Haidingerite
A valid IMA mineral species - grandfathered
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About Haidingerite
Formula:
CaHAsO4 · H2O
Colour:
Colorless, white; colorless in transmitted light
Lustre:
Sub-Vitreous, Greasy, Silky, Pearly
Hardness:
2 - 2½
Specific Gravity:
2.848
Crystal System:
Orthorhombic
Name:
Named in 1827 by Edward Turner to honour Wilhelm Karl von Haidinger (5 February 1795, Vienna, Austria – 19 March 1871, Dornbach, Austria). Haidinger was a pupil of Friedrich Mohs and translated some of his works. Director of the Haidinger porcelain factory at Elbogen, Austria. Later, he was a councilor of mines in Vienna and director of the Imperial Geological Institute. He was a prolific researcher and author.
Unique Identifiers
Mindat ID:
1797
Long-form identifier:
mindat:1:1:1797:4
Similar Names
| Haidingerite (of Berthier) | A synonym of Berthierite |
IMA Classification of Haidingerite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca(As5+O3OH)·H2O
First published:
1825
Classification of Haidingerite
8.CJ.20
8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
J : With only large cations
8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
J : With only large cations
39.1.5.1
39 : HYDRATED ACID PHOSPHATES,ARSENATES AND VANADATES
1 : A[HXO4]·xH2O
39 : HYDRATED ACID PHOSPHATES,ARSENATES AND VANADATES
1 : A[HXO4]·xH2O
20.2.7
20 : Arsenates (also arsenates with phosphate, but without other anions)
2 : Arsenates of Be, Mg, Ca or Ba
20 : Arsenates (also arsenates with phosphate, but without other anions)
2 : Arsenates of Be, Mg, Ca or Ba
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Hdi | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Haidingerite
Sub-Vitreous, Greasy, Silky, Pearly
Transparency:
Transparent, Translucent
Comment:
Lustre pearly on cleavage.
Colour:
Colorless, white; colorless in transmitted light
Streak:
White
Hardness:
2 - 2½ on Mohs scale
Tenacity:
Sectile
Cleavage:
Perfect
On {010}, perfect.
On {010}, perfect.
Density:
2.848 g/cm3 (Measured) 2.971 g/cm3 (Calculated)
Comment:
2.962 ± 0.008 (artificial material).
Optical Data of Haidingerite
Type:
Biaxial (+)
RI values:
nα = 1.590 nβ = 1.602 nγ = 1.638
2V:
Measured: 58° , Calculated: 62°
Birefringence:
0.048
Max. Birefringence:
δ = 0.048
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Moderate
Dispersion:
r > v distinct
Optical Extinction:
parallel
Pleochroism:
Non-pleochroic
Chemistry of Haidingerite
Mindat Formula:
CaHAsO4 · H2O
Element Weights:
Elements listed:
Crystallography of Haidingerite
Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pbcn
Cell Parameters:
a = 6.93 Å, b = 16.15 Å, c = 7.94 Å
Ratio:
a:b:c = 0.429 : 1 : 0.492
Unit Cell V:
888.64 ų (Calculated from Unit Cell)
Z:
8
Morphology:
Isolated crystals rare, brushy sprays of somewhat equidimensional to short prismatic [001] or [100]. Fine-grained botryoidal to fibrous coatings.
Twinning:
On {110}, rare.
Comment:
Chosen cell is Pcnb
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0009421 | Haidingerite | Ferraris G, Jones D W, Yerkess J (1972) A neutron and X-ray refinement of the crystal structure of CaHAsO4*H2O (haidingerite) Acta Crystallographica B28 209-214 | ![]() | 1972 | synthetic | 0 | 293 |
| 0009420 | Haidingerite | Ferraris G, Jones D W, Yerkess J (1972) A neutron and X-ray refinement of the crystal structure of CaHAsO4*H2O (haidingerite) Acta Crystallographica B28 209-214 | ![]() | 1972 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 8.06 Å | (80) |
| 5.25 Å | (80) |
| 5.22 Å | (100) |
| 3.84 Å | (80) |
| 3.19 Å | (80) |
| 3.15 Å | (80) |
| 3.11 Å | (70) |
| 2.96 Å | (90) |
Comments:
ICDD 18-0288, also 17-0161
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47d : [Arsenates, antimonates, selenates, bismuthinates] |
Geological Setting:
Oxidized zones of arsenical ore deposits.
