Ixiolite-(Fe2+)
A valid IMA mineral species
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Formula:
(Ta0.67Fe2+0.33)O2
Crystal System:
Orthorhombic
Member of:
Name:
First referred to as Kimito-Tantalit, but later named by Nordenskiöld (1857) after Ixion, a king in Greek mythology punished by Zeus and bound to a fiery, spinning wheel for eternity and -lite, from Greek lithos (stone). The name was given parallel with tantalite (who was named after Tantalus, also a king in Greek mythology and relative of Ixion), in allusiuon to the tantalum content of the material.
The suffix -(Fe2+) was added later (in 2022), for the dominant kation at the M1-site.
The suffix -(Fe2+) was added later (in 2022), for the dominant kation at the M1-site.
Ixiolite-(Fe2+) is the Fe²⁺‑dominant member of the Ixiolite Group and of the Ixiolite-(Mn2+)-Ixiolite-(Fe2+) series, with the ideal end‑member formula (Ta₂/₃Fe²⁺₁/₃)O₂.
Ixiolite (sensu lacto) was first described as a tantalum oxide, with subordinate Fe and Mn and minor Sn by Nordenskiöld (1857). The chemical analysis was however incomplete, the Mn:Fe ratio was not determined. At the type locality, Skogsböle in Finland, ixiolite occurs with both Fe > Mn and Mn > Fe compositions.
Nickel et al. (1963) investigated the crystal structure of an ixiolite sample from Skogsböle. Structurally, ixiolite (sensu stricto) can be regarded as a disordered form of columbite.
In 2022, the IMA redefined the ixiolite into two distinct species, ixiolite-(Fe2+) and ixiolite-(Mn2+).
The sample investigated Nickel et al. (1963) corresponds, after the redefinition to a Fe2+-dominant ixiolite.
Ixiolite (sensu lacto) was first described as a tantalum oxide, with subordinate Fe and Mn and minor Sn by Nordenskiöld (1857). The chemical analysis was however incomplete, the Mn:Fe ratio was not determined. At the type locality, Skogsböle in Finland, ixiolite occurs with both Fe > Mn and Mn > Fe compositions.
Nickel et al. (1963) investigated the crystal structure of an ixiolite sample from Skogsböle. Structurally, ixiolite (sensu stricto) can be regarded as a disordered form of columbite.
In 2022, the IMA redefined the ixiolite into two distinct species, ixiolite-(Fe2+) and ixiolite-(Mn2+).
The sample investigated Nickel et al. (1963) corresponds, after the redefinition to a Fe2+-dominant ixiolite.
Unique Identifiers
Mindat ID:
56147
Long-form identifier:
mindat:1:1:56147:3
Similar Names
| Ixiolite-(Mn2+) | A valid IMA mineral species | (Ta0.67Mn2+0.33)O2 |
| Ixiolite-(Mn2+)-Ixiolite-(Fe2+) Series | A solid-solution series between two end-member minerals | |
| Ixiolite-(Sc) | A valid IMA mineral species | (Ta0.5Sc0.5)O2 |
| Ixolite |
IMA Classification of Ixiolite-(Fe2+)
Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
(Ta2/3Fe2+1/3)O2
Approval year:
2022
First published:
1857
Approval history:
Redefined by IMA in 2022.
The old “ixiolite” was redefined and results now in two distinct mineral species: ixiolite-(Mn2+), with end-member formula (TaMn)O2, and ixiolite-(Fe2+), with end-member formula (TaFe)O2. The type locality for both is Skogsböle, Kimito Island, Finland.
The old “ixiolite” was redefined and results now in two distinct mineral species: ixiolite-(Mn2+), with end-member formula (TaMn)O2, and ixiolite-(Fe2+), with end-member formula (TaFe)O2. The type locality for both is Skogsböle, Kimito Island, Finland.
