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Betzite

A valid IMA mineral species
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About BetziteHide

08982650017271954013951.jpg
Volker Betz
Formula:
Na6Ca2(Al6Si6O24)Cl4
Colour:
Colorless
Hardness:
Specific Gravity:
2.38
Crystal System:
Hexagonal
Name:
Named in honor of Volker Betz (b. 1947, Heilbronn, Germany), amateur mineral collector specializing in zeolite minerals and minerals from zeolite localities. He has also written a number of articles about those interests.
Dimorph of:
Betzite occurs as colourless hexagonal prismatic crystals visually identical to its dimorph quadridavyne (6/m), with which it is associated at the type locality. They can only be distinguished by SXRD.


Unique IdentifiersHide

Mindat ID:
55549
Long-form identifier:
mindat:1:1:55549:0

Similar NamesHide

BatisiteA valid IMA mineral speciesBaNaNaTi2(Si4O12)O2
BitositeA rock subtype
BotesiteA synonym of Hessite
BytíziteA valid IMA mineral speciesCu3SbSe3
PetziteA valid IMA mineral species - grandfatheredAg3AuTe2

IMA Classification of BetziteHide

Approved
Approval year:
2021
First published:
2023

Classification of BetziteHide

9.FB.

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
BztIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BetziteHide

Transparency:
Transparent
Colour:
Colorless
Streak:
White
Hardness:
5½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
{1010}
Parting:
parting on {0001}
Density:
2.38(2) g/cm3 (Measured)    2.363 g/cm3 (Calculated)

Optical Data of BetziteHide

Type:
Uniaxial (+)
RI values:
nω = 1.528(2) nε = 1.545(3)
Max. Birefringence:
δ = 0.017
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
None to Very Low
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of BetziteHide

Mindat Formula:
Na6Ca2(Al6Si6O24)Cl4
Element Weights:
Element% weight
O35.743 %
Si15.686 %
Al15.069 %
Cl13.201 %
Na12.840 %
Ca7.461 %

Calculated from ideal end-member formula.
O
Si
Al
Cl
Na
Ca

Crystallography of BetziteHide

Crystal System:
Hexagonal
Class (H-M):
6 - Pyramidal
Space Group:
P63
Cell Parameters:
a = 12.8166(9) Å, c = 5.3562(3) Å
Ratio:
a:c = 1 : 0.418
Unit Cell V:
761.96 ų (Calculated from Unit Cell)
Z:
3
Morphology:
Hexagonal prismatic crystals.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
11.14 Å(31)
4.833 Å(93)
3.715 Å(95)
3.313 Å(100)
2.787 Å(37)
2.681 Å(56)
2.474 Å(35)
2.146 Å(24)
Comments:
Bellerberg volcano, Rhineland-Palatinate, Germany. Data from the type description.

Type Occurrence of BetziteHide

General Appearance of Type Material:
Colorless hexagonal prismatic crystals up to 2 mm long and up to 0.5 mm thick.
Place of Conservation of Type Material:
Collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia, registration number 5706/1.
Geological Setting of Type Material:
Metasomatically altered (pyrometamorphosed) calcic xenolith, hosted by alkaline basalt.
Associated Minerals at Type Locality:

Synonyms of BetziteHide

Other Language Names for BetziteHide

Dutch:Betziet
German:Betzit

Relationship of Betzite to other SpeciesHide

Other Members of Cancrinite Group:
Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P31c
Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P31c
Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClTrig. 3m : P31c
Cancrinite(Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex. 6mm : P63mc
CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P31c
Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5)Hex. 6 : P63
Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P31c
HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex. 6 : P63
KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 32 : R32
KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
Liottite(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4Hex. 6 : P6
Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P31c
MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex. 622 : P6322
PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex. 6 : P63
Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex. 6/m : P63/m
Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2OHex.
SteudeliteNa3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2OHex. 6m2 : P62c
SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P31c
Tounkite(Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2OHex. 622 : P6222
'UM2004-48-SiO:AlClCaNaS'(Na,Ca)8(Si6Al6)O24(SO4)1.7Cl1.3
'UM2009-23-SiO:AlCCaClHKNaS'(Na,Ca)24K10[(Si,Al)60O120](SO4)5.6Cl1.5(CO3)0.4 · 11H2OTrig. 3 : P3
Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Betzite associated with AnorthiteCa(Al2Si2O8)
1 photo of Betzite associated with GrossularCa3Al2(SiO4)3
1 photo of Betzite associated with Pyroxene GroupADSi2O6

