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Hydroxycalciopyrochlore

A valid IMA mineral species
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About HydroxycalciopyrochloreHide

Formula:
(Ca,Na,U,◻)2(Nb,Ti)2O6(OH)
Colour:
Brownish-black, greenish-black and black
Lustre:
Greasy
Hardness:
5 - 6
Specific Gravity:
5.10
Crystal System:
Isometric
The Ca analogue of hydroxymanganopyrochlore and hydroxyplumbopyrochlore. The OH analogue of fluorcalciopyrochlore. Chemically related to charleshatchettite and 'Unnamed (MSH UK-56)'.


Unique IdentifiersHide

Mindat ID:
40340
Long-form identifier:
mindat:1:1:40340:7

IMA Classification of HydroxycalciopyrochloreHide

Approved
IMA Formula:
(Ca,Na,U4+,◻)2(Nb5+,Ti4+)2O6(OH)
Approval year:
2011
First published:
2014

Classification of HydroxycalciopyrochloreHide

4.DH.15

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
H : With large (+- medium-sized) cations; sheets of edge-sharing octahedra

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
HcpclIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of HydroxycalciopyrochloreHide

Greasy
Transparency:
Translucent
Colour:
Brownish-black, greenish-black and black
Comment:
Colors on fresh sections
Streak:
Brown streak
Hardness:
5 - 6 on Mohs scale
Hardness:
VHN100=572 - Vickers
Cleavage:
None Observed
Metamict
Parting:
None observed
Fracture:
Conchoidal
Density:
5.10(3) g/cm3 (Measured)    5.15 g/cm3 (Calculated)
Comment:
Measured by hydrostatic weighing

Chemistry of HydroxycalciopyrochloreHide

Mindat Formula:
(Ca,Na,U,◻)2(Nb,Ti)2O6(OH)
Element Weights:
Element% weight
Nb49.031 %
O29.553 %
Ca21.151 %
H0.266 %

Calculated from ideal end-member formula.
Common Impurities:
Na,U,Ti,Ce,F

Chemical AnalysisHide

Empirical formulas:
Sample IDEmpirical Formula
1(Ca1.08Na0.67U4+0.03Ce0.03La0.02)(Nb1.74Ti0.21Ta0.05(O6.00(OH)0.89·nH2O

Crystallography of HydroxycalciopyrochloreHide

Crystal System:
Isometric
Class (H-M):
m3m(4/m32/m) - Hexoctahedral
Space Group:
Fd3m
Cell Parameters:
a = 10.381(4) Å
Unit Cell V:
1118.7 ų
Z:
8
Morphology:
Mostly as octahedra, and less often as dodecahedra and tetrahexahedra or combinations thereof. Some occur with an allotriomorphic habit with a thick triangular tabular form.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0020233HydroxycalciopyrochloreYang G, Li G, Xiong M, Pan B, Yan C (2014) Hydroxycalciopyrochlore, a new mineral species from Sichuan, China Acta Geologica Sinica 88 748-7532014Maoniuping mine, Mianning County, Xichang prefecture, Sichuan Province, China0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.9657 Å(100)
2.569 Å(18)
1.8142 Å(34)
1.5463 Å(21)
2.5688 Å(18)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of HydroxycalciopyrochloreHide

Place of Conservation of Type Material:
China University of Geosciences, Beijng,China, catalogue number M595-22
Geological Setting of Type Material:
Alkali feldspar granite rare-earth ore deposit (26–27 Ma).
Associated Minerals at Type Locality:

Synonyms of HydroxycalciopyrochloreHide

Other Language Names for HydroxycalciopyrochloreHide

Relationship of Hydroxycalciopyrochlore to other SpeciesHide

Other Members of Pyrochlore Group:
Cesiokenopyrochlore◻Nb2(O,OH)6(Cs,◻) Iso. m3m(4/m32/m) : Fd3m
Fluorcalciopyrochlore(Ca,Na)2(Nb,Ti)2O6FIso.
'Fluorhydropyrochlore'A possible new species (See discussion in Atencio et al.
'Fluorkenopyrochlore'(◻,Sr,Ce,Ca,Na)2(Nb,Ti)2O6F
Fluornatropyrochlore(Na,Pb,Ca,REE,U)2Nb2O6FIso. m3m(4/m32/m)
'Fluorplumbopyrochlore'(Pb,Y,Th,U,Na,Ca)2-x(Nb,Ti)2O6FIso.
'Fluorstrontiopyrochlore'(Sr,◻)2Nb2(O,OH)6F
Hydrokenopyrochlore(◻,x)2Nb2O6(H2O,Cs)Iso. m3m(4/m32/m) : Fd3m
Hydropyrochlore(H2O,◻)2Nb2(O,OH)6(H2O)Iso. m3m(4/m32/m) : Fd3m
Hydroxykenopyrochlore(◻,Ce,Ba)2(Nb,Ti)2O6(OH,F)Iso. m3m(4/m32/m) : Fd3m
Hydroxymanganopyrochlore(Mn2+,Th,Na,Ca,REE)2(Nb,Ti)2O6(OH) Iso. m3(2/m3)
Hydroxynatropyrochlore(Na,Ca,Ce)2Nb2O6(OH)Iso. m3m(4/m32/m) : Fd3m
Hydroxyplumbopyrochlore (Pb1.50.5)Nb2O6(OH)Iso. m3m(4/m32/m) : Fd3m
'Kenoplumbopyrochlore'(Pb,◻)Nb2O6(◻,O)
OxycalciopyrochloreCa2Nb2O6OIso. m3m(4/m32/m) : Fd3m
'Oxynatropyrochlore'(Na,Ca,U)2Nb2O6(O,OH)
OxyplumbopyrochlorePb2Nb2O6OIso. m3m(4/m32/m) : Fd3m
'Oxyyttropyrochlore-(Y)'(Y,◻)2Nb2O6O
'Strontiopyrochlore (of Hogarth 1977)'(Sr,Ce,Ca)0.66(Nb,Fe)2(O,OH)7
'Unnamed (Sb-analogue of Hydroxymanganopyrochlor)'(Mn,Ca,Y)2(Sb,Ti)2O6(OH)

Common AssociatesHide

Associations Based on Photo Data:
18 photos of Hydroxycalciopyrochlore associated with QuartzSiO2
9 photos of Hydroxycalciopyrochlore associated with MicroclineK(AlSi3O8)
4 photos of Hydroxycalciopyrochlore associated with ZirconZr(SiO4)
3 photos of Hydroxycalciopyrochlore associated with SogdianiteK◻2Zr2Li3[Si12O30]
3 photos of Hydroxycalciopyrochlore associated with Fluorcalciopyrochlore(Ca,Na)2(Nb,Ti)2O6F
2 photos of Hydroxycalciopyrochlore associated with PolylithioniteKLi2Al(Si4O10)(F,OH)2
2 photos of Hydroxycalciopyrochlore associated with NiobophylliteK2NaFe2+7(NbTi)[Si4O12]2O2(OH)4O
2 photos of Hydroxycalciopyrochlore associated with Monazite-(Ce)Ce(PO4)
2 photos of Hydroxycalciopyrochlore associated with WillemiteZn2SiO4
2 photos of Hydroxycalciopyrochlore associated with CalciteCaCO3

