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Tadzhikite-(Ce)

A valid IMA mineral species
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About Tadzhikite-(Ce)Hide

08996720017271927046245.jpg
Flag of Tajikistan
Formula:
Ca4Ce3+2Ti◻2(B4Si4O22)(OH)2
Colour:
Brown, grey
Lustre:
Vitreous
Hardness:
6
Specific Gravity:
3.73 - 3.86
Crystal System:
Monoclinic
Name:
Named by A.F. Efimov, V.D. Dusmatov, V.Y. Alkhazov, Z.G. Pudovkina, and M.Y. Kazakova in 1970 for the country of the type locality. The name is from an alternate spelling for the Republic of Tajikistan, and the suffix indicates the dominant REE.
Specimens of tadzhikite-(Ce) from the type locality have earlier erroneously been labelled as tadzhikite-(Y). The mineral, which originally was named as tadzhikite (without the suffix), was described by Efimov et al. (1970) as two varieties: "tadzhikikite-I" and "tadzhikite-II". The "tadzhikite-I" is enriched in Y relative to "tadzhikite-II", and was thus informally named as tadzhikite-(Y) by Pekov (1988). However, structural analysis has established that the mineral is in fact Ce-dominant (Hawthorne et al., 1988); Oberti et al., 2002).


Unique IdentifiersHide

Mindat ID:
3866
Long-form identifier:
mindat:1:1:3866:5

IMA Classification of Tadzhikite-(Ce)Hide

Approved
IMA status notes:
Renamed by the IMA
IMA Formula:
Ca4Ce3+2Ti4+◻(B4Si4O22)(OH)2
Approval year:
1969
Approval history:
Approved by IMA in 1969 as tadzhikite.
Tadzhikite was renamed as tadzhikite-(Ce) by IMA in 2000 (special procedure 00-F)

Classification of Tadzhikite-(Ce)Hide

9.DK.20

9 : SILICATES (Germanates)
D : Inosilicates
K : Inosilicates with 5-periodic single chains
17.5.19

17 : Silicates Containing other Anions
5 : Borosilicates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
Tad-CeIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Tadzhikite-(Ce)Hide

Vitreous
Transparency:
Translucent, Opaque
Colour:
Brown, grey
Streak:
White
Hardness:
Parting:
Parting on {010}
Density:
3.73 - 3.86 g/cm3 (Measured)    3.77 g/cm3 (Calculated)

Optical Data of Tadzhikite-(Ce)Hide

Type:
Biaxial (+/-)
RI values:
nα = 1.750 - 1.761 nβ = 1.767 nγ = 1.763 - 1.772
2V:
Measured: 80° to 92°
Max. Birefringence:
δ = 0.011 - 0.013
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
distinct to strong

Chemistry of Tadzhikite-(Ce)Hide

Mindat Formula:
Ca4Ce3+2Ti◻2(B4Si4O22)(OH)2
Element Weights:
Element% weight
O37.280 %
Ce27.207 %
Ca15.564 %
Si10.907 %
Ti4.647 %
B4.199 %
H0.196 %

Calculated from ideal end-member formula.
O
Ce
Ca
Si
Ti
B
H

Crystallography of Tadzhikite-(Ce)Hide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P2/b
Setting:
P2/a
Cell Parameters:
a = 18.946(4) Å, b = 4.714(4) Å, c = 10.302(2) Å
β = 11.58(2)°
Ratio:
a:b:c = 4.019 : 1 : 2.185
Unit Cell V:
184.69 ų (Calculated from Unit Cell)
Z:
2

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005547Tadzhikite-(Ce)Hawthorne F C, Cooper M A, Taylor M C (1998) Refinement of the crystal structure of tadzhikite The Canadian Mineralogist 36 817-8221998Dara-i-Pioz, Tadzhikistan0293
0015611Tadzhikite-(Ce)Chernitsova N M, Pudovkina Z V, Pyatenko Y A (1982) About the crystal structure of tadzhikite {(Ca,Tr)4(Y,Tr)2(Ti,Fe,Al)(O,OH)2 [Si4B4O22]} Soviet Physics Doklady 27 367-36819820293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.65 Å(100)
1.913 Å(55)
4.96 Å(30)
2.94 Å(30)
1.665 Å(30)
2.86 Å(25)
2.19 Å(25)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of Tadzhikite-(Ce)Hide

Synonyms of Tadzhikite-(Ce)Hide

Other Language Names for Tadzhikite-(Ce)Hide

Simplified Chinese:塔吉克石
Traditional Chinese:塔吉克石

Relationship of Tadzhikite-(Ce) to other SpeciesHide

Other Members of Hellandite Group:
CiprianiiteCa4[(Th,U),Ca]Σ2Al(Be0.51.5)Σ2[B4Si4O22](OH)2Mon. 2/m : P2/b
Ferri-hellandite-(Ce)(Ca3Ce)Ce2Fe3+2B4Si4O22(OH)2Mon. 2/m : P2/b
Ferri-mottanaite-(Ce)Ca4Ce2Fe3+(Be1.50.5)[Si4B4O22]O2Mon. 2/m : P2/b
Hellandite-(Ce)(Ca,REE)4Ce2Al◻2(B4Si4O22) (OH)2Mon. 2/m
Hellandite-(Y)(Ca,REE)4Y2Al◻2(B4Si4O22) (OH)2Mon. 2/m : P2/b
Mottanaite-(Ce)Ca4(Ce,REE)Σ2Al(Be1.50.5)Σ2[B4Si4O22]O2Mon. 2/m