Related Minerals - Strunz-mindat GroupingHide

9.FB.Perchukite-(Y)PbYAsSi2O8Mon. 2/m : B2/b
9.FB.Åsgruvanite-(Ce)Ce16Ca5Al(SiO4)6(AsO3)8(CO3)2Cl4F3(OH)2Trig. 3m(32/m) : P3m1
9.FB.SteudeliteNa3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2OHex. 6m2 : P62c
9.FB.Wenlanzhangite-(Y)Y2V3+2V4+2(SiO4)2O4(OH)4Tric. 1 : P1
9.FB.SlyudyankaiteNa28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2OTric. 1 : P1
9.FB.Bolotinaite(Na7◻)(Al6Si6O24)F · 4H2OIso. 43m : I43m
9.FB.SapozhnikoviteNa8(Al6Si6O24)(HS)2Iso. 43m : P43n
9.FB.05Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex. 6/m : P63/m
9.FB.05SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P31c
9.FB.05Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P31c
9.FB.05Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P31c
9.FB.05Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClTrig. 3m : P31c
9.FB.05Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
9.FB.05KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
9.FB.05Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63
9.FB.05Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
9.FB.05Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P31c
9.FB.05Liottite(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4Hex. 6 : P6
9.FB.05DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5)Hex. 6 : P63
9.FB.05Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
9.FB.05Cancrinite(Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
9.FB.05CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex. 6mm : P63mc
9.FB.05Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
9.FB.05CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P31c
9.FB.05MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex. 622 : P6322
9.FB.05PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex. 6 : P63
9.FB.05Tounkite(Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2OHex. 622 : P6222
9.FB.05Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
9.FB.05Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P31c
9.FB.05Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2OHex.
9.FB.05KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 32 : R32
9.FB.05HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex. 6 : P63
9.FB.05Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
9.FB.10HaüyneNa3Ca(Si3Al3)O12(SO4)Iso. 43m : P43n
9.FB.10LazuriteNa7Ca(Al6Si6O24)(SO4)(S3) · H2OIso. 43m : P43n
9.FB.10DanaliteBe3Fe2+4(SiO4)3SIso. 43m : P43n
9.FB.10HelvineBe3Mn2+4(SiO4)3SIso. 43m : P43n
9.FB.10KamaishiliteCa2(Al2SiO6)(OH)2Tet.
9.FB.10SodaliteNa4(Si3Al3)O12ClIso. 43m : P43n
9.FB.10NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 43m : P43n
9.FB.10GenthelviteBe3Zn4(SiO4)3SIso. 43m : P43n
9.FB.10BicchuliteCa2(Al2SiO6)(OH)2Iso. 43m : I43m
9.FB.10Tsaregorodtsevite(N(CH3)4)(AlSi5O12)Orth. 222 : I222
9.FB.10VladimirivanoviteNa6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2OOrth. mmm(2/m2/m2/m)
9.FB.10Tugtupite(BeAlSi)Na4(SiO4)3ClTet. 4 : I4
9.FB.15MarialiteNa4Al3Si9O24ClTet. 4/m : I4/m
9.FB.15MeioniteCa4Al6Si6O24CO3Tet. 4/m : I4/m
9.FB.15Silvialite(Ca,Na)4(Al6Si6O24)(SO4,CO3)Tet. 4/m : I4/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BetziteHide

References for BetziteHide

Localities for BetziteHide

Showing 1 localities.

ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Germany (TL)
 
  • Rhineland-Palatinate
    • Mayen-Koblenz
      • Vordereifel
Miyawaki et al. (2021) +1 other reference
 
and/or  
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