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Ixiolite-(Fe2+)

A valid IMA mineral species
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02754670017271924234344.jpg
Ixion
Formula:
(Ta0.67Fe2+0.33)O2
Crystal System:
Orthorhombic
Name:
First referred to as Kimito-Tantalit, but later named by Nordenskiöld (1857) after Ixion, a king in Greek mythology punished by Zeus and bound to a fiery, spinning wheel for eternity and -lite, from Greek lithos (stone). The name was given parallel with tantalite (who was named after Tantalus, also a king in Greek mythology and relative of Ixion), in allusiuon to the tantalum content of the material.
The suffix -(Fe2+) was added later (in 2022), for the dominant kation at the M1-site.
Ixiolite-(Fe2+) is the Fe²⁺‑dominant member of the Ixiolite Group and of the Ixiolite-(Mn2+)-Ixiolite-(Fe2+) series, with the ideal end‑member formula (Ta₂/₃Fe²⁺₁/₃)O₂.

Ixiolite (sensu lacto) was first described as a tantalum oxide, with subordinate Fe and Mn and minor Sn by Nordenskiöld (1857). The chemical analysis was however incomplete, the Mn:Fe ratio was not determined. At the type locality, Skogsböle in Finland, ixiolite occurs with both Fe > Mn and Mn > Fe compositions.

Nickel et al. (1963) investigated the crystal structure of an ixiolite sample from Skogsböle. Structurally, ixiolite (sensu stricto) can be regarded as a disordered form of columbite.

In 2022, the IMA redefined the ixiolite into two distinct species, ixiolite-(Fe2+) and ixiolite-(Mn2+).
The sample investigated Nickel et al. (1963) corresponds, after the redefinition to a Fe2+-dominant ixiolite.


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Unique IdentifiersHide

Mindat ID:
56147
Long-form identifier:
mindat:1:1:56147:3

Similar NamesHide

Ixiolite-(Mn2+)A valid IMA mineral species(Ta0.67Mn2+0.33)O2
Ixiolite-(Mn2+)-Ixiolite-(Fe2+) SeriesA solid-solution series between two end-member minerals
Ixiolite-(Sc)A valid IMA mineral species(Ta0.5Sc0.5)O2
Ixolite

IMA Classification of Ixiolite-(Fe2+)Hide

Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
(Ta2/3Fe2+1/3)O2
Approval year:
2022
First published:
1857
Approval history:
Redefined by IMA in 2022.
The old “ixiolite” was redefined and results now in two distinct mineral species: ixiolite-(Mn2+), with end-member formula (TaMn)O2, and ixiolite-(Fe2+), with end-member formula (TaFe)O2. The type locality for both is Skogsböle, Kimito Island, Finland.

Classification of Ixiolite-(Fe2+)Hide

4.DB.25

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
B : With medium-sized cations; chains of edge-sharing octahedra

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
Ix-Fe2+IMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Chemistry of Ixiolite-(Fe2+)Hide

Mindat Formula:
(Ta0.67Fe2+0.33)O2
Element Weights:
Element% weight
Ta70.624 %
O18.641 %
Fe10.736 %

Calculated from ideal end-member formula.

Crystallography of Ixiolite-(Fe2+)Hide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pbcn
Cell Parameters:
a = 4.785 Å, b = 5.758 Å, c = 5.160 Å
Ratio:
a:b:c = 0.831 : 1 : 0.896
Unit Cell V:
142.17 ų (Calculated from Unit Cell)
Morphology:
a = 4.785 Å, b = 5.758 Å, c = 5.160 Å
Comment:
Nickel et al. (1963) give space group Pcan (non-standard setting) and unit-cell parameters a = 5.731, b = 4.742, c = 5.152 Å. Grice et al. (1976) give space group Pbcn (non-standard setting) and the unit-cell parameters a = 4.785, b = 5.758, c = 5.160 Å (used above). Heating usually produces an ordered wodginite-type structure.

Type Occurrence of Ixiolite-(Fe2+)Hide

Place of Conservation of Type Material:
In the Royal Ontario Museum with the catalogue number M-6591 (sample investigated by Nickel et al.,1963).
Geological Setting of Type Material:
Granite pegmatite

Other Language Names for Ixiolite-(Fe2+)Hide

Relationship of Ixiolite-(Fe2+) to other SpeciesHide

Other Members of Ixiolite Group:
Ixiolite-(Mn2+)(Ta0.67Mn2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
Ixiolite-(Sc)(Ta0.5Sc0.5)O2Orth. mmm(2/m2/m2/m) : Pbcn
Nioboixiolite-(Fe2+)(Nb0.67Fe2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
Nioboixiolite-(Fe3+)(Nb0.5Fe3+0.5)O2Orth. mmm(2/m2/m2/m) : Pbcn
Nioboixiolite-(Mn2+)(Nb0.67Mn2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
Nioboixiolite-([])(Nb0.80.2)4+O2Orth. mmm(2/m2/m2/m) : Pbcn
Scrutinyiteα-PbO2Orth. mmm(2/m2/m2/m) : Pbcn
SeifertiteSiO2Orth. mmm(2/m2/m2/m) : Pbcn
SrilankiteTiO2Orth. mmm(2/m2/m2/m) : Pbcn
Forms a series with:

