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Tsilaisite

A valid IMA mineral species
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09326710017271929147148.jpg
Tsilaisite

Grotta d'Oggi, San Piero in Campo, Campo nell'Elba, Livorno Province, Tuscany, Italy
06314030017710643406986.jpg
Tsilaisite

Grotta d'Oggi, San Piero in Campo, Campo nell'Elba, Livorno Province, Tuscany, Italy
05941060017271929201304.jpg
Tsilaisite

Grotta d'Oggi, San Piero in Campo, Campo nell'Elba, Livorno Province, Tuscany, Italy
09326710017271929147148.jpg
Tsilaisite

Grotta d'Oggi, San Piero in Campo, Campo nell'Elba, Livorno Province, Tuscany, Italy
09321180017705965471218.jpg
Tsilaisite

Grotta d'Oggi, San Piero in Campo, Campo nell'Elba, Livorno Province, Tuscany, Italy
05941060017271929201304.jpg
Tsilaisite

Grotta d'Oggi, San Piero in Campo, Campo nell'Elba, Livorno Province, Tuscany, Italy
06790170017271929223348.jpg
Tsilaisite

Grotta d'Oggi, San Piero in Campo, Campo nell'Elba, Livorno Province, Tuscany, Italy
09321180017705965471218.jpg
Tsilaisite

Grotta d'Oggi, San Piero in Campo, Campo nell'Elba, Livorno Province, Tuscany, Italy
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About TsilaisiteHide

Formula:
NaMn2+3Al6(Si6O18)(BO3)3(OH)3(OH)
Colour:
Greenish yellow
Lustre:
Vitreous
Hardness:
7
Specific Gravity:
3.133 (Calculated)
Crystal System:
Trigonal
Name:
Named after the originally reported locality, Tsilaizina (Madagascar).
Originally described as tsilaisite, but then recognised as only a manganese-rich variety of elbaite, and therefore discredited in 2006. In 2011, a Mn-dominant material from Elba, Italy, was redefined and finally approved as tsilaisite.
The OH analogue of fluor-tsilaisite.

Originally reported from Tsilaizina (Tsilaisina), Sahatany Valley, Vakinankaratra Region, Antananarivo Province, Madagascar.


Unique IdentifiersHide

Mindat ID:
8016
Long-form identifier:
mindat:1:1:8016:9

IMA Classification of TsilaisiteHide

IMA status:
Approved
IMA status notes:
Renamed by the IMA
IMA Formula:
NaMn2+3Al6(Si6O18)(BO3)3(OH)3OH
Approval year:
2011
Approval history:
Renamed by IMA: 2011

Classification of TsilaisiteHide

Strunz-mindat (2026):
9.CK.05

9 : SILICATES (Germanates)
C : Cyclosilicates
K : [Si6O18]12- 6-membered single rings, with insular complex anions

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
TslIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TsilaisiteHide

Lustre:
Vitreous
Colour:
Greenish yellow
Streak:
White
Hardness:
7 on Mohs scale
Hardness Data:
Estimated
Tenacity:
Brittle
Fracture:
Sub-Conchoidal
Density:
3.133 g/cm3 (Calculated)

Optical Data of TsilaisiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.645(5) nε = 1.625(5)
Max. Birefringence:
δ = 0.020
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.

Surface Relief:
Moderate
Pleochroism:
Visible
Comments:
Pleochroic in plane-polarized light, O = pale greenish yellow, E = very pale greenish yellow

Chemistry of TsilaisiteHide

Mindat Formula:
NaMn2+3Al6(Si6O18)(BO3)3(OH)3(OH)
Element Weights:
Element% weight
O47.207 %
Si16.039 %
Mn15.687 %
Al15.408 %
B3.087 %
Na2.188 %
H0.384 %

Calculated from ideal end-member formula.
Elements listed:
Al, B, H, Mn, Na, O, Si - search for minerals with similar chemistry

Crystallography of TsilaisiteHide

Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
R3m
Cell Parameters:
a = 15.9461(5) Å, c = 7.1380(3) Å
Ratio:
a:c = 1 : 0.448
Unit Cell V:
1571.9 ų
Z:
3

