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Okanoganite-(Y)

A valid IMA mineral species
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About Okanoganite-(Y)Hide

Formula:
(Na,Ca)3(Y,Ce)12Si6B2O27F14
Colour:
Tan to pale pink
Hardness:
4
Specific Gravity:
4.31 - 4.37
Crystal System:
Trigonal
Member of:
Name:
After the type locality at Washington Pass, Okanogan Co., Washington, USA. The name is pronounced oh-ka-NOG-an-ite.
A rare-earth borofluorosilicate first described by Boggs (1980) from the peralkaline arfvedsonite granite from the Golden Horn batholith near Washington Pass, Okanogan County, U.S.A. The crystal structure was established by Boiocchi (2004).



Unique IdentifiersHide

Mindat ID:
2966
Long-form identifier:
mindat:1:1:2966:3

IMA Classification of Okanoganite-(Y)Hide

Approved
IMA Formula:
(Y,REE,Ca,Na,Th4+)16(Fe3+,Ti4+)(Si,B,P)10(O,OH)38F10
Approval year:
1979
First published:
1980

Classification of Okanoganite-(Y)Hide

9.AJ.35

9 : SILICATES (Germanates)
A : Nesosilicates
J : Nesosilicates with BO3 triangles and/or B[4], Be[4] tetrahedra, cornersharing with SiO4
54.2.4.3

54 : NESOSILICATES Borosilicates and Some Beryllosilicates
2 : Borosilicates and Some Beryllosilicates with B in [4] coordination
17.5.21

17 : Silicates Containing other Anions
5 : Borosilicates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
Oka-YIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Okanoganite-(Y)Hide

Colour:
Tan to pale pink
Comment:
Colourless in thin fragments.
Streak:
White
Hardness:
Comment:
The surface may have altered to a softer material
Density:
4.31 - 4.37 g/cm3 (Measured)    4.37 g/cm3 (Calculated)

Optical Data of Okanoganite-(Y)Hide

Type:
Uniaxial (-)
RI values:
nω = 1.753 nε = 1.74
Max. Birefringence:
δ = 0.013
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Comments:
Shows no dichroism

Chemistry of Okanoganite-(Y)Hide

Mindat Formula:
(Na,Ca)3(Y,Ce)12Si6B2O27F14
Element Weights:
Element% weight
Y52.713 %
O21.344 %
F13.142 %
Si8.326 %
Na3.408 %
B1.068 %

Calculated from ideal end-member formula.
Y
O
F
Si
Na
B

Crystallography of Okanoganite-(Y)Hide

Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
R3m
Cell Parameters:
a = 10.7108(5) Å, c = 27.0398(11) Å
Ratio:
a:c = 1 : 2.525
Unit Cell V:
2,686.44 ų (Calculated from Unit Cell)
Z:
3
Morphology:
As pseudotetrahedral fourlings with twin plane {01-14}. Forms observed: c{0001} and s{10-4}.
Twinning:
Common at TL as fourlings twinned on the composition plane
{01-14} with the c face of each individual forming the faces of the pseudotetrahedra.
Comment:
Crystal system and cell parameters from Boiocchi (2004)

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0003650Okanoganite-(Y)Boiocchi M, Callegari A, Ottolini L, Maras A (2004) The chemistry and crystal structure of okanoganite-(Y) and comparison with vicanite-(Ce) American Mineralogist 89 1540-154520040293
CIF Raw Data - click here to close

Epitaxial Relationships of Okanoganite-(Y)Hide

Epitaxial Minerals:
'Arfvedsonite'NaNa2(Fe2+4Fe3+)Si8O22(OH)2
'Microcline'K(AlSi3O8)
'Zektzerite'LiNaZrSi6O15
'Zircon'Zr(SiO4)

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.38 Å(41)
3.11 Å(48)
2.970 Å(100)
2.939 Å(95)
2.926 Å(50)
2.676 Å(32)
1.978 Å(35)
1.822 Å(32)
1.784 Å(43)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4a: Earth’s earliest continental crust>4.4-3.0
19 : Granitic intrusive rocks
High-? alteration and/or metamorphism
31 : Thermally altered carbonate, phosphate, and iron formations
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of Okanoganite-(Y)Hide

General Appearance of Type Material:
As crystals up to 4 mm across. Both as isolated fourlings or as intergrown clusters.
Place of Conservation of Type Material:
In the mineral collection at the Universityof California, Santa Barbara (specimens #UCSB 8256 and 8257)
Geological Setting of Type Material:
In miarolitic cavities in an alkaline arfvedsonite granite
Associated Minerals at Type Locality:

Synonyms of Okanoganite-(Y)Hide

Other Language Names for Okanoganite-(Y)Hide

Relationship of Okanoganite-(Y) to other SpeciesHide

Member of:
Other Members of Vicanite Group:
Arrheniusite-(Ce)CaMg[(Ce7Y3)Ca5](SiO4)4(Si2B3AsO18)(BO3)F11Trig. 3m : R3m
Hundholmenite-(Y)(Y,REE,Ca,Na)15(Al,Fe3+)(CaxAs3+1-x)(Si,As5+)Si6B3(O,F)48Trig. 3m : R3m
Laptevite-(Ce)Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11Trig. 3m : R3m
Proshchenkoite-(Y)Ca(Y,REE,Ca,Na,Mn)15Fe2+(P,Si)Si6B3O34F14Trig. 3m : R3m
Vicanite-(Ce)(Ca,Ce,La,Th)15As5+(As3+0.5,Na0.5)Fe3+Si6B4O40F7Trig. 3m : R3m