Classification of Ixiolite-(Fe2+)
4.DB.25
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
B : With medium-sized cations; chains of edge-sharing octahedra
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
B : With medium-sized cations; chains of edge-sharing octahedra
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Ix-Fe2+ | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Chemistry of Ixiolite-(Fe2+)
Mindat Formula:
(Ta0.67Fe2+0.33)O2
Element Weights:
Elements listed:
Crystallography of Ixiolite-(Fe2+)
Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pbcn
Cell Parameters:
a = 4.785 Å, b = 5.758 Å, c = 5.160 Å
Ratio:
a:b:c = 0.831 : 1 : 0.896
Unit Cell V:
142.17 ų (Calculated from Unit Cell)
Morphology:
a = 4.785 Å, b = 5.758 Å, c = 5.160 Å
Comment:
Nickel et al. (1963) give space group Pcan (non-standard setting) and unit-cell parameters a = 5.731, b = 4.742, c = 5.152 Å. Grice et al. (1976) give space group Pbcn (non-standard setting) and the unit-cell parameters a = 4.785, b = 5.758, c = 5.160 Å (used above). Heating usually produces an ordered wodginite-type structure.
Type Occurrence of Ixiolite-(Fe2+)
Place of Conservation of Type Material:
In the Royal Ontario Museum with the catalogue number M-6591 (sample investigated by Nickel et al.,1963).
Geological Setting of Type Material:
Granite pegmatite
Other Language Names for Ixiolite-(Fe2+)
Relationship of Ixiolite-(Fe2+) to other Species
Member of:
Other Members of Ixiolite Group:
| Ixiolite-(Mn2+) | (Ta0.67Mn2+0.33)O2 | Orth. mmm(2/m2/m2/m) : Pbcn |
| Ixiolite-(Sc) | (Ta0.5Sc0.5)O2 | Orth. mmm(2/m2/m2/m) : Pbcn |
| Nioboixiolite-(Fe2+) | (Nb0.67Fe2+0.33)O2 | Orth. mmm(2/m2/m2/m) : Pbcn |
| Nioboixiolite-(Fe3+) | (Nb0.5Fe3+0.5)O2 | Orth. mmm(2/m2/m2/m) : Pbcn |
| Nioboixiolite-(Mn2+) | (Nb0.67Mn2+0.33)O2 | Orth. mmm(2/m2/m2/m) : Pbcn |
| Nioboixiolite-([]) | (Nb0.8◻0.2)4+O2 | Orth. mmm(2/m2/m2/m) : Pbcn |
| Scrutinyite | α-PbO2 | Orth. mmm(2/m2/m2/m) : Pbcn |
| Seifertite | SiO2 | Orth. mmm(2/m2/m2/m) : Pbcn |
| Srilankite | TiO2 | Orth. mmm(2/m2/m2/m) : Pbcn |
Forms a series with:
Related Minerals - Strunz-mindat Grouping
| 4.DB. | Tianhongqiite | CrTiO3(OH) |
| 4.DB. | Nioboheftetjernite | ScNbO4 |
| 4.DB. | Huangshanite | Fe3+TaO4 |
| 4.DB. | Nioboixiolite-(Mn2+) | (Nb0.67Mn2+0.33)O2 |
| 4.DB. | Shakhdaraite-(Y) | ScYNb2O8 |
| 4.DB.05 | Varlamoffite | Sn1-xFexO2-x(OH) |
| 4.DB.05 | Argutite | GeO2 |
| 4.DB.05 | Cassiterite | SnO2 |
| 4.DB.05 | Rutile | TiO2 |
| 4.DB.05 | Plattnerite | PbO2 |
| 4.DB.05 | Tripuhyite | Fe3+Sb5+O4 |
| 4.DB.05 | Tugarinovite | MoO2 |
| 4.DB.05 | Pyrolusite | Mn4+O2 |
| 4.DB.10 | Byströmite | MgSb2O6 |
| 4.DB.10 | Ordoñezite | ZnSb2O6 |
| 4.DB.10 | Tredouxite | NiSb2O6 |
| 4.DB.10 | Tapiolite-(Mn) | Mn2+Ta2O6 |
| 4.DB.10 | Tapiolite-(Fe) | Fe2+Ta2O6 |