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0018866TsilaisiteBosi F, Skogby H, Agrosi G, Scandale E (2012) Tsilaisite, NaMn3Al6(Si6O18)(BO3)3(OH)3OH, a new mineral species of the tourmaline supergroup from Grotta d'Oggi, San Pietro in Campo, island of Elba, Italy American Mineralogist 97 989-9942012Grotta d'Oggi, San Pietro in Campo, island of Elba, Italy0293
0018865TsilaisiteBosi F, Skogby H, Agrosi G, Scandale E (2012) Tsilaisite, NaMn3Al6(Si6O18)(BO3)3(OH)3OH, a new mineral species of the tourmaline supergroup from Grotta d'Oggi, San Pietro in Campo, island of Elba, Italy American Mineralogist 97 989-9942012Grotta d'Oggi, San Pietro in Campo, island of Elba, Italy0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.329 Å(22)
4.205 Å(41)
3.974 Å(100)
3.452 Å(71)
2.942 Å(94)
2.570 Å(79)
2.377 Å(21)
2.034 Å(49)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites

Type Occurrence of TsilaisiteHide

Type Locality:
ⓘ Grotta d'Oggi, San Piero in Campo, Campo nell'Elba, Livorno Province, Tuscany, Italy
Place of Conservation of Type Material:
Museo di Scienze della Terra, settore Mineralogico Pertografico ‘‘Carlo Lorenzo Garavelli’’, Campus Universitario, Bari, Italy,catalogue number 12/nm
Geological Setting of Type Material:
An aplitic dike of a LCT-type pegmatite body
Associated Minerals at Type Locality:
PlagioclaseElbaiteK FeldsparQuartzSchorl

Synonyms of TsilaisiteHide

Other Language Names for TsilaisiteHide

German:Tsilaisit
Simplified Chinese:钠锰电气石
Spanish:Tsilaisita

Relationship of Tsilaisite to other SpeciesHide

Member of:
Tourmaline Group
Other Members of Tourmaline:
AdachiiteCaFe3Al6(Si5AlO18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Alumino-oxy-rossmanite◻Al3Al6(Si5AlO18)(BO3)3(OH)3OTrig. 3m : R3m
BosiiteNaFe3+3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Celleriite◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Chromium-draviteNaMg3Cr3+6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Chromo-alumino-povondraiteNaCr3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
DarrellhenryiteNa(Al2Li)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
DraviteNaMg3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
DutrowiteNa(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
ErtliteNaAl3Al6(Si4B2O18)(BO3)3(OH)3OTrig. 3m : R3m
Ferro-bosiiteNaFe3+3(Al4Fe2+2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
FeruviteCaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Fluor-buergeriteNaFe3+3Al6(Si6O18)(BO3)3O3FTrig. 3m : R3m
Fluor-draviteNaMg3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-elbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-liddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-rossmanite◻(Al2Li)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m(32/m) : R3m
Fluor-schorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-tsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-uviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Foitite◻(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
LiddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
LucchesiiteCaFe2+3 Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Magnesio-dutrowiteNa(Mg2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Magnesio-foitite◻(Mg2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Magnesio-lucchesiiteCaMg3Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
MaruyamaiteK(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
OleniteNaAl3Al6(Si6O18)(BO3)3O3(OH)Trig. 3m : R3m
Oxy-chromium-draviteNaCr3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
Oxy-draviteNa(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Oxy-foitite◻(Fe2+Al2)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m(32/m) : R3m
Oxy-schorlNa(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Oxy-vanadium-draviteNaV3(V4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
PovondraiteNaFe3+3(Mg2Fe3+4)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
PrincivalleiteNa(Mn2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Rossmanite◻(LiAl2)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
SchorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
'UM2000-64-SiO:BFeHKMg'(K,Na)Fe3+3(Mg2Fe3+4)Si6O18(BO3)3(OH)3O
'UM2008-52-SiO:AlBCaFFeHLiMgNa'(Ca,Na,◻)(Al,Li,Fe,Mg)3Al6[Si6O18](BO3)3(OH,O)3(F,O)
'Unnamed (F analogue of feruvite)'CaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3F
'Unnamed (Mn2+-F-analogue of foitite)'◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3F ?
'Unnamed (Pb-analogue of Fluor-liddicoatite)'Pb(Li2Al)Al6(Si6O18)(BO3)3(OH)3F
UviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Vanadio-oxy-chromium-draviteNaV3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
Vanadio-oxy-draviteNaV3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m

