Wadsleyite
A valid IMA mineral species
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About Wadsleyite
Formula:
Mg4O(Si2O7)
Although the formula is typically written as β-Mg2SiO4 to emphasize its polymorphic relationship to forsterite, wadsleyite is actually a sorosilicate and not a member of the olivine group. This formula format also better illustrates where hydration of the bridging O occurs in "hydrous wadsleyite".
Colour:
Light grayish brown
Specific Gravity:
3.84 (Calculated)
Crystal System:
Orthorhombic
Name:
It was proposed by Ringwood and Major (1970), who first made synthetic material, that if it was ever found in nature, it should be named after A.D. Wadsley.
Named by G.D. Price, A. Putnis, S.O. Agrell, and D.G.W. Smith in 1982 in honor of David Arthur Wadsley (1 August 1918, Hobart, Tasmania, Australia - 6 January 1969 Canberra, Australian Capital Territory, Australia), Australian solid-state chemist and crystallographer, former research scientist of the Commonwealth Scientific and Industrial Research Organization (CSIRO), Australia, for his significant contributions to crystallography, including the concept of crystallographic shearing.
Named by G.D. Price, A. Putnis, S.O. Agrell, and D.G.W. Smith in 1982 in honor of David Arthur Wadsley (1 August 1918, Hobart, Tasmania, Australia - 6 January 1969 Canberra, Australian Capital Territory, Australia), Australian solid-state chemist and crystallographer, former research scientist of the Commonwealth Scientific and Industrial Research Organization (CSIRO), Australia, for his significant contributions to crystallography, including the concept of crystallographic shearing.
Type Locality:
Polymorph of:
The orthorhombic, high-pressure polymorph of Ringwoodite and Forsterite (a member of the Olivine group of minerals). Initially found in the Peace River meteorite (from Alberta, Canada), it is thought to be formed from the transformation of Olivine during an extraterrestrial shock event (eg meteorite impact). It is known to be a stable and probably the most abundant phase in the transition zone of the Earth's upper mantle (between 400 and 525km depth).
Recent lab experiments, published in 2009, led by Thomas Ahrens at the California Institute of Technology (Caltech) have been able to replicate the formation of Wadsleyite by launching a high-velocity tantalum projectile at a sample containing magnesium oxide and silicon dioxide (Quartz).
Coupled substitution of Fe3+ and H+ for Si is possible, as shown for a synthetic, hydrous material (Kawazoe et al., 2016).
Recent lab experiments, published in 2009, led by Thomas Ahrens at the California Institute of Technology (Caltech) have been able to replicate the formation of Wadsleyite by launching a high-velocity tantalum projectile at a sample containing magnesium oxide and silicon dioxide (Quartz).
Coupled substitution of Fe3+ and H+ for Si is possible, as shown for a synthetic, hydrous material (Kawazoe et al., 2016).
Unique Identifiers
Mindat ID:
4228
Long-form identifier:
mindat:1:1:4228:0
IMA Classification of Wadsleyite
Approved
IMA Formula:
Mg2SiO4
Approval year:
1982
First published:
1983
Classification of Wadsleyite
9.BE.02
9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
51.3.4.1
51 : NESOSILICATES Insular SiO4 Groups Only
3 : Insular SiO4 Groups Only with all cations in octahedral [6] coordination
51 : NESOSILICATES Insular SiO4 Groups Only
3 : Insular SiO4 Groups Only with all cations in octahedral [6] coordination
14.21.3
14 : Silicates not Containing Aluminum
21 : Silicates of Fe and Mg
14 : Silicates not Containing Aluminum
21 : Silicates of Fe and Mg
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Wds | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Wds | Whitney & Evans (2010) | Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371 |
Physical Properties of Wadsleyite
Transparency:
Transparent
Colour:
Light grayish brown
Comment:
Color of polycrystalline aggregates.
Density:
3.84 g/cm3 (Calculated)
Optical Data of Wadsleyite
Type:
Biaxial
Dispersion:
r > v
Chemistry of Wadsleyite
Mindat Formula:
Mg4O(Si2O7)
Although the formula is typically written as β-Mg2SiO4 to emphasize its polymorphic relationship to forsterite, wadsleyite is actually a sorosilicate and not a member of the olivine group. This formula format also better illustrates where hydration of the bridging O occurs in "hydrous wadsleyite".
Although the formula is typically written as β-Mg2SiO4 to emphasize its polymorphic relationship to forsterite, wadsleyite is actually a sorosilicate and not a member of the olivine group. This formula format also better illustrates where hydration of the bridging O occurs in "hydrous wadsleyite".
