Okhotskite
A valid IMA mineral species
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About Okhotskite
Formula:
Ca2Mn2+Mn3+2[Si2O6OH][SiO4](OH)2(OH)
Colour:
Deep orange
Lustre:
Vitreous
Hardness:
6
Specific Gravity:
3.40 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
Named for the Sea of Okhotsk, located near the type locality.
Unique Identifiers
Mindat ID:
2968
Long-form identifier:
mindat:1:1:2968:7
Similar Names
| Okhotskite-(Mg) | Valid as an unnamed mineral | Ca8(Mn2+,Mg)(Mn3+,Al,Fe3+)(SiO4)(Si2O7)(OH)2 · H2O |
IMA Classification of Okhotskite
Approved
IMA Formula:
Ca2Mn2+Mn3+2(Si2O7)(SiO4)(OH)2·H2O
Approval year:
1985
First published:
1987
Classification of Okhotskite
9.BG.20
9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
16.16.23
16 : Silicates Containing Aluminum and other Metals
16 : Aluminosilicates of Mn
16 : Silicates Containing Aluminum and other Metals
16 : Aluminosilicates of Mn
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Okh | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Okhotskite
Vitreous
Transparency:
Transparent
Colour:
Deep orange
Streak:
Pale orange
Hardness:
6 on Mohs scale
Cleavage:
Distinct/Good
One set observed in thin section.
One set observed in thin section.
Density:
3.40 g/cm3 (Calculated)
Optical Data of Okhotskite
Type:
Biaxial (-)
RI values:
nα = 1.782(5) nβ = 1.820(5) nγ = 1.827(5)
2V:
Measured: 46° (5), Calculated: 46°
Max. Birefringence:
δ = 0.045
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
indiscernible
Pleochroism:
Strong
Comments:
X = yellow, Y and Z = deep orange, X < Y < Z.
Chemistry of Okhotskite
Mindat Formula:
Ca2Mn2+Mn3+2[Si2O6OH][SiO4](OH)2(OH)
Element Weights:
Common Impurities:
Ti,Na,K
Crystallography of Okhotskite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 8.887(5) Å, b = 6.000(4) Å, c = 19.53(2) Å
β = 97.08(6)°
β = 97.08(6)°
Ratio:
a:b:c = 1.481 : 1 : 3.255
Unit Cell V:
1,033.44 ų (Calculated from Unit Cell)
Z:
4
Comment:
Space Group: A2/m; by analogy to the pumpellyite group
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 2.961 Å | (100) |
| 3.87 Å | (70) |
| 2.720 Å | (70) |
| 4.76 Å | (60) |
| 2.665 Å | (45) |
| 2.553 Å | (45) |
| 2.384 Å | (45) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Near-surface Processes | |
| 22 : Hydration and low-? subsurface aqueous alteration (see also #23) |
Type Occurrence of Okhotskite
General Appearance of Type Material:
long prismatic crystals
Place of Conservation of Type Material:
Unknown
Synonyms of Okhotskite
Other Language Names for Okhotskite
Relationship of Okhotskite to other Species
Member of:
Other Members of Pumpellyite Group:
| Julgoldite Subgroup | Ca2XFe3+2[Si2O6(OH)][SiO4](OH)2A | |
| Poppiite | Ca2V3+V3+2[Si2O6OH][SiO4](OH)2O | Mon. 2/m : B2/m |
| Pumpellyite Subgroup | Ca2XAl2[Si2O6(OH)][SiO4](OH)2A | |
| Shuiskite Subgroup | Ca2XCr3+2[Si2O6(OH)][SiO4](OH)2A |
Related Minerals - Strunz-mindat Grouping
| 9.BG. | Alumovesuvianite | Ca19AlAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
| 9.BG. | Alnaperbøeite-(Ce) | Ca(Ce2.5Na0.5)(AlAl2Al)[Si2O7][SiO4]3O(OH)2 |
| 9.BG. | Zilbermintsite-(La) | (CaLa5)(Fe3+Al3Fe2+)[Si2O7][SiO4]5O(OH)3 |
| 9.BG. | Heflikite | (CaCa)(AlAlSc)O[Si2O7][SiO4](OH) |
| 9.BG. | Magnesiovesuvianite | Ca19MgAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
| 9.BG. | Zoisite-(Pb) | (CaPb)(AlAlAl)O[Si2O7][SiO4](OH) |
| 9.BG. | Shuiskite-(Cr) | Ca2Cr3+Cr3+2[Si2O6OH][SiO4](OH)2O |
| 9.BG. | Radekškodaite Group | |
