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Castellaroite

A valid IMA mineral species
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About CastellaroiteHide

08217020017272472603012.jpg
My friend Fabrizio Castellaro
Formula:
Mn2+3(AsO4)2 · 4H2O
Colour:
colorless
Lustre:
Vitreous, Silky
Hardness:
Specific Gravity:
3.14
Crystal System:
Monoclinic
Name:
Named in honour of the mineral collector Fabrizio Castellaro who has discovered castellaroite, but also balestraite, cerchiaraite-(Fe) and lavinskyite-1M.
Probably a polymorph of sterlinghillite. Structurally related to metaswitzerite.
A higher hydrate (octahydrate) is manganohörnesite.


Unique IdentifiersHide

Mindat ID:
46905
Long-form identifier:
mindat:1:1:46905:0

Classification of CastellaroiteHide

1. Raman spectrum of castellaroite. Castellaroite, Mn2+3(AsO4)2·4.5H2O, a new mineral from Italy related to metaswitzerite ANTHONY R. KAMPF,FERNANDO CÁMARA, MARCO E. CIRIOTTI, BARBARA. NASH, CORRADO BALESTRA, and LUIGI CHIAPPINO, 2016, European Journal of Mineralogy, online.

IMA Classification of CastellaroiteHide

Approved
IMA Formula:
Mn2+3(As5+O4)2·4.5H2O
Approval year:
2015
8.CD.

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
D : With only medium-sized cations, RO4:H2O = 1:2

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
CtrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CastellaroiteHide

Vitreous, Silky
Transparency:
Transparent
Colour:
Colorless
Streak:
White
Hardness:
3½ on Mohs scale
Tenacity:
Flexible
Cleavage:
Perfect
{001}
Density:
3.14(2) g/cm3 (Measured)    3.164 g/cm3 (Calculated)

Optical Data of CastellaroiteHide

Type:
Biaxial (-)
RI values:
nα = 1.644(1) nβ = 1.662(1) nγ = 1.667(1)
2V:
Measured: 57° (1)
Birefringence:
0.023
Max. Birefringence:
δ = 0.023
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
moderate r < v

Chemistry of CastellaroiteHide

Mindat Formula:
Mn2+3(AsO4)2 · 4H2O
Element Weights:
Element% weight
O37.301 %
Mn32.021 %
As29.112 %
H1.567 %

Calculated from ideal end-member formula.
O
Mn
As
H

Crystallography of CastellaroiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 8.752(2) Å, b = 13.463(4) Å, c = 18.636(6) Å
β = 94.851(7)°
Ratio:
a:b:c = 0.65 : 1 : 1.384
Unit Cell V:
2,187.98 ų (Calculated from Unit Cell)
Z:
8
Morphology:
Thin blades, flattened on [001], striated and elongated parallel to [100] and exhibiting the forms {110}, {012} and {001}.
Comment:
P21/n

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.9056 Å(100)
9.2922 Å(84)
7.6485 Å(4)
6.9849 Å(28)
6.6529 Å(22)
5.6280 Å(3)
5.5618 Å(5)
5.1963 Å(7)
4.7313 Å(5)
4.5714 Å(10)
4.3624 Å(7)
4.1487 Å(3)
4.0424 Å(8)
3.9920 Å(2)
3.8721 Å(2)
3.8258 Å(6)
3.7207 Å(8)
3.6352 Å(11)
3.6172 Å(3)
3.5963 Å(22)
3.4158 Å(18)
3.3244 Å(22)
3.3131 Å(3)
3.2285 Å(6)
3.2229 Å(2)
3.1286 Å(7)
3.1261 Å(12)
3.0878 Å(3)
3.0534 Å(50)
3.0213 Å(15)
2.9773 Å(6)
2.9583 Å(5)
Comments:
KAMPF, ANTHONY R., CÁMARA, FERNANDO, CIRIOTTI, MARCO E., NASH, BARBARA P., BALESTRA, CORRADO, and CHIAPPINO, LUIGI (2016) Castellaroite, Mn2+3(AsO4)2· 4.5 H2O, a new mineral from Italy related to metaswitzerite, European Journal of Mineralogy, 28, 687-696.

Geological EnvironmentHide

Type Occurrence of CastellaroiteHide

General Appearance of Type Material:
thin blades, flattened on [001], striated and elongated parallel to [100] and exhibiting the forms {110}, {012} and {001}.
Place of Conservation of Type Material:
Type material is deposited in the mineralogical collections of the Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA, cataloguenumbers 65603 (holotype - MN) and 65604 (cotype - MN), and the Museo Regionale
Geological Setting of Type Material:
Secondary arsenate mineral
Associated Minerals at Type Locality:

Synonyms of CastellaroiteHide

Other Language Names for CastellaroiteHide

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Castellaroite associated with WallkilldelliteCa2Mn2+3(AsO4)2(OH)4 · 9H2O

Related Minerals - Strunz-mindat GroupingHide

8.CD.SergeysmirnoviteMgZn2(PO4)2 · 4H2OOrth. mmm(2/m2/m2/m) : Pnma
8.CD.05PhosphosideriteFePO4 · 2H2OMon. 2/m
8.CD.05MetavarisciteAlPO4 · 2H2OMon. 2/m : P21/b
8.CD.05BonacinaiteSc(AsO4) · 2H2OMon. 2/m
8.CD.05KolbeckiteScPO4 · 2H2OMon. 2/m
8.CD.10YanomamiteInAsO4 · 2H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CD.10MansfielditeAlAsO4 · 2H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CD.10ScoroditeFe3+AsO4 · 2H2OOrth. mmm(2/m2/m2/m)
8.CD.10VarisciteAlPO4 · 2H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CD.10StrengiteFePO4 · 2H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CD.15ParascoroditeFeAsO4 · 2H2OHex. 6/mmm(6/m2/m2/m) : P63/mcm
8.CD.20LudlamiteFe2+3(PO4)2 · 4H2OMon. 2/m : P21/b
8.CD.25SterlinghilliteMn2+3(AsO4)2 · 3H2OMon.
8.CD.30RollanditeCu3(AsO4)2 · 4H2OOrth. mmm(2/m2/m2/m) : Pnma
8.CD.35LiversidgeiteZn6(PO4)4 · 7H2OTric. 1 : P1
8.CD.40ThorasphiteTh2H(PO4,AsO4)3 · 6H2OOrth. mmm(2/m2/m2/m) : Pbcn

Other InformationHide

Notes:
easily soluble in dilute HCl at room temperature
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for CastellaroiteHide

References for CastellaroiteHide

Localities for CastellaroiteHide

Showing 5 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy
 
  • Liguria
    • Genoa
      • Ne
Castellaro et al. (2021)
    • La Spezia Province
      • Rocchetta di Vara
Hålenius et al. (2015) +1 other reference
  • Piedmont
    • Cuneo Province
      • Canosio
        • Vallone della Valletta
Hålenius et al. (2015) +1 other reference
Switzerland
 
  • Valais
    • Leuk
      • Turtmann-Unterems
        • Turtmann Valley
          • Pipjitälli
Ansermet et al. (2026)
USA
 
  • New Jersey
    • Sussex County
      • Ogdensburg
        • Sterling Hill
Earl Verbeek
 
and/or  
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