Element Weights:
Elements listed:
Common Impurities:
Cr,Mn,Ni,Ca,Zn
Crystallography of Wadsleyite
Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Imma
Setting:
Imma
Cell Parameters:
a = 5.70(2) Å, b = 11.71(7) Å, c = 8.24(4) Å
Ratio:
a:b:c = 0.487 : 1 : 0.704
Unit Cell V:
550.00 ų (Calculated from Unit Cell)
Z:
8
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0019743 | Wadsleyite | Trots D M, Kurnosov A, Ballaran T F, Frost D J (2012) High-temperature structural behaviors of anhydrous wadsleyite and forsterite American Mineralogist 97 1582-1590 | 2012 | synthetic | 0 | 297 | |
| 0004545 | Wadsleyite | Holl C M, Smyth J R, Jacobsen S D, Frost D J (2008) Effects of hydration on the structure and compressibility of wadsleyite, beta-(Mg2SiO4) American Mineralogist 93 598-607 | ![]() | 2008 | synthetic | 0 | 293 |
| 0004544 | Wadsleyite | Holl C M, Smyth J R, Jacobsen S D, Frost D J (2008) Effects of hydration on the structure and compressibility of wadsleyite, beta-(Mg2SiO4) American Mineralogist 93 598-607 | ![]() | 2008 | synthetic | 0 | 293 |
| 0004543 | Wadsleyite | Holl C M, Smyth J R, Jacobsen S D, Frost D J (2008) Effects of hydration on the structure and compressibility of wadsleyite, beta-(Mg2SiO4) American Mineralogist 93 598-607 | ![]() | 2008 | synthetic | 0 | 293 |
| 0007971 | Wadsleyite | Kudoh Y, Inoue T, Arashi H (1996) Structure and crystal chemistry of hydrous wadsleyite, Mg1.75SiH0.5O4: possible hydrous magnesium silicate in the mantle transition zone Physics and Chemistry of Minerals 23 461-469 | 1996 | synthetic | 0 | 293 | |
| 0000277 | Wadsleyite | Baur W H (1972) Computer-simulated crystal structures of observed and hypothetical Mg2SiO4 Polymorphs of low and high density American Mineralogist 57 709-731 | ![]() | 1972 | hypothetical | 0 | 293 |
| 0019744 | Wadsleyite | Trots D M, Kurnosov A, Ballaran T F, Frost D J (2012) High-temperature structural behaviors of anhydrous wadsleyite and forsterite American Mineralogist 97 1582-1590 | 2012 | synthetic | 0 | 728 | |
| 0019745 | Wadsleyite | Trots D M, Kurnosov A, Ballaran T F, Frost D J (2012) High-temperature structural behaviors of anhydrous wadsleyite and forsterite American Mineralogist 97 1582-1590 | 2012 | synthetic | 0 | 929 | |
| 0019746 | Wadsleyite | Trots D M, Kurnosov A, Ballaran T F, Frost D J (2012) High-temperature structural behaviors of anhydrous wadsleyite and forsterite American Mineralogist 97 1582-1590 | 2012 | synthetic | 0 | 1084 | |
| 0004546 | Wadsleyite | Holl C M, Smyth J R, Jacobsen S D, Frost D J (2008) Effects of hydration on the structure and compressibility of wadsleyite, beta-(Mg2SiO4) American Mineralogist 93 598-607 | ![]() | 2008 | 0 | 293 | |
| 0003665 | Wadsleyite | Jacobsen S D, Demouchy S, Frost D J, Ballaran T B, Kung J (2005) A systematic study of OH in hydrous wadsleyite from polarized FTIR spectroscopy and single-crystal X-ray diffraction: Oxygen sites for hydrogen storage in Earth's interior American Mineralogist 90 61-70 | ![]() | 2005 | 0 | 293 | |
| 0003664 | Wadsleyite | Jacobsen S D, Demouchy S, Frost D J, Ballaran T B, Kung J (2005) A systematic study of OH in hydrous wadsleyite from polarized FTIR spectroscopy and single-crystal X-ray diffraction: Oxygen sites for hydrogen storage in Earth's interior American Mineralogist 90 61-70 | ![]() | 2005 | 0 | 293 | |
| 0003663 | Wadsleyite | Jacobsen S D, Demouchy S, Frost D J, Ballaran T B, Kung J (2005) A systematic study of OH in hydrous wadsleyite from polarized FTIR spectroscopy and single-crystal X-ray diffraction: Oxygen sites for hydrogen storage in Earth's interior American Mineralogist 90 61-70 | ![]() | 2005 | 0 | 293 | |