Common AssociatesHide

Associations Based on Photo Data:
15 photos of Okanoganite-(Y) associated with MicroclineK(AlSi3O8)
15 photos of Okanoganite-(Y) associated with AlbiteNa(AlSi3O8)
9 photos of Okanoganite-(Y) associated with ZirconZr(SiO4)
6 photos of Okanoganite-(Y) associated with QuartzSiO2
6 photos of Okanoganite-(Y) associated with FluoriteCaF2
2 photos of Okanoganite-(Y) associated with ZektzeriteLiNaZrSi6O15
2 photos of Okanoganite-(Y) associated with AegirineNaFe3+Si2O6
2 photos of Okanoganite-(Y) associated with ArfvedsoniteNaNa2(Fe2+4Fe3+)Si8O22(OH)2
1 photo of Okanoganite-(Y) associated with ChamositeFe2+5Al(AlSi3O10)(OH)8
1 photo of Okanoganite-(Y) associated with OpalSiO2 · nH2O

Related Minerals - Strunz-mindat GroupingHide

9.AJ.Hingganite-(Nd)Nd2◻Be2Si2O8(OH)2Mon. 2/m : P21/b
9.AJ.Arrheniusite-(Ce)CaMg[(Ce7Y3)Ca5](SiO4)4(Si2B3AsO18)(BO3)F11Trig. 3m : R3m
9.AJ.05Ominelite(Fe2+,Mg)(Al,Fe3+)3(SiO4)(BO3)O2Orth. mmm(2/m2/m2/m)
9.AJ.05Grandidierite(Mg,Fe2+)(Al,Fe3+)3(SiO4)(BO3)O2Orth. mmm(2/m2/m2/m)
9.AJ.10DumortieriteAl(Al2O)(Al2O)2(SiO4)3(BO3)Orth. mmm(2/m2/m2/m)
9.AJ.10Nioboholtite(Nb0.60.4)Al6BSi3O18Orth. mmm(2/m2/m2/m) : Pbcm
9.AJ.10Titanoholtite(Ti0.750.25)Al6BSi3O18Orth. mmm(2/m2/m2/m) : Pbcm
9.AJ.10Holtite(Ta0.60.4)Al6BSi3O18(O,OH)2.25Orth. mmm(2/m2/m2/m) : Pnma
9.AJ.10MagnesiodumortieriteMg(Al2OH)(Al2O)2(SiO4)3(BO3)Orth. mmm(2/m2/m2/m)
9.AJ.15GarrelsiteBa3NaSi2B7O16(OH)4Mon. 2/m : B2/b
9.AJ.20'Muromontite'near Be2FeY2Si3O12
9.AJ.20Gadolinite-(Nd)Nd2Fe2+Be2O2(SiO4)2Mon. 2/m : P21/b
9.AJ.20DatoliteCaB(SiO4)(OH)Mon. 2/m : P21/b
9.AJ.20Melanocerite-(Ce)(Ce,Ca)5(SiO4,BO4)3(OH,O)Hex.
9.AJ.20Gadolinite-(Ce)(Ce,La,Nd,Y)2Fe2+Be2Si2O10Mon. 2/m
9.AJ.20Gadolinite-(Y)Y2Fe2+Be2Si2O10Mon. 2/m : P21/b
9.AJ.20'Unnamed (OH-analogue of Gadolinite-(Y))'(Y,Ca)2(Fe,◻)Be2Si2O8(OH,O)2Mon. 2/m
9.AJ.20Hingganite-(Ce)(Ce,REE)2(◻,Fe2+)Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20Hingganite-(Y)(Y,REE,Ca)2(◻,Fe2+)Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20Hingganite-(Yb)(Yb,Y,REE)2◻Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20HomiliteCa2(Fe2+,Mg)B2Si2O10Mon. 2/m : P21/b
9.AJ.20'Minasgeraisite-(Y)'(Ca2Y2)◻2(Be2B2)[SiO4]4(OH)4Tric. 1 : P1
9.AJ.20Calcybeborosilite-(Y)(Y,Ca)2(◻,Fe2+)(B,Be)2[SiO4]2(OH,O)2Mon.
9.AJ.25Stillwellite-(La)LaBSiO5Trig. 32 : P3221
9.AJ.25Stillwellite-(Ce)(Ce,La,Ca)BSiO5Trig. 3 : P31
9.AJ.30Cappelenite-(Y)Ba(Y,Ce)6Si3B6O24F2Trig. 3 : P3
9.AJ.35Laptevite-(Ce)Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11Trig. 3m : R3m
9.AJ.35Proshchenkoite-(Y)Ca(Y,REE,Ca,Na,Mn)15Fe2+(P,Si)Si6B3O34F14Trig. 3m : R3m
9.AJ.35Hundholmenite-(Y)(Y,REE,Ca,Na)15(Al,Fe3+)(CaxAs3+1-x)(Si,As5+)Si6B3(O,F)48Trig. 3m : R3m
9.AJ.35Vicanite-(Ce)(Ca,Ce,La,Th)15As5+(As3+0.5,Na0.5)Fe3+Si6B4O40F7Trig. 3m : R3m
9.AJ.40JadariteLiNaSiB3O7(OH)Mon. 2/m

Fluorescence of Okanoganite-(Y)Hide

Does not fluoresce

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Okanoganite-(Y)Hide

References for Okanoganite-(Y)Hide

Localities for Okanoganite-(Y)Hide

Showing 5 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Norway
 
  • Nordland
    • Hamarøy
Raade (1993)
    • Narvik
Larsen (1990) +1 other reference
Portugal
 
  • Azores
    • São Miguel
Samples collected by Luigi Chiappino ... +1 other reference
USA
 
  • Washington
    • Okanogan County
Markus B. Raschke et al. (2016)
p. 1138-1142 +4 other references
 
and/or  
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