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Lithiotantite

A valid IMA mineral species
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About LithiotantiteHide

Formula:
LiTa3O8
Colour:
Colourless
Lustre:
Adamantine
Hardness:
6 - 6½
Specific Gravity:
7.0
Crystal System:
Monoclinic
Name:
Named for its composition, containing LITHIum and TANTalum.
Dimorph of:
Corresponds to the low-temperature form of synthetic LiTa3O8.


Unique IdentifiersHide

Mindat ID:
2390
Long-form identifier:
mindat:1:1:2390:6

IMA Classification of LithiotantiteHide

Classification of LithiotantiteHide

4.DB.40

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
B : With medium-sized cations; chains of edge-sharing octahedra
8.7.7.1

8 : MULTIPLE OXIDES CONTAINING NIOBIUM,TANTALUM OR TITANIUM
7 : Miscellaneous
18.1.1

18 : Niobates and Tantalates
1 : Niobates and tantalates containing neither rare earths nor U

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
LtanIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of LithiotantiteHide

Adamantine
Transparency:
Transparent
Colour:
Colourless
Comment:
creamy pink to brownish pink when included by cassiterite
Streak:
White
Hardness:
6 - 6½ on Mohs scale
Hardness:
VHN40=1200 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven, Conchoidal
Density:
7.0 g/cm3 (Measured)    7.08 g/cm3 (Calculated)

Optical Data of LithiotantiteHide

Type:
Biaxial
Anisotropism:
Weak
Dispersion:
Strong
Reflectivity:
WavelengthR1 (%)R2 (%)
486nm18.6%18.5%
553nm18.5%18.3%
589nm18.6%18.3%
656nm19.1%19.0%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 19.1%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Grayish-white
Pleochroism:
Non-pleochroic
Comments:
n = >1.9

Chemistry of LithiotantiteHide

Mindat Formula:
LiTa3O8
Element Weights:
Element% weight
Ta80.091 %
O18.885 %
Li1.024 %

Calculated from ideal end-member formula.
Ta
O
Li

Crystallography of LithiotantiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 7.444 Å, b = 5.044 Å, c = 15.255 Å
β = 107.18°
Ratio:
a:b:c = 1.476 : 1 : 3.024
Unit Cell V:
547.23 ų (Calculated from Unit Cell)
Z:
4

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0018780LithiotantiteMenezes L A D, Yang H, Downs R T, Chaves M L S C, Persiano A C (2012) Lithiotantite, ideally LiTa3O8 Acta Crystallographica E68 i27-i282012Murundu mine, the Jenipapo District, Itinga, Minas Gerais, Brazil0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.96 Å(100)
1.722 Å(80)
1.451 Å(80)
1.772 Å(60b)
4.13 Å(50)
2.490 Å(50)
1.900 Å(50)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites

Type Occurrence of LithiotantiteHide

General Appearance of Type Material:
Equant, poorly formed crystals up to 0.4 mm.
Place of Conservation of Type Material:
Mining Institute, St. Petersburg, Russia, 1655/1.
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 82543.
Geological Setting of Type Material:
Granite pegmatite
Associated Minerals at Type Locality:

Synonyms of LithiotantiteHide

Other Language Names for LithiotantiteHide

Relationship of Lithiotantite to other SpeciesHide

Other Members of Wodginite Group:
Achalaite(Fe2+,Mn)(Ti,Fe3+,Ta)(Nb,Ta)2O8Mon. 2/m : B2/b
FerrotitanowodginiteFe2+TiTa2O8Mon. 2/m : B2/b
FerrowodginiteFe2+Sn4+Ta2O8Mon. 2/m : B2/b
LithiowodginiteLiTa3O8Mon. 2/m : B2/b
Tantalowodginite(Mn2+0.50.5)TaTa2O8Mon. 2/m : B2/b
TitanowodginiteMn2+TiTa2O8Mon. 2/m : B2/b
WodginiteMn2+Sn4+Ta2O8Mon. 2/m : B2/b

Common AssociatesHide

Associations Based on Photo Data:
6 photos of Lithiotantite associated with CassiteriteSnO2
5 photos of Lithiotantite associated with AlbiteNa(AlSi3O8)
5 photos of Lithiotantite associated with ThoreauliteSn2+Ta2O6
4 photos of Lithiotantite associated with Rankamaite(Na,K)3(Ta,Nb,Al)11(O,OH)31
1 photo of Lithiotantite associated with WodginiteMn2+Sn4+Ta2O8

