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Tredouxite

A valid IMA mineral species
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About TredouxiteHide

06806140017272473042656.jpg
Marian Tredoux
Formula:
NiSb2O6
Colour:
Light gray
Lustre:
Sub-Metallic
Hardness:
3
Crystal System:
Tetragonal
Name:
Named in honour of Marian Tredoux (20 September 1952 - 19 January 2019), professor in the Department of Geology, University of the Free State, Bloemfontein, South Africa for her work on the type locality - the Bon Accord nickel oxide deposit in the Barberton greenstone belt.
Isostructural with:
The Ni analogue of byströmite.
As subhedral to anhedral grains intergrown with bottinoite.


Unique IdentifiersHide

Mindat ID:
52170
Long-form identifier:
mindat:1:1:52170:3

IMA Classification of TredouxiteHide

Classification of TredouxiteHide

4.DB.10

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
B : With medium-sized cations; chains of edge-sharing octahedra

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
TdxIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TredouxiteHide

Sub-Metallic
Colour:
Light gray
Comment:
In polished sections
Streak:
Gray
Hardness:
Hardness:
VHN10=218 - 240 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
None Observed

Optical Data of TredouxiteHide

Anisotropism:
Very weak
Bireflectance:
Weak
Reflectivity:
WavelengthR1 (%)R2 (%)
471nm15.6% 15.8%
548nm14.6% 14.4%
586nm14.5% 14.3%
652nm14.6% 14.4%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 15.8%.
R1 shown in black, R2 shown in red
Internal Reflections:
Weak red-brown
Pleochroism:
Non-pleochroic

Chemistry of TredouxiteHide

Mindat Formula:
NiSb2O6
Element Weights:
Element% weight
Sb61.154 %
O24.107 %
Ni14.739 %

Calculated from ideal end-member formula.
Sb
O
Ni

Crystallography of TredouxiteHide

Crystal System:
Tetragonal
Class (H-M):
4/mmm(4/m2/m2/m) - Ditetragonal Dipyramidal
Space Group:
P42/mnm
Setting:
P42/mnm
Cell Parameters:
a = 4.6324(5) Å, c = 9.2154(8) Å
Ratio:
a:c = 1 : 1.989
Unit Cell V:
197.91 ų
Z:
2
Morphology:
Subhedral to anhedral grains

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):

Type Occurrence of TredouxiteHide

General Appearance of Type Material:
Subhedral to anhedral grains from 10 to 500μm
Place of Conservation of Type Material:
Mineralogical collections of the Museo di Storia Naturale, University of Florence, Florence, Italy, catalogue number 3281/I
Associated Minerals at Type Locality:

Synonyms of TredouxiteHide

Other Language Names for TredouxiteHide

German:Tredouxit

Relationship of Tredouxite to other SpeciesHide

Other Members of Byströmite Group:
ByströmiteMgSb2O6Tet. 4/mmm(4/m2/m2/m) : P4/nmm
OrdoñeziteZnSb2O6Tet. 4/mmm(4/m2/m2/m) : P42/mnm

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Tredouxite associated with TrevoriteNi2+Fe3+2O4
2 photos of Tredouxite associated with WillemseiteNi3Si4O10(OH)2

