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Unnamed (Ga-analogue of Epidote)

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Formula:
(CaCa)(AlAlGa3+)O[Si2O7][SiO4](OH)
The first silicate mineral with species-defining gallium. Author's proposed name is "epidote-(Ga)". As inclusions in sphalerite (common), more rarely in galena and pyrite; also rarely between quartz and sulfides. Confirmed by EPMA, Raman spectroscopy, stoichiometry, and habit.
The zonal grains are elongated, somewhat rounded or well-shaped, up to 100 microns in length. The "epidote-(Ga)" forms cores, which contain 6-20 wt.% Ga2O3. This is followed by Gallian Allanite-(Ce), relatively Ga-low allanite-(Ce), and Ga-devoid epidote-allanite.


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Unique IdentifiersHide

Mindat ID:
47652
Long-form identifier:
mindat:1:1:47652:8

Classification of Unnamed (Ga-analogue of Epidote)Hide

Strunz-mindat (2026):
9.BG.05a v

9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination

Chemistry of Unnamed (Ga-analogue of Epidote)Hide

Mindat Formula:
(CaCa)(AlAlGa3+)O[Si2O7][SiO4](OH)
Element Weights:
Element% weight
O41.841 %
Si16.950 %
Ca16.125 %
Ga14.026 %
Al10.856 %
H0.203 %

Calculated from ideal end-member formula.
Elements listed:
Al, Ca, Ga, H, O, Si - search for minerals with similar chemistry

Synonyms of Unnamed (Ga-analogue of Epidote)Hide

Relationship of Unnamed (Ga-analogue of Epidote) to other SpeciesHide

Member of:
Epidote Group > Epidote Supergroup
Other Members of Epidote Group:
Clinozoisite(CaCa)(AlAlAl)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Epidote(CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Epidote-(Sr)(CaSr)(AlAlFe3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Hancockite(CaPb)(AlAlFe3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Heflikite(CaCa)(AlAlSc)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Mukhinite(CaCa)(AlAlV3+)O[Si2O7][SiO4](OH)Mon.
Niigataite(CaSr)(AlAlAl)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Piemontite(CaCa)(AlAlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Piemontite-(Pb)(CaPb)(AlAlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Piemontite-(Sr)(CaSr)(AlAlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Tweddillite(CaSr)(Mn3+AlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
'Unnamed (Fe3+ analogue of Piemontite-(Pb))'(CaPb)(Fe3+AlMn3+)O[Si2O7][SiO4](OH)
'Unnamed (Fe3+-analogue of Piemontite)'(CaCa)(Fe3+AlMn3+)O[Si2O7][SiO4](OH)
'Unnamed (Fe3+-analogue of Piemontite-(Sr))'(CaSr)(Fe3+AlMn3+)O[Si2O7][SiO4](OH)

