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Holtite

A valid IMA mineral species
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About HoltiteHide

03820060017271923837884.jpg
Harold Edward Holt
Formula:
(Ta0.60.4)Al6BSi3O18(O,OH)2.25
Originally assumed to be Al6(Al,Ta)(SiO4,SbO4,AsO4)3(BO3)O3.
Colour:
Light buff to cream-buff, deep olive-buff, brown, russet
Lustre:
Vitreous, Resinous, Dull
Hardness:
Specific Gravity:
3.60 - 3.90
Crystal System:
Orthorhombic
Name:
Named in honor of Harold Edward Holt (5 August 1908, Stanmore, New South Wales, Australia - 17 December 1967, Cheviot Beach, Victoria, Australia), Prime Minister of Australia (1966-1967).
Note: Groat et al. (2008) give the formula (Ta,◻,Al)Al6(BO3)(Si,Sb,As)3O12(O,OH,◻)3.

Closely related to dumortierite.


Unique IdentifiersHide

Mindat ID:
1925
Long-form identifier:
mindat:1:1:1925:1

Similar NamesHide

IMA Classification of HoltiteHide

Approved
IMA Formula:
(Ta5+0.60.4)Al6BSi3O18
Approval year:
1969
First published:
1971

Classification of HoltiteHide

9.AJ.10

9 : SILICATES (Germanates)
A : Nesosilicates
J : Nesosilicates with BO3 triangles and/or B[4], Be[4] tetrahedra, cornersharing with SiO4
54.1.3.1

54 : NESOSILICATES Borosilicates and Some Beryllosilicates
1 : Borosilicates and Some Beryllosilicates with (BO3)
17.5.26

17 : Silicates Containing other Anions
5 : Borosilicates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
HltIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
HolThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Pronunciation of HoltiteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of HoltiteHide

Vitreous, Resinous, Dull
Transparency:
Translucent
Comment:
Dull when weathered
Colour:
Light buff to cream-buff, deep olive-buff, brown, russet
Streak:
Light buff
Hardness:
8½ on Mohs scale
Cleavage:
Distinct/Good
Good on {001}, may be parting
Density:
3.60 - 3.90 g/cm3 (Measured)    

Optical Data of HoltiteHide

Type:
Biaxial (-)
RI values:
nα = 1.705 - 1.746 nβ = 1.728 - 1.759 nγ = 1.73 - 1.761
2V:
Measured: 20° to 55°, Calculated: 32° to 42°
Max. Birefringence:
δ = 0.015 - 0.025
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r < v
Optical Extinction:
X = a.
Pleochroism:
Visible
Comments:
Various shades of yellow to colorless

Chemistry of HoltiteHide

Mindat Formula:
(Ta0.60.4)Al6BSi3O18(O,OH)2.25

Originally assumed to be Al6(Al,Ta)(SiO4,SbO4,AsO4)3(BO3)O3.
Element Weights:
Element% weight
O46.988 %
Al23.479 %
Ta15.746 %
Si12.220 %
B1.568 %

Calculated from ideal end-member formula.
Common Impurities:
Ti,Fe,As,Nb,Mn,Be,Mg,Ca,Li,Na,K,Rb,Cs

Crystallography of HoltiteHide

Polytype:
Formula:
Crystal System:
Class (H-M)
Space Group:
Space Group Setting:
Cell Parameters:
Ratio:
Unit Cell Volume (calc):
Z:
Comment:
Holtite IHoltite II
(Ta0.60.4)Al6BSi3O18(O,OH)2.25(Ta0.60.4)Al6BSi3O18(O,OH)2.25
Orthorhombic Orthorhombic 
mmm(2/m2/m2/m) - Dipyramidalmmm(2/m2/m2/m) - Dipyramidal
PnmaPnma
  
a = 4.695(1) Å, b = 11.906(3) Å, c = 20.38(3) Å
a = 4.6893(1) Å, b = 11.881(1) Å, c = 20.394(1) Å
a:b:c = 0.394 : 1 : 1.712a:b:c = 0.395 : 1 : 1.717
V 1,139.21 ų
(Calculated from Unit Cell)
V 1,136.22 ų
(Calculated from Unit Cell)
44
  