Related Minerals - Strunz-mindat GroupingHide

4.DH.Cesiokenopyrochlore◻Nb2(O,OH)6(Cs,◻) Iso. m3m(4/m32/m) : Fd3m
4.DH.Roméite GroupA2(Sb5+)2O6Z
4.DH.OxyplumboroméitePb2Sb2O6OIso. m3m(4/m32/m) : Fd3m
4.DH.Fluornatropyrochlore(Na,Pb,Ca,REE,U)2Nb2O6FIso. m3m(4/m32/m)
4.DH.Hydroxykenomicrolite(◻,Na,Sb3+)2Ta2O6(OH,Cs)Iso. m3m(4/m32/m) : Fd3m
4.DH.'Fluornatroroméite'(Na,Ca)2Sb2(O,OH)6F
4.DH.Oxyyttrobetafite-(Y)Y2Ti2O6OIso. m3m(4/m32/m) : Fd3m
4.DH.05Thorutite(Th,U,Ca)Ti2(O,OH)6Mon.
4.DH.05OrthobranneriteU4+U6+Ti4O12(OH)2Orth.
4.DH.05BranneriteUTi2O6Mon. 2/m : B2/m
4.DH.10KassiteCaTi2O4(OH)2Mon. 2/m : P21/b
4.DH.10Lucasite-(La)Mon. 2 : B2
4.DH.10Lucasite-(Ce)CeTi2(O,OH)6Mon.
4.DH.15'Fluorhydropyrochlore'
4.DH.15Hydrokenoelsmoreite2W2O6(H2O)Iso. m3m(4/m32/m) : Fd3m
4.DH.15'Hydroxynatromicrolite'(Na,Bi3+,◻)2Ta2O6(OH)Iso. m3m(4/m32/m) : Fd3m
4.DH.15Hydroplumboelsmoreite(Pb,◻)(W,Fe3+)2O6 · H2OIso. m3m(4/m32/m) : Fd3m
4.DH.15Hydropyrochlore(H2O,◻)2Nb2(O,OH)6(H2O)Iso. m3m(4/m32/m) : Fd3m
4.DH.15'Unnamed (Sb-analogue of Hydroxymanganopyrochlor)'(Mn,Ca,Y)2(Sb,Ti)2O6(OH)
4.DH.15Hydroxynatropyrochlore(Na,Ca,Ce)2Nb2O6(OH)Iso. m3m(4/m32/m) : Fd3m
4.DH.15Hydrokenopyrochlore(◻,x)2Nb2O6(H2O,Cs)Iso. m3m(4/m32/m) : Fd3m
4.DH.15Oxybismutomicrolite(Bi1.330.67)Σ2Ta2O6OIso. m3m(4/m32/m) : Fd3m
4.DH.15Kenomicrolite2Ta2[O4(OH)2]◻Iso. m3m(4/m32/m) : Fd3m
4.DH.15Fluornatromicrolite(Na1.5Bi0.5)Ta2O6FIso. m3m(4/m32/m) : Fd3m
4.DH.15'Oxynatropyrochlore'(Na,Ca,U)2Nb2O6(O,OH)
4.DH.15Fluorcalciopyrochlore(Ca,Na)2(Nb,Ti)2O6FIso.
4.DH.15OxycalciopyrochloreCa2Nb2O6OIso. m3m(4/m32/m) : Fd3m
4.DH.15'Fluorstrontiopyrochlore'(Sr,◻)2Nb2(O,OH)6F
4.DH.15OxyplumbopyrochlorePb2Nb2O6OIso. m3m(4/m32/m) : Fd3m
4.DH.15'Fluorplumbopyrochlore'(Pb,Y,Th,U,Na,Ca)2-x(Nb,Ti)2O6FIso.
4.DH.15'Bismutomicrolite (of Hogarth 1977)'Iso. m3m(4/m32/m) : Fd3m
4.DH.15'Bismutopyrochlore (of Chukanov et al.)'(Bi,Ca,U,Pb)2-xNb2(O,OH)6(OH)Amor.
4.DH.15'Kenoplumbopyrochlore'(Pb,◻)Nb2O6(◻,O)
4.DH.15Hydroxyplumbopyrochlore (Pb1.50.5)Nb2O6(OH)Iso. m3m(4/m32/m) : Fd3m
4.DH.15'Stibiomicrolite (of Groat et al.)'
4.DH.15'Oxyyttropyrochlore-(Y)'(Y,◻)2Nb2O6O
4.DH.15'Fluorkenopyrochlore'(◻,Sr,Ce,Ca,Na)2(Nb,Ti)2O6F
4.DH.15HydroxycalciomicroliteCa1.5Ta2O6(OH)Iso. 432 : P4232