Related Minerals - Strunz-mindat GroupingHide

9.CK.AdachiiteCaFe3Al6(Si5AlO18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.Magnesio-dutrowiteNa(Mg2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.DarrellhenryiteNa(Al2Li)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Fluor-schorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.PrincivalleiteNa(Mn2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Alumino-oxy-rossmanite◻Al3Al6(Si5AlO18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.DutrowiteNa(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Ferro-bosiiteNaFe3+3(Al4Fe2+2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.BosiiteNaFe3+3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Celleriite◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05FeruviteCaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Chromium-draviteNaMg3Cr3+6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-rossmanite◻(Al2Li)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m(32/m) : R3m
9.CK.05Oxy-schorlNa(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-elbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05DraviteNaMg3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-uviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Foitite◻(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Vanadio-oxy-draviteNaV3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-buergeriteNaFe3+3Al6(Si6O18)(BO3)3O3FTrig. 3m : R3m
9.CK.05'Unnamed (F analogue of feruvite)'CaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3F
9.CK.05ErtliteNaAl3Al6(Si4B2O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-liddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05UviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-tsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Oxy-foitite◻(Fe2+Al2)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m(32/m) : R3m
9.CK.05LiddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Vanadio-oxy-chromium-draviteNaV3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
9.CK.05Rossmanite◻(LiAl2)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Oxy-vanadium-draviteNaV3(V4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05OleniteNaAl3Al6(Si6O18)(BO3)3O3(OH)Trig. 3m : R3m
9.CK.05'UM2000-64-SiO:BFeHKMg'(K,Na)Fe3+3(Mg2Fe3+4)Si6O18(BO3)3(OH)3O
9.CK.05Magnesio-lucchesiiteCaMg3Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05PovondraiteNaFe3+3(Mg2Fe3+4)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05LucchesiiteCaFe2+3 Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Chromo-alumino-povondraiteNaCr3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-draviteNaMg3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Oxy-draviteNa(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Oxy-chromium-draviteNaCr3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
9.CK.05'Luinaite-(OH)'NaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Mon. m : Bm
9.CK.05SchorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Magnesio-foitite◻(Mg2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05MaruyamaiteK(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.10Abenakiite-(Ce)Na26Ce6(Si6O18)(PO4)6(CO3)6(SO2)OTrig. 3 : R3
9.CK.15ScawtiteCa7(Si3O9)2CO3 · 2H2OMon. 2/m
9.CK.20Thorosteenstrupine(Ca,Th,Mn)3Si4O11F · 6H2O
9.CK.20Steenstrupine-(Ce)Na14Mn2+2Fe3+2Ce6Zr(Si6O18)2(PO4)6(PO3OH)(OH)2 · 2H2OTrig. 3m(32/m) : R3m

Fluorescence of TsilaisiteHide

In UV light:
Shows no fluorescence

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for TsilaisiteHide

References for TsilaisiteHide

Localities for TsilaisiteHide

Showing 7 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Newfoundland and Labrador
    • Newfoundland
Malay et al. (2026)
Czech Republic
 
  • South Bohemian Region
    • Český Krumlov District
Vácha et al. (2025)
  • South Moravian Region
    • Znojmo District
      • Ctidružice
Scarlett Urbanová (2021)
Italy (TL)
 
  • Tuscany
    • Livorno Province
      • Campo nell'Elba
        • San Piero in Campo
Williams et al. (2011) +1 other reference
Japan
 
  • Iwate Prefecture
    • Ofunato City
Yohei Shirose (2018)
Russia
 
  • Zabaykalsky Krai
    • Krasnochikoysky District
      • Krasnyi Chikoy
Lees et al. (2019)
    • Nerchinsky District
AmMin 88:1369-1376 (2003)
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