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Garrelsite

A valid IMA mineral species - grandfathered
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About GarrelsiteHide

05909910017271923428980.jpg
Robert M. Garrels
Formula:
Ba3NaSi2B7O16(OH)4
Colour:
Colourless
Lustre:
Vitreous
Hardness:
6
Specific Gravity:
3.68
Crystal System:
Monoclinic
Name:
Named by C. Milton, J.M. Axelrod, and F.S. Grimaldi in 1955 in honor of Robert Minard Garrels (24 August 1916, Detroit, Michigan, USA – 8 March 1988, St. Petersburg, Florida, USA), geochemist. He was Chief, Solid State Group, Geochemistry and Petrology Branch, U. S. Geological Survey, when the mineral was discovered. He also was a professor at several institutions including Northwestern, Harvard, and U. Hawaii. His work on aqueous geochemistry was revolutionary. He was the recipient of several awards including the Penrose, Wollaston, and Roebling Medals.
Minute dipyramidal crystals.


Unique IdentifiersHide

Mindat ID:
1652
Long-form identifier:
mindat:1:1:1652:6

Similar NamesHide

Garrelsite-VBa3NaSi2B7O16(OH)4

IMA Classification of GarrelsiteHide

Classification of GarrelsiteHide

9.AJ.15

9 : SILICATES (Germanates)
A : Nesosilicates
J : Nesosilicates with BO3 triangles and/or B[4], Be[4] tetrahedra, cornersharing with SiO4
54.2.4.1

54 : NESOSILICATES Borosilicates and Some Beryllosilicates
2 : Borosilicates and Some Beryllosilicates with B in [4] coordination
17.5.31

17 : Silicates Containing other Anions
5 : Borosilicates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
GrrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of GarrelsiteHide

Vitreous
Transparency:
Transparent
Colour:
Colourless
Streak:
White
Hardness:
Cleavage:
Perfect
{001}
Density:
3.68 g/cm3 (Measured)    3.89 g/cm3 (Calculated)

Optical Data of GarrelsiteHide

Type:
Biaxial
RI values:
nα = 1.620(3) nβ = 1.633(3) nγ = 1.640(3)
2V:
Measured: 53° to 57°
Max. Birefringence:
δ = 0.020
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Optical Extinction:
Y = b; Z ∧ [101] (the edge of the {111} form) = 33°; one optic axis is nearly normal to this edge.

Chemistry of GarrelsiteHide

Mindat Formula:
Ba3NaSi2B7O16(OH)4
Element Weights:
Element% weight
Ba46.246 %
O35.920 %
B8.495 %
Si6.305 %
Na2.581 %
H0.453 %

Calculated from ideal end-member formula.
Common Impurities:
Mg,Ca

Crystallography of GarrelsiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 14.65 Å, b = 8.48 Å, c = 13.46 Å
β = 114.3°
Ratio:
a:b:c = 1.728 : 1 : 1.587
Unit Cell V:
1,524.01 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Crystals steep dipyramidal, prismatic, bounded by {110}, {110}, {211}, and {211}; commonly striated.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0009552GarrelsiteGhose S, Wan C, Ulbrich H H (1976) Structural chemistry of borosilicates. I. Garrelsite, NaBa3Si2B7O16(OH)4, a silicoborate with the pentaborate [B5O12]9- polyanion Acta Crystallographica B32 824-8321976South Ouray, Utah0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.05 Å(100)
3.64 Å(80)
2.026 Å(60)
2.873 Å(45)
2.757 Å(45)
6.13 Å(30)
4.23 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47)

Type Occurrence of GarrelsiteHide

General Appearance of Type Material:
Four-sided, steep bipyramidal colorless crystals, to a few millimeters in size.
Place of Conservation of Type Material:
No defined type material.
Geological Setting of Type Material:
Authigenic origin, in dolomitic shale in drill core from the Green River Formation .
Associated Minerals at Type Locality:

Other Language Names for GarrelsiteHide

Related Minerals - Strunz-mindat GroupingHide

9.AJ.Hingganite-(Nd)Nd2◻Be2Si2O8(OH)2Mon. 2/m : P21/b
9.AJ.Arrheniusite-(Ce)CaMg[(Ce7Y3)Ca5](SiO4)4(Si2B3AsO18)(BO3)F11Trig. 3m : R3m
9.AJ.05Ominelite(Fe2+,Mg)(Al,Fe3+)3(SiO4)(BO3)O2Orth. mmm(2/m2/m2/m)
9.AJ.05Grandidierite(Mg,Fe2+)(Al,Fe3+)3(SiO4)(BO3)O2Orth. mmm(2/m2/m2/m)
9.AJ.10DumortieriteAl(Al2O)(Al2O)2(SiO4)3(BO3)Orth. mmm(2/m2/m2/m)
9.AJ.10Nioboholtite(Nb0.60.4)Al6BSi3O18Orth. mmm(2/m2/m2/m) : Pbcm
9.AJ.10Titanoholtite(Ti0.750.25)Al6BSi3O18Orth. mmm(2/m2/m2/m) : Pbcm
9.AJ.10Holtite(Ta0.60.4)Al6BSi3O18(O,OH)2.25Orth. mmm(2/m2/m2/m) : Pnma
9.AJ.10MagnesiodumortieriteMg(Al2OH)(Al2O)2(SiO4)3(BO3)Orth. mmm(2/m2/m2/m)
9.AJ.20'Muromontite'near Be2FeY2Si3O12
9.AJ.20Gadolinite-(Nd)Nd2Fe2+Be2O2(SiO4)2Mon. 2/m : P21/b
9.AJ.20DatoliteCaB(SiO4)(OH)Mon. 2/m : P21/b
9.AJ.20Melanocerite-(Ce)(Ce,Ca)5(SiO4,BO4)3(OH,O)Hex.
9.AJ.20Gadolinite-(Ce)(Ce,La,Nd,Y)2Fe2+Be2Si2O10Mon. 2/m
9.AJ.20Gadolinite-(Y)Y2Fe2+Be2Si2O10Mon. 2/m : P21/b
9.AJ.20'Unnamed (OH-analogue of Gadolinite-(Y))'(Y,Ca)2(Fe,◻)Be2Si2O8(OH,O)2Mon. 2/m
9.AJ.20Hingganite-(Ce)(Ce,REE)2(◻,Fe2+)Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20Hingganite-(Y)(Y,REE,Ca)2(◻,Fe2+)Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20Hingganite-(Yb)(Yb,Y,REE)2◻Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20HomiliteCa2(Fe2+,Mg)B2Si2O10Mon. 2/m : P21/b
9.AJ.20'Minasgeraisite-(Y)'(Ca2Y2)◻2(Be2B2)[SiO4]4(OH)4Tric. 1 : P1
9.AJ.20Calcybeborosilite-(Y)(Y,Ca)2(◻,Fe2+)(B,Be)2[SiO4]2(OH,O)2Mon.
9.AJ.25Stillwellite-(La)LaBSiO5Trig. 32 : P3221
9.AJ.25Stillwellite-(Ce)(Ce,La,Ca)BSiO5Trig. 3 : P31
9.AJ.30Cappelenite-(Y)Ba(Y,Ce)6Si3B6O24F2Trig. 3 : P3
9.AJ.35Laptevite-(Ce)Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11Trig. 3m : R3m
9.AJ.35Proshchenkoite-(Y)Ca(Y,REE,Ca,Na,Mn)15Fe2+(P,Si)Si6B3O34F14Trig. 3m : R3m
9.AJ.35Okanoganite-(Y)(Na,Ca)3(Y,Ce)12Si6B2O27F14Trig. 3m : R3m
9.AJ.35Hundholmenite-(Y)(Y,REE,Ca,Na)15(Al,Fe3+)(CaxAs3+1-x)(Si,As5+)Si6B3(O,F)48Trig. 3m : R3m
9.AJ.35Vicanite-(Ce)(Ca,Ce,La,Th)15As5+(As3+0.5,Na0.5)Fe3+Si6B4O40F7Trig. 3m : R3m
9.AJ.40JadariteLiNaSiB3O7(OH)Mon. 2/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for GarrelsiteHide

References for GarrelsiteHide

Localities for GarrelsiteHide

Showing 6 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
USA
 
  • California
    • Kern County
www.mineralsocal.org (1999)
U.S. Borax
Tank (1972) +3 other references
  • Utah
    • Duchesne County
      • Castle Peak Mining District (Uninta Basin)
Smith et al. (1972)
    • Uintah County
Chao et al. (1961)
      • Uteland Knoll Mining District (Ouray Mining District)
        • Ouray
Milton et al. (1955) +1 other reference
 
and/or  
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