| 4.DB.15a | Paramontroseite | V4+O2 |
| 4.DB.15a | Ramsdellite | Mn4+O2 |
| 4.DB.15b | Akhtenskite | ε-Mn4+O2 |
| 4.DB.15c | Nsutite | (Mn4+,Mn2+)(O,OH)2 |
| 4.DB.20 | Scrutinyite | α-PbO2 |
| 4.DB.20 | Nioboixiolite-([]) | (Nb0.8◻0.2)4+O2 |
| 4.DB.25 | Ishikawaite | U4+Fe2+Nb2O8 |
| 4.DB.25 | Yttrocolumbite-(Y) | Y(U4+,Fe2+)Nb2O8 |
| 4.DB.25 | Calciosamarskite | (Ca,U4+)Fe3+(Nb,Ta,Ti)2O8 |
| 4.DB.25 | Samarskite-(Yb) | YbFe3+(Nb,Ta)2O8 |
| 4.DB.25 | Ixiolite-(Sc) | (Ta0.5Sc0.5)O2 |
| 4.DB.25 | Ixiolite-(Mn2+) | (Ta0.67Mn2+0.33)O2 |
| 4.DB.25 | Nioboixiolite-(Fe2+) | (Nb0.67Fe2+0.33)O2 |
| 4.DB.25 | Srilankite | TiO2 |
| 4.DB.25 | Samarskite-(Y) | YFe3+Nb2O8 |
| 4.DB.25 | Nioboixiolite-(Fe3+) | (Nb0.5Fe3+0.5)O2 |
| 4.DB.30 va | Wolframite Group | |
| 4.DB.30 | Rossovskyite | (Fe3+,Ta)(Nb,Ti)O4 |
| 4.DB.30 | Huanzalaite | MgWO4 |
| 4.DB.30 | Heftetjernite | ScTaO4 |
| 4.DB.30 | Hübnerite | MnWO4 |
| 4.DB.30 | Sanmartinite | (Zn,Fe)WO4 |
| 4.DB.30 | Ferberite | FeWO4 |
| 4.DB.30 | 'Krasnoselskite' | CoWO4 |
| 4.DB.35 | Qitianlingite | (Fe,Mn)2(Nb,Ta)2WO10 |
| 4.DB.35 | Tantalaeschynite-(Ce) | Ce(TiTa)O6 |
| 4.DB.35 | Tantalite-(Mg) | (Mg,Fe2+)(Ta,Nb)2O6 |
| 4.DB.35 | Columbite-(Mn) | Mn2+Nb2O6 |
| 4.DB.35 | Tantalite-(Mn) | Mn2+Ta2O6 |
| 4.DB.35 | Columbite-(Fe) | Fe2+Nb2O6 |
| 4.DB.35 | Columbite-(Mg) | (Mg,Fe,Mn)(Nb,Ta)2O6 |
| 4.DB.35 | Tantalite-(Fe) | Fe2+Ta2O6 |
| 4.DB.40 | Ferrotitanowodginite | Fe2+TiTa2O8 |
| 4.DB.40 | 'Wolframowodginite' | Mn(Mn,Sn,Fe,Ta)(W,Ta,Nb)2O8 |
| 4.DB.40 | Lithiotantite | LiTa3O8 |
| 4.DB.40 | Lithiowodginite | LiTa3O8 |
| 4.DB.40 | Titanowodginite | Mn2+TiTa2O8 |
| 4.DB.40 | Tantalowodginite | (Mn2+0.5◻0.5)TaTa2O8 |
| 4.DB.40 | Wodginite | Mn2+Sn4+Ta2O8 |
| 4.DB.40 | Ferrowodginite | Fe2+Sn4+Ta2O8 |
| 4.DB.45 | Tivanite | V3+TiO3(OH) |
| 4.DB.50 | Carmichaelite | (Ti,Cr,Fe)[O2-x(OH)x] |
| 4.DB.55 | Alumotantite | AlTaO4 |
| 4.DB.60 | Biehlite | ((Sb,As)O)2[MoO4] |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Ixiolite-(Fe2+)
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https://www.mindat.org/min-56147.html
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References for Ixiolite-(Fe2+)
Reference List:
Nordenskiöld, A. E. (1857) Beitrag zu Finnlands Mineralogie. Annalen der Physik und Chemie, 177. 625-642 doi:10.1002/andp.18571770807
Nickel, E. H., Rowland, J. F., McAdam, R. C. (1963) Ixiolite---a columbite substructure. American Mineralogist, 48 (9-10) 961-979
Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 68. European Journal of Mineralogy, 34 (5) 385-391 doi:10.5194/ejm-34-385-2022
Localities for Ixiolite-(Fe2+)
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Finland (TL) | |
| Nordenskiöld (1857) +2 other references |

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