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Sincosite

A valid IMA mineral species - grandfathered
This page kindly sponsored by Thomas Loomis
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About SincositeHide

Formula:
Ca(V4+O)2(PO4)2 · 4H2O
Colour:
Grass-green, yellow- to olive-green, brownish green, blue-green; light green, olive-green, brownish green, yellowish green, bluish green in transmitted light.
Lustre:
Vitreous, Pearly, Sub-Metallic, Dull
Hardness:
1 - 2
Specific Gravity:
2.84 - 2.98
Crystal System:
Tetragonal
Member of:
Name:
Named after its discovery locality at Sincos, Junín, Cerro de Pasco, Alcides Carrión Province, Pasco Department, Peru.
Isostructural with:
Determined structures for sincosite are triclinic (see Sincosite (triclinic polytype)), as is its arsenate analogue fulbrightite. Disorder, poor crystallinity, and quasi-tetragonal symmetry of its vanadyl-phosphate sheets make determination of the correct space group and structure difficult for most samples. In the absence of a tetragonal structure, the P1 "triclinic polytype" cannot be demonstrated to be a polytype and may simply be the correct space group assignment for the mineral. However, as this is a layered structure, we cannot rule out polytypism from translation of the interlayer Ca(H2O)4 groups. (C. Emproto 1/2026)

Triclinic (1A) sincosite is isostructural with fulbrightite. Related to other members of the sincosite group through polytypism.

Structurally related to the meta-autunite group.


Unique IdentifiersHide

Mindat ID:
3671
Long-form identifier:
mindat:1:1:3671:5

Similar NamesHide

Native ZincA valid IMA mineral species - grandfatheredZn
ZinciteA valid IMA mineral species - grandfatheredZnO
ZinkeniteA valid IMA mineral species - grandfatheredPb9Sb22S42
ZinkositeA valid IMA mineral species - grandfathered - questionableZnSO4

Classification of SincositeHide

06456030017683497231659.jpg
Sincosite-type sheet

The sincosite-type sheet.

IMA Classification of SincositeHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca(V4+O)2(PO4)2·4H2O
First published:
1922
8.CJ.65

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
J : With only large cations
42.11.19.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
19.10.10

19 : Phosphates
10 : Phosphates of Pb, Th, V and Bi

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
ScsIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of SincositeHide

Vitreous, Pearly, Sub-Metallic, Dull
Transparency:
Transparent, Translucent
Comment:
Lustre pearly on basal cleavage; submetallic if partially dehydrated
Colour:
Grass-green, yellow- to olive-green, brownish green, blue-green; light green, olive-green, brownish green, yellowish green, bluish green in transmitted light.
Comment:
Typically zoned parallel to {001}.
Streak:
Green
Hardness:
1 - 2 on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
On (001) perfect, on {110} good, on {010} poor.
Density:
2.84 - 2.98 g/cm3 (Measured)    2.97 g/cm3 (Calculated)
Comment:
Actual value for measured density is ~2.84 to 2.98.

Optical Data of SincositeHide

Type:
Uniaxial (-)
RI values:
nα = 1.67 - 1.675 nβ = 1.69 nγ = 1.693 - 1.694 nω = 1.68 nε = 1.655
2V:
Measured: 10° to 83°
Max. Birefringence:
δ = 0.025
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Pleochroism:
Visible
Comments:
E = X = Nearly colourless to pale yellow
O = Z = Grey-green
Comments:
Partially biaxial (-) if dehydrated.

Chemistry of SincositeHide

Mindat Formula:
Ca(V4+O)2(PO4)2 · 4H2O
Element Weights:
Element% weight
O51.379 %
V23.370 %
P14.209 %
Ca9.193 %
H1.850 %

Calculated from ideal end-member formula.
O
V
P
Ca
H

Crystallography of SincositeHide

Polytype:
Formula:
Crystal System:
Class (H-M)
Space Group:
Space Group Setting:
Cell Parameters:
Ratio:
Unit Cell Volume (calc):
Z:
Comment:
Sincosite (triclinic polytype)
Ca(VO)2(PO4)2 · 5H2O
Triclinic 
1 - Pedial
P1
 
a = 6.3531(12) Å, b = 6.3567(14) Å, c = 6.6050(18) Å
α = 106.995(22)°, β = 94.115(19)°, γ = 90.006(16)°
a:b:c = 0.999 : 1 : 1.039
V 254.37 ų
(Calculated from Unit Cell)
 