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Tadzhikite-(Ce) associated with Zirsilite-(Ce)Na11-12(Ce,Na)3Ca6Mn3Zr3Nb(Si19O55)(Si3O9)2(CO3)(OH)3 · H2O
1 photo of Tadzhikite-(Ce) associated with MicroclineK(AlSi3O8)
1 photo of Tadzhikite-(Ce) associated with BiotiteK(Fe2+/Mg)2(Al/Fe3+/Mg/Ti)([Si/Al/Fe]2Si2O10)(OH/F)2
1 photo of Tadzhikite-(Ce) associated with Hornblende Root Name Group◻Ca2(C2+4C3+)(AlSi7O22)W2
1 photo of Tadzhikite-(Ce) associated with FerrokentbrooksiteNa15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3Cl2
1 photo of Tadzhikite-(Ce) associated with FluoriteCaF2
1 photo of Tadzhikite-(Ce) associated with SanidineK(AlSi3O8)
1 photo of Tadzhikite-(Ce) associated with Rinkite-(Y)Na2Ca4YTi(Si2O7)2OF3
1 photo of Tadzhikite-(Ce) associated with QuartzSiO2
1 photo of Tadzhikite-(Ce) associated with TitaniteCaTiO(SiO4)

Related Minerals - Strunz-mindat GroupingHide

9.DK.FerrorhodoniteCaMn3Fe[Si5O15]Tric. 1 : P1
9.DK.VittinkiiteMnMn3Mn[Si5O15]Tric. 1 : P1
9.DK.Ferri-hellandite-(Ce)(Ca3Ce)Ce2Fe3+2B4Si4O22(OH)2Mon. 2/m : P2/b
9.DK.ShijiangshanitePb3CaAl(Si5O14)(OH)3 · 3H2OTrig. 3m : R3c
9.DK.05NambuliteLiMn2+4Si5O14(OH)Tric.
9.DK.05MarsturiteNaCaMn3Si5O14(OH)Tric. 1 : P1
9.DK.05Natronambulite(Na,Li)(Mn,Ca)4Si5O14OHTric.
9.DK.05RhodoniteCaMn3Mn[Si5O15]Tric. 1
9.DK.05Scandiobabingtonite(Ca,Na)2(Fe2+,Mn)(Sc,Fe3+)Si5O14(OH)Tric.
9.DK.05LithiomarsturiteLiCaMn3Si5O14(OH)Tric. 1 : P1
9.DK.05ManganbabingtoniteCa2Mn2+Fe3+Si5O14(OH)Tric. 1 : P1
9.DK.05Fowlerite(Mn2+,Zn,Ca)SiO3
9.DK.05BabingtoniteCa2Fe2+Fe3+Si5O14(OH)Tric. 1 : P1
9.DK.10SantaclaraiteCaMn4[Si5O14OH](OH) · H2OTric. 1 : P1
9.DK.15SaneroiteNaMn2+5[Si5O14(OH)](VO3)(OH)Tric. 1 : P1
9.DK.20Ferri-mottanaite-(Ce)Ca4Ce2Fe3+(Be1.50.5)[Si4B4O22]O2Mon. 2/m : P2/b
9.DK.20'Hellandite-(Yb)'(Ca,Y)4(Yb,Y)2(Al,Fe3+,Ti4+)(Be,Li)2[B4Si4O22](O,F,OH)2
9.DK.20Mottanaite-(Ce)Ca4(Ce,REE)Σ2Al(Be1.50.5)Σ2[B4Si4O22]O2Mon. 2/m
9.DK.20CiprianiiteCa4[(Th,U),Ca]Σ2Al(Be0.51.5)Σ2[B4Si4O22](OH)2Mon. 2/m : P2/b
9.DK.20Hellandite-(Y)(Ca,REE)4Y2Al◻2(B4Si4O22) (OH)2Mon. 2/m : P2/b
9.DK.20Hellandite-(Ce)(Ca,REE)4Ce2Al◻2(B4Si4O22) (OH)2Mon. 2/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Tadzhikite-(Ce)Hide

References for Tadzhikite-(Ce)Hide

Reference List:

Localities for Tadzhikite-(Ce)Hide

Showing 19 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
A. McDonald & L. Horvath pers. comm. +2 other references
Italy
 
  • Lazio
    • Viterbo Province
      • Vetralla
BERNABE' E. (1987)
      • Viterbo
Thorne (n.d.)
Kyrgyzstan
 
  • Batken Region
    • Batken District
Pautov et al. (2013)
Norway
 
  • Telemark
    • Porsgrunn
      • Auenlandet
        • Sagåsen
Engvoldsen et al. (1991)
Larsen et al. (2005)
      • Bjørkøya
Larsen et al. (2010)
  • Vestfold
    • Larvik Commune
      • Barkevik area
+1 other reference
Larsen et al. (2010)
Andersen et al. (1996)
- (n.d.)
Andersen et al. (1996)
Engvoldsen et al. (1991)
      • Tvedalen
Peter Andresen collection
      • Vesle Arøya
Engvoldsen et al. (1991)
Sweden
 
  • Jönköping County
    • Jönköping
      • Gränna
Christian Brand coll.
Tajikistan (TL)
 
  • Districts of Republican Subordination
Efimov et al. (1970) +2 other references
 
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