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Povondraite

A valid IMA mineral species
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About PovondraiteHide

05129270017271926067197.jpg
Pavel Povondra
Formula:
NaFe3+3(Mg2Fe3+4)(Si6O18)(BO3)3(OH)3O
Colour:
Dark brown to brownish black
Lustre:
Resinous
Hardness:
7
Specific Gravity:
3.26
Crystal System:
Trigonal
Name:
Named in honour of Pavel Povondra (7 December 1924, Žamberk, Ústí nad Orlicí District, Pardubice Region, Czech Republic - 9 September 2013), mineralogist at Charles University, Prague, Czech Republic, for his extensive work on the chemistry of the tourmaline group.
Povondraite was redefined (IMA 90-E) from the original “ferridravite” (Walenta and Dunn, 1979) because the initially assumed site assignments were incorrect and did not correspond to the Fe3+-equivalent of dravite (Grice et al. 1993). Hawthorne and Henry (1999) suggested that Mg is ordered at the Z site and should be part of the end-member formula.

The type locality was originally given imprecisely as the San Francisco mine. However, povondraite does not occur in the asbestos mine itself, but rather in the rock unit known as the Locotal Breccia, several hundred meters from the asbestos ore veins.




Unique IdentifiersHide

Mindat ID:
3274
Long-form identifier:
mindat:1:1:3274:8

IMA Classification of PovondraiteHide

Approved
IMA status notes:
Renamed by the IMA
IMA Formula:
NaFe3+3(Fe3+4Mg2)(Si6O18)(BO3)3(OH)3O
Approval year:
1978
First published:
1979
Approval history:
Renamed by IMA: 1990

Classification of PovondraiteHide

9.CK.05

9 : SILICATES (Germanates)
C : Cyclosilicates
K : [Si6O18]12- 6-membered single rings, with insular complex anions
Dana 7th ed.:
61.3.1.8
61.3.1.6

61 : CYCLOSILICATES Six-Membered Rings
3 : Six-Membered Rings with borate groups

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
PovIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
PovThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of PovondraiteHide

Resinous
Transparency:
Opaque
Colour:
Dark brown to brownish black
Comment:
Light is transmitted only in thin splinters.
Streak:
Brown
Hardness:
Cleavage:
None Observed
Density:
3.26(3) g/cm3 (Measured)    3.33 g/cm3 (Calculated)

Optical Data of PovondraiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.82 nε = 1.751
Max. Birefringence:
δ = 0.069
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Pleochroism:
Strong
Comments:
E : light brown and O: dark brown, blackish brown to opaque.

Chemistry of PovondraiteHide

Mindat Formula:
NaFe3+3(Mg2Fe3+4)(Si6O18)(BO3)3(OH)3O
Element Weights:
Element% weight
O42.666 %
Fe33.628 %
Si14.496 %
Mg4.182 %
B2.790 %
Na1.978 %
H0.260 %

Calculated from ideal end-member formula.
O
Fe
Si
Mg
B
Na
H
Common Impurities:
K,Mg,Al,Cu,Pb,Sn,Ti,V,H2O

Crystallography of PovondraiteHide

Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
R3m
Cell Parameters:
a = 16.18 Å, c = 7.44 Å
Ratio:
a:c = 1 : 0.46
Unit Cell V:
1,686.79 ų (Calculated from Unit Cell)
Z:
3
Morphology:
Equant and simple. Crystals are comprised of the second-order hexagonal prism {1120} and the trigonal pyramids, {1011} and {2021}.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0018783PovondraiteGrice J D, Ercit T S (1993) Ordering of Fe and Mg in the tourmaline crystal structure: The correct formula Neues Jahrbuch fur Mineralogie, Abhandlungen 165 245-2661993San Francisco mine, Villa Tu nari, Bolivia0293
0001555PovondraiteGrice J D, Ercit T S, Hawthorne F C (1993) Povondraite, a redefinition of the tourmaline ferridravite American Mineralogist 78 433-4361993San Francisco mine, Villa Tunari, Bolivia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.63 Å(100)
6.63 Å(90)
4.05 Å(90)
3.05 Å(90)
3.61 Å(80)
5.13 Å(70)
4.71 Å(70)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4a: Earth’s earliest continental crust>4.4-3.0
19 : Granitic intrusive rocks
Near-surface Processes
23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47)
26 : Hadean detrital minerals
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites
Stage 5: Initiation of plate tectonics<3.5-2.5
40 : Regional metamorphism (greenschist, amphibolite, granulite facies)
Geological Setting:
Saltdome caprock