| 0002456 | Wadsleyite | Hazen R M, Yang H, Prewitt C T (2000) High-pressure crystal chemistry of Fe3+-wadsleyite, beta-Fe2.33Si0.67O4 Pressure = 8.95 GPa American Mineralogist 85 778-783 | ![]() | 2000 | 0 | 293 | |
| 0002455 | Wadsleyite | Hazen R M, Yang H, Prewitt C T (2000) High-pressure crystal chemistry of Fe3+-wadsleyite, beta-Fe2.33Si0.67O4 Pressure = 7.35 GPa American Mineralogist 85 778-783 | ![]() | 2000 | 0 | 293 | |
| 0002454 | Wadsleyite | Hazen R M, Yang H, Prewitt C T (2000) High-pressure crystal chemistry of Fe3+-wadsleyite, beta-Fe2.33Si0.67O4 Pressure = 5.45 GPa American Mineralogist 85 778-783 | ![]() | 2000 | 0 | 293 | |
| 0002453 | Wadsleyite | Hazen R M, Yang H, Prewitt C T (2000) High-pressure crystal chemistry of Fe3+-wadsleyite, beta-Fe2.33Si0.67O4 Pressure = 3.80 GPa American Mineralogist 85 778-783 | ![]() | 2000 | 0 | 293 | |
| 0002452 | Wadsleyite | Hazen R M, Yang H, Prewitt C T (2000) High-pressure crystal chemistry of Fe3+-wadsleyite, beta-Fe2.33Si0.67O4 Pressure = 1.95 GPa American Mineralogist 85 778-783 | ![]() | 2000 | 0 | 293 | |
| 0002451 | Wadsleyite | Hazen R M, Yang H, Prewitt C T (2000) High-pressure crystal chemistry of Fe3+-wadsleyite, beta-Fe2.33Si0.67O4 Pressure = 0.00 GPa American Mineralogist 85 778-783 | ![]() | 2000 | 0 | 293 | |
| 0002445 | Wadsleyite | Hazen R M, Weinberger M B, Yang H, Prewitt C T (2000) Comparative high-pressure crystal chemistry of wadsleyite, beta-(Mg_1-xFe_x)2SiO4, with x=0 and 0.25 American Mineralogist 85 770-777 | ![]() | 2000 | 0 | 293 | |
| 0002439 | Wadsleyite | Hazen R M, Weinberger M B, Yang H, Prewitt C T (2000) Comparative high-pressure crystal chemistry of wadsleyite, beta-(Mg_1-xFe_x)2SiO4, with x=0 and 0.25 American Mineralogist 85 770-777 | ![]() | 2000 | 0 | 293 | |
| 0008219 | Wadsleyite | Kudoh Y, Inoue T (1999) Mg-vacant structural modules and dilution of the symmetry of hydrous wadsleyite, beta-Mg2-xSiH2xO4 with 0.00<=x<=0.25 Physics and Chemistry of Minerals 26 382-388 | 1999 | 0 | 293 | ||
| 0008218 | Wadsleyite | Kudoh Y, Inoue T (1999) Mg-vacant structural modules and dilution of the symmetry of hydrous wadsleyite, beta-Mg2-xSiH2xO4 with 0.00<=x<=0.25 Physics and Chemistry of Minerals 26 382-388 | 1999 | 0 | 293 | ||
| 0001980 | Wadsleyite | Woodland A B, Angel R J (1998) Crystal structure of a new spinelloid with the wadsleyite structure in the system Fe2SiO4-Fe3O4 and implications for the Earth's mantle Fe2.45Si.55O4 American Mineralogist 83 404-408 | ![]() | 1998 | 0 | 293 | |
| 0001873 | Wadsleyite | Smyth J R, Kawamoto T, Jacobsen S D, Swope R J, Hervig R L, Holloway J R (1997) Crystal structure of monoclinic hydrous wadsleyite [beta-(Mg,Fe)2SiO4] American Mineralogist 82 270-275 | ![]() | 1997 | 0 | 293 | |
| 0007738 | Wadsleyite | Finger L W, Hazen R M, Zhang J, Ko J, Navrotsky A (1993) The effect of Fe on the crystal structure of wadsleyite beta-(Mg1-xFex)2SiO4, 0.00<=x<=0.40 Physics and Chemistry of Minerals 19 361-368 | 1993 | 0 | 293 | ||
| 0007737 | Wadsleyite | Finger L W, Hazen R M, Zhang J, Ko J, Navrotsky A (1993) The effect of Fe on the crystal structure of wadsleyite beta-(Mg1-xFex)2SiO4, 0.00<=x<=0.40 Physics and Chemistry of Minerals 19 361-368 | 1993 | 0 | 293 | ||
| 0007736 | Wadsleyite | Finger L W, Hazen R M, Zhang J, Ko J, Navrotsky A (1993) The effect of Fe on the crystal structure of wadsleyite beta-(Mg1-xFex)2SiO4, 0.00<=x<=0.40 Physics and Chemistry of Minerals 19 361-368 | 1993 | 0 | 293 | ||
| 0007735 | Wadsleyite | Finger L W, Hazen R M, Zhang J, Ko J, Navrotsky A (1993) The effect of Fe on the crystal structure of wadsleyite beta-(Mg1-xFex)2SiO4, 0.00<=x<=0.40 Physics and Chemistry of Minerals 19 361-368 | 1993 | 0 | 293 | ||
| 0007734 | Wadsleyite | Finger L W, Hazen R M, Zhang J, Ko J, Navrotsky A (1993) The effect of Fe on the crystal structure of wadsleyite beta-(Mg1-xFex)2SiO4, 0.00<=x<=0.40 Physics and Chemistry of Minerals 19 361-368 | 1993 | 0 | 293 | ||
| 0007489 | Wadsleyite | Sawamoto H, Horiuchi H (1990) Beta (Mg0.9Fe0.1)2SiO4: single crystal structure, cation distribution, and properties of coordination polyhedra Physics and Chemistry of Minerals 17 293-300 | 1990 | 0 | 293 | ||
| 0000835 | Wadsleyite | Horiuchi H, Sawamoto H (1981) Beta-Mg2SiO4: Single-crystal X-ray diffraction study case 2 American Mineralogist 66 568-575 | ![]() | 1981 | 0 | 293 | |
| 0000834 | Wadsleyite | Horiuchi H, Sawamoto H (1981) Beta-Mg2SiO4: Single-crystal X-ray diffraction study case 1 American Mineralogist 66 568-575 | ![]() | 1981 | 0 | 293 | |
| 0002446 | Wadsleyite | Hazen R M, Weinberger M B, Yang H, Prewitt C T (2000) Comparative high-pressure crystal chemistry of wadsleyite, beta-(Mg_1-xFe_x)2SiO4, with x=0 and 0.25 American Mineralogist 85 770-777 | ![]() | 2000 | 2.72 | 293 | |
| 0002440 | Wadsleyite | Hazen R M, Weinberger M B, Yang H, Prewitt C T (2000) Comparative high-pressure crystal chemistry of wadsleyite, beta-(Mg_1-xFe_x)2SiO4, with x=0 and 0.25 American Mineralogist 85 770-777 | ![]() | 2000 | 2.72 | 293 | |
| 0002447 | Wadsleyite | Hazen R M, Weinberger M B, Yang H, Prewitt C T (2000) Comparative high-pressure crystal chemistry of wadsleyite, beta-(Mg_1-xFe_x)2SiO4, with x=0 and 0.25 American Mineralogist 85 770-777 | ![]() | 2000 | 5.23 | 293 | |
| 0002441 | Wadsleyite | Hazen R M, Weinberger M B, Yang H, Prewitt C T (2000) Comparative high-pressure crystal chemistry of wadsleyite, beta-(Mg_1-xFe_x)2SiO4, with x=0 and 0.25 American Mineralogist 85 770-777 | ![]() | 2000 | 5.23 | 293 | |
| 0002448 | Wadsleyite | Hazen R M, Weinberger M B, Yang H, Prewitt C T (2000) Comparative high-pressure crystal chemistry of wadsleyite, beta-(Mg_1-xFe_x)2SiO4, with x=0 and 0.25 American Mineralogist 85 770-777 | ![]() | 2000 | 6.8 | 293 | |
| 0002442 | Wadsleyite | Hazen R M, Weinberger M B, Yang H, Prewitt C T (2000) Comparative high-pressure crystal chemistry of wadsleyite, beta-(Mg_1-xFe_x)2SiO4, with x=0 and 0.25 American Mineralogist 85 770-777 | ![]() | 2000 | 6.8 | 293 | |
| 0002449 | Wadsleyite | Hazen R M, Weinberger M B, Yang H, Prewitt C T (2000) Comparative high-pressure crystal chemistry of wadsleyite, beta-(Mg_1-xFe_x)2SiO4, with x=0 and 0.25 American Mineralogist 85 770-777 | ![]() | 2000 | 8.49 | 293 | |
| 0002443 | Wadsleyite | Hazen R M, Weinberger M B, Yang H, Prewitt C T (2000) Comparative high-pressure crystal chemistry of wadsleyite, beta-(Mg_1-xFe_x)2SiO4, with x=0 and 0.25 American Mineralogist 85 770-777 | ![]() | 2000 | 8.49 | 293 | |
| 0002450 | Wadsleyite | Hazen R M, Weinberger M B, Yang H, Prewitt C T (2000) Comparative high-pressure crystal chemistry of wadsleyite, beta-(Mg_1-xFe_x)2SiO4, with x=0 and 0.25 American Mineralogist 85 770-777 | ![]() | 2000 | 10.12 | 293 | |
| 0002444 | Wadsleyite | Hazen R M, Weinberger M B, Yang H, Prewitt C T (2000) Comparative high-pressure crystal chemistry of wadsleyite, beta-(Mg_1-xFe_x)2SiO4, with x=0 and 0.25 American Mineralogist 85 770-777 | ![]() | 2000 | 10.12 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 2.452 Å | (100) |
| 2.038 Å | (80) |
| 1.441 Å | (80) |
| 2.886 Å | (50) |
| 2.691 Å | (40) |
| 2.637 Å | (30) |
| 1.567 Å | (30) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 2: Planetesimal differentiation and alteration | 4.566-4.550 |
| 6 : Secondary asteroid phases | 4.566-4.560 |
Type Occurrence of Wadsleyite
General Appearance of Type Material:
Fine-grained aggregates with a grain size of 5 µm.
Place of Conservation of Type Material:
Department of Geology, University of Alberta, Edmonton, Canada.
Geological Setting of Type Material:
Found in vein in the Peace River meteorite, believed to have formed from an extraterrestrial shock event.
Associated Minerals at Type Locality:
Synonyms of Wadsleyite
Other Language Names for Wadsleyite
Common Associates
Associations Based on Photo Data:
| 1 photo of Wadsleyite associated with Olivine Group | M2SiO4 |
Related Minerals - Strunz-mindat Grouping
| 9.BE. | Zinkgruvanite | Ba4Mn2+4Fe3+2(Si2O7)2(SO4)2O2(OH)2 |
| 9.BE. | Calciomurmanite | (Na,◻)2Ca(Ti,Mg,Nb)4[Si2O7]2O2(OH,O)2(H2O)4 |
| 9.BE. | Cámaraite | Ba3Na(Fe2+,Mn)8Ti4(Si2O7)4O4(OH,F)7 |
| 9.BE. | Alfredcasparite | Sr2TiO(Si2O7) |
| 9.BE. | Batievaite-(Y) | Y2Ca2Ti(Si2O7)2(OH)2(H2O)4 |
| 9.BE. | Nacareniobsite-(Y) | Na3Ca3YNb(Si2O7)2OF3 |
| 9.BE. | Alexkuznetsovite-(Ce) | Ce2Mn(CO3)(Si2O7) |
| 9.BE. | Bobshannonite | Na2KBa(Mn,Na)8(Nb,Ti)4(Si2O7)4O4(OH)4(O,F)2 |
| 9.BE. | Paralomonosovite | Na6◻4Ti4(Si2O7)2[PO3OH][PO2(OH)2]O2(OF) |
| 9.BE. | Madeiraite | Na2Ca2Fe2Zr2(Si2O7)2O2F2 |
| 9.BE. | Bortolanite | Ca2(Ca1.5Zr0.5)Na(NaCa)Ti(Si2O7)2(OF)F2 |
| 9.BE. | Longshoushanite-(Ce) | Ce4MgAl2Ti2(Si2O7)2O8 |
| 9.BE. | Moxuanxueite | NaCa6Zr(Si2O7)2OF3 |
| 9.BE. | Delhuyarite-(Ce) | Ce4Mg(Fe3+,W)3◻(Si2O7)2O6(OH)2 |
| 9.BE. | Christofschäferite-(Ce) | Ce3CaMnTiFe3+Ti2(Si2O7)2O8 |
| 9.BE.X | Asimowite | Fe2+4O(Si2O7) |
| 9.BE. | Biraite-(La) | La2Fe2+(CO3)(Si2O7) |
| 9.BE. | Pilanesbergite | Na2Ca2Fe2Ti2(Si2O7)2O2F2 |
| 9.BE.02 | Ohtaniite | Mg3(Si0.5◻0.5)Si2O8 |
| 9.BE.05 | Lawsonite | CaAl2(Si2O7)(OH)2 · H2O |
| 9.BE.05 | Hennomartinite | SrMn3+2(Si2O7)(OH)2 · H2O |
| 9.BE.05 | Cortesognoite | CaV2(Si2O7)(OH)2 · H2O |
| 9.BE.05 | Noelbensonite | BaMn3+2(Si2O7)(OH)2 · H2O |
| 9.BE.05 | Itoigawaite | SrAl2(Si2O7)(OH)2 · H2O |
| 9.BE.07 | Ilvaite | CaFe3+Fe2+2(Si2O7)O(OH) |
| 9.BE.07 | Amamoorite | CaMn2+2Mn3+(Si2O7)O(OH) |
| 9.BE.07 | Manganilvaite | CaFe2+Fe3+Mn2+(Si2O7)O(OH) |
| 9.BE.10 | Suolunite | Ca2(H2Si2O7) · H2O |
| 9.BE.12 | Jaffeite | Ca6(Si2O7)(OH)6 |
| 9.BE.15 | Fresnoite | Ba2Ti(Si2O7)O |
| 9.BE.17 | Janhaugite | (Na,Ca)3(Mn2+,Fe2+)3(Ti,Zr,Nb)2(Si2O7)2O2(OH,F)2 |
| 9.BE.17 | Burpalite | Na2CaZr(Si2O7)F2 |
| 9.BE.17 | Niocalite | (Ca,Nb)4(Si2O7)(O,OH,F)2 |
| 9.BE.17 | Normandite | NaCa(Mn,Fe)(Ti,Nb,Zr)(Si2O7)OF |
| 9.BE.17 | Hiortdahlite | Na2Ca4(Ca0.5Zr0.5)Zr(Si2O7)2OF3 |
| 9.BE.17 | Låvenite | Na2Ca2Mn2Zr2(Si2O7)2O2F2 |
| 9.BE.17 | Cuspidine | Ca8(Si2O7)2F4 |
| 9.BE.17 | Wöhlerite | Na2Ca4ZrNb(Si2O7)2O3F |
| 9.BE.17 | Baghdadite | Ca6Zr2(Si2O7)2O4 |
| 9.BE.20 | Nacareniobsite-(Ce) | Na3Ca3(Ce,REE)Nb(Si2O7)2OF3 |
| 9.BE.20 | Roumaite | (Ca,Na,REE,◻)7(Nb,Ti)[Si2O7]2OF3 |
| 9.BE.20 | Rinkite-(Ce) | (Ca3Ce)Na(NaCa)Ti(Si2O7)2(OF)F2 |
| 9.BE.20 | Nacareniobsite-(Nd) | Ca2(CaNd)Na3Nb(Si2O7)2(OF)F2 |
| 9.BE.20 | Rinkite-(Y) | Na2Ca4YTi(Si2O7)2OF3 |
| 9.BE.20 | Mosandrite-(Ce) | (Ca3REE)[(H2O)2Ca0.5◻0.5]Ti(Si2O7)2(OH)2(H2O)2 |
| 9.BE.22 | Hainite-(Y) | Na2Ca4(Y,REE)Ti(Si2O7)2OF3 |
| 9.BE.22 | Rosenbuschite | Na6Ca6Zr3Ti(Si2O7)4O2F6 |
| 9.BE.22 | Götzenite | NaCa6Ti(Si2O7)2OF3 |
| 9.BE.22 | Fogoite-(Y) | Na3Ca2Y2Ti(Si2O7)2OF3 |
| 9.BE.22 | Kochite | Na3Ca2MnZrTi(Si2O7)2OF3 |
| 9.BE.23 | Dovyrenite | Ca6Zr(Si2O7)2(OH)4 |
| 9.BE.25 | Lamprophyllite | (Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2 |
| 9.BE.25 | Seidozerite | Na4MnZr2Ti(Si2O7)2O2F2 |
| 9.BE.25 | Nabalamprophyllite | (BaNa)Ti2Na3Ti(Si2O7)2O2(OH)2 |
| 9.BE.25 | Schüllerite | Ba2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4 |
| 9.BE.25 | Ericssonite | BaMn2+2Fe3+(Si2O7)O(OH) |
| 9.BE.25 | Grenmarite | Na4MnZr3(Si2O7)2O2F2 |
| 9.BE.25 | Kazanskyite | BaNa3Ti2Nb(Si2O7)2O2(OH)2(H2O)4 |
| 9.BE.25 | Saamite | Ba◻Na3Ti2Nb(Si2O7)2O2(OH)F(H2O)2 |
| 9.BE.25 | Emmerichite | Ba2Na(Na,Fe2+)2(Fe3+,Mg)Ti2(Si2O7)2O2F2 |
| 9.BE.25 | Barytolamprophyllite | (Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F) |
| 9.BE.25 | 'Ericssonite-2O' | BaMn2+2Fe3+(Si2O7)O(OH) |
| 9.BE.25 | Fluorbarytolamprophyllite | (Ba,Sr)2[(Na,Fe2+)3(Ti,Mg)F2][Ti2(Si2O7)2O2] |
| 9.BE.25 | Fluorlamprophyllite | Na3(SrNa)Ti3(Si2O7)2O2F2 |
| 9.BE.25 | Lileyite | Ba2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2 |
| 9.BE.27 | Kolskyite | CaNa2Ti4(Si2O7)2O4(H2O)7 |
| 9.BE.27 | Vigrishinite | NaZnTi4(Si2O7)2O3(OH)(H2O)4 |
| 9.BE.27 | Selivanovaite | NaFe3+Ti4(Si2O7)2O4(H2O)4 |
| 9.BE.27 | Murmanite | Na2Ti2(Si2O7)O2 · 2H2O |
| 9.BE.30 | Epistolite | (Na◻)Nb2Na3Ti(Si2O7)2O2(OH)2(H2O)4 |
| 9.BE.32 | Lomonosovite | Na5Ti2(Si2O7)(PO4)O2 |
| 9.BE.35 | Vuonnemite | Na11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH) |
| 9.BE.37 | Sobolevite | Na13Ca2Mn2Ti3(Si2O7)2(PO4)4O3F3 |
| 9.BE.40 | Ferroinnelite | Ba4Ti2Na(NaFe2+)Ti(Si2O7)2[(SO4)(PO4)]O2[O(OH)] |
| 9.BE.40 | Phosphoinnelite | Na3Ba4Ti3(Si2O7)2(PO4,SO4)2O2F |
| 9.BE.40 | Innelite | Ba4Ti2Na(NaMn2+)Ti(Si2O7)2[(SO4)(PO4)]O2[O(OH)] |
| 9.BE.42 | Yoshimuraite | Ba2Mn2Ti(Si2O7)(PO4)O(OH) |
| 9.BE.42 | Horiite | Ba2Mn2Mn4Ti2(Si2O7)2(PO4)2O2(OH)2 |
| 9.BE.45 | Quadruphite | Na6Na2(CaNa)2Na2Ti2Na2Ti2(Si2O7)2(PO4)4O4F2 |
| 9.BE.47 | Polyphite | Na5(Na4Ca2)Ti2(Si2O7)(PO4)3O2F2 |
| 9.BE.50 | Shkatulkalite | Na2Nb2Na3Ti(Si2O7)2O2(FO)(H2O)4(H2O)3 |
| 9.BE.50 | Bornemanite | Na6BaTi2Nb(Si2O7)2(PO4)O2(OH)F |
| 9.BE.55 | Hejtmanite | Ba2Mn2+4Ti2(Si2O7)2O2(OH)2F2 |
| 9.BE.55 | Bykovaite | (Ba,Na,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(H2O,F,OH)2 · 3.5H2O |
| 9.BE.55 | Nechelyustovite | (Ba,Sr,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(O,H2O,F)2 · 4.5H2O |
| 9.BE.55 | Bafertisite | Ba2Fe2+4Ti2(Si2O7)2O2(OH)2F2 |
| 9.BE.60 | Delindeite | (Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2O |
| 9.BE.62 | 'Orthochevkinite' | (Ce,La,Ca,Na,Th)4(Fe2+,Mg)2(Ti,Fe3+)3Si4O22 |
| 9.BE.62 va | 'Strontium Perrierite' | (Ce,Sr,La,Ca)4Fe2+(Ti,Zr,Fe)2Ti2(Si2O7)2O8 |
| 9.BE.62 | 'Chevkinite-(Nd)' | (Nd,REE)4(Fe2+,Mg)(Fe2+,Ti,Fe3+)2(Ti,Fe3+)2(Si2O7)2O8 ? |
| 9.BE.62 | 'Perrierite-(Nd)' | Nd4MgFe3+2Ti2(Si2O7)2O8 ? |
| 9.BE.65 | Bussenite | Na2Ba2Fe2+Ti(Si2O7)(CO3)(OH)3F |
| 9.BE.67 | Jinshajiangite | BaNaFe2+4Ti2(Si2O7)2O2(OH)2F |
| 9.BE.67 | Perraultite | BaNaMn2+4Ti2(Si2O7)2O2(OH)2F |
| 9.BE.70 | Dingdaohengite-(Ce) | (Ce,La)4Fe2+(Ti,Fe2+,Mg,Fe3+)2Ti2(Si2O7)2O8 |
| 9.BE.70 | Perrierite-(Ce) | Ce4MgFe3+2Ti2(Si2O7)2O8 |
| 9.BE.70 | Karnasurtite-(Ce) | (Ce,La,Th)(Ti,Nb)(Al,Fe)(Si2O7)(OH)4 · 3H2O |
| 9.BE.70 | Maoniupingite-(Ce) | (Ce,Ca)4(Fe3+,Ti,Fe2+,◻)(Ti,Fe3+,Fe2+,Nb)4(Si2O7)2O8 |
| 9.BE.70 | Matsubaraite | Sr4Ti5(Si2O7)2O8 |
| 9.BE.70 | Rengeite | Sr4ZrTi4(Si2O7)2O8 |
| 9.BE.70 | Polyakovite-(Ce) | (Ce,Ca)4(Mg,Fe2+)(Cr3+,Fe3+)2(Ti,Nb)2(Si2O7)2O8 |
| 9.BE.70 | Hezuolinite | (Sr,REE)4Zr(Ti,Fe3+)4(Si2O7)2O8 |
| 9.BE.70 | 'UM2008-53-SiO:SrTiZr' | Sr4ZrTi4(Si2O7)2O8 |
| 9.BE.70 | Chevkinite-(Ce) | Ce4(Ti,Fe2+,Fe3+)5O8(Si2O7)2 |
| 9.BE.70 | Perrierite-(La) | (La,Ce,Ca)4(Fe2+,Mn)(Ti,Fe3+,Al)4[(Si2O7)O4]2 |
| 9.BE.70 | Strontiochevkinite | (Sr,La,Ce,Ca)4Fe2+(Ti,Zr)2Ti2(Si2O7)2O8 |
| 9.BE.72 | Fersmanite | Ca4(Na,Ca)4(Ti,Nb)4(Si2O7)2O8F3 |
| 9.BE.75 | Belkovite | Ba3(Nb,Ti)6(Si2O7)2O12 |
| 9.BE.77 | Nasonite | Pb6Ca4(Si2O7)3Cl2 |
| 9.BE.80 | Melanotekite | Pb2Fe3+2(Si2O7)O2 |
| 9.BE.80 | Kentrolite | Pb2Mn3+2(Si2O7)O2 |
| 9.BE.82 | Alexkuznetsovite-(La) | La2Mn(CO3)(Si2O7) |
| 9.BE.82 | Tilleyite | Ca5(Si2O7)(CO3)2 |
| 9.BE.85 | Killalaite | Ca6.4(H0.6Si2O7)2(OH)2 |
| 9.BE.87 | Stavelotite-(La) | (La,Nd,Ca)3Mn2+3Cu(Mn3+,Fe3+,Mn4+)26(Si2O7)6O30 |
| 9.BE.90 | Magnesiorowlandite-(Y) | Y4(Mg,Fe)(Si2O7)2F2 |
| 9.BE.90 | Biraite-(Ce) | Ce2Fe2+(Si2O7)(CO3) |
| 9.BE.92 | Cervandonite-(Ce) | (Ce,Nd,La)(Fe3+,Fe2+,Ti,Al)3O2(Si2O7)(As3+O3)(OH) |
| 9.BE.92 | Chirvinskyite | (Na,Ca)13(Fe,Mn,◻)2(Ti,Zr)5(Si2O7)4(OH,O)12 · 2H2O |
| 9.BE.95 | Rusinovite | Ca10(Si2O7)3Cl2 |
| 9.BE.95 | Batisivite | BaV3+8Ti6(Si2O7)O22 |
| 9.BE.97 | Schlüterite-(Y) | (Y,REE)2AlSi2O7(OH)2F |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Wadsleyite
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https://www.mindat.org/min-4228.html
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References for Wadsleyite
Reference List:
Dunn, P.J.; Grice, J.D.; Fleischer, M.; Pabst, A. (1983) New mineral names. American Mineralogist, 68 (9-10). 1038-1041
Reynard, Bruno; Takir, Fouzia; Guyot, Francois; Gwanmesia, Gabriel D.; Liebermann, Robert C.; Gillet, Philippe (1996) High-temperature Raman spectroscopic and X-ray diffraction study of β–Mg2SiO4: Insights into its high-temperature thermodynamic properties and the β– to α–phase-transformation mechanism and kinetics. American Mineralogist, 81 (5). 585-594 doi:10.2138/am-1996-5-605
Smyth, Joseph R.; Kawamoto, Tatsuhiko; Jacobsen, Stephen D.; Swope, R. Jeffrey; Hervig, Richard L.; Holloway, John R. (1997) Crystal structure of monoclinic hydrous wadsleyite β-(Mg,Fe)2SiO4. American Mineralogist, 82 (3). 270-275 doi:10.2138/am-1997-3-404
Sinogeikin, S. V., Katsura, T., Bass, J. D. (1998) Sound velocities and elastic properties of Fe-bearing wadsleyite and ringwoodite. Journal of Geophysical Research: Solid Earth, 103. 20819-20825 doi:10.1029/98jb01819
Holl, C. M.; Smyth, J. R.; Jacobsen, S. D.; Frost, D. J. (2008) Effects of hydration on the structure and compressibility of wadsleyite, β-(Mg2SiO4). American Mineralogist, 93 (4). 598-607 doi:10.2138/am.2008.2620
Trots, D. M., Kurnosov, A., Ballaran, T. B., Frost, D. J. (2012) High-temperature structural behaviors of anhydrous wadsleyite and forsterite. American Mineralogist, 97 (10) 1582-1590 doi:10.2138/am.2012.3992
Kawazoe, Takaaki, Buchen, Johannes, Marquardt, Hauke (2015) Synthesis of large wadsleyite single crystals by solid-state recrystallization. American Mineralogist, 100 (10) 2336-2339 doi:10.2138/am-2015-5400
Martinek, Loïs, Bolfan-Casanova, Nathalie (2021) Water quantification in olivine and wadsleyite by Raman spectroscopy and study of errors and uncertainties. American Mineralogist, 106 (4) 570-580 doi:10.2138/am-2021-7264
Wang, Wenzhong, Wu, Zhongqing (2022) A first-principles study of water in wadsleyite and ringwoodite: Implication for the 520 km discontinuity. American Mineralogist, 107 (7) 1361-1368 doi:10.2138/am-2021-7929
Localities for Wadsleyite
Showing 21 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Africa | |
| Ozawa et al. (2007, December) |
Antarctica | |
| www.lpi.usra.edu (n.d.) |
| Ozawa et al. (2007, December) |
Australia | |
| Tomioka et al. (1997) +1 other reference |
Canada (TL) | |
| Price et al. (1983) +1 other reference |
China | |
| Zhang et al. (1999) |
| Kuiren Wang et al. (1995) |
| Bindi et al. (2024) |
| Chen et al. (2004) |
France | |
| Baziotis et al. (2018) |
| Malavergne et al. (2001) |
Germany | |
| Weiß (1990) |
Nigeria | |
| Weisberg et al. (2010) |
Northwest Africa Meteorites | |
| Ma et al. (2022) | |
Oman | |
| Litasov et al. (2019) |
| Litasov et al. (2019) | |
| D.D. Badjukov et al. et al. (2005) | |
Romania | |
| Baziotis et al. (2021) |
Russia | |
| Nakamura et al. (2019) |
USA | |
| Acosta et al. (2012) |
| Tomioka et al. (2021) |
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Northwest Africa 1662 meteorite, Northwest Africa Meteorites