 

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0015719SincositeFranke W A, Luger P, Weber M, Ivanova T I (1997) Low hydrothermal growth of sincosite Ca(VO/PO4)2*4H2O Zapiski Vserossijskogo Mineralogicheskogo Obshchestva 126N2 85-861997synthetic0293
0012705SincositeKang H Y, Lee W C, Wang S L (1992) Hydrothermal synthesis and structural characterization of four layered vanadyl(IV) phosphate hydrates A(VO)2(PO4)2*4H2O (A=Co,Ca,Sr,Pb) Inorganic Chemistry 31 4743-47481992synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.35 Å(100)
3.190 Å(80)
3.511 Å(60)
2.682 Å(50)
2.907 Å(40)
2.100 Å(40)
3.841 Å(25)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47c : [Carbonates, phosphates, borates, nitrates]
47e : [Vanadates, chromates, manganates]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
50 : Coal and/or oil shale minerals<0.36

Type Occurrence of SincositeHide

Place of Conservation of Type Material:
National School of Mines, Paris, France. Harvard University, Cambridge, Massachusetts, USA: #99139, 101699. U.S. National Museum of Natural History, Washington, D.C., USA: #95096.
Geological Setting of Type Material:
Veinlets in Cretaceous black carbonaceous shale
Associated Minerals at Type Locality:

Synonyms of SincositeHide

Other Language Names for SincositeHide

Dutch:Sincosiet
German:Sincosit
Spanish:Sincosita

Relationship of Sincosite to other SpeciesHide

Member of:
Other Members of Sincosite Group:
AirditeSr(V4+O)2(PO4)2 · 4H2OMon. m : Bb
BariosincositeBa(V4+O)2(PO4)2 · 4H2OTet.
FulbrightiteCa(V4+O)2(As5+O4)2 · 4H2OTric. 1 : P1

Common AssociatesHide

Associations Based on Photo Data:
23 photos of Sincosite associated with MinyuliteKAl2(PO4)2F · 4H2O
12 photos of Sincosite associated with Phosphovanadylite-CaCa[V4+4P2O12(OH)4] · 12H2O
6 photos of Sincosite associated with QuartzSiO2
4 photos of Sincosite associated with Native SeleniumSe
2 photos of Sincosite associated with Fernandinite(Ca,K)(V5+,V4+,Fe2+)8O20 · 10H2O

