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Fluor-buergerite

A valid IMA mineral species
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07448760017588936608122.jpg
Fluor-buergerite

Fluor-buergerite occurrence, Mexquitic de Carmona Municipality, San Luis Potosí, Mexico
09439160017363581755046.jpg
Fluor-buergerite

Fluor-buergerite occurrence, Mexquitic de Carmona Municipality, San Luis Potosí, Mexico
03660800017588936619660.jpg
Fluor-buergerite

Fluor-buergerite occurrence, Mexquitic de Carmona Municipality, San Luis Potosí, Mexico
09025550017866397411672.jpg
Fluor-buergerite

Fluor-buergerite occurrence, Mexquitic de Carmona Municipality, San Luis Potosí, Mexico
06906820017366649625480.jpg
Fluor-buergerite

Fluor-buergerite occurrence, Mexquitic de Carmona Municipality, San Luis Potosí, Mexico
09927400017271921793526.jpg
Fluor-buergerite

Fluor-buergerite occurrence, Mexquitic de Carmona Municipality, San Luis Potosí, Mexico
07448760017588936608122.jpg
Fluor-buergerite

Fluor-buergerite occurrence, Mexquitic de Carmona Municipality, San Luis Potosí, Mexico
09439160017363581755046.jpg
Fluor-buergerite

Fluor-buergerite occurrence, Mexquitic de Carmona Municipality, San Luis Potosí, Mexico
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About Fluor-buergeriteHide

04912070017271921891704.jpg
Martin J. Buerger
Formula:
NaFe3+3Al6(Si6O18)(BO3)3O3F
Colour:
Bronze-brown to dark-brown.
Lustre:
Vitreous, Sub-Vitreous, Silky
Hardness:
7
Specific Gravity:
3.311
Crystal System:
Trigonal
Name:
Named in 1966 by Gaibriel Donnay, C. O. Ingamells, and Brian H. Mason, in honor of Martin Julian Buerger [April 8, 1903 Detroit, Michigan, USA - February 26, 1986 Lincoln, Massachusetts, USA], Professor of Mineralogy at the Massachusetts Institute of Technology and a pioneer of crystal structure analysis. He invented the X-ray precession camera permitting undistorted photography of the reciprocal lattice. He wrote many standard works concerning X-ray crystallography and was the PhD adviser for Harvard University mineralogist Clifford Frondel. It was renamed fluor-buergerite by Henry et al. (2011).
Originally named buergerite, but renamed as part of a nomenclature revision, because the type material is F-dominant (Henry et al., 2011).

Buergerite, i.e. the OH-dominant analogue, is currently not known to occur.

Visit gemdat.org for gemological information about Fluor-buergerite.



Unique IdentifiersHide

Mindat ID:
818
Long-form identifier:
mindat:1:1:818:7

IMA Classification of Fluor-buergeriteHide

IMA status:
Approved
IMA status notes:
Redefined by the IMA, Renamed by the IMA
Approval year:
1965
Approval history:
Published without approval: 2011

Classification of Fluor-buergeriteHide

Strunz-mindat (2026):
9.CK.05

9 : SILICATES (Germanates)
C : Cyclosilicates
K : [Si6O18]12- 6-membered single rings, with insular complex anions
Dana 7th ed.:
61.3.1.7
Dana 8th ed.:
61.3.1.5

61 : CYCLOSILICATES Six-Membered Rings
3 : Six-Membered Rings with borate groups
Hey's CIM Ref.:
17.5.45

17 : Silicates Containing other Anions
5 : Borosilicates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
FbuIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Fluor-buergeriteHide

Lustre:
Vitreous, Sub-Vitreous, Silky
Transparency:
Translucent
Colour:
Bronze-brown to dark-brown.
Streak:
Light brown.
Hardness:
7 on Mohs scale
Hardness Data:
Measured
Tenacity:
Brittle
Cleavage:
Distinct/Good
on {11_20}
Density:
3.311 g/cm3 (Measured)    3.29 g/cm3 (Calculated)

Optical Data of Fluor-buergeriteHide

Type:
Uniaxial (-)
RI values:
nω = 1.735 nε = 1.655
Birefringence:
0.080
Max. Birefringence:
δ = 0.080
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Optical Extinction:
Parrallel

Chemistry of Fluor-buergeriteHide

Mindat Formula:
NaFe3+3Al6(Si6O18)(BO3)3O3F
Element Weights:
Element% weight
O45.611 %
Si16.013 %
Fe15.920 %
Al15.384 %
B3.082 %
Na2.185 %
F1.805 %

Calculated from ideal end-member formula.
Elements listed:
Al, B, F, Fe, Na, O, Si - search for minerals with similar chemistry
Common Impurities:
Ti,Mn,Mg,Ca,K

