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Tristramite

A valid IMA mineral species
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About TristramiteHide

03460420017271927207028.jpg
Sir Tristram, King of Lyonesse
Formula:
(Ca,U4+,Fe3+)(PO4,SO4) · 2H2O
Colour:
Light yellow, greenish-yellow
Lustre:
Vitreous
Hardness:
3 - 4
Specific Gravity:
3.8 - 4.2
Crystal System:
Hexagonal
Name:
Named after Tristram, a medieval figure of the Arthurian legend and a possible resident of the discovery area.
Compare the very similar brockite which contains Th instead of U.


Unique IdentifiersHide

Mindat ID:
4025
Long-form identifier:
mindat:1:1:4025:5

IMA Classification of TristramiteHide

Classification of TristramiteHide

8.CJ.45

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
J : With only large cations
40.4.7.6

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
4 : (AB)5(XO4)2·xH2O
22.3.22

22 : Phosphates, Arsenates or Vanadates with other Anions
3 : Phosphates, arsenates or vanadates with sulphates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
TtmIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of TristramiteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of TristramiteHide

Vitreous
Transparency:
Translucent
Colour:
Light yellow, greenish-yellow
Hardness:
3 - 4 on Mohs scale
Cleavage:
None Observed
Density:
3.8 - 4.2 g/cm3 (Measured)    4.18 g/cm3 (Calculated)

Optical Data of TristramiteHide

Type:
Uniaxial (+)
RI values:
nω = 1.644(2) nε = 1.664(2)
Max. Birefringence:
δ = 0.020
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Pleochroism:
Not Visible
Comments:
Under crossed polars there is a tendency to show an anomalous blue birefringence colour.

Chemistry of TristramiteHide

Mindat Formula:
(Ca,U4+,Fe3+)(PO4,SO4) · 2H2O
Element Weights:
Element% weight
O56.112 %
Ca23.427 %
P18.105 %
H2.357 %

Calculated from ideal end-member formula.

Crystallography of TristramiteHide

Crystal System:
Hexagonal
Class (H-M):
622 - Trapezohedral
Space Group:
P6222
Cell Parameters:
a = 6.913(6) Å, c = 6.422(6) Å
Ratio:
a:c = 1 : 0.929
Unit Cell V:
265.79 ų (Calculated from Unit Cell)
Z:
3

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.99 Å(100)
2.83 Å(100)
2.14 Å(50)
1.850 Å(50)
5.99 Å(40)
4.37 Å(40)
3.46 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):

Type Occurrence of TristramiteHide

General Appearance of Type Material:
Fine-grained aggregates of acicular to fibrous crystals and as coarser-grained infillings occupying fine fractures and cavities.
Place of Conservation of Type Material:
1) Geochemistry and Petrology Division of the Institute of Geological Sciences
2) British Museum (Natural History), London, England
Geological Setting of Type Material:
Uraninite (var. pitchblende)-bearing quartz veins, with sulfides
Associated Minerals at Type Locality:

Synonyms of TristramiteHide

Other Language Names for TristramiteHide

German:Tristramit
Simplified Chinese:水磷钙铀矿
Spanish:Tristramita

Relationship of Tristramite to other SpeciesHide

Other Members of Rhabdophane Group:
Brockite(Ca,Th,Ce)PO4 · H2OHex. 622 : P6222
Grayite(Th,Pb,Ca)(PO4) · H2OHex. 622 : P6222
Rhabdophane-(Ce)Ce(PO4) · 0.6H2OTrig. 32 : P3121
Rhabdophane-(La)La(PO4) · H2OHex. 622 : P6222
Rhabdophane-(Nd)Nd(PO4) · H2OHex. 622 : P6222
Rhabdophane-(Y)YPO4 · H2OHex. 622 : P6222
'UM1993-07-PO:CaCeHLa'(Ca,Ce,La,REE)PO4 · nH2OHex. 622 : P6222