| 9.BG.05 | Dissakisite-(La) | (CaLa)(AlAlMg)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Manganiandrosite-(Ce) | (Mn2+Ce)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Dissakisite-(Ce) | (CaCe)(AlAlMg)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Allanite-(Sm) | (CaSm)(AlAlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05a | Hancockite | (CaPb)(AlAlFe3+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Dollaseite-(Ce) | (CaCe)(MgAlMg)F[Si2O7][SiO4](OH) |
| 9.BG.05a v | 'Unnamed (Ga-analogue of Epidote)' | (CaCa)(AlAlGa3+)O[Si2O7][SiO4](OH) |
| 9.BG.05a | Clinozoisite | (CaCa)(AlAlAl)O[Si2O7][SiO4](OH) |
| 9.BG.05a | Epidote-(Sr) | (CaSr)(AlAlFe3+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Vanadoandrosite-(Ce) | (Mn2+Ce)(V3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Vanadoallanite-(La) | (CaLa)(V3+AlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | 'Unnamed (Mg-analogue of Ferriallanite-(Ce))' | (CaCe)(Fe3+AlMg)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Ferriallanite-(La) | (CaLa)(Fe3+AlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Uedaite-(Ce) | (Mn2+Ce)(AlAlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05a | Epidote | (CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Tweddillite | (CaSr)(Mn3+AlMn3+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Åskagenite-(Nd) | (Mn2+Nd)(AlAlFe3+)O[Si2O7][SiO4]O |
| 9.BG.05 | Piemontite-(Pb) | (CaPb)(AlAlMn3+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Allanite-(Ce) | (CaCe)(AlAlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Allanite-(La) | (CaLa)(AlAlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Allanite-(Y) | (CaY)(AlAlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05a | Piemontite | (CaCa)(AlAlMn3+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Akasakaite-(Ce) | (CaCe)(AlAlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Manganiandrosite-(La) | (Mn2+La)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Akasakaite-(La) | (CaLa)(AlAlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Vanadoakasakaite-(La) | (CaLa)(V3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Khristovite-(Ce) | (CaCe)(MgAlMn2+)F[Si2O7][SiO4](OH) |
| 9.BG.05b | Ferriakasakaite-(La) | (CaLa)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Ferriandrosite-(La) | (Mn2+La)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | 'Androsite-(Ce)' | (Mn2+Ce)(AlAlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Vielleaureite-(Ce) | Mn2+Ce(MgAlMn2+)(Si2O7)(SiO4)F(OH) |
| 9.BG.05 | Ferriandrosite-(Ce) | (Mn2+Ce)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Ferriallanite-(Ce) | (CaCe)(Fe3+AlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | 'Unnamed (Mn3+-analogue of Ferriakasakaite-(Ce))' | (CaCe)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Vanadoakasakaite-(Ce) | (CaCe)(V3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Piemontite-(Sr) | (CaSr)(AlAlMn3+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Niigataite | (CaSr)(AlAlAl)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Ferriakasakaite-(Ce) | (CaCe)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Allanite-(Nd) | (CaNd)(AlAlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | 'UM1989-32-SiO:AlCaFeHREE' | (Ca0.5◻0.5REE)(AlAlFe3+)O[Si2O7][SiO4](OH) |
| 9.BG.05a | Mukhinite | (CaCa)(AlAlV3+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Manganiakasakaite-(La) | (CaLa)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.10 | Zoisite | (CaCa)(AlAlAl)O[Si2O7][SiO4](OH) |
| 9.BG.15 | Macfallite | Ca2Mn3+3(SiO4)(Si2O7)(OH)3 |
| 9.BG.15 | Sursassite | Mn2+2Al3(SiO4)(Si2O7)(OH)3 |
| 9.BG.20 | Pumpellyite-(Al) | Ca2AlAl2[Si2O6OH][SiO4](OH)2O |
| 9.BG.20 | Shuiskite-(Mg) | Ca2MgCr3+2[Si2O6OH][SiO4](OH)2(OH) |
| 9.BG.20 | Julgoldite-(Fe2+) | Ca2Fe2+Fe3+2[Si2O6OH][SiO4](OH)2(OH) |