Type Occurrence of PovondraiteHide

General Appearance of Type Material:
Crystals (to several mm), intergrown or forming subparallel aggregates. Not easily recognized as tourmaline. Crystals are not elongated along the c axis, but are more equant in habit.
Place of Conservation of Type Material:
Royal Ontario Museum, Toronto, Canada, M35899.
National Museum of Natural History, Washington, D.C., USA, 144478.
Geological Setting of Type Material:
Schist, possibly limited to younger fissures. Rare.
Associated Minerals at Type Locality:

Synonyms of PovondraiteHide

Other Language Names for PovondraiteHide

Relationship of Povondraite to other SpeciesHide

Other Members of Tourmaline:
AdachiiteCaFe3Al6(Si5AlO18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Alumino-oxy-rossmanite◻Al3Al6(Si5AlO18)(BO3)3(OH)3OTrig. 3m : R3m
BosiiteNaFe3+3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Celleriite◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Chromium-draviteNaMg3Cr3+6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Chromo-alumino-povondraiteNaCr3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
DarrellhenryiteNa(Al2Li)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
DraviteNaMg3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
DutrowiteNa(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
ErtliteNaAl3Al6(Si4B2O18)(BO3)3(OH)3OTrig. 3m : R3m
Ferro-bosiiteNaFe3+3(Al4Fe2+2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
FeruviteCaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Fluor-buergeriteNaFe3+3Al6(Si6O18)(BO3)3O3FTrig. 3m : R3m
Fluor-draviteNaMg3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-elbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-liddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-rossmanite◻(Al2Li)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m(32/m) : R3m
Fluor-schorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-tsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-uviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Foitite◻(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
LiddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
LucchesiiteCaFe2+3 Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Magnesio-dutrowiteNa(Mg2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Magnesio-foitite◻(Mg2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Magnesio-lucchesiiteCaMg3Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
MaruyamaiteK(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
OleniteNaAl3Al6(Si6O18)(BO3)3O3(OH)Trig. 3m : R3m
Oxy-chromium-draviteNaCr3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
Oxy-draviteNa(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Oxy-foitite◻(Fe2+Al2)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m(32/m) : R3m
Oxy-schorlNa(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Oxy-vanadium-draviteNaV3(V4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
PrincivalleiteNa(Mn2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Rossmanite◻(LiAl2)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
SchorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
TsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
'UM2000-64-SiO:BFeHKMg'(K,Na)Fe3+3(Mg2Fe3+4)Si6O18(BO3)3(OH)3O
'UM2008-52-SiO:AlBCaFFeHLiMgNa'(Ca,Na,◻)(Al,Li,Fe,Mg)3Al6[Si6O18](BO3)3(OH,O)3(F,O)
'Unnamed (F analogue of feruvite)'CaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3F
'Unnamed (Mn2+-F-analogue of foitite)'◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3F ?
'Unnamed (Pb-analogue of Fluor-liddicoatite)'Pb(Li2Al)Al6(Si6O18)(BO3)3(OH)3F
UviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Vanadio-oxy-chromium-draviteNaV3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
Vanadio-oxy-draviteNaV3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m

Common AssociatesHide

Associations Based on Photo Data:
4 photos of Povondraite associated with MicroclineK(AlSi3O8)
3 photos of Povondraite associated with MagnesiteMgCO3
2 photos of Povondraite associated with Hydroniumjarosite(H3O)Fe3+3(SO4)2(OH)6
2 photos of Povondraite associated with QuartzSiO2
2 photos of Povondraite associated with ClinoenstatiteMgSiO3