Related Minerals - Strunz-mindat GroupingHide

8.CJ.AirditeSr(V4+O)2(PO4)2 · 4H2OMon. m : Bb
8.CJ.DobšináiteCa2Ca(AsO4)2 · 2H2OMon. 2/m : P21/b
8.CJ.SainfelditeCa5(AsO4)2(AsO3OH)2 · 4H2OMon. 2/m : B2/b
8.CJ.CaesiumpharmacosideriteCsFe3+4[(AsO4)3(OH)4] · 4H2OIso. 43m : P43m
8.CJ.JeankempiteCa5(AsO4)2(HAsO4)2 · 7H2OTric. 1 : P1
8.CJ.05Stercorite(NH4)Na(PO3OH) · 4H2OTric. 1 : P1
8.CJ.10Swaknoite(NH4)2Ca(PO3OH)2 · H2OOrth.
8.CJ.10Mundrabillaite(NH4)2Ca(PO3OH)2 · H2OMon. m : Pm
8.CJ.15NabaphiteNaBaPO4 · 9H2OIso. 23 : P213
8.CJ.15NastrophiteNa(Sr,Ba)PO4 · 9H2OIso. 23 : P213
8.CJ.20HaidingeriteCaHAsO4 · H2OOrth. mmm(2/m2/m2/m) : Pbcn
8.CJ.25Rhabdophane-(Y)YPO4 · H2OHex. 622 : P6222
8.CJ.25VladimiriteCa4(AsO4)2(AsO3OH) · 4H2OMon. 2/m : P21/b
8.CJ.27'Churchite-(Dy)'(Dy,Sm,Gd,Nd)PO4 · 2H2OMon.
8.CJ.30FerrarisiteCa5(AsO4)2(HAsO4)2 · 9H2OTric. 1 : P1
8.CJ.35FulbrightiteCa(V4+O)2(As5+O4)2 · 4H2OTric. 1 : P1
8.CJ.35Machatschkiite(Ca,Na)6(AsO4)(HAsO4)3(PO4,SO4) · 15H2OTrig. 3m : R3c
8.CJ.40RauenthaliteCa3(AsO4)2 · 10H2OTric. 1 : P1
8.CJ.40PhaunouxiteCa3(AsO4)2 · 11H2OTric.
8.CJ.45Brockite(Ca,Th,Ce)PO4 · H2OHex. 622 : P6222
8.CJ.45Smirnovskite(Th,Ca)PO4 · nH2OHex. 622 : P6222
8.CJ.45Rhabdophane-(Ce)Ce(PO4) · 0.6H2OTrig. 32 : P3121
8.CJ.45Rhabdophane-(La)La(PO4) · H2OHex. 622 : P6222
8.CJ.45Rhabdophane-(Nd)Nd(PO4) · H2OHex. 622 : P6222
8.CJ.45Tristramite(Ca,U4+,Fe3+)(PO4,SO4) · 2H2OHex. 622 : P6222
8.CJ.45Grayite(Th,Pb,Ca)(PO4) · H2OHex. 622 : P6222
8.CJ.45ŠtěpiteU(AsO3OH)2 · 4H2O Tet. 4/mmm(4/m2/m2/m) : I41/acd
8.CJ.47VysokýiteU4+[AsO2(OH)2]4 · 4H2OTric. 1 : P1
8.CJ.50Churchite-(Y)Y(PO4) · 2H2OMon. 2/m : B2/b
8.CJ.50BrushiteCa(PO3OH) · 2H2OMon. m : Bb
8.CJ.50ArdealiteCa2(PO3OH)(SO4) · 4H2OMon. m : Bb
8.CJ.50PharmacoliteCa(HAsO4) · 2H2OMon. m
8.CJ.50'Churchite-(Nd)'Nd(PO4) · 2H2OMon.
8.CJ.55McneariteNaCa5(AsO4)(HAsO4)4 · 4H2OTric.
8.CJ.60DorfmaniteNa2(PO3OH) · 2H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CJ.65BariosincositeBa(V4+O)2(PO4)2 · 4H2OTet.
8.CJ.70CatalanoiteNa2(PO3OH) · 8H2OOrth. mmm(2/m2/m2/m) : Ibca
8.CJ.75GuériniteCa6(HAsO4)3(AsO4)2 · 10.5H2OMon. 2/m : P21/b
8.CJ.85Ningyoite(U,Ca,Ce)2(PO4)2 · 1-2H2OOrth.

Other InformationHide

Notes:
Readily soluble in dilute acids to a blue solution. Insoluble in water.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for SincositeHide

References for SincositeHide

Reference List:

Localities for SincositeHide

Showing 15 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Germany
 
  • Thuringia
    • Greiz District
      • Kauern
Witzke et al. (2001)
Peru (TL)
 
  • Junín
    • Jauja province
      • Sincos district
Progr. Abstr. et al. (1948) +2 other references
Spain
 
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • Tenerife
        • Arona
Dill et al. (2023)
Dill et al. (2023)
USA
 
  • Arkansas
    • Garland County
      • Wilson Springs (Potash Sulfur Springs)
        • Union Carbide Mine
Howard (2017)
Howard +1 other reference
  • Idaho
    • Bear Lake County
Ream (1995)
    • Caribou County
      • Blackfoot River Mining District
Mandarino (1999)
      • Soda Springs Area
[Sincosite (triclinic polytype)] Kampf et al. (2013)
  • Nevada
    • Eureka County
      • Carlin Trend
        • Maggie Creek Mining Subdistrict
Newmont Mining Corporation
      • Lynn Mining District
Jensen et al. (1995)
  • New Mexico
    • Cibola County
Northrop et al. (1996)
NMBMMR Memoir 15 Geology and Technology ...
  • South Dakota
    • Lawrence County
      • Lead Mining District
Loomis (1999)
 
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