Related Minerals - Strunz-mindat GroupingHide

4.DB.TianhongqiiteCrTiO3(OH)Mon. 2/m
4.DB.NioboheftetjerniteScNbO4Mon. 2/m : P21/b
4.DB.HuangshaniteFe3+TaO4Mon. 2/m : P2/b
4.DB.Nioboixiolite-(Mn2+)(Nb0.67Mn2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.Shakhdaraite-(Y)ScYNb2O8Mon. 2/m : P2/b
4.DB.05VarlamoffiteSn1-xFexO2-x(OH)
4.DB.05ArgutiteGeO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05CassiteriteSnO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05RutileTiO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05PlattneritePbO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05TripuhyiteFe3+Sb5+O4Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05TugarinoviteMoO2Mon. 2/m : P21/b
4.DB.05PyrolusiteMn4+O2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.10ByströmiteMgSb2O6Tet. 4/mmm(4/m2/m2/m) : P4/nmm
4.DB.10OrdoñeziteZnSb2O6Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.10TredouxiteNiSb2O6Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.10Tapiolite-(Mn)Mn2+Ta2O6Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.10Tapiolite-(Fe)Fe2+Ta2O6Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.15aParamontroseiteV4+O2Orth. mmm(2/m2/m2/m)
4.DB.15aRamsdelliteMn4+O2Orth. mmm(2/m2/m2/m)
4.DB.15bAkhtenskiteε-Mn4+O2Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.DB.15cNsutite(Mn4+,Mn2+)(O,OH)2Hex.
4.DB.20Scrutinyiteα-PbO2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.20Nioboixiolite-([])(Nb0.80.2)4+O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25IshikawaiteU4+Fe2+Nb2O8Mon.
4.DB.25Yttrocolumbite-(Y)Y(U4+,Fe2+)Nb2O8
4.DB.25Calciosamarskite(Ca,U4+)Fe3+(Nb,Ta,Ti)2O8Orth. mmm(2/m2/m2/m)
4.DB.25Samarskite-(Yb)YbFe3+(Nb,Ta)2O8Mon. 2/m : P2/b
4.DB.25Ixiolite-(Sc)(Ta0.5Sc0.5)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25Ixiolite-(Mn2+)(Ta0.67Mn2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25Nioboixiolite-(Fe2+)(Nb0.67Fe2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25SrilankiteTiO2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25Samarskite-(Y)YFe3+Nb2O8Mon. 2/m : P2/b
4.DB.25Nioboixiolite-(Fe3+)(Nb0.5Fe3+0.5)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.30 vaWolframite Group
4.DB.30Rossovskyite(Fe3+,Ta)(Nb,Ti)O4Mon. 2/m : P2/b
4.DB.30HuanzalaiteMgWO4Mon. 2/m : P2/b
4.DB.30HeftetjerniteScTaO4Mon. 2/m : P2/b
4.DB.30HübneriteMnWO4Mon. 2/m : P2/b
4.DB.30Sanmartinite(Zn,Fe)WO4Mon. 2/m : P21/b
4.DB.30FerberiteFeWO4Mon. 2/m : P2/b
4.DB.30'Krasnoselskite'CoWO4Mon.
4.DB.35Qitianlingite(Fe,Mn)2(Nb,Ta)2WO10Orth. mmm(2/m2/m2/m)
4.DB.35Tantalaeschynite-(Ce)Ce(TiTa)O6Orth. mmm(2/m2/m2/m) : Pnma
4.DB.35Tantalite-(Mg)(Mg,Fe2+)(Ta,Nb)2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.35Columbite-(Mn)Mn2+Nb2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.35Tantalite-(Mn)Mn2+Ta2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.35Columbite-(Fe)Fe2+Nb2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.35Columbite-(Mg)(Mg,Fe,Mn)(Nb,Ta)2O6Orth.
4.DB.35Tantalite-(Fe)Fe2+Ta2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.40FerrotitanowodginiteFe2+TiTa2O8Mon. 2/m : B2/b
4.DB.40'Wolframowodginite'Mn(Mn,Sn,Fe,Ta)(W,Ta,Nb)2O8
4.DB.40LithiotantiteLiTa3O8Mon. 2/m : P21/b
4.DB.40LithiowodginiteLiTa3O8Mon. 2/m : B2/b
4.DB.40TitanowodginiteMn2+TiTa2O8Mon. 2/m : B2/b
4.DB.40Tantalowodginite(Mn2+0.50.5)TaTa2O8Mon. 2/m : B2/b
4.DB.40WodginiteMn2+Sn4+Ta2O8Mon. 2/m : B2/b
4.DB.40FerrowodginiteFe2+Sn4+Ta2O8Mon. 2/m : B2/b
4.DB.45TivaniteV3+TiO3(OH)Mon. 2/m : P21/b
4.DB.50Carmichaelite(Ti,Cr,Fe)[O2-x(OH)x]Mon. 2/m : P21/b
4.DB.55AlumotantiteAlTaO4Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.60Biehlite((Sb,As)O)2[MoO4]Mon. 2/m : B2/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Ixiolite-(Fe2+)Hide

References for Ixiolite-(Fe2+)Hide

Localities for Ixiolite-(Fe2+)Hide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Finland (TL)
 
  • Southwest Finland
    • Kimitoön (Kemiönsaari)
      • Kimitoön Island
Nordenskiöld (1857) +2 other references
 
and/or  
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