Related Minerals - Strunz-mindat GroupingHide

4.DB.TianhongqiiteCrTiO3(OH)Mon. 2/m
4.DB.NioboheftetjerniteScNbO4Mon. 2/m : P21/b
4.DB.HuangshaniteFe3+TaO4Mon. 2/m : P2/b
4.DB.Nioboixiolite-(Mn2+)(Nb0.67Mn2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.Shakhdaraite-(Y)ScYNb2O8Mon. 2/m : P2/b
4.DB.05VarlamoffiteSn1-xFexO2-x(OH)
4.DB.05ArgutiteGeO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05CassiteriteSnO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05RutileTiO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05PlattneritePbO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05TripuhyiteFe3+Sb5+O4Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05TugarinoviteMoO2Mon. 2/m : P21/b
4.DB.05PyrolusiteMn4+O2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.10ByströmiteMgSb2O6Tet. 4/mmm(4/m2/m2/m) : P4/nmm
4.DB.10OrdoñeziteZnSb2O6Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.10Tapiolite-(Mn)Mn2+Ta2O6Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.10Tapiolite-(Fe)Fe2+Ta2O6Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.15aParamontroseiteV4+O2Orth. mmm(2/m2/m2/m)
4.DB.15aRamsdelliteMn4+O2Orth. mmm(2/m2/m2/m)
4.DB.15bAkhtenskiteε-Mn4+O2Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.DB.15cNsutite(Mn4+,Mn2+)(O,OH)2Hex.
4.DB.20Scrutinyiteα-PbO2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.20Nioboixiolite-([])(Nb0.80.2)4+O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25IshikawaiteU4+Fe2+Nb2O8Mon.
4.DB.25Yttrocolumbite-(Y)Y(U4+,Fe2+)Nb2O8
4.DB.25Calciosamarskite(Ca,U4+)Fe3+(Nb,Ta,Ti)2O8Orth. mmm(2/m2/m2/m)
4.DB.25Samarskite-(Yb)YbFe3+(Nb,Ta)2O8Mon. 2/m : P2/b
4.DB.25Ixiolite-(Sc)(Ta0.5Sc0.5)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25Ixiolite-(Fe2+)(Ta0.67Fe2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25Ixiolite-(Mn2+)(Ta0.67Mn2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25Nioboixiolite-(Fe2+)(Nb0.67Fe2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25SrilankiteTiO2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25Samarskite-(Y)YFe3+Nb2O8Mon. 2/m : P2/b
4.DB.25Nioboixiolite-(Fe3+)(Nb0.5Fe3+0.5)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.30 vaWolframite Group
4.DB.30Rossovskyite(Fe3+,Ta)(Nb,Ti)O4Mon. 2/m : P2/b
4.DB.30HuanzalaiteMgWO4Mon. 2/m : P2/b
4.DB.30HeftetjerniteScTaO4Mon. 2/m : P2/b
4.DB.30HübneriteMnWO4Mon. 2/m : P2/b
4.DB.30Sanmartinite(Zn,Fe)WO4Mon. 2/m : P21/b
4.DB.30FerberiteFeWO4Mon. 2/m : P2/b
4.DB.30'Krasnoselskite'CoWO4Mon.
4.DB.35Qitianlingite(Fe,Mn)2(Nb,Ta)2WO10Orth. mmm(2/m2/m2/m)
4.DB.35Tantalaeschynite-(Ce)Ce(TiTa)O6Orth. mmm(2/m2/m2/m) : Pnma
4.DB.35Tantalite-(Mg)(Mg,Fe2+)(Ta,Nb)2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.35Columbite-(Mn)Mn2+Nb2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.35Tantalite-(Mn)Mn2+Ta2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.35Columbite-(Fe)Fe2+Nb2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.35Columbite-(Mg)(Mg,Fe,Mn)(Nb,Ta)2O6Orth.
4.DB.35Tantalite-(Fe)Fe2+Ta2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.40FerrotitanowodginiteFe2+TiTa2O8Mon. 2/m : B2/b
4.DB.40'Wolframowodginite'Mn(Mn,Sn,Fe,Ta)(W,Ta,Nb)2O8
4.DB.40LithiotantiteLiTa3O8Mon. 2/m : P21/b
4.DB.40LithiowodginiteLiTa3O8Mon. 2/m : B2/b
4.DB.40TitanowodginiteMn2+TiTa2O8Mon. 2/m : B2/b
4.DB.40Tantalowodginite(Mn2+0.50.5)TaTa2O8Mon. 2/m : B2/b
4.DB.40WodginiteMn2+Sn4+Ta2O8Mon. 2/m : B2/b
4.DB.40FerrowodginiteFe2+Sn4+Ta2O8Mon. 2/m : B2/b
4.DB.45TivaniteV3+TiO3(OH)Mon. 2/m : P21/b
4.DB.50Carmichaelite(Ti,Cr,Fe)[O2-x(OH)x]Mon. 2/m : P21/b
4.DB.55AlumotantiteAlTaO4Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.60Biehlite((Sb,As)O)2[MoO4]Mon. 2/m : B2/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for TredouxiteHide

References for TredouxiteHide

Localities for TredouxiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
South Africa (TL)
 
  • Mpumalanga
    • Ehlanzeni District Municipality
      • Mbombela Local Municipality
        • Barberton
Hålenius et al. (2017) +1 other reference
 
and/or  
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