Crystallography of Fluor-buergeriteHide

Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
R3m
Cell Parameters:
a = 15.8692 Å, c = 7.1882 Å
Ratio:
a:c = 1 : 0.453
Unit Cell V:
1,567.69 ų (Calculated from Unit Cell)
Z:
3
Morphology:
Columnar trigonal with pyramidal terminations

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0018787Fluor-buergeriteGrice J D, Ercit T S (1993) Ordering of Fe and Mg in the tourmaline crystal structure: The correct formula Neues Jahrbuch fur Mineralogie, Abhandlungen 165 245-2661993Mapimi, Durango, Mexico0293
0000221Fluor-buergeriteTippe A, Hamilton W C (1971) A neutron-diffraction study of the ferric tourmaline, buergerite American Mineralogist 56 101-1131971Mexquitic, San Luis Potosi, Mexico0293
0018672Fluor-buergeriteBarton R (1969) Refinement of the crystal structure of buergerite and the absolute orientation of tourmalines Acta Crystallographica B25 1524-15331969Mexquitic, San Luis Potosi, Mexico0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Loading XRD data...
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacingIntensity
6.33 Å(45)
4.95 Å(16)
4.57 Å(14)
4.20 Å(40)
3.96 Å(52)
3.47 Å(48)
3.54 Å(15)
2.99 Å(10)
2.952 Å(64)
2.887 Å(5)
2.563 Å(100)
2.367 Å(16)
2.334 Å(14)
2.181 Å(17)
2.152 Å(12)
2.121 Å(15)
2.048 Å(7)
2.032 Å(43)
2.011 Å(5)
1.981 Å(5)
1.911 Å(30)
1.870 Å(10)
1.841 Å(10)
1.815 Å(5)
1.778 Å(2)
1.738 Å(2)
1.656 Å(20)
1.634 Å(18)
1.586 Å(22)
1.521 Å(4)
1.504 Å(6)
1.453 Å(18)
1.412 Å(5)
1.409 Å(16)
1.350 Å(10)
1.338 Å(2)
1.322 Å(10)
1.305 Å(7)
1.272 Å(12)
1.145 Å(5)
1.092 Å(2)
1.062 Å(2)
1.025 Å(10)
1.018 Å(10)
0.994 Å(5)
Comments:
ICDD 25-703

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4a: Earth’s earliest continental crust>4.4-3.0
20 : Acidic volcanic rocks
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites

Type Occurrence of Fluor-buergeriteHide

Synonyms of Fluor-buergeriteHide

Other Language Names for Fluor-buergeriteHide

Relationship of Fluor-buergerite to other SpeciesHide

Member of:
Tourmaline Group
Other Members of Tourmaline:
AdachiiteCaFe3Al6(Si5AlO18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Alumino-oxy-rossmanite◻Al3Al6(Si5AlO18)(BO3)3(OH)3OTrig. 3m : R3m
BosiiteNaFe3+3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Celleriite◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Chromium-draviteNaMg3Cr3+6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Chromo-alumino-povondraiteNaCr3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
DarrellhenryiteNa(Al2Li)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
DraviteNaMg3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
DutrowiteNa(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
ErtliteNaAl3Al6(Si4B2O18)(BO3)3(OH)3OTrig. 3m : R3m
Ferro-bosiiteNaFe3+3(Al4Fe2+2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
FeruviteCaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Fluor-draviteNaMg3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-elbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-liddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-rossmanite◻(Al2Li)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m(32/m) : R3m
Fluor-schorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-tsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-uviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Foitite◻(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
LiddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
LucchesiiteCaFe2+3 Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Magnesio-dutrowiteNa(Mg2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Magnesio-foitite◻(Mg2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Magnesio-lucchesiiteCaMg3Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
MaruyamaiteK(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
OleniteNaAl3Al6(Si6O18)(BO3)3O3(OH)Trig. 3m : R3m
Oxy-chromium-draviteNaCr3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
Oxy-draviteNa(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Oxy-foitite◻(Fe2+Al2)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m(32/m) : R3m
Oxy-schorlNa(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Oxy-vanadium-draviteNaV3(V4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
PovondraiteNaFe3+3(Mg2Fe3+4)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
PrincivalleiteNa(Mn2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Rossmanite◻(LiAl2)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
SchorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
TsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
'UM2000-64-SiO:BFeHKMg'(K,Na)Fe3+3(Mg2Fe3+4)Si6O18(BO3)3(OH)3O
'UM2008-52-SiO:AlBCaFFeHLiMgNa'(Ca,Na,◻)(Al,Li,Fe,Mg)3Al6[Si6O18](BO3)3(OH,O)3(F,O)
'Unnamed (F analogue of feruvite)'CaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3F
'Unnamed (Mn2+-F-analogue of foitite)'◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3F ?
'Unnamed (Pb-analogue of Fluor-liddicoatite)'Pb(Li2Al)Al6(Si6O18)(BO3)3(OH)3F
UviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Vanadio-oxy-chromium-draviteNaV3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
Vanadio-oxy-draviteNaV3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Forms a series with:
DraviteFluor-buergerite-Dravite Series