Related Minerals - Strunz-mindat GroupingHide

8.CJ.AirditeSr(V4+O)2(PO4)2 · 4H2OMon. m : Bb
8.CJ.DobšináiteCa2Ca(AsO4)2 · 2H2OMon. 2/m : P21/b
8.CJ.SainfelditeCa5(AsO4)2(AsO3OH)2 · 4H2OMon. 2/m : B2/b
8.CJ.CaesiumpharmacosideriteCsFe3+4[(AsO4)3(OH)4] · 4H2OIso. 43m : P43m
8.CJ.JeankempiteCa5(AsO4)2(HAsO4)2 · 7H2OTric. 1 : P1
8.CJ.05Stercorite(NH4)Na(PO3OH) · 4H2OTric. 1 : P1
8.CJ.10Swaknoite(NH4)2Ca(PO3OH)2 · H2OOrth.
8.CJ.10Mundrabillaite(NH4)2Ca(PO3OH)2 · H2OMon. m : Pm
8.CJ.15NabaphiteNaBaPO4 · 9H2OIso. 23 : P213
8.CJ.15NastrophiteNa(Sr,Ba)PO4 · 9H2OIso. 23 : P213
8.CJ.20HaidingeriteCaHAsO4 · H2OOrth. mmm(2/m2/m2/m) : Pbcn
8.CJ.25Rhabdophane-(Y)YPO4 · H2OHex. 622 : P6222
8.CJ.25VladimiriteCa4(AsO4)2(AsO3OH) · 4H2OMon. 2/m : P21/b
8.CJ.27'Churchite-(Dy)'(Dy,Sm,Gd,Nd)PO4 · 2H2OMon.
8.CJ.30FerrarisiteCa5(AsO4)2(HAsO4)2 · 9H2OTric. 1 : P1
8.CJ.35FulbrightiteCa(V4+O)2(As5+O4)2 · 4H2OTric. 1 : P1
8.CJ.35Machatschkiite(Ca,Na)6(AsO4)(HAsO4)3(PO4,SO4) · 15H2OTrig. 3m : R3c
8.CJ.40RauenthaliteCa3(AsO4)2 · 10H2OTric. 1 : P1
8.CJ.40PhaunouxiteCa3(AsO4)2 · 11H2OTric.
8.CJ.45Brockite(Ca,Th,Ce)PO4 · H2OHex. 622 : P6222
8.CJ.45Smirnovskite(Th,Ca)PO4 · nH2OHex. 622 : P6222
8.CJ.45Rhabdophane-(Ce)Ce(PO4) · 0.6H2OTrig. 32 : P3121
8.CJ.45Rhabdophane-(La)La(PO4) · H2OHex. 622 : P6222
8.CJ.45Rhabdophane-(Nd)Nd(PO4) · H2OHex. 622 : P6222
8.CJ.45Grayite(Th,Pb,Ca)(PO4) · H2OHex. 622 : P6222
8.CJ.45ŠtěpiteU(AsO3OH)2 · 4H2O Tet. 4/mmm(4/m2/m2/m) : I41/acd
8.CJ.47VysokýiteU4+[AsO2(OH)2]4 · 4H2OTric. 1 : P1
8.CJ.50Churchite-(Y)Y(PO4) · 2H2OMon. 2/m : B2/b
8.CJ.50BrushiteCa(PO3OH) · 2H2OMon. m : Bb
8.CJ.50ArdealiteCa2(PO3OH)(SO4) · 4H2OMon. m : Bb
8.CJ.50PharmacoliteCa(HAsO4) · 2H2OMon. m
8.CJ.50'Churchite-(Nd)'Nd(PO4) · 2H2OMon.
8.CJ.55McneariteNaCa5(AsO4)(HAsO4)4 · 4H2OTric.
8.CJ.60DorfmaniteNa2(PO3OH) · 2H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CJ.65SincositeCa(V4+O)2(PO4)2 · 4H2OTet. 4/mmm(4/m2/m2/m) : P42/nnm
8.CJ.65BariosincositeBa(V4+O)2(PO4)2 · 4H2OTet.
8.CJ.70CatalanoiteNa2(PO3OH) · 8H2OOrth. mmm(2/m2/m2/m) : Ibca
8.CJ.75GuériniteCa6(HAsO4)3(AsO4)2 · 10.5H2OMon. 2/m : P21/b
8.CJ.85Ningyoite(U,Ca,Ce)2(PO4)2 · 1-2H2OOrth.

Fluorescence of TristramiteHide

Does not fluoresce in either short-wave or long-wave UV

Other InformationHide

Notes:
Radioactive
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for TristramiteHide

References for TristramiteHide

Localities for TristramiteHide

Showing 8 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
China
 
  • Inner Mongolia
    • Xilingol League (Xilinguole Prefecture)
      • Erenhot City (Erlianhaote Co.)
Guang Fan et al. (2013)
Madagascar
 
  • Amoron'i Mania
    • Ambositra District
      • Tsarasaotra
Berger et al. (2014)
UK (TL)
 
  • England
    • Cornwall
      • Breage
        • Rinsey
Atkin et al. (1983)
Atkin et al. (1983)
      • Carharrack
        • Wheal Damsel United Mines
Golley et al. (1995)
      • Ludgvan
        • Trencrom
Bernard et al. (2004)
      • Redruth
        • Wheal Buller and Beauchamp
Golley et al. (1995)
      • St Ives
        • Carbis Bay
          • Providence Mines
Golley et al. (1995)
 
and/or  
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