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0019928HoltiteGroat L A, Grew E S, Evans R J, Pieczka A, Ercit T S (2009) The crystal chemistry of holtite Mineralogical Magazine 73 1033-10502009Mt. Szklana Mine, Szklary, Zabkowice, Lower Silesia, Poland0293
0019927HoltiteGroat L A, Grew E S, Evans R J, Pieczka A, Ercit T S (2009) The crystal chemistry of holtite Mineralogical Magazine 73 1033-10502009Greenbushes tinfield, Bridgetown-Greenbushes Shire, Australia0293
0019926HoltiteGroat L A, Grew E S, Evans R J, Pieczka A, Ercit T S (2009) The crystal chemistry of holtite Mineralogical Magazine 73 1033-10502009Greenbushes tinfield, Bridgetown-Greenbushes Shire, Australia0293
0019925HoltiteGroat L A, Grew E S, Evans R J, Pieczka A, Ercit T S (2009) The crystal chemistry of holtite Mineralogical Magazine 73 1033-10502009Voroni Tundry, Kola Peninsula, Murmanskaja Oblast, Russia0293
0019738HoltiteKazantsev S S, Zubkova N V, Voloshin A V (2006) Refinement of composition and structure of holtite I Crystallography Reports 51 412-4132006Voroni Tundry deposit, Kola Peninsula, Russia0293
0019758HoltiteZubkova N V, Pushcharovskii D Y, Kabalov Y K, Kazantsev S S, Voloshin A V (2006) Crystal structure of holtite II Crystallography Reports 51 16-222006Kola Peninsula, Russia0293
0014489HoltiteHoskins B F, Mumme W G, Pryce M W (1989) Holtite, (Si2.25Sb0.75)B[Al6(Al0.43 Ta0.27[]0.30)O15(O,OH)2.25]: crystal structure and crystal chemistry Mineralogical Magazine 53 457-4631989Greenbrushes, Australia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.28 Å(100)
2.94 Å(40)
5.89 Å(34)
5.93 Å(32)
5.08 Å(32)
2.338 Å(26)
5.12 Å(24)
Comments:
Greenbushes, Western Australia.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites
Geological Setting:
Pegmatites

Type Occurrence of HoltiteHide

General Appearance of Type Material:
Intergrown prisms and acicular coatings on stibiotantalite and as parallel acicular to asbestiform replacements of tantalite. Also as hard resinous pebbles composed of parallel needles often with S-shaped contortions. Crystals to 1 mm in length.
Place of Conservation of Type Material:
The Australian Museum, Sydney, Australia, number D43778 (type).
Western Australian Museum, Perth, Australia, number MDC 550 (holotype).
Geological Setting of Type Material:
Alluvial pebbles.
Associated Minerals at Type Locality:

Synonyms of HoltiteHide

Other Language Names for HoltiteHide

Dutch:Holtiet
German:Holtit
Russian:Холтит
Spanish:Holtita

Relationship of Holtite to other SpeciesHide

Other Members of Holtite Group:
Nioboholtite(Nb0.60.4)Al6BSi3O18Orth. mmm(2/m2/m2/m) : Pbcm
Titanoholtite(Ti0.750.25)Al6BSi3O18Orth. mmm(2/m2/m2/m) : Pbcm

Common AssociatesHide

Associations Based on Photo Data:
5 photos of Holtite associated with ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)
5 photos of Holtite associated with QuartzSiO2
5 photos of Holtite associated with PolylithioniteKLi2Al(Si4O10)(F,OH)2
2 photos of Holtite associated with AlbiteNa(AlSi3O8)
1 photo of Holtite associated with StibiotantaliteSb3+TaO4
1 photo of Holtite associated with Nioboholtite(Nb0.60.4)Al6BSi3O18
1 photo of Holtite associated with Titanoholtite(Ti0.750.25)Al6BSi3O18

Related Minerals - Strunz-mindat GroupingHide

9.AJ.Hingganite-(Nd)Nd2◻Be2Si2O8(OH)2Mon. 2/m : P21/b
9.AJ.Arrheniusite-(Ce)CaMg[(Ce7Y3)Ca5](SiO4)4(Si2B3AsO18)(BO3)F11Trig. 3m : R3m
9.AJ.05Ominelite(Fe2+,Mg)(Al,Fe3+)3(SiO4)(BO3)O2Orth. mmm(2/m2/m2/m)
9.AJ.05Grandidierite(Mg,Fe2+)(Al,Fe3+)3(SiO4)(BO3)O2Orth. mmm(2/m2/m2/m)
9.AJ.10DumortieriteAl(Al2O)(Al2O)2(SiO4)3(BO3)Orth. mmm(2/m2/m2/m)
9.AJ.10Nioboholtite(Nb0.60.4)Al6BSi3O18Orth. mmm(2/m2/m2/m) : Pbcm
9.AJ.10Titanoholtite(Ti0.750.25)Al6BSi3O18Orth. mmm(2/m2/m2/m) : Pbcm
9.AJ.10MagnesiodumortieriteMg(Al2OH)(Al2O)2(SiO4)3(BO3)Orth. mmm(2/m2/m2/m)
9.AJ.15GarrelsiteBa3NaSi2B7O16(OH)4Mon. 2/m : B2/b
9.AJ.20'Muromontite'near Be2FeY2Si3O12
9.AJ.20Gadolinite-(Nd)Nd2Fe2+Be2O2(SiO4)2Mon. 2/m : P21/b
9.AJ.20DatoliteCaB(SiO4)(OH)Mon. 2/m : P21/b
9.AJ.20Melanocerite-(Ce)(Ce,Ca)5(SiO4,BO4)3(OH,O)Hex.
9.AJ.20Gadolinite-(Ce)(Ce,La,Nd,Y)2Fe2+Be2Si2O10Mon. 2/m
9.AJ.20Gadolinite-(Y)Y2Fe2+Be2Si2O10Mon. 2/m : P21/b
9.AJ.20'Unnamed (OH-analogue of Gadolinite-(Y))'(Y,Ca)2(Fe,◻)Be2Si2O8(OH,O)2Mon. 2/m
9.AJ.20Hingganite-(Ce)(Ce,REE)2(◻,Fe2+)Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20Hingganite-(Y)(Y,REE,Ca)2(◻,Fe2+)Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20Hingganite-(Yb)(Yb,Y,REE)2◻Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20HomiliteCa2(Fe2+,Mg)B2Si2O10Mon. 2/m : P21/b
9.AJ.20'Minasgeraisite-(Y)'(Ca2Y2)◻2(Be2B2)[SiO4]4(OH)4Tric. 1 : P1
9.AJ.20Calcybeborosilite-(Y)(Y,Ca)2(◻,Fe2+)(B,Be)2[SiO4]2(OH,O)2Mon.
9.AJ.25Stillwellite-(La)LaBSiO5Trig. 32 : P3221
9.AJ.25Stillwellite-(Ce)(Ce,La,Ca)BSiO5Trig. 3 : P31
9.AJ.30Cappelenite-(Y)Ba(Y,Ce)6Si3B6O24F2Trig. 3 : P3
9.AJ.35Laptevite-(Ce)Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11Trig. 3m : R3m
9.AJ.35Proshchenkoite-(Y)Ca(Y,REE,Ca,Na,Mn)15Fe2+(P,Si)Si6B3O34F14Trig. 3m : R3m
9.AJ.35Okanoganite-(Y)(Na,Ca)3(Y,Ce)12Si6B2O27F14Trig. 3m : R3m
9.AJ.35Hundholmenite-(Y)(Y,REE,Ca,Na)15(Al,Fe3+)(CaxAs3+1-x)(Si,As5+)Si6B3(O,F)48Trig. 3m : R3m
9.AJ.35Vicanite-(Ce)(Ca,Ce,La,Th)15As5+(As3+0.5,Na0.5)Fe3+Si6B4O40F7Trig. 3m : R3m
9.AJ.40JadariteLiNaSiB3O7(OH)Mon. 2/m

Fluorescence of HoltiteHide

Dull orange (SW UV) and bright yellow (LW UV).

Other InformationHide

Thermal Behaviour:
Becomes colourless on heating to 800°C.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HoltiteHide

References for HoltiteHide

Reference List:

Localities for HoltiteHide

Showing 6 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • San Luis Province
    • Coronel Pringles Department
      • Estancia Grande
        • Las Águilas deposit
Galliski et al. (2012)
Australia
 
  • Western Australia
    • Bridgetown-Greenbushes Shire
      • Greenbushes tinfield
Jacobson et al. (2007)
Pryce (1971)
Poland
 
  • Lower Silesian Voivodeship
    • Ząbkowice Śląskie County
      • Gmina Ząbkowice Śląskie
        • Szklary
Pieczka (2000) +5 other references
Pieczka et al. (2001)
Russia
 
  • Murmansk Oblast
    • Voron'i Tundry
Voloshin et al. (1976) +4 other references
 
and/or  
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