Type Occurrence of Haidingerite
Place of Conservation of Type Material:
No designated type material.
Synonyms of Haidingerite
Other Language Names for Haidingerite
Common Associates
Associations Based on Photo Data:
| 7 photos of Haidingerite associated with Pharmacolite | Ca(HAsO4) · 2H2O |
| 1 photo of Haidingerite associated with Erythrite | Co3(AsO4)2 · 8H2O |
| 1 photo of Haidingerite associated with Realgar | As4S4 |
| 1 photo of Haidingerite associated with Phaunouxite | Ca3(AsO4)2 · 11H2O |
| 1 photo of Haidingerite associated with Rauenthalite | Ca3(AsO4)2 · 10H2O |
| 1 photo of Haidingerite associated with Picropharmacolite | Ca4Mg(AsO4)2(HAsO4)2 · 11H2O |
| 1 photo of Haidingerite associated with Sainfeldite | Ca5(AsO4)2(AsO3OH)2 · 4H2O |
| 1 photo of Haidingerite associated with Brassite | Mg(HAsO4) · 4H2O |
Related Minerals - Strunz-mindat Grouping
| 8.CJ. | Airdite | Sr(V4+O)2(PO4)2 · 4H2O |
| 8.CJ. | Dobšináite | Ca2Ca(AsO4)2 · 2H2O |
| 8.CJ. | Sainfeldite | Ca5(AsO4)2(AsO3OH)2 · 4H2O |
| 8.CJ. | Caesiumpharmacosiderite | CsFe3+4[(AsO4)3(OH)4] · 4H2O |
| 8.CJ. | Jeankempite | Ca5(AsO4)2(HAsO4)2 · 7H2O |
| 8.CJ.05 | Stercorite | (NH4)Na(PO3OH) · 4H2O |
| 8.CJ.10 | Swaknoite | (NH4)2Ca(PO3OH)2 · H2O |
| 8.CJ.10 | Mundrabillaite | (NH4)2Ca(PO3OH)2 · H2O |
| 8.CJ.15 | Nabaphite | NaBaPO4 · 9H2O |
| 8.CJ.15 | Nastrophite | Na(Sr,Ba)PO4 · 9H2O |
| 8.CJ.25 | Rhabdophane-(Y) | YPO4 · H2O |
| 8.CJ.25 | Vladimirite | Ca4(AsO4)2(AsO3OH) · 4H2O |
| 8.CJ.27 | 'Churchite-(Dy)' | (Dy,Sm,Gd,Nd)PO4 · 2H2O |
| 8.CJ.30 | Ferrarisite | Ca5(AsO4)2(HAsO4)2 · 9H2O |
| 8.CJ.35 | Fulbrightite | Ca(V4+O)2(As5+O4)2 · 4H2O |
| 8.CJ.35 | Machatschkiite | (Ca,Na)6(AsO4)(HAsO4)3(PO4,SO4) · 15H2O |
| 8.CJ.40 | Rauenthalite | Ca3(AsO4)2 · 10H2O |
| 8.CJ.40 | Phaunouxite | Ca3(AsO4)2 · 11H2O |
| 8.CJ.45 | Brockite | (Ca,Th,Ce)PO4 · H2O |
| 8.CJ.45 | Smirnovskite | (Th,Ca)PO4 · nH2O |
| 8.CJ.45 | Rhabdophane-(Ce) | Ce(PO4) · 0.6H2O |
| 8.CJ.45 | Rhabdophane-(La) | La(PO4) · H2O |
| 8.CJ.45 | Rhabdophane-(Nd) | Nd(PO4) · H2O |
| 8.CJ.45 | Tristramite | (Ca,U4+,Fe3+)(PO4,SO4) · 2H2O |
| 8.CJ.45 | Grayite | (Th,Pb,Ca)(PO4) · H2O |
| 8.CJ.45 | Štěpite | U(AsO3OH)2 · 4H2O |
| 8.CJ.47 | Vysokýite | U4+[AsO2(OH)2]4 · 4H2O |
| 8.CJ.50 | Churchite-(Y) | Y(PO4) · 2H2O |
| 8.CJ.50 | Brushite | Ca(PO3OH) · 2H2O |
| 8.CJ.50 | Ardealite | Ca2(PO3OH)(SO4) · 4H2O |
| 8.CJ.50 | Pharmacolite | Ca(HAsO4) · 2H2O |
| 8.CJ.50 | 'Churchite-(Nd)' | Nd(PO4) · 2H2O |
| 8.CJ.55 | Mcnearite | NaCa5(AsO4)(HAsO4)4 · 4H2O |
