90 g/cm3 (Measured) 2.97 g/cm3 (Calculated)
Optical Data of Kazakovite
Type:
Uniaxial (-)
RI values:
nω = 1.648 - 1.650 nε = 1.625 - 1.638
Max. Birefringence:
δ = 0.012 - 0.023
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Moderate
Chemistry of Kazakovite
Mindat Formula:
Na6Mn2+Ti(Si6O18)
Element Weights:
Common Impurities:
Al,Fe,Nb,Mg,Ca,K,P,H2O
Crystallography of Kazakovite
Crystal System:
Trigonal
Class (H-M):
3m(32/m) - Hexagonal Scalenohedral
Space Group:
R3m
Setting:
R3m
Cell Parameters:
a = 10.174 Å, c = 13.053 Å
Ratio:
a:c = 1 : 1.283
Unit Cell V:
1,170.10 ų (Calculated from Unit Cell)
Z:
3
Morphology:
Small (0.01-2mm) crystals showing the forms {1121} and {ll24}.
Twinning:
Simple, complex, and polysynthetic twins with twinning
axis normal to (1124}
axis normal to (1124}
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0012462 | Kazakovite | Voronkov A A, Pudovkina Z V, Blinov V A, Ilyukhin V V, Pyatenko Y A (1979) Crystal structure of kazakovite Na6Mn{Ti[Si6O18]} Doklady Akademii Nauk SSSR 245 106-109 | 1979 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 2.60 Å | (10) |
| 2.52 Å | (8) |
| 1.816 Å | (8) |
| 3.60 Å | (7) |
| 1.480 Å | (7) |
| 3.28 Å | (6) |
| 3.17 Å | (6) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 35 : Ultra-alkali and agpaitic igneous rocks |
Type Occurrence of Kazakovite
General Appearance of Type Material:
Disseminated in ussingite.
Place of Conservation of Type Material:
Mining Institute, St. Petersburg, 1081/2; A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 75513, 76106, vis3466.
Associated Minerals at Type Locality:
Synonyms of Kazakovite
Other Language Names for Kazakovite
Dutch:Kazakoviet
German:Kazakovit
Kazakhovit
Kazakhovit
Russian:Казаковит
Simplified Chinese:硅钛钠石
Spanish:Kazakhovita
Kazakovita
Kazakovita
Traditional Chinese:矽鈦鈉石
Relationship of Kazakovite to other Species
Member of:
Other Members of Zirsinalite-Lovozerite Subgroup:
| Combeite | Na4.5Ca3.5Si6O17.5(OH)0.5 | Trig. 3m(32/m) : R3m |
| Kapustinite | Na6ZrSi6O16(OH)2 | Mon. 2/m : B2/m |
| Litvinskite | Na2(◻,Na,Mn)ZrSi6O12(OH,O)6 | Mon. m : Bm |
| Lovozerite | Na2Ca(Zr,Ti)(Si6O12)[(OH)4O2] · H2O | Trig. 3 : R3 |
| Tisinalite | Na3H3(Mn,Ca,Fe)TiSi6(O,OH)18 · 2H2O | Trig. 3m(32/m) |
| Townendite | Na8ZrSi6O18 | Trig. 3m(32/m) : R3m |
| Zirsinalite | Na6(Ca,Mn2+,Fe2+)Zr(Si6O18) | Trig. 3m(32/m) : R3m |
Common Associates
Associations Based on Photo Data:
| 4 photos of Kazakovite associated with Aegirine | NaFe3+Si2O6 |
| 2 photos of Kazakovite associated with Grumantite | Na(HSi2O5) · H2O |
| 2 photos of Kazakovite associated with Ussingite | Na2AlSi3O8OH |
| 1 photo of Kazakovite associated with Kapustinite | Na6ZrSi6O16(OH)2 |
