Ecandrewsite
A valid IMA mineral species
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About Ecandrewsite
Formula:
ZnTiO3
Colour:
Dark brown, black
Lustre:
Sub-Metallic
Hardness:
5
Specific Gravity:
4.98 (Calculated)
Crystal System:
Trigonal
Member of:
Name:
Named in 1988 by W.D. Birch, E.A.J. Burke, V.J. Wall and M.A. Etheridge in honor of Ernest Clayton Andrews (18 October 1870, Sydney, New South Wales, Australia - 1 July 1948, Sydney, New South Wales, Australia), formerly New South Wales government geologist, who mapped the Broken Hill region.
The zinc analogue of Geikielite, Ilmenite, and Pyrophanite. Forms series with all of the latter species.
Unique Identifiers
Mindat ID:
1346
Long-form identifier:
mindat:1:1:1346:4
IMA Classification of Ecandrewsite
Classification of Ecandrewsite
4.CB.05
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
B : With medium-sized cations
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
B : With medium-sized cations
4.3.5.4
4 : SIMPLE OXIDES
3 : A2X3
4 : SIMPLE OXIDES
3 : A2X3
7.9.30
7 : Oxides and Hydroxides
9 : Oxides of Ti
7 : Oxides and Hydroxides
9 : Oxides of Ti
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Ec | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Ec | Whitney & Evans (2010) | Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371 |
| Ecn | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Ecandrewsite
Sub-Metallic
Transparency:
Transparent
Colour:
Dark brown, black
Streak:
Brown-black
Hardness:
5 on Mohs scale
Hardness:
VHN100=500 - 600 kg/mm2 - Vickers
Cleavage:
None Observed
Density:
4.98 g/cm3 (Calculated)
Optical Data of Ecandrewsite
Type:
Uniaxial (+)
Anisotropism:
Strong, greenish grey to dark brownish grey
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 470nm | 17.2% | 19.9% |
| 546nm | 17.2% | 19.7% |
| 589nm | 17.0% | 19.6% |
| 650nm | 16.8% | 19.2% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 19.9%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Greyish-white
Pleochroism:
Weak
Chemistry of Ecandrewsite
Mindat Formula:
ZnTiO3
Element Weights:
Elements listed:
Crystallography of Ecandrewsite
Crystal System:
Trigonal
Class (H-M):
3 - Rhombohedral
Space Group:
R3
Cell Parameters:
a = 5.09 Å, c = 14.03 Å
Ratio:
a:c = 1 : 2.756
Unit Cell V:
314.79 ų (Calculated from Unit Cell)
Z:
6
Morphology:
Tabular crystals.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0006000 | Ecandrewsite | Mitchell R H, Liferovich R P (2004) The pyrophanite-ecandrewsite solid-solution: crystal structures of the Mn1-xZnxSiO3 series (0.1 <= x <= 0.8) The Canadian Mineralogist 42 1871-1880 | ![]() | 2004 | 0 | 293 | |
| 0005999 | Ecandrewsite | Mitchell R H, Liferovich R P (2004) The pyrophanite-ecandrewsite solid-solution: crystal structures of the Mn1-xZnxSiO3 series (0.1 <= x <= 0.8) The Canadian Mineralogist 42 1871-1880 | ![]() | 2004 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 2.73 Å | (100) |
| 2.53 Å | (90) |
| 1.71 Å | (70) |
| 2.23 Å | (60) |
| 1.87 Å | (40) |
| 3.69 Å | (20) |
| 1.502 Å | (20) |
| 1.469 Å | (20) |
Comments:
San Valentin mine, Spain. Data from the type description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-? alteration and/or metamorphism | |
| 32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits |
Type Occurrence of Ecandrewsite
General Appearance of Type Material:
Euhedral grains up to 250 x 50 µm with a tabular habit, and as intergrowths with zincian ilmenite up to 50 µm across.
Place of Conservation of Type Material:
Melbourne Rockwell mine at Museum of Victoria (M35700)
San Valentin occurrence are deposited in the collections of the Free University, Amsterdam, The Netherlands.
San Valentin occurrence are deposited in the collections of the Free University, Amsterdam, The Netherlands.
Geological Setting of Type Material:
Disseminated in quartz-rich metasediments of amphibolite-granulite facies.