4.DH.15'Strontiopyrochlore (of Hogarth 1977)'(Sr,Ce,Ca)0.66(Nb,Fe)2(O,OH)7
4.DH.15 va'Alumotungstite'2W2O6(H2O)Iso. m3m(4/m32/m) : Fd3m
4.DH.15'Oxycalciobetafite'Ca2(Ti,Nb)2O6O
4.DH.15'Oxyuranobetafite'(U,Ca,◻)2(Ti,Nb)2O6O
4.DH.15Fluorcalciomicrolite(Ca,Na)2(Ta,Nb)2O6FIso. m3m(4/m32/m) : Fd3m
4.DH.15OxycalciomicroliteCa2Ta2O6OIso. m3m(4/m32/m) : Fd3m
4.DH.15OxystannomicroliteSn2Ta2O6OIso. m3m(4/m32/m) : Fd3m
4.DH.15Kenoplumbomicrolite(Pb,◻)2Ta2O6(◻,OH,O)Iso.
4.DH.15Oxynatromicrolite(Na,Ca,U)2(Ta,Nb)2O6(O,F)Iso. m3m(4/m32/m) : Fd3m
4.DH.15Oxystibiomicrolite(Sb3+,Ca)2Ta2O6OIso. m3m(4/m32/m) : Fd3m
4.DH.15'Hydromicrolite'(H2O,◻)2Ta2(O,OH)6(H2O)
4.DH.15'Plumbomicrolite (of Hogarth 1977)'
4.DH.15Hydrokenomicrolite(◻,H2O)2Ta2(O,OH)6(H2O)Iso. m3m(4/m32/m)
4.DH.15Hydroxykenoelsmoreite(◻,Pb)2(W,Fe3+,Al)2(O,OH)6(OH)Trig. 3 : R3
4.DH.15 va'Yttromicrolite (of Hogarth)'(Ca,Y3+,U,Na)2-x(Ta,Nb,Ti,Fe3+)2O7Iso. m3m(4/m32/m) : Fd3m
4.DH.15Hydroxykenopyrochlore(◻,Ce,Ba)2(Nb,Ti)2O6(OH,F)Iso. m3m(4/m32/m) : Fd3m
4.DH.15Hydroxymanganopyrochlore(Mn2+,Th,Na,Ca,REE)2(Nb,Ti)2O6(OH) Iso. m3(2/m3)
4.DH.20'Cuproroméite'Cu2Sb2(O,OH)7Iso.
4.DH.20Hydroxycalcioroméite(Ca,Sb3+)2(Sb5+,Ti)2O6(OH)Iso. m3m(4/m32/m) : Fd3m
4.DH.20BindheimitePb2Sb2O6OIso. m3m(4/m32/m) : Fd3m
4.DH.20Hydroxyferroroméite(Fe2+1.50.5)Sb5+2O6(OH)Iso. m3m(4/m32/m) : Fd3m
4.DH.20Fluorcalcioroméite(Ca,Na,◻)2Sb5+2(O,OH)6FIso. m3m(4/m32/m) : Fd3m
4.DH.20OxycalcioroméiteCa2Sb2O6OIso. m3m(4/m32/m) : Fd3m
4.DH.20StetefeldtiteAg2Sb2(O,OH)7Iso.
4.DH.20StibiconiteSb3+Sb5+2O6(OH) Iso. m3m(4/m32/m)
4.DH.20MonimolitePb2Sb5+2O7Iso. m3m(4/m32/m)
4.DH.25RosiaitePbSb5+2O6Trig. 3m(32/m) : P31m
4.DH.30Stefanweissite(Ca,REE)2Zr2(Nb,Ti)(Ti,Nb)2Fe2+O14Orth. mmm(2/m2/m2/m) : Cmca
4.DH.30ZirconoliteCaZrTi2O7Orth.
4.DH.30Laachite(Ca,Mn)2Zr2Nb2TiFeO14Mon. 2/m : B2/b
4.DH.30Nöggerathite-(Ce)(Ce,Ca)2Zr2(Nb,Ti)(Ti,Nb)2Fe2+O14Orth. mmm(2/m2/m2/m) : Cmca
4.DH.35LiandratiteU(Nb,Ta)2O8Trig. 3m(32/m) : P31m
4.DH.35PetscheckiteUFe(Nb,Ta)2O8Hex.
4.DH.40IngersoniteCa3Mn2+Sb5+4O14Trig. 32 : P3121
4.DH.45PittongiteNa0.22(W,Fe3+)(O,OH)3 · 0.44H2OHex. 6m2 : P6m2
4.DH.50TazzoliiteBa4-xNaxTi2Nb3SiO17[PO2(OH)2]x(OH)(1-2x) Orth. mmm(2/m2/m2/m) : Fmmm