Common AssociatesHide

Associations Based on Photo Data:
8 photos of Fluor-buergerite associated with OpalSiO2 · nH2O
8 photos of Fluor-buergerite associated with QuartzSiO2

Related Minerals - Strunz-mindat GroupingHide

9.CK.AdachiiteCaFe3Al6(Si5AlO18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.Magnesio-dutrowiteNa(Mg2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.DarrellhenryiteNa(Al2Li)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Fluor-schorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.PrincivalleiteNa(Mn2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Alumino-oxy-rossmanite◻Al3Al6(Si5AlO18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.DutrowiteNa(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Ferro-bosiiteNaFe3+3(Al4Fe2+2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.BosiiteNaFe3+3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Celleriite◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05FeruviteCaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Chromium-draviteNaMg3Cr3+6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-rossmanite◻(Al2Li)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m(32/m) : R3m
9.CK.05Oxy-schorlNa(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-elbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05DraviteNaMg3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-uviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Foitite◻(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Vanadio-oxy-draviteNaV3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05'Unnamed (F analogue of feruvite)'CaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3F
9.CK.05ErtliteNaAl3Al6(Si4B2O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05TsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-liddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05UviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-tsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Oxy-foitite◻(Fe2+Al2)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m(32/m) : R3m
9.CK.05LiddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Vanadio-oxy-chromium-draviteNaV3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
9.CK.05Rossmanite◻(LiAl2)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Oxy-vanadium-draviteNaV3(V4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05OleniteNaAl3Al6(Si6O18)(BO3)3O3(OH)Trig. 3m : R3m
9.CK.05'UM2000-64-SiO:BFeHKMg'(K,Na)Fe3+3(Mg2Fe3+4)Si6O18(BO3)3(OH)3O
9.CK.05Magnesio-lucchesiiteCaMg3Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05PovondraiteNaFe3+3(Mg2Fe3+4)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05LucchesiiteCaFe2+3 Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Chromo-alumino-povondraiteNaCr3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-draviteNaMg3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Oxy-draviteNa(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Oxy-chromium-draviteNaCr3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
9.CK.05'Luinaite-(OH)'NaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Mon. m : Bm
9.CK.05SchorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Magnesio-foitite◻(Mg2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05MaruyamaiteK(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.10Abenakiite-(Ce)Na26Ce6(Si6O18)(PO4)6(CO3)6(SO2)OTrig. 3 : R3
9.CK.15ScawtiteCa7(Si3O9)2CO3 · 2H2OMon. 2/m
9.CK.20Thorosteenstrupine(Ca,Th,Mn)3Si4O11F · 6H2O
9.CK.20Steenstrupine-(Ce)Na14Mn2+2Fe3+2Ce6Zr(Si6O18)2(PO4)6(PO3OH)(OH)2 · 2H2OTrig. 3m(32/m) : R3m

Fluorescence of Fluor-buergeriteHide

In UV light:
Not known to fluoresce in UV

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Fluor-buergeriteHide

References for Fluor-buergeriteHide

Localities for Fluor-buergeriteHide

Showing 6 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Brazil
 
  • Minas Gerais
    • Coronel Murta
erroneously reported [MinRec 33:209]
Czech Republic
 
  • Central Bohemian Region
    • Kutná Hora District
STANĚK et al. (1993)
Italy
 
  • Piedmont
    • Biella Province
Domenico Preite collection
Mexico (TL)
 
  • San Luis Potosí
    • Mexquitic de Carmona Municipality
Donnay et al. (1966)
Poland
 
  • Lower Silesian Voivodeship
    • Karkonosze County
      • Gmina Stara Kamienica
        • Kopaniec
Długoszewska (2005)
Sri Lanka
 
  • Sabaragamuwa Province
    • Ratnapura District
      • Ratnapura
Ceylon Aluvial Mine (Book, Co. 2002)
Quick NavTopAbout Fluor-buergeriteUnique IdentifiersIMA Classification Classification Mineral SymbolsPhysical Properties Optical Data Chemistry Crystallography Crystal StructureX-Ray Powder DiffractionGeological EnvironmentType Occurrence SynonymsOther LanguagesRelationshipsCommon AssociatesStrunz-MindatFluorescence Other InformationInternet Links References Localities Locality List
 
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To cite: Ralph, J., Von Bargen, D., Martynov, P., Zhang, J., Que, X., Prabhu, A., Morrison, S. M., Li, W., Chen, W., & Ma, X. (2025). Mindat.org: The open access mineralogy database to accelerate data-intensive geoscience research. American Mineralogist, 110(6), 833–844. doi:10.2138/am-2024-9486.
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