Related Minerals - Strunz-mindat GroupingHide

9.CK.AdachiiteCaFe3Al6(Si5AlO18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.Magnesio-dutrowiteNa(Mg2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.DarrellhenryiteNa(Al2Li)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Fluor-schorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.PrincivalleiteNa(Mn2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Alumino-oxy-rossmanite◻Al3Al6(Si5AlO18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.DutrowiteNa(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Ferro-bosiiteNaFe3+3(Al4Fe2+2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.BosiiteNaFe3+3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Celleriite◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05FeruviteCaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Chromium-draviteNaMg3Cr3+6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-rossmanite◻(Al2Li)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m(32/m) : R3m
9.CK.05Oxy-schorlNa(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-elbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05DraviteNaMg3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-uviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Foitite◻(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Vanadio-oxy-draviteNaV3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-buergeriteNaFe3+3Al6(Si6O18)(BO3)3O3FTrig. 3m : R3m
9.CK.05'Unnamed (F analogue of feruvite)'CaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3F
9.CK.05ErtliteNaAl3Al6(Si4B2O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05TsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-liddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05UviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-tsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Oxy-foitite◻(Fe2+Al2)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m(32/m) : R3m
9.CK.05LiddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Vanadio-oxy-chromium-draviteNaV3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
9.CK.05Rossmanite◻(LiAl2)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Oxy-vanadium-draviteNaV3(V4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05OleniteNaAl3Al6(Si6O18)(BO3)3O3(OH)Trig. 3m : R3m
9.CK.05'UM2000-64-SiO:BFeHKMg'(K,Na)Fe3+3(Mg2Fe3+4)Si6O18(BO3)3(OH)3O
9.CK.05Magnesio-lucchesiiteCaMg3Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05LucchesiiteCaFe2+3 Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Chromo-alumino-povondraiteNaCr3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-draviteNaMg3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Oxy-draviteNa(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Oxy-chromium-draviteNaCr3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
9.CK.05'Luinaite-(OH)'NaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Mon. m : Bm
9.CK.05SchorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Magnesio-foitite◻(Mg2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05MaruyamaiteK(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.10Abenakiite-(Ce)Na26Ce6(Si6O18)(PO4)6(CO3)6(SO2)OTrig. 3 : R3
9.CK.15ScawtiteCa7(Si3O9)2CO3 · 2H2OMon. 2/m
9.CK.20Thorosteenstrupine(Ca,Th,Mn)3Si4O11F · 6H2O
9.CK.20Steenstrupine-(Ce)Na14Mn2+2Fe3+2Ce6Zr(Si6O18)2(PO4)6(PO3OH)(OH)2 · 2H2OTrig. 3m(32/m) : R3m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for PovondraiteHide

References for PovondraiteHide

Reference List:

Localities for PovondraiteHide

Showing 20 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • New South Wales
    • Argyle Co.
Jones et al. (1981)
  • Western Australia
    • Upper Gascoyne Shire
      • Yinnietharra
Fetherston et al. (2013)
        • Tomkap tourmaline mines (Soklich)
T Kapitany (pers comm)
Austria
 
  • Carinthia
    • Wolfsberg District
      • Preitenegg
B. Moser (2002)
Bolivia
 
  • Cochabamba
    • Chapare Province
Žáček et al. (1998) +1 other reference
        • Cristalmayu subdistrict
          • Cristalmayu
- (erroneously attributed to San Francisco mine in the type description)
- (erroneously attributed to this mine in the type description)
Brazil
 
  • Minas Gerais
    • Coronel Murta
erroneously reported [MinRec 33:209]
China
 
  • Tibet
    • Lhasa
      • Maizhokunggar Co. (Mozhugongka Co.)
Zhao et al. (2025)
Mali
 
  • Kayes Region
    • Kayes Cercle
      • Sadiola Commune
Masurel et al. (2017)
Norway
 
  • Telemark
    • Bamble
      • Bjordammen
...
Russia
 
  • Chukotka Autonomous Okrug
    • Bilibinsky District
      • Vesenniy
Mineralogy of the Peschanka porphyry copper deposit et al. (Trans. Inst. Min. Metall. B)
    • Chaunskii District (Chaun)
      • Ilirney ore district
Nikolaev et al. (2013)
  • Zabaykalsky Krai
    • Tungokochensky District
      • Vershino-Darasunskiy
Baksheev et al. (2015)
Baksheev et al. (2015)
Baksheev et al. (2015)
Slovakia
 
  • Bratislava Region
    • Bratislava
Bačík et al. (2008)
      • Bratislava IV
        • Devín
Bačík et al. (2008)
USA
 
  • New Jersey
    • Sussex County
      • Ogdensburg
Robert Jemkins +1 other reference
  • Utah
    • Tooele County
      • Gold Hill Mining District (Clifton Mining District)
Ex collection Dipl. Min. Ulrich Vetter
 
and/or  
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To cite: Ralph, J., Von Bargen, D., Martynov, P., Zhang, J., Que, X., Prabhu, A., Morrison, S. M., Li, W., Chen, W., & Ma, X. (2025). Mindat.org: The open access mineralogy database to accelerate data-intensive geoscience research. American Mineralogist, 110(6), 833–844. doi:10.2138/am-2024-9486.
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