Associated Minerals at Type Locality:
Synonyms of Ecandrewsite
Other Language Names for Ecandrewsite
Relationship of Ecandrewsite to other Species
Member of:
Other Members of Ilmenite Group:
| Akimotoite | MgSiO3 | Trig. 3 : R3 |
| Geikielite | MgTiO3 | Trig. 3 : R3 |
| Hemleyite | Fe2+SiO3 | Trig. 3 : R3 |
| Ilmenite | Fe2+TiO3 | Trig. 3 : R3 |
| Pyrophanite | Mn2+TiO3 | Trig. 3 : R3 |
| 'Unnamed (Fe-Cr Oxide)' | FeCrO3 | Trig. 3 : R3 |
Common Associates
Associations Based on Photo Data:
| 1 photo of Ecandrewsite associated with 'Almandine-Spessartine Series' | |
| 1 photo of Ecandrewsite associated with Garnet Group | X3Z2(SiO4)3 |
| 1 photo of Ecandrewsite associated with Frondelite | (Mn2+0.5Fe3+0.5)2Fe3+3(PO4)3(OH)5 |
Related Minerals - Strunz-mindat Grouping
| 4.CB. | Magnesiohögbomite-6N12S | Mg5Al11TiO23(OH) |
| 4.CB. | Kidodite | BaMg2Fe16O27 |
| 4.CB. | Ferrohögbomite-2N2S | [(Fe2+,Mg,Zn,Al)3(Al,Ti,Fe3+)8O15(OH)]2 |
| 4.CB. | Zhenruite | (MoO3)2 · H2O |
| 4.CB. | Fuyuanite | Mg7Nb6O18(OH)8 |
| 4.CB. | Virgilluethite | MoO3 · H2O |
| 4.CB. | Pengite | (Pb8Sb3+3)Σ11Sb5+9O35 |
| 4.CB.05 | Brizziite | NaSb5+O3 |
| 4.CB.05 | Tistarite | Ti3+2O3 |
| 4.CB.05 | Hematite | Fe2O3 |
| 4.CB.05 | Melanostibite | Mn2+2Fe3+Sb5+O6 |
| 4.CB.05 | 'UM1998-11-O-AuHSb' | Au+2Sb3+O2(OH) |
| 4.CB.05 | Karelianite | V3+2O3 |
| 4.CB.05 | Corundum | Al2O3 |
| 4.CB.05 | Eskolaite | Cr2O3 |
| 4.CB.05 | Geikielite | MgTiO3 |
| 4.CB.05 | Akimotoite | MgSiO3 |
| 4.CB.05 | 'Unnamed (Fe-Cr Oxide)' | FeCrO3 |
| 4.CB.05 | 'Auroantimonate' | AuSbO3 |
| 4.CB.05 | Hemleyite | Fe2+SiO3 |
| 4.CB.05 | Ilmenite | Fe2+TiO3 |
| 4.CB.05 | Pyrophanite | Mn2+TiO3 |
| 4.CB.10 | Bixbyite-(Fe) | (Fe,Mn)2O3 |
| 4.CB.10 | Bixbyite-(Mn) | Mn3+2O3 |
| 4.CB.10 | Avicennite | Tl3+2O3 |
| 4.CB.15 | Armalcolite | MgTi4+2O5 |
| 4.CB.15 | Ferropseudobrookite | Fe2+Ti4+2O5 |
| 4.CB.15 | Griffinite | Al2Ti4+O5 |
| 4.CB.15 | Pseudobrookite Group | |
| 4.CB.15 | Sassite | Ti3+2Ti4+O5 |
| 4.CB.15 | Pseudobrookite | Fe3+2Ti4+O5 |
| 4.CB.20 | Zincovelesite-6N6S | Zn3(Fe3+,Mn3+,Al,Ti)8O15(OH) |
| 4.CB.20 | Magnesiohögbomite-2N4S | (Mg8.43Fe2+1.57)Σ=10Al22Ti4+2O46(OH)2 |
| 4.CB.20 | Magnesiobeltrandoite-2N3S | (Mg6Al2)(Al18Fe3+2)O38(OH)2 |
| 4.CB.20 | Zincohögbomite-2N6S | [(Zn,Mg)7(Al,Fe3+,Ti)16O31(OH)]2 |
| 4.CB.20 | Magnesiohögbomite-6N6S | [(Mg,Fe2+)3(Al,Ti,Fe3+)8O15(OH)]6 |
| 4.CB.20 | Magnesiohögbomite-2N3S | [(Mg,Fe2+,Zn)4(Al,Ti,Fe3+)10O19(OH)]2 |
| 4.CB.20 | Magnesiohögbomite-2N2S | [(Mg,Fe2+)3[Al7(Ti,Fe3+)]O15(OH)]2 |
| 4.CB.20 | 'Ferrohögbomite-6N12S' | [(Fe2+,Mg,Zn)5(Al,Ti,Fe3+)12O23(OH)]6 |
| 4.CB.20 | Zincohögbomite-2N2S | [(Zn,Al,Fe2+)3(Al,Fe3+,Ti)8O15(OH)]2 |
| 4.CB.25 | Kleberite | FeTi6O11(OH)5 |
| 4.CB.25 | Pseudorutile | Fe3+2Ti4+3O9 |
| 4.CB.30 | Oxyvanite | V3+2V4+O5 |
| 4.CB.30 | Berdesinskiite | V3+2TiO5 |
| 4.CB.30 | Kaitianite | Ti3+2Ti4+O5 |
| 4.CB.35 | Machiite | Al2Ti3O9 |
| 4.CB.35 | Vestaite | (Ti4+Fe2+)Ti4+3O9 |
| 4.CB.35 | Olkhonskite | (Cr,V)2Ti3O9 |
| 4.CB.35 | Schreyerite | V3+2Ti4+3O9 |
| 4.CB.40 | Zincorinmanite-(Zn) | Zn2Sb2(Fe3+4Zn2)O14(OH)2 |