| 1 photo of Kazakovite associated with Natrolite | Na2Al2Si3O10 · 2H2O |
| 1 photo of Kazakovite associated with Villiaumite | NaF |
| 1 photo of Kazakovite associated with Thermonatrite | Na2CO3 · H2O |
| 1 photo of Kazakovite associated with Sodalite | Na4(Si3Al3)O12Cl |
Related Minerals - Strunz-mindat Grouping
| 9.CJ. | Zolotarevite | Na5Zr[Si6O15(OH)3] · 3H2O |
| 9.CJ. | 'Avdeevite' | NaAl4(Be5Li)(Si6O18)2(H2O)1-2 |
| 9.CJ. | 'Beryllocordierite-Na' | NaMg4(Al5Be)(AlSi5O18)2 · 2H2O |
| 9.CJ. | Sachanbińskiite | NaMn4(Al5Be)(AlSi5O18)2 · 2H2O |
| 9.CJ. | Nakkaalaaqite | K2[Na3Ca]LiCa2Ti2Be4Si12O38 |
| 9.CJ.05 | Johnkoivulaite-(Cs) | Cs[Be2B]Mg2Si6O18 |
| 9.CJ.05 | Beryl | Be3Al2(Si6O18) |
| 9.CJ.05 | Bazzite | Be3Sc2(Si6O18) |
| 9.CJ.05 | Ferroindialite | (Fe2+,Mg)2Al4Si5O18 |
| 9.CJ.05 va | 'Vorobyevite' | Be3Al2(Si6O18) |
| 9.CJ.05 | Stoppaniite | Be3Fe3+2(Si6O18) · H2O |
| 9.CJ.05 | Indialite | Mg2Al3(AlSi5O18) |
| 9.CJ.10 | Sekaninaite | Fe2+2Al4Si5O18 |
| 9.CJ.10 | Cordierite | Mg2Al4Si5O18 |
| 9.CJ.15a | Zirsinalite | Na6(Ca,Mn2+,Fe2+)Zr(Si6O18) |
| 9.CJ.15a | Kapustinite | Na6ZrSi6O16(OH)2 |
| 9.CJ.15a | Townendite | Na8ZrSi6O18 |
| 9.CJ.15a | Combeite | Na4.5Ca3.5Si6O17.5(OH)0.5 |
| 9.CJ.15a | Tisinalite | Na3H3(Mn,Ca,Fe)TiSi6(O,OH)18 · 2H2O |
| 9.CJ.15a | Lovozerite | Na2Ca(Zr,Ti)(Si6O12)[(OH)4O2] · H2O |
| 9.CJ.15a | Litvinskite | Na2(◻,Na,Mn)ZrSi6O12(OH,O)6 |
| 9.CJ.15c | Koashvite | Na6(Ca,Mn)(Ti,Fe)Si6O18 · H2O |
| 9.CJ.15b | Imandrite | Na12Ca3Fe3+2(Si6O18)2 |
| 9.CJ.25 | Baratovite | KCa7(Ti,Zr)2Li3Si12O36F2 |
| 9.CJ.25 | Aleksandrovite | KCa7Sn2Li3Si12O36F2 |
| 9.CJ.25 | Katayamalite | KLi3Ca7Ti2(SiO3)12(OH)2 |
| 9.CJ.30 | Dioptase | CuSiO3 · H2O |
| 9.CJ.35 | Kostylevite | K2Zr(Si3O9) · H2O |
| 9.CJ.40 | Petarasite | Na5Zr2(Si6O18)(Cl,OH) · 2H2O |
| 9.CJ.45 | Gerenite-(Y) | (Ca,Na)2(Y,REE)3Si6O18 · 2H2O |
| 9.CJ.50 | Odintsovite | K2Na4Ca3Ti2Be4Si12O38 |
| 9.CJ.55 | Mathewrogersite | Pb7FeAl3GeSi12O36(OH,H2O)6 |
| 9.CJ.60 | Pezzottaite-(Cs) | Cs(Be2Li)Al2(Si6O18) |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Kazakovite
mindat.org URL:
https://www.mindat.org/min-2172.html
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References for Kazakovite
Reference List:
Localities for Kazakovite
Showing 7 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Russia | |
| ... |
| Pekov (1998) |
| Pekov (1998) |
| Khomyakov A. P. et al. (1974) +1 other reference |
| Pekov (2005) |
| Pakhomovsky et al. (2014) | |
| Pekov I.V. et al. (2010) |
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Palitra pegmatite, Karnasurt mine, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia