Lawsonite
A valid IMA mineral species - grandfathered
This page kindly sponsored by Donna Whitney
About Lawsonite
Formula:
CaAl2(Si2O7)(OH)2 · H2O
Colour:
colorless, white, grayish blue, pale blue, pink
Lustre:
Vitreous, Pearly
Hardness:
7½
Specific Gravity:
3.1
Crystal System:
Orthorhombic
Member of:
Name:
Named by Frederick Leslie Ransome and Charles Palache in 1895 in honour of geologist Andrew Cowper Lawson (July 25, 1861 Anstruther, Scotland — San Leandro, California, June 16, 1952), geologist with the Canadian Geological Survey and for most of his career a professor of geology and mineralogy at the University of California.
The Al analogue of cortesognoite.
Chemically and stoichiometrically very similar to anorthite (which is anhydrous, however).
Chemically and stoichiometrically very similar to anorthite (which is anhydrous, however).
Unique Identifiers
Mindat ID:
2353
Long-form identifier:
mindat:1:1:2353:1
Similar Names
| Dawsonite | A valid IMA mineral species - grandfathered | NaAlCO3(OH)2 |
| Lausenite | A valid IMA mineral species - grandfathered | Fe2(SO4)3 · 5H2O |
| Lazionite | A synonym of Wavellite | |
| Lisanite | A valid IMA mineral species - pending publication | CaNiP2O7 |
| Lossenite | A discredited species name | |
| Luzonite | A valid IMA mineral species - grandfathered | Cu3AsS4 |
| Mawsonite | A valid IMA mineral species | Cu6Fe2SnS8 |
| Slawsonite | A valid IMA mineral species | Sr(Al2Si2O8) |
IMA Classification of Lawsonite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
CaAl2Si2O7(OH)2·H2O
First published:
1895
Classification of Lawsonite
9.BE.05
9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
56.2.3.1
56 : SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
2 : Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordination
56 : SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
2 : Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordination
16.9.18
16 : Silicates Containing Aluminum and other Metals
9 : Aluminosilicates of Ca
16 : Silicates Containing Aluminum and other Metals
9 : Aluminosilicates of Ca
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Lws | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Lws | Kretz (1983) | Kretz, R. (1983) Symbols of rock-forming minerals. American Mineralogist, 68, 277–279. |
| Lws | Siivolam & Schmid (2007) | Siivolam, J. and Schmid, R. (2007) Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: List of mineral abbreviations. Web-version 01.02.07. IUGS Commission on the Systematics in Petrology. download |
| Lws | Whitney & Evans (2010) | Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371 |
| Lws | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Lawsonite
Vitreous, Pearly
Transparency:
Translucent
Colour:
Colorless, white, grayish blue, pale blue, pink
Streak:
White
Hardness:
7½ on Mohs scale
Cleavage:
Perfect
[001] perfect
[110] poor
[001] perfect
[110] poor
Fracture:
Irregular/Uneven
Density:
3.1 g/cm3 (Measured) 3.09 g/cm3 (Calculated)
Optical Data of Lawsonite
Type:
Biaxial (+)
RI values:
nα = 1.665 nβ = 1.674(2) nγ = 1.685(1)
2V:
Measured: 84° to 85°, Calculated: 76° to 86°
Max. Birefringence:
δ = 0.020
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
strong
Chemistry of Lawsonite
Mindat Formula:
CaAl2(Si2O7)(OH)2 · H2O
Element Weights:
Crystallography of Lawsonite
Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Cmcm
Cell Parameters:
a = 5.847 Å, b = 8.79 Å, c = 13.128 Å
Ratio:
a:b:c = 0.665 : 1 : 1.494
Unit Cell V:
674.72 ų
Z:
4
Morphology:
prismatic/tabular
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0018952 | Lawsonite | Liebscher A, Dorsam G, Franz G, Wunder B, Gottschalk M (2010) Crystal chemistry of synthetic lawsonite solid-solution series CaAl2 [(OH)2/(Si2O7)](H2O)-SrAl2[(OH)2/(Si2O7)](H2O) and the Cmcm-P2_1/m phase transition American Mineralogist 95 724-735 | ![]() | 2010 | synthetic | 0 | 293 |
| 0018951 | Lawsonite | Liebscher A, Dorsam G, Franz G, Wunder B, Gottschalk M (2010) Crystal chemistry of synthetic lawsonite solid-solution series CaAl2 [(OH)2/(Si2O7)](H2O)-SrAl2[(OH)2/(Si2O7)](H2O) and the Cmcm-P2_1/m phase transition American Mineralogist 95 724-735 | ![]() | 2010 | synthetic | 0 | 293 |
| 0018950 | Lawsonite | Liebscher A, Dorsam G, Franz G, Wunder B, Gottschalk M (2010) Crystal chemistry of synthetic lawsonite solid-solution series CaAl2 [(OH)2/(Si2O7)](H2O)-SrAl2[(OH)2/(Si2O7)](H2O) and the Cmcm-P2_1/m phase transition American Mineralogist 95 724-735 | ![]() | 2010 | synthetic | 0 | 293 |
| 0018949 | Lawsonite | Liebscher A, Dorsam G, Franz G, Wunder B, Gottschalk M (2010) Crystal chemistry of synthetic lawsonite solid-solution series CaAl2 [(OH)2/(Si2O7)](H2O)-SrAl2[(OH)2/(Si2O7)](H2O) and the Cmcm-P2_1/m phase transition American Mineralogist 95 724-735 | ![]() | 2010 | synthetic | 0 | 293 |
| 0018948 | Lawsonite | Liebscher A, Dorsam G, Franz G, Wunder B, Gottschalk M (2010) Crystal chemistry of synthetic lawsonite solid-solution series CaAl2 [(OH)2/(Si2O7)](H2O)-SrAl2[(OH)2/(Si2O7)](H2O) and the Cmcm-P2_1/m phase transition American Mineralogist 95 724-735 | ![]() | 2010 | synthetic | 0 | 293 |
| 0018947 | Lawsonite | Liebscher A, Dorsam G, Franz G, Wunder B, Gottschalk M (2010) Crystal chemistry of synthetic lawsonite solid-solution series CaAl2 [(OH)2/(Si2O7)](H2O)-SrAl2[(OH)2/(Si2O7)](H2O) and the Cmcm-P2_1/m phase transition American Mineralogist 95 724-735 | ![]() | 2010 | synthetic | 0 | 293 |
| 0018946 | Lawsonite | Liebscher A, Dorsam G, Franz G, Wunder B, Gottschalk M (2010) Crystal chemistry of synthetic lawsonite solid-solution series CaAl2 [(OH)2/(Si2O7)](H2O)-SrAl2[(OH)2/(Si2O7)](H2O) and the Cmcm-P2_1/m phase transition American Mineralogist 95 724-735 | ![]() | 2010 | synthetic | 0 | 293 |
| 0018939 | Lawsonite | Liebscher A, Dorsam G, Franz G, Wunder B, Gottschalk M (2010) Crystal chemistry of synthetic lawsonite solid-solution series CaAl2 [(OH)2/(Si2O7)](H2O)-SrAl2[(OH)2/(Si2O7)](H2O) and the Cmcm-P2_1/m phase transition American Mineralogist 95 724-735 | ![]() | 2010 | synthetic | 0 | 293 |
| 0018938 | Lawsonite | Liebscher A, Dorsam G, Franz G, Wunder B, Gottschalk M (2010) Crystal chemistry of synthetic lawsonite solid-solution series CaAl2 [(OH)2/(Si2O7)](H2O)-SrAl2[(OH)2/(Si2O7)](H2O) and the Cmcm-P2_1/m phase transition American Mineralogist 95 724-735 | ![]() | 2010 | synthetic | 0 | 293 |
| 0018937 | Lawsonite | Liebscher A, Dorsam G, Franz G, Wunder B, Gottschalk M (2010) Crystal chemistry of synthetic lawsonite solid-solution series CaAl2 [(OH)2/(Si2O7)](H2O)-SrAl2[(OH)2/(Si2O7)](H2O) and the Cmcm-P2_1/m phase transition American Mineralogist 95 724-735 | ![]() | 2010 | synthetic | 0 | 293 |
| 0018936 | Lawsonite | Liebscher A, Dorsam G, Franz G, Wunder B, Gottschalk M (2010) Crystal chemistry of synthetic lawsonite solid-solution series CaAl2 [(OH)2/(Si2O7)](H2O)-SrAl2[(OH)2/(Si2O7)](H2O) and the Cmcm-P2_1/m phase transition American Mineralogist 95 724-735 | ![]() | 2010 | synthetic | 0 | 293 |
| 0018935 | Lawsonite | Liebscher A, Dorsam G, Franz G, Wunder B, Gottschalk M (2010) Crystal chemistry of synthetic lawsonite solid-solution series CaAl2 [(OH)2/(Si2O7)](H2O)-SrAl2[(OH)2/(Si2O7)](H2O) and the Cmcm-P2_1/m phase transition American Mineralogist 95 724-735 | ![]() | 2010 | synthetic | 0 | 293 |
| 0018934 | Lawsonite | Liebscher A, Dorsam G, Franz G, Wunder B, Gottschalk M (2010) Crystal chemistry of synthetic lawsonite solid-solution series CaAl2 [(OH)2/(Si2O7)](H2O)-SrAl2[(OH)2/(Si2O7)](H2O) and the Cmcm-P2_1/m phase transition American Mineralogist 95 724-735 | ![]() | 2010 | synthetic | 0 | 293 |
| 0018953 | Lawsonite | Pawley A R, Allan D R (2001) A high-pressure study of lawsonite using angle-dispersive powder-diffraction methods with synchrotron radiation Mineralogical Magazine 65 41-58 | 2001 | synthetic | 0 | 293 | |
| 0000639 | Lawsonite | Baur W H (1978) Crystal structure refinement of lawsonite American Mineralogist 63 311-315 | ![]() | 1978 | Tiburon Peninsula, Marin County, California, USA | 0 | 293 |
| 0018954 | Lawsonite | Pawley A R, Allan D R (2001) A high-pressure study of lawsonite using angle-dispersive powder-diffraction methods with synchrotron radiation Mineralogical Magazine 65 41-58 | 2001 | synthetic | 9.8 | 293 | |
| 0018955 | Lawsonite | Pawley A R, Allan D R (2001) A high-pressure study of lawsonite using angle-dispersive powder-diffraction methods with synchrotron radiation Mineralogical Magazine 65 41-58 | 2001 | synthetic | 11.9 | 293 | |
| 0018956 | Lawsonite | Pawley A R, Allan D R (2001) A high-pressure study of lawsonite using angle-dispersive powder-diffraction methods with synchrotron radiation Mineralogical Magazine 65 41-58 | 2001 | synthetic | 16.5 | 293 | |
| 0007253 | Lawsonite | Kolesov B A, Lager G A, Schultz A J (2008) Behaviour of H2O and OH in lawsonite: a single-crystal neutron diffraction and Raman spectroscopic investigation European Journal of Mineralogy 20 63-72 | 2008 | 0 | 293 | ||
| 0001800 | Lawsonite | Comodi P, Zanazzi P F (1996) Effects of temperature and pressure on the structure of lawsonite American Mineralogist 81 833-841 | ![]() | 1996 | 0.0001 | 293 | |
| 0001768 | Lawsonite | Libowitzky E, Armbruster T (1995) Low-temperature phase transitions and the role of hydrogen bonds in lawsonite American Mineralogist 80 1277-1285 | ![]() | 1995 | 0 | 293 | |
| 0001767 | Lawsonite | Libowitzky E, Armbruster T (1995) Low-temperature phase transitions and the role of hydrogen bonds in lawsonite American Mineralogist 80 1277-1285 | ![]() | 1995 | 0 | 293 | |
| 0001766 | Lawsonite | Libowitzky E, Armbruster T (1995) Low-temperature phase transitions and the role of hydrogen bonds in lawsonite American Mineralogist 80 1277-1285 | ![]() | 1995 | 0 | 293 | |
| 0001765 | Lawsonite | Libowitzky E, Armbruster T (1995) Low-temperature phase transitions and the role of hydrogen bonds in lawsonite American Mineralogist 80 1277-1285 | ![]() | 1995 | 0 | 293 | |
| 0001764 | Lawsonite | Libowitzky E, Armbruster T (1995) Low-temperature phase transitions and the role of hydrogen bonds in lawsonite American Mineralogist 80 1277-1285 | ![]() | 1995 | 0 | 293 | |
| 0001763 | Lawsonite | Libowitzky E, Armbruster T (1995) Low-temperature phase transitions and the role of hydrogen bonds in lawsonite American Mineralogist 80 1277-1285 | ![]() | 1995 | 0 | 293 | |
| 0006433 | Lawsonite | Armbruster T, Oberhansli R, Bermanec V (1992) Crystal structure of SrMn2(Si2O7)(OH)2.H2O, a new mineral of the lawsonite type European Journal of Mineralogy 4 17-22 | 1992 | 0 | 293 | ||
| 0003737 | Lawsonite | Sondergeld P, Schranz W, Troster A, Armbruster T, Giester G, Kityk A, Carpenter M A (2005) Ordering and elasticity associated with low-temperature phase transitions in lawsonite American Mineralogist 90 448-456 | ![]() | 2005 | 0 | 215 | |
| 0001803 | Lawsonite | Comodi P, Zanazzi P F (1996) Effects of temperature and pressure on the structure of lawsonite American Mineralogist 81 833-841 | ![]() | 1996 | 0.0001 | 717 | |
| 0001804 | Lawsonite | Comodi P, Zanazzi P F (1996) Effects of temperature and pressure on the structure of lawsonite American Mineralogist 81 833-841 | ![]() | 1996 | 0.0001 | 811 | |
| 0001801 | Lawsonite | Comodi P, Zanazzi P F (1996) Effects of temperature and pressure on the structure of lawsonite American Mineralogist 81 833-841 | ![]() | 1996 | 0.05 | 293 | |
| 0001802 | Lawsonite | Comodi P, Zanazzi P F (1996) Effects of temperature and pressure on the structure of lawsonite American Mineralogist 81 833-841 | ![]() | 1996 | 2.87 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Loading XRD data...
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 4.84 Å | (60) |
| 3.66 Å | (60) |
| 2.726 Å | (70) |
| 2.680 Å | (50) |
| 2.624 Å | (100) |
| 2.433 Å | (60) |
| 2.129 Å | (60) |
| 1.550 Å | (80) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 3b: Earth’s earliest hydrosphere | >4.45 |
| 16 : Low-? aqueous alteration of Hadean subaerial lithologies (see also #23) | |
| Stage 5: Initiation of plate tectonics | <3.5-2.5 |
| 39 : High-? metamorphism (blueschist, eclogite, ultrahigh ? facies) | |
| 40 : Regional metamorphism (greenschist, amphibolite, granulite facies) | |
| 41 : Mantle metasomatism |
Geological Setting:
Lawsonite forms at high pressures and low temperatures, especially in low-grade regionally metamorphosed glaucophane schists. It also forms from plagioclase during saussuritization of gabbros and diabases; rarely in eclogites.
Type Occurrence of Lawsonite
Other Language Names for Lawsonite
Varieties of Lawsonite
| Chromium-bearing Lawsonite | A chromium-bearing variety of Lawsonite. |
Relationship of Lawsonite to other Species
Member of:
Other Members of Lawsonite Group:
| Amamoorite | CaMn2+2Mn3+(Si2O7)O(OH) | Mon. 2/m : P21/b |
| Cortesognoite | CaV2(Si2O7)(OH)2 · H2O | Orth. mmm(2/m2/m2/m) : Cmcm |
| Hennomartinite | SrMn3+2(Si2O7)(OH)2 · H2O | Orth. mmm(2/m2/m2/m) : Cmcm |
| Ilvaite | CaFe3+Fe2+2(Si2O7)O(OH) | Orth. mmm(2/m2/m2/m) |
| Itoigawaite | SrAl2(Si2O7)(OH)2 · H2O | Orth. mmm(2/m2/m2/m) : Cmcm |
| Manganilvaite | CaFe2+Fe3+Mn2+(Si2O7)O(OH) | Mon. 2/m : P21/b |
| Noelbensonite | BaMn3+2(Si2O7)(OH)2 · H2O | Orth. mm2 |
Common Associates
Associations Based on Photo Data:
| 40 photos of Lawsonite associated with Glaucophane | ◻Na2(Mg3Al2)Si8O22(OH)2 |
| 16 photos of Lawsonite associated with Quartz | SiO2 |
| 10 photos of Lawsonite associated with Muscovite | KAl2(AlSi3O10)(OH)2 |
| 2 photos of Lawsonite associated with Albite | Na(AlSi3O8) |
| 2 photos of Lawsonite associated with Epidote | (CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH) |
| 1 photo of Lawsonite associated with Joaquinite-(Ce) | NaBa2Ce2FeTi2[Si4O12]2O2(OH,F) · H2O |
| 1 photo of Lawsonite associated with Omphacite | (NaaCabFe2+cMgd)(AleFe3+fFe2+gMgh)Si2O6 |
| 1 photo of Lawsonite associated with Cymrite | BaAl2Si2(O,OH)8 · H2O |
| 1 photo of Lawsonite associated with Actinolite | ◻Ca2(Mg4.5-2.5Fe0.5-2.5)Si8O22(OH)2 |
| 1 photo of Lawsonite associated with 'Bitumen' |
Related Minerals - Strunz-mindat Grouping
| 9.BE. | Zinkgruvanite | Ba4Mn2+4Fe3+2(Si2O7)2(SO4)2O2(OH)2 |
| 9.BE. | Calciomurmanite | (Na,◻)2Ca(Ti,Mg,Nb)4[Si2O7]2O2(OH,O)2(H2O)4 |
| 9.BE. | Cámaraite | Ba3Na(Fe2+,Mn)8Ti4(Si2O7)4O4(OH,F)7 |
| 9.BE. | Alfredcasparite | Sr2TiO(Si2O7) |
| 9.BE. | Batievaite-(Y) | Y2Ca2Ti(Si2O7)2(OH)2(H2O)4 |
| 9.BE. | Nacareniobsite-(Y) | Na3Ca3YNb(Si2O7)2OF3 |
| 9.BE. | Alexkuznetsovite-(Ce) | Ce2Mn(CO3)(Si2O7) |
| 9.BE. | Bobshannonite | Na2KBa(Mn,Na)8(Nb,Ti)4(Si2O7)4O4(OH)4(O,F)2 |
| 9.BE. | Paralomonosovite | Na6◻4Ti4(Si2O7)2[PO3OH][PO2(OH)2]O2(OF) |
| 9.BE. | Madeiraite | Na2Ca2Fe2Zr2(Si2O7)2O2F2 |
| 9.BE. | Bortolanite | Ca2(Ca1.5Zr0.5)Na(NaCa)Ti(Si2O7)2(OF)F2 |
| 9.BE. | Longshoushanite-(Ce) | Ce4MgAl2Ti2(Si2O7)2O8 |
| 9.BE. | Moxuanxueite | NaCa6Zr(Si2O7)2OF3 |
| 9.BE. | Delhuyarite-(Ce) | Ce4Mg(Fe3+,W)3◻(Si2O7)2O6(OH)2 |
| 9.BE. | Christofschäferite-(Ce) | Ce3CaMnTiFe3+Ti2(Si2O7)2O8 |
| 9.BE.X | Asimowite | Fe2+4O(Si2O7) |
| 9.BE. | Biraite-(La) | La2Fe2+(CO3)(Si2O7) |
| 9.BE. | Pilanesbergite | Na2Ca2Fe2Ti2(Si2O7)2O2F2 |
| 9.BE.02 | Wadsleyite | Mg4O(Si2O7) |
| 9.BE.02 | Ohtaniite | Mg3(Si0.5◻0.5)Si2O8 |
| 9.BE.05 | Hennomartinite | SrMn3+2(Si2O7)(OH)2 · H2O |
| 9.BE.05 | Cortesognoite | CaV2(Si2O7)(OH)2 · H2O |
| 9.BE.05 | Noelbensonite | BaMn3+2(Si2O7)(OH)2 · H2O |
| 9.BE.05 | Itoigawaite | SrAl2(Si2O7)(OH)2 · H2O |
| 9.BE.07 | Ilvaite | CaFe3+Fe2+2(Si2O7)O(OH) |
| 9.BE.07 | Amamoorite | CaMn2+2Mn3+(Si2O7)O(OH) |
| 9.BE.07 | Manganilvaite | CaFe2+Fe3+Mn2+(Si2O7)O(OH) |
| 9.BE.10 | Suolunite | Ca2(H2Si2O7) · H2O |
| 9.BE.12 | Jaffeite | Ca6(Si2O7)(OH)6 |
| 9.BE.15 | Fresnoite | Ba2Ti(Si2O7)O |
| 9.BE.17 | Janhaugite | (Na,Ca)3(Mn2+,Fe2+)3(Ti,Zr,Nb)2(Si2O7)2O2(OH,F)2 |
| 9.BE.17 | Burpalite | Na2CaZr(Si2O7)F2 |
| 9.BE.17 | Niocalite | (Ca,Nb)4(Si2O7)(O,OH,F)2 |
| 9.BE.17 | Normandite | NaCa(Mn,Fe)(Ti,Nb,Zr)(Si2O7)OF |
| 9.BE.17 | Hiortdahlite | Na2Ca4(Ca0.5Zr0.5)Zr(Si2O7)2OF3 |
| 9.BE.17 | Låvenite | Na2Ca2Mn2Zr2(Si2O7)2O2F2 |
| 9.BE.17 | Cuspidine | Ca8(Si2O7)2F4 |
| 9.BE.17 | Wöhlerite | Na2Ca4ZrNb(Si2O7)2O3F |
| 9.BE.17 | Baghdadite | Ca6Zr2(Si2O7)2O4 |
| 9.BE.20 | Nacareniobsite-(Ce) | Na3Ca3(Ce,REE)Nb(Si2O7)2OF3 |
| 9.BE.20 | Roumaite | (Ca,Na,REE,◻)7(Nb,Ti)[Si2O7]2OF3 |
| 9.BE.20 | Rinkite-(Ce) | (Ca3Ce)Na(NaCa)Ti(Si2O7)2(OF)F2 |
| 9.BE.20 | Nacareniobsite-(Nd) | Ca2(CaNd)Na3Nb(Si2O7)2(OF)F2 |
| 9.BE.20 | Rinkite-(Y) | Na2Ca4YTi(Si2O7)2OF3 |
| 9.BE.20 | Mosandrite-(Ce) | (Ca3REE)[(H2O)2Ca0.5◻0.5]Ti(Si2O7)2(OH)2(H2O)2 |
| 9.BE.22 | Hainite-(Y) | Na2Ca4(Y,REE)Ti(Si2O7)2OF3 |
| 9.BE.22 | Rosenbuschite | Na6Ca6Zr3Ti(Si2O7)4O2F6 |
| 9.BE.22 | Götzenite | NaCa6Ti(Si2O7)2OF3 |
| 9.BE.22 | Fogoite-(Y) | Na3Ca2Y2Ti(Si2O7)2OF3 |
| 9.BE.22 | Kochite | Na3Ca2MnZrTi(Si2O7)2OF3 |
| 9.BE.23 | Dovyrenite | Ca6Zr(Si2O7)2(OH)4 |
| 9.BE.25 | Lamprophyllite | (Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2 |
| 9.BE.25 | Seidozerite | Na4MnZr2Ti(Si2O7)2O2F2 |
| 9.BE.25 | Nabalamprophyllite | (BaNa)Ti2Na3Ti(Si2O7)2O2(OH)2 |
| 9.BE.25 | Schüllerite | Ba2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4 |
| 9.BE.25 | Ericssonite | BaMn2+2Fe3+(Si2O7)O(OH) |
| 9.BE.25 | Grenmarite | Na4MnZr3(Si2O7)2O2F2 |
| 9.BE.25 | Kazanskyite | BaNa3Ti2Nb(Si2O7)2O2(OH)2(H2O)4 |
| 9.BE.25 | Saamite | Ba◻Na3Ti2Nb(Si2O7)2O2(OH)F(H2O)2 |
| 9.BE.25 | Emmerichite | Ba2Na(Na,Fe2+)2(Fe3+,Mg)Ti2(Si2O7)2O2F2 |
| 9.BE.25 | Barytolamprophyllite | (Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F) |
| 9.BE.25 | 'Ericssonite-2O' | BaMn2+2Fe3+(Si2O7)O(OH) |
| 9.BE.25 | Fluorbarytolamprophyllite | (Ba,Sr)2[(Na,Fe2+)3(Ti,Mg)F2][Ti2(Si2O7)2O2] |
| 9.BE.25 | Fluorlamprophyllite | Na3(SrNa)Ti3(Si2O7)2O2F2 |
| 9.BE.25 | Lileyite | Ba2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2 |
| 9.BE.27 | Kolskyite | CaNa2Ti4(Si2O7)2O4(H2O)7 |
| 9.BE.27 | Vigrishinite | NaZnTi4(Si2O7)2O3(OH)(H2O)4 |
| 9.BE.27 | Selivanovaite | NaFe3+Ti4(Si2O7)2O4(H2O)4 |
| 9.BE.27 | Murmanite | Na2Ti2(Si2O7)O2 · 2H2O |
| 9.BE.30 | Epistolite | (Na◻)Nb2Na3Ti(Si2O7)2O2(OH)2(H2O)4 |
| 9.BE.32 | Lomonosovite | Na5Ti2(Si2O7)(PO4)O2 |
| 9.BE.35 | Vuonnemite | Na11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH) |
| 9.BE.37 | Sobolevite | Na13Ca2Mn2Ti3(Si2O7)2(PO4)4O3F3 |
| 9.BE.40 | Ferroinnelite | Ba4Ti2Na(NaFe2+)Ti(Si2O7)2[(SO4)(PO4)]O2[O(OH)] |
| 9.BE.40 | Phosphoinnelite | Na3Ba4Ti3(Si2O7)2(PO4,SO4)2O2F |
| 9.BE.40 | Innelite | Ba4Ti2Na(NaMn2+)Ti(Si2O7)2[(SO4)(PO4)]O2[O(OH)] |
| 9.BE.42 | Yoshimuraite | Ba2Mn2Ti(Si2O7)(PO4)O(OH) |
| 9.BE.42 | Horiite | Ba2Mn2Mn4Ti2(Si2O7)2(PO4)2O2(OH)2 |
| 9.BE.45 | Quadruphite | Na6Na2(CaNa)2Na2Ti2Na2Ti2(Si2O7)2(PO4)4O4F2 |
| 9.BE.47 | Polyphite | Na5(Na4Ca2)Ti2(Si2O7)(PO4)3O2F2 |
| 9.BE.50 | Shkatulkalite | Na2Nb2Na3Ti(Si2O7)2O2(FO)(H2O)4(H2O)3 |
| 9.BE.50 | Bornemanite | Na6BaTi2Nb(Si2O7)2(PO4)O2(OH)F |
| 9.BE.55 | Hejtmanite | Ba2Mn2+4Ti2(Si2O7)2O2(OH)2F2 |
| 9.BE.55 | Bykovaite | (Ba,Na,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(H2O,F,OH)2 · 3.5H2O |
| 9.BE.55 | Nechelyustovite | (Ba,Sr,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(O,H2O,F)2 · 4.5H2O |
| 9.BE.55 | Bafertisite | Ba2Fe2+4Ti2(Si2O7)2O2(OH)2F2 |
| 9.BE.60 | Delindeite | (Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2O |
| 9.BE.62 | 'Orthochevkinite' | (Ce,La,Ca,Na,Th)4(Fe2+,Mg)2(Ti,Fe3+)3Si4O22 |
| 9.BE.62 va | 'Strontium Perrierite' | (Ce,Sr,La,Ca)4Fe2+(Ti,Zr,Fe)2Ti2(Si2O7)2O8 |
| 9.BE.62 | 'Chevkinite-(Nd)' | (Nd,REE)4(Fe2+,Mg)(Fe2+,Ti,Fe3+)2(Ti,Fe3+)2(Si2O7)2O8 ? |
| 9.BE.62 | 'Perrierite-(Nd)' | Nd4MgFe3+2Ti2(Si2O7)2O8 ? |
| 9.BE.65 | Bussenite | Na2Ba2Fe2+Ti(Si2O7)(CO3)(OH)3F |
| 9.BE.67 | Jinshajiangite | BaNaFe2+4Ti2(Si2O7)2O2(OH)2F |
| 9.BE.67 | Perraultite | BaNaMn2+4Ti2(Si2O7)2O2(OH)2F |
| 9.BE.70 | Dingdaohengite-(Ce) | (Ce,La)4Fe2+(Ti,Fe2+,Mg,Fe3+)2Ti2(Si2O7)2O8 |
| 9.BE.70 | Perrierite-(Ce) | Ce4MgFe3+2Ti2(Si2O7)2O8 |
| 9.BE.70 | Karnasurtite-(Ce) | (Ce,La,Th)(Ti,Nb)(Al,Fe)(Si2O7)(OH)4 · 3H2O |
| 9.BE.70 | Maoniupingite-(Ce) | (Ce,Ca)4(Fe3+,Ti,Fe2+,◻)(Ti,Fe3+,Fe2+,Nb)4(Si2O7)2O8 |
| 9.BE.70 | Matsubaraite | Sr4Ti5(Si2O7)2O8 |
| 9.BE.70 | Rengeite | Sr4ZrTi4(Si2O7)2O8 |
| 9.BE.70 | Polyakovite-(Ce) | (Ce,Ca)4(Mg,Fe2+)(Cr3+,Fe3+)2(Ti,Nb)2(Si2O7)2O8 |
| 9.BE.70 | Hezuolinite | (Sr,REE)4Zr(Ti,Fe3+)4(Si2O7)2O8 |
| 9.BE.70 | 'UM2008-53-SiO:SrTiZr' | Sr4ZrTi4(Si2O7)2O8 |
| 9.BE.70 | Chevkinite-(Ce) | Ce4(Ti,Fe2+,Fe3+)5O8(Si2O7)2 |
| 9.BE.70 | Perrierite-(La) | (La,Ce,Ca)4(Fe2+,Mn)(Ti,Fe3+,Al)4[(Si2O7)O4]2 |
| 9.BE.70 | Strontiochevkinite | (Sr,La,Ce,Ca)4Fe2+(Ti,Zr)2Ti2(Si2O7)2O8 |
| 9.BE.72 | Fersmanite | Ca4(Na,Ca)4(Ti,Nb)4(Si2O7)2O8F3 |
| 9.BE.75 | Belkovite | Ba3(Nb,Ti)6(Si2O7)2O12 |
| 9.BE.77 | Nasonite | Pb6Ca4(Si2O7)3Cl2 |
| 9.BE.80 | Melanotekite | Pb2Fe3+2(Si2O7)O2 |
| 9.BE.80 | Kentrolite | Pb2Mn3+2(Si2O7)O2 |
| 9.BE.82 | Alexkuznetsovite-(La) | La2Mn(CO3)(Si2O7) |
| 9.BE.82 | Tilleyite | Ca5(Si2O7)(CO3)2 |
| 9.BE.85 | Killalaite | Ca6.4(H0.6Si2O7)2(OH)2 |
| 9.BE.87 | Stavelotite-(La) | (La,Nd,Ca)3Mn2+3Cu(Mn3+,Fe3+,Mn4+)26(Si2O7)6O30 |
| 9.BE.90 | Magnesiorowlandite-(Y) | Y4(Mg,Fe)(Si2O7)2F2 |
| 9.BE.90 | Biraite-(Ce) | Ce2Fe2+(Si2O7)(CO3) |
| 9.BE.92 | Cervandonite-(Ce) | (Ce,Nd,La)(Fe3+,Fe2+,Ti,Al)3O2(Si2O7)(As3+O3)(OH) |
| 9.BE.92 | Chirvinskyite | (Na,Ca)13(Fe,Mn,◻)2(Ti,Zr)5(Si2O7)4(OH,O)12 · 2H2O |
| 9.BE.95 | Rusinovite | Ca10(Si2O7)3Cl2 |
| 9.BE.95 | Batisivite | BaV3+8Ti6(Si2O7)O22 |
| 9.BE.97 | Schlüterite-(Y) | (Y,REE)2AlSi2O7(OH)2F |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Lawsonite in petrology
An essential component of rock names highlighted in red, an accessory component in rock names highlighted in green.
Internet Links for Lawsonite
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References for Lawsonite
Reference List:
Davis, G. A. (1960) Lawsonite and pumpellyite in glaucophane schist, North Berkeley Hills, California, with notes on the X-ray crystallography of lawsonite, by A. Pabst. American Journal of Science, 258 (10) 689-704 doi:10.2475/ajs.258.10.689
Nitsch, K. -H. (1968) Die Stabilität von Lawsonit. Die Naturwissenschaften, 55 (8) 388 doi:10.1007/bf00593292
Nitsch, Karl-Heinz (1972) Das P - T - XCO2 Stabilitätsfeld von Lawsonit. Contributions to Mineralogy and Petrology, 34 (2) 116-134 doi:10.1007/bf00373768
Labotka, Theodore C., Rossman, George R. (1974) The infrared pleochroism of lawsonite: The orientation of the water and hydroxide groups. American Mineralogist, 59 (7-8). 799-806
Brown, E. H. (1977) Phase equilibria among pumpellyite, lawsonite, epidote and associated minerals in low grade metamorphic rocks. Contributions to Mineralogy and Petrology, 64 (2) 123-136 doi:10.1007/bf00371507
Baur, Werner H. (1978) Crystal structure refinement of lawsonite. American Mineralogist, 63 (3-4) 311-315
Le Cléac'h, Andrée; Gillet, Philippe (1990) IR and Raman spectroscopic study of natural lawsonite. European Journal of Mineralogy, 2 (1). p.43-54. doi:10.1127/ejm/2/1/0043
Schmidt, Max W., Poli, Stefano (1994) The stability of lawsonite and zoisite at high pressures: Experiments in CASH to 92 kbar and implications for the presence of hydrous phases in subducted lithosphere. Earth and Planetary Science Letters, 124 (1) 105-118 doi:10.1016/0012-821x(94)00080-8
Libowitzky, Eugen, Armbruster, Thomas (1995) Low-temperature phase transitions and role of hydrogen bonds in lawsonite. American Mineralogist, 80 (11) 1277-1285 doi:10.2138/am-1995-11-1217
Pawley, A. R., Redfern, Simon A. T., Holland, T. J. B. (1996) Volume behavior of hydrous minerals at high pressure and temperature: I. Thermal expansion of lawsonite, zoisite, clinozoisite, and diaspore. American Mineralogist, 81 (3). 335-340 doi:10.2138/am-1996-3-407
Holland, T. J. B., Redfern, Simon A. T., Pawley, A. R. (1996) Volume behavior of hydrous minerals at high pressure and temperature: II. Compressibilities of lawsonite, zoisite, clinozoisite, and epidote. American Mineralogist, 81 (3). 341-348 doi:10.2138/am-1996-3-408
Libowitzky, Eugen, Rossman, George R. (1996) FTIR spectroscopy of lawsonite between 82 and 325 K. American Mineralogist, 81 (9) 1080-1091 doi:10.2138/am-1996-9-1004
Scott, H. P., Williams, Q. (1999) An infrared spectroscopic study of lawsonite to 20 GPa. Physics and Chemistry of Minerals, 26 (6) 437-445 doi:10.1007/s002690050206
Sinogeikin, Stanislav V., Schilling, Frank R., Bass, Jay D. (2000) Single crystal elasticity of lawsonite. American Mineralogist, 85 (11) 1834-1837 doi:10.2138/am-2000-11-1230
Daniel, Isabelle, Fiquet, Guillaume, Gillet, Philippe, Schmidt, Max W., Hanfland, Michael (2000) High-pressure behaviour of lawsonite: a phase transition at 8.6 GPa. European Journal of Mineralogy, 12 (4) 721-733 doi:10.1127/0935-1221/2000/0012-0721
Grevel, Klaus-D., Nowlan, Elke Ursula, Fasshauer, Detlef W., Burchard, Michael (2000) In situ X-ray diffraction investigation of lawsonite and zoisite at high pressures and temperatures. American Mineralogist, 85 (1) 206-216 doi:10.2138/am-2000-0120
Meyerl, Hinrich-Wilhelm, Carpenterl, Michael A., Graeme-Barberl, Anne, Sondergeld, Peter, Schranz, Wilfried (2000) Local and macroscopic order parameter variations associated with low temperature phase transitions in lawsonite, CaAl2Si2O7(OH)2 . H2O. European Journal of Mineralogy, 12 (6) 1139-1150 doi:10.1127/ejm/12/6/1139
Sondergeld, P., Schranz, W., Kityk, A. V., Carpenter, M. A., Libowitzky, E. (2000) Ordering behaviour of the mineral lawsonite. Phase Transitions, 71 (3) 189-203 doi:10.1080/01411590008229651
Sondergeld, P., Schranz, W., Tröster, A., Carpenter, M. A., Libowitzky, E., Kityk, A. V. (2000) Optical, elastic, and dielectric studies of the phase transitions in lawsonite. Physical Review B, 62 (10) 6143-6147 doi:10.1103/physrevb.62.6143
Martín-Olalla, José -María, Hayward, Stuart A., Meyer, Hinrich-Wilhelm, Ramos, Saturio, Cerro, Jaime Del, Carpenter, Michael A. (2001) Phase transitions in lawsonite: a calorimetric study. European Journal of Mineralogy, 13 (1) 5-14 doi:10.1127/0935-1221/01/0013-0005
Meyer, Hinrich-Wilhelm, Marion, Stefan, Sondergeld, Peter, Carpenter, Michael A., Knight, Kevin S., Redfern, Simon A.T., Dove, Martin T. (2001) Displacive components of the low-temperature phase transitions in lawsonite. American Mineralogist, 86 (4) 566-577 doi:10.2138/am-2001-0419
Pawley, A. R., Allan, D. R. (2001) A high-pressure structural study of lawsonite using angle-dispersive powder-diffraction methods with synchrotron radiation. Mineralogical Magazine, 65 (1) 41-58 doi:10.1180/002646101550118
Sondergeld, P.; Schranz, W.; Tröster, A.; Kabelka, H.; Meyer, H.; Carpenter, M. A.; Lodziana, Z.; Kityk, A. V. (2001) Dielectric relaxation and order-parameter dynamics in lawsonite. Physical Review B, 64 (2). 024105 doi:10.1103/physrevb.64.024105
Hayward, Stuart A., Burriel, Ramon, Marion, Stefan, Meyer, Hinrich-Wilhelm, Carpenter, Michael A. (2002) Kinetic effects associated with the low-temperature phase transitions in lawsonite. European Journal of Mineralogy, 14 (6) 1145-1153 doi:10.1127/0935-1221/2002/0014-1145
Carpenter, Michael A., Meyer, Hinrich-Wilhelm, Sondergeld, Peter, Marion, Stefan, Knight, Kevin S. (2003) Spontaneous strain variations through the low temperature phase transitions of deuterated lawsonite. American Mineralogist, 88 (4) 534-546 doi:10.2138/am-2003-0407
Schilling, Frank R., Sinogeikin, Stanislav V., Bass, Jay D. (2003) Single-crystal elastic properties of lawsonite and their variation with temperature. Physics of the Earth and Planetary Interiors, 136 (1). 107-118 doi:10.1016/s0031-9201(03)00024-4
Sondergeld, P. (2005) Ordering and elasticity associated with low-temperature phase transitions in lawsonite. American Mineralogist, 90 (2) 448-456 doi:10.2138/am.2005.1243
Weber, S.-U., Grodzicki, M., Geiger, C. A., Lottermoser, W., Tippelt, G., Redhammer, G. J., Bernroider, M., Amthauer, G. (2006) 57Fe Mössbauer measurements and electronic structure calculations on natural lawsonites. Physics and Chemistry of Minerals, 34 (1) 1-9 doi:10.1007/s00269-006-0121-y
Mulcahy, Sean R., King, Robert L., Vervoort, Jeffrey D. (2009) Lawsonite Lu-Hf geochronology: A new geochronometer for subduction zone processes. Geology, 37 (11) 987-990 doi:10.1130/g30292a.1
Kozlova, S. G., Gabuda, S. P. (2013) Single-crystal 1H NMR data and hydrogen atom disorder in lawsonite, CaAl2[Si2O7](OH)2·H2O. Journal of Structural Chemistry, 54 (S1). S146-S151 doi:10.1134/s0022476613070159
Vitale Brovarone, A., Alard, O., Beyssac, O., Martin, L., Picatto, M. (2014) Lawsonite metasomatism and trace element recycling in subduction zones. Journal of Metamorphic Geology, 32 (5) 489-514 doi:10.1111/jmg.12074
Martin, L. A. J., Hermann, J., Gauthiez-Putallaz, L., Whitney, D. L., Vitale Brovarone, A., Fornash, K. F., Evans, N. J. (2014) Lawsonite geochemistry and stability - implication for trace element and water cycles in subduction zones. Journal of Metamorphic Geology, 32 (5) 455-478 doi:10.1111/jmg.12093
Fornash, Katherine F., Whitney, Donna L., Seaton, Nicholas C.A. (2019) Lawsonite composition and zoning as an archive of metamorphic processes in subduction zones. Geosphere, 15. 24-46 doi:10.1130/ges01455.1
Whitney, Donna L., Fornash, Katherine F., Kang, Patricia, Ghent, Edward D., Martin, Laure, Okay, Aral I., Vitale Brovarone, Alberto (2020) Lawsonite composition and zoning as tracers of subduction processes: A global review. Lithos, 370. 105636pp. doi:10.1016/j.lithos.2020.105636
Localities for Lawsonite
Showing 170 localities.
Locality List
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(TL) - Type Locality for a valid mineral species.
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All localities listed without proper references should be considered as questionable.
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The
Reed Station, Tiburon Peninsula, Marin County, California, USA