Related Minerals - Strunz-mindat GroupingHide

4.DB.TianhongqiiteCrTiO3(OH)Mon. 2/m
4.DB.NioboheftetjerniteScNbO4Mon. 2/m : P21/b
4.DB.HuangshaniteFe3+TaO4Mon. 2/m : P2/b
4.DB.Nioboixiolite-(Mn2+)(Nb0.67Mn2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.Shakhdaraite-(Y)ScYNb2O8Mon. 2/m : P2/b
4.DB.05VarlamoffiteSn1-xFexO2-x(OH)
4.DB.05ArgutiteGeO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05CassiteriteSnO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05RutileTiO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05PlattneritePbO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05TripuhyiteFe3+Sb5+O4Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.05TugarinoviteMoO2Mon. 2/m : P21/b
4.DB.05PyrolusiteMn4+O2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.10ByströmiteMgSb2O6Tet. 4/mmm(4/m2/m2/m) : P4/nmm
4.DB.10OrdoñeziteZnSb2O6Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.10TredouxiteNiSb2O6Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.10Tapiolite-(Mn)Mn2+Ta2O6Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.10Tapiolite-(Fe)Fe2+Ta2O6Tet. 4/mmm(4/m2/m2/m) : P42/mnm
4.DB.15aParamontroseiteV4+O2Orth. mmm(2/m2/m2/m)
4.DB.15aRamsdelliteMn4+O2Orth. mmm(2/m2/m2/m)
4.DB.15bAkhtenskiteε-Mn4+O2Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.DB.15cNsutite(Mn4+,Mn2+)(O,OH)2Hex.
4.DB.20Scrutinyiteα-PbO2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.20Nioboixiolite-([])(Nb0.80.2)4+O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25IshikawaiteU4+Fe2+Nb2O8Mon.
4.DB.25Yttrocolumbite-(Y)Y(U4+,Fe2+)Nb2O8
4.DB.25Calciosamarskite(Ca,U4+)Fe3+(Nb,Ta,Ti)2O8Orth. mmm(2/m2/m2/m)
4.DB.25Samarskite-(Yb)YbFe3+(Nb,Ta)2O8Mon. 2/m : P2/b
4.DB.25Ixiolite-(Sc)(Ta0.5Sc0.5)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25Ixiolite-(Fe2+)(Ta0.67Fe2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25Ixiolite-(Mn2+)(Ta0.67Mn2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25Nioboixiolite-(Fe2+)(Nb0.67Fe2+0.33)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25SrilankiteTiO2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.25Samarskite-(Y)YFe3+Nb2O8Mon. 2/m : P2/b
4.DB.25Nioboixiolite-(Fe3+)(Nb0.5Fe3+0.5)O2Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.30 vaWolframite Group
4.DB.30Rossovskyite(Fe3+,Ta)(Nb,Ti)O4Mon. 2/m : P2/b
4.DB.30HuanzalaiteMgWO4Mon. 2/m : P2/b
4.DB.30HeftetjerniteScTaO4Mon. 2/m : P2/b
4.DB.30HübneriteMnWO4Mon. 2/m : P2/b
4.DB.30Sanmartinite(Zn,Fe)WO4Mon. 2/m : P21/b
4.DB.30FerberiteFeWO4Mon. 2/m : P2/b
4.DB.30'Krasnoselskite'CoWO4Mon.
4.DB.35Qitianlingite(Fe,Mn)2(Nb,Ta)2WO10Orth. mmm(2/m2/m2/m)
4.DB.35Tantalaeschynite-(Ce)Ce(TiTa)O6Orth. mmm(2/m2/m2/m) : Pnma
4.DB.35Tantalite-(Mg)(Mg,Fe2+)(Ta,Nb)2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.35Columbite-(Mn)Mn2+Nb2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.35Tantalite-(Mn)Mn2+Ta2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.35Columbite-(Fe)Fe2+Nb2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.35Columbite-(Mg)(Mg,Fe,Mn)(Nb,Ta)2O6Orth.
4.DB.35Tantalite-(Fe)Fe2+Ta2O6Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.40FerrotitanowodginiteFe2+TiTa2O8Mon. 2/m : B2/b
4.DB.40'Wolframowodginite'Mn(Mn,Sn,Fe,Ta)(W,Ta,Nb)2O8
4.DB.40LithiowodginiteLiTa3O8Mon. 2/m : B2/b
4.DB.40TitanowodginiteMn2+TiTa2O8Mon. 2/m : B2/b
4.DB.40Tantalowodginite(Mn2+0.50.5)TaTa2O8Mon. 2/m : B2/b
4.DB.40WodginiteMn2+Sn4+Ta2O8Mon. 2/m : B2/b
4.DB.40FerrowodginiteFe2+Sn4+Ta2O8Mon. 2/m : B2/b
4.DB.45TivaniteV3+TiO3(OH)Mon. 2/m : P21/b
4.DB.50Carmichaelite(Ti,Cr,Fe)[O2-x(OH)x]Mon. 2/m : P21/b
4.DB.55AlumotantiteAlTaO4Orth. mmm(2/m2/m2/m) : Pbcn
4.DB.60Biehlite((Sb,As)O)2[MoO4]Mon. 2/m : B2/b

Fluorescence of LithiotantiteHide

Other InformationHide

Notes:
Weak yellow-green cathodoluminescence.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for LithiotantiteHide

References for LithiotantiteHide

Localities for LithiotantiteHide

Showing 6 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Brazil
 
  • Minas Gerais
    • Itinga
specimen from Luis Menezes
Menezes Filho et al. (2012) +1 other reference
DR Congo
 
  • Tanganyika
Pavel M. Kartashov analythical data of ...
Kazakhstan
 
  • East Kazakhstan Region
    • Irtysh River
Pekov (1998)
    • Ulan District
Voloshin et al. (1983) +1 other reference
Spain
 
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • Tenerife
        • Granadilla de Abona
Dill et al. (2023)
 
and/or  
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