| 4.CB.40 | Majindeite | Mg2Mo3O8 |
| 4.CB.40 | Almagreraite | CuZnMn4+3O8 |
| 4.CB.40 | Kamiokite | Fe2Mo3O8 |
| 4.CB.40 | Nolanite | V3+8Fe3+2O14(OH)2 |
| 4.CB.40 | Iseite | Mn2Mo3O8 |
| 4.CB.40 | Rinmanite | Zn2Sb2Mg2Fe4O14(OH)2 |
| 4.CB.45 | Stibioclaudetite | AsSbO3 |
| 4.CB.45 | Claudetite | As2O3 |
| 4.CB.50 | Senarmontite | Sb2O3 |
| 4.CB.50 | Arsenolite | As2O3 |
| 4.CB.55 | Valentinite | Sb2O3 |
| 4.CB.60 | Bismite | Bi2O3 |
| 4.CB.65 | Sphaerobismoite | Bi2O3 |
| 4.CB.70 | Sillénite | Bi12SiO20 |
| 4.CB.75 | Kyzylkumite | V3+Ti2O5(OH) |
| 4.CB.80 | 'Tietaiyangite' | Fe3+4Fe2+TiO9 |
| 4.CB.85 | Liuite | FeTiO3 |
| 4.CB.90 | Luogufengite | Fe2O3 |
| 4.CB.95 | Wangdaodeite | FeTiO3 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Ecandrewsite
mindat.org URL:
https://www.mindat.org/min-1346.html
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References for Ecandrewsite
Reference List:
Birch, W. D., Burke, E. A. J., Wall, V. J., Etheridge, M. A. (1988) Ecandrewsite, the zinc analogue of ilmenite, from Little Broken Hill, New South Wales, Australia, and the San Valentin Mine, Sierra de Cartegena, Spain. Mineralogical Magazine, 52 (365) 237-240 doi:10.1180/minmag.1988.052.365.10
Whitney, D. L., Hirschmann, M., Miller, M. G. (1993) Zincian ilmenite-ecandrewsite from a pelitic schist, Death Valley, California, and the paragenesis of (Zn,Fe)TiO3 solid solution in metamorphic rocks. The Canadian Mineralogist, 31 (2). 425-436 doi:10.3749/1499-1276-31.2.425
Liferovich, Ruslan P., Mitchell, Roger H. (2004) Geikielite–ecandrewsite solid solutions: synthesis and crystal structures of the Mg1−xZnxTiO3 (0 ≤x≤ 0.8) series. Acta Crystallographica Section B Structural Science, 60 (5) 496-501 doi:10.1107/s0108768104017963
Mitchell, R. H., Liferovich, R. P. (2004) Ecandrewsite — zincian pyrophanite from lujavrite, Pilansberg alkaline complex, South Africa. The Canadian Mineralogist, 42 (4) 1169-1178 doi:10.2113/gscanmin.42.4.1169
Mitchell, R. H., LIferovich, R. P. (2004) The pyrophanite-ecandrewsite solid-solution: crystal structures of the Mn1-xZnxTiO3 series (0.1 ≤ x ≤ 0.8) The Canadian Mineralogist, 42 (6) 1871-1880 doi:10.2113/gscanmin.42.6.1871
Localities for Ecandrewsite
Showing 18 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Argentina | |
| Espeche et al. (2022) |
Australia (TL) | |
| Birch et al. (1988) +1 other reference |
| Munro-Smith (2006) | |
| Le Gleuher M. (2008) |
Austria | |
| Niedermayr et al. (2001) |
China | |
| Wu et al. (2021) |
Egypt | |
| Zoheir et al. (2022) |
India | |
| Ghosh et al. (2007) |
Madagascar | |
| Dekoninck et al. (2024) |
Portugal | |
| Alves et al. (2012) |
Russia | |
| Voloshin et al. (2005) +1 other reference |
South Africa | |
| Mitchell et al. (2004) |
| Mitchell et al. (2004) | |
Spain | |
| Manteca (2013) |
| Birch et al. (1988) | |
UK | |
| LeBoutillier et al. (2000) |
Ukraine | |
| Sharygin et al. (2011) |
USA | |
| Whitney et al. (1993) |
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Sítio do Castelo Mine, Folgosinho, Gouveia, Guarda, Portugal