| 9.BG.20 | Julgoldite-(Mg) | Ca2MgFe3+2[Si2O6OH][SiO4](OH)2(OH) |
| 9.BG.20 | Poppiite | Ca2V3+V3+2[Si2O6OH][SiO4](OH)2O |
| 9.BG.20 | Julgoldite-(Fe3+) | Ca2Fe3+Fe3+2[Si2O6OH][SiO4](OH)2O |
| 9.BG.20 | Pumpellyite-(Fe2+) | Ca2Fe2+Al2[Si2O6OH][SiO4](OH)2(OH) |
| 9.BG.20 | Pumpellyite-(Fe3+) | Ca2Fe3+Al2[Si2O6OH][SiO4](OH)2O |
| 9.BG.20 | Pumpellyite-(Mg) | Ca2MgAl2[Si2O6OH][SiO4](OH)2(OH) |
| 9.BG.20 | Pumpellyite-(Mn2+) | Ca2Mn2+Al2[Si2O6OH][SiO4](OH)2(OH) |
| 9.BG.25 | Ganomalite | Pb9Ca5Mn(Si2O7)4(SiO4)O |
| 9.BG.25 | Wayneburnhamite | Pb9Ca6(Si2O7)3(SiO4)3 |
| 9.BG.30 | Rustumite | Ca10(Si2O7)2(SiO4)(OH)2Cl2 |
| 9.BG.35 | Modraite | Ca19Fe2+Al4(Al6Fe2+2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
| 9.BG.35 | Fluorvesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(F,OH)9 |
| 9.BG.35 | Vesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
| 9.BG.35 | Milanriederite | (Ca18[REE])Fe3+Al4(Mg4Al4)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
| 9.BG.35 | Manaevite-(Ce) | (Ca13Ce4[H2O]2)Mg(Al3Mg)(Mg3Ti3Fe3+2)(◻4)◻[Si2O7]4[(SiO4)8(H4O4)2]O(OH)9 |
| 9.BG.35 | Hongheite | Ca19Fe2+Al4(Fe3+,Mg)8(◻4)B[Si2O7]4[(SiO4)10]O(OH,O)9 |
| 9.BG.35 | Wiluite | Ca19MgAl4(Al,Mg)8(B,◻)4◻[Si2O7]4[(SiO4)10]O(O,OH)9 |
| 9.BG.35 | Cyprine | Ca19Cu2+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
| 9.BG.35 | Manganvesuvianite | Ca19Mn3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
| 9.BG.40 | Vyuntspakhkite-(Y) | (Y,Yb)4Al2.5-1.5(Si,Al)1.5-2.5(SiO4)4O(OH)7 |
| 9.BG.45 | Dellaite | Ca6Si3O11(OH)2 |
| 9.BG.50 | Ferriperbøeite-(Ce) | CaCe3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2 |
| 9.BG.50 | Perbøeite-(La) | CaLa3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 |
| 9.BG.50 | Perbøeite-(Ce) | CaCe3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 |
| 9.BG.50 | Gatelite-(Ce) | CaCe3(AlAl2Mg)[Si2O7][SiO4]3O(OH)2 |
| 9.BG.50 | Ferriperbøeite-(La) | CaLa3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2 |
| 9.BG.55 | Västmanlandite-(Ce) | CaCe3(MgAl2Mg)[Si2O7][SiO4]3F(OH)2 |
| 9.BG.60 | Radekškodaite-(La) | (CaLa5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3 |
| 9.BG.60 | Radekškodaite-(Ce) | (CaCe5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3 |
Fluorescence of Okhotskite
Not fluorescent
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Okhotskite
mindat.org URL:
https://www.mindat.org/min-2968.html
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References for Okhotskite
Reference List:
Togari, K., Akasaka, M. (1987) Okhotskite, a new mineral, an Mn3+-dominant member of the pumpellyite group, from the Kokuriki mine, Hokkaido, Japan. Mineralogical Magazine, 51 (362) 611-614 doi:10.1180/minmag.1987.051.362.17
Jambor, John L., Ercit, Ernst A. J. Burke T. Scott, Grice, Joel D. (1988) New Mineral Names. American Mineralogist, 73 (11-12) 1492-1499 pp.1495-1496
Dasgupta, Somnath, Chakraborti, Sanjib, Sengupta, Pulak, Bhattacharya, P. K., Banerjee, H., Roy, Supriya, Fukuoka, M. (1991) Manganese-rich minerals of the pumpellyite group from the Precambrian Sausar Group, India. American Mineralogist, 76 (1-2) 241-245
Localities for Okhotskite
Showing 10 localities.
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
India | |
| Dasgupta et al. (1991) |
Italy | |
| M.E. Ciriotti collection (EDS probed) |
| Identification by EDS and PXRD as ... |
| Castellaro et al. (2023) |
Japan | |
| Fukushima et al. (2005) |
| Togari et al. (1987) |
| Yamada (2004) |
| Minakawa et al. (2008) |
Russia | |
| Kassandrov et al. (2009) |
| Kassandrov et al. (2009) |
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Kokuriki mine, Kitami City, Okhotsk Subprefecture, Hokkaidō Prefecture, Japan