Related Minerals - Strunz-mindat GroupingHide

9.BG.AlumovesuvianiteCa19AlAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9Tet. 4/m : P4/n
9.BG.Alnaperbøeite-(Ce)Ca(Ce2.5Na0.5)(AlAl2Al)[Si2O7][SiO4]3O(OH)2Mon. 2/m : P21/m
9.BG.Zilbermintsite-(La)(CaLa5)(Fe3+Al3Fe2+)[Si2O7][SiO4]5O(OH)3Mon. 2/m : P21/m
9.BG.Heflikite(CaCa)(AlAlSc)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.MagnesiovesuvianiteCa19MgAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9Tet. 4/m : P4/n
9.BG.Zoisite-(Pb)(CaPb)(AlAlAl)O[Si2O7][SiO4](OH)Orth. mmm (2/m 2/m 2/m) : Pnma
9.BG.Shuiskite-(Cr)Ca2Cr3+Cr3+2[Si2O6OH][SiO4](OH)2OMon. 2/m : B2/m
9.BG.Radekškodaite Group
9.BG.05Dissakisite-(La)(CaLa)(AlAlMg)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Manganiandrosite-(Ce)(Mn2+Ce)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bDissakisite-(Ce)(CaCe)(AlAlMg)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(Sm)(CaSm)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05aHancockite(CaPb)(AlAlFe3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Dollaseite-(Ce)(CaCe)(MgAlMg)F[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05aClinozoisite(CaCa)(AlAlAl)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05aEpidote-(Sr)(CaSr)(AlAlFe3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Vanadoandrosite-(Ce)(Mn2+Ce)(V3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bVanadoallanite-(La)(CaLa)(V3+AlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05b'Unnamed (Mg-analogue of Ferriallanite-(Ce))'(CaCe)(Fe3+AlMg)O[Si2O7][SiO4](OH)
9.BG.05bFerriallanite-(La)(CaLa)(Fe3+AlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Uedaite-(Ce)(Mn2+Ce)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05aEpidote(CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Tweddillite(CaSr)(Mn3+AlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bÅskagenite-(Nd)(Mn2+Nd)(AlAlFe3+)O[Si2O7][SiO4]OMon. 2/m : P21/m
9.BG.05Piemontite-(Pb)(CaPb)(AlAlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(Ce)(CaCe)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(La)(CaLa)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(Y)(CaY)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05aPiemontite(CaCa)(AlAlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAkasakaite-(Ce)(CaCe)(AlAlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bManganiandrosite-(La)(Mn2+La)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAkasakaite-(La)(CaLa)(AlAlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bVanadoakasakaite-(La)(CaLa)(V3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Khristovite-(Ce)(CaCe)(MgAlMn2+)F[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bFerriakasakaite-(La)(CaLa)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Ferriandrosite-(La)(Mn2+La)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05'Androsite-(Ce)'(Mn2+Ce)(AlAlMn2+)O[Si2O7][SiO4](OH)
9.BG.05Vielleaureite-(Ce)Mn2+Ce(MgAlMn2+)(Si2O7)(SiO4)F(OH)Mon. 2/m : P21/m
9.BG.05Ferriandrosite-(Ce)(Mn2+Ce)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bFerriallanite-(Ce)(CaCe)(Fe3+AlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05b'Unnamed (Mn3+-analogue of Ferriakasakaite-(Ce))'(CaCe)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)
9.BG.05bVanadoakasakaite-(Ce)(CaCe)(V3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Piemontite-(Sr)(CaSr)(AlAlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Niigataite(CaSr)(AlAlAl)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bFerriakasakaite-(Ce)(CaCe)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(Nd)(CaNd)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05b'UM1989-32-SiO:AlCaFeHREE'(Ca0.5◻0.5REE)(AlAlFe3+)O[Si2O7][SiO4](OH)
9.BG.05aMukhinite(CaCa)(AlAlV3+)O[Si2O7][SiO4](OH)Mon.
9.BG.05bManganiakasakaite-(La)(CaLa)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.10Zoisite(CaCa)(AlAlAl)O[Si2O7][SiO4](OH)Orth. mmm (2/m 2/m 2/m) : Pnma
9.BG.15MacfalliteCa2Mn3+3(SiO4)(Si2O7)(OH)3Mon. 2/m : P21/m
9.BG.15SursassiteMn2+2Al3(SiO4)(Si2O7)(OH)3Mon. 2/m : P21/m
9.BG.20Pumpellyite-(Al)Ca2AlAl2[Si2O6OH][SiO4](OH)2OMon. 2/m
9.BG.20Shuiskite-(Mg)Ca2MgCr3+2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.20Julgoldite-(Fe2+)Ca2Fe2+Fe3+2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.20OkhotskiteCa2Mn2+Mn3+2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.20Julgoldite-(Mg)Ca2MgFe3+2[Si2O6OH][SiO4](OH)2(OH)Mon.
9.BG.20PoppiiteCa2V3+V3+2[Si2O6OH][SiO4](OH)2OMon. 2/m : B2/m
9.BG.20Julgoldite-(Fe3+)Ca2Fe3+Fe3+2[Si2O6OH][SiO4](OH)2OMon.
9.BG.20Pumpellyite-(Fe2+)Ca2Fe2+Al2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.20Pumpellyite-(Fe3+)Ca2Fe3+Al2[Si2O6OH][SiO4](OH)2OMon. 2/m
9.BG.20Pumpellyite-(Mg)Ca2MgAl2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.20Pumpellyite-(Mn2+)Ca2Mn2+Al2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.25GanomalitePb9Ca5Mn(Si2O7)4(SiO4)OHex. 6 : P6
9.BG.25WayneburnhamitePb9Ca6(Si2O7)3(SiO4)3Hex. 6 : P6
9.BG.30RustumiteCa10(Si2O7)2(SiO4)(OH)2Cl2Mon. 2/m : B2/b
9.BG.35ModraiteCa19Fe2+Al4(Al6Fe2+2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc
9.BG.35FluorvesuvianiteCa19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(F,OH)9Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc
9.BG.35VesuvianiteCa19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc
9.BG.35Milanriederite(Ca18[REE])Fe3+Al4(Mg4Al4)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc
9.BG.35Manaevite-(Ce)(Ca13Ce4[H2O]2)Mg(Al3Mg)(Mg3Ti3Fe3+2)(◻4)◻[Si2O7]4[(SiO4)8(H4O4)2]O(OH)9Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc
9.BG.35HongheiteCa19Fe2+Al4(Fe3+,Mg)8(◻4)B[Si2O7]4[(SiO4)10]O(OH,O)9Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc
9.BG.35WiluiteCa19MgAl4(Al,Mg)8(B,◻)4◻[Si2O7]4[(SiO4)10]O(O,OH)9Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc
9.BG.35CyprineCa19Cu2+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9Tet. 4/m : P4/n
9.BG.35ManganvesuvianiteCa19Mn3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9Tet. 4/m : P4/n
9.BG.40Vyuntspakhkite-(Y)(Y,Yb)4Al2.5-1.5(Si,Al)1.5-2.5(SiO4)4O(OH)7Mon.
9.BG.45DellaiteCa6Si3O11(OH)2Tric.
9.BG.50Ferriperbøeite-(Ce)CaCe3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2Mon. 2/m : P21/m
9.BG.50Perbøeite-(La)CaLa3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 Mon. 2/m : P21/m
9.BG.50Perbøeite-(Ce)CaCe3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 Mon. 2/m : P21/m
9.BG.50Gatelite-(Ce)CaCe3(AlAl2Mg)[Si2O7][SiO4]3O(OH)2Mon. 2/m : P21/b
9.BG.50Ferriperbøeite-(La) CaLa3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2Mon. 2/m : P21/m
9.BG.55Västmanlandite-(Ce)CaCe3(MgAl2Mg)[Si2O7][SiO4]3F(OH)2Mon. 2/m : P21/m
9.BG.60Radekškodaite-(La) (CaLa5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3Mon. 2/m : P21/m
9.BG.60Radekškodaite-(Ce)(CaCe5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3Mon. 2/m : P21/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Unnamed (Ga-analogue of Epidote)Hide

References for Unnamed (Ga-analogue of Epidote)Hide

Localities for Unnamed (Ga-analogue of Epidote)Hide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia
 
  • Khanty-Mansi Autonomous Okrug
    • Berezovo district
Varlamov et al. (2019) +1 other reference
Soboleva et al. (2011)
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