Other InformationHide

Notes:
Dissolves in H3PO4; does not dissolve in HCl and HNO3
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HydroxycalciopyrochloreHide

References for HydroxycalciopyrochloreHide

Localities for HydroxycalciopyrochloreHide

Showing 27 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Angola
 
  • Huíla Province
    • Quilengues
Amores-Casals et al. (2019)
Argentina
 
  • La Rioja Province
    • Sanagasta department
Lira et al. (2023)
Canada
 
  • Newfoundland and Labrador
    • Labrador
      • Seal Lake alkaline complex (Letitia Lake)
Pavel M. Kartashov analytical data (2013)
  • Ontario
    • Haliburton County
      • Minden Hills Township
        • Lutterworth Township
Hogarth (1961)
    • Hastings County
      • Hastings Highlands Municipality
        • Monteagle Township
Ontario Geological Survey Mineral ... +2 other references
  • Québec
    • Outaouais
Hogarth (1961)
China (TL)
 
  • Sichuan
    • Liangshan Yi
      • Mianning County
Williams et al. (2011) +1 other reference
  • Xinjiang
    • Akesu Prefecture
      • Baicheng Co.
Jingwu Yin et al. (2013)
Czech Republic
 
  • Moravian-Silesian Region
    • Nový Jičín District
      • Nový Jičín
        • Bludovice
Matýsek et al. (2025)
  • South Bohemian Region
    • Český Krumlov District
      • Černá v Pošumaví
        • Bližná
Drábek +1 other reference
Finland
 
  • Southwest Finland
    • Laitila
Pavel M. Kartashov analytical data 2019
Germany
 
  • Hesse
    • Darmstadt
      • Darmstadt-Dieburg
        • Fischbachtal
          • Lichtenberg
Belendorff (2021)
  • Rhineland-Palatinate
    • Mayen-Koblenz
      • Mendig
        • Mendig
Zubkova. N.V. et al. (2015)
Greenland
 
  • Kujalleq
    • Igaliku
      • Narsaarsuk Plateau
Bonazzi (2006) +1 other reference
Italy
 
  • Lombardy
    • Sondrio Province
      • Chiesa in Valmalenco
Marchesini et al. (2025)
Norway
 
  • Telemark
    • Bamble
      • Bjordammen
Larsen (2025)
Romania
 
  • Hunedoara County
HÎRTOPANU et al. (2014)
Russia
 
  • Chelyabinsk Oblast
    • Ilmen Mountains
Makagonov et al. (2017)
Chukanov (2014)
Pavel M. Kartashov analytical data of ...
  • Murmansk Oblast
    • Kovdorsky District
Ivanyuk et al. (2018)
    • Northern Karelia
      • Vuoriyarvi alkaline-ultrabasic massif
Kozlov +6 other references
    • Voron'i Tundry
Zozulya et al. (2024)
Slovakia
 
  • Košice Region
    • Rožňava District
      • Dobšiná
        • Dobšiná mining district
Uher P. et al. (2018)
Tajikistan
 
  • Districts of Republican Subordination
Ефимов А.Ф. et al. (1980)
USA
 
  • New Jersey
    • Sussex County
      • Franklin
        • Franklin Mine
Chris O'neill
      • Vernon Township
        • McAfee
van Rossen (2026)
 
and/or  
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