| 8.CJ.60 | Dorfmanite | Na2(PO3OH) · 2H2O |
| 8.CJ.65 | Sincosite | Ca(V4+O)2(PO4)2 · 4H2O |
| 8.CJ.65 | Bariosincosite | Ba(V4+O)2(PO4)2 · 4H2O |
| 8.CJ.70 | Catalanoite | Na2(PO3OH) · 8H2O |
| 8.CJ.75 | Guérinite | Ca6(HAsO4)3(AsO4)2 · 10.5H2O |
| 8.CJ.85 | Ningyoite | (U,Ca,Ce)2(PO4)2 · 1-2H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Haidingerite
mindat.org URL:
https://www.mindat.org/min-1797.html
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References for Haidingerite
Reference List:
Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 p.82
Cassien, M., Herpin, Paulette, Permingeat, François (1966) Structure cristalline de la haidingérite. Bulletin de Minéralogie, 89 (1) 18-22 doi:10.3406/bulmi.1966.5927
Jagannathan Iyer, V., Nabar, M. A. (1970) The Infra-red Spectrum of Synthetic Haidingerite, CaHAsO4 · H2O. Zeitschrift für Naturforschung B, 25. 1077-1079 doi:10.1515/znb-1970-1001
Ferraris, G., Jones, D. W., Yerkess, J. (1972) A neutron and X-ray refinement of the crystal structure of CaHAsO4.H2O (haidingerite) Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 28 (1) 209-214 doi:10.1107/s0567740872002080
Catti, Michele, Franchini-Angela, Marinella (1979) Krautite, Mn(H2O)(AsO3OH): crystal structure, hydrogen bonding and relations with haidingerite and pharmacolite. American Mineralogist, 64 (11-12) 1248-1254
Localities for Haidingerite
Showing 30 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Czech Republic (TL) | |
| Palache et al. (1951) +1 other reference |
| Palache et al. (1951) +1 other reference | |
France | |
| Bari (1982) |
| Fleischer et al. (1982) |
| Bari (1982) +1 other reference | |
| This mine worked the same vein as Gabe ... +2 other references | |
Germany | |
| Walenta (1992) |
| Palache et al. (1951) +1 other reference |
| Weiß (1990) |
| Weiß (1990) | |
| Hofmann (1992) |
| Stolze et al. (10/2020) |
| Palache et al. (1951) | |
| www.dergraul.de (2001) |
| Palache et al. (1951) | |
Greece | |
| Rieck et al. (2018) |
| Rieck et al. (2018) | |
| Rieck et al. (2018) | |
Morocco | |
| Weiß (2006) |
| |
Russia | |
| Abrosimova et al. (2015) |
Switzerland | |
| Stalder et al. (1998) +1 other reference |
USA | |
| Dunning (1988) |
| Castor et al. (2004) | |
| - (2005) | |
| - (2005) | |
| Barrick Gold Corporation | |
| - (2005) | |
| Palache et al. (1951) +1 other reference |
| Bayliss et al. (1987) |
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Jáchymov, Karlovy Vary District, Karlovy Vary Region, Czech Republic