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Hellandite-(Y)

A valid IMA mineral species
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About Hellandite-(Y)Hide

05161810017271923795449.jpg
Amund T. Helland
Formula:
(Ca,REE)4Y2Al◻2(B4Si4O22) (OH)2
In the IMA approved report on hellandites [Am. Mineral.,87 (2002), 745–752], the occupancy at the T sites was given as (Be,Li)2–x, however the value of x was not specified. Actually, it is always x > 1, therefore the T site is vacant in the ideal formula of hellandite-(Y).
Colour:
Nut-brown, brownish red, black, gray, green, yellow, cream, pinkish
Lustre:
Vitreous, Dull
Hardness:
4½ - 6½
Specific Gravity:
2.95 - 3.63
Crystal System:
Monoclinic
Name:
Named in 1903 by Waldemar Christofer Brøgger in honour of Amund Theodor Helland (11 October 1846, Bergen, Norway - 15 November 1918, Kristiania (now Oslo), Norway), professor of geology and geography at the Royal Frederick University (University of Oslo). It was renamed in 1987, but the renaming was not approved until 2002 (IMA Case 00-F). The suffix/modifier indicates the dominant essential REE.
Y analogue of hellandite-(Ce) and hellandite-(Yb).


Unique IdentifiersHide

Mindat ID:
1852
Long-form identifier:
mindat:1:1:1852:0

Similar NamesHide

Hellandite
Hellandite-(Ce)A valid IMA mineral species(Ca,REE)4Ce2Al◻2(B4Si4O22) (OH)2
Hellandite-(Yb)(Ca,Y)4(Yb,Y)2(Al,Fe3+,Ti4+)(Be,Li)2[B4Si4O22](O,F,OH)2
HeulanditA synonym of Heulandite Subgroup
HollanditeA valid IMA mineral species - grandfatheredBa(Mn64+Mn23+)O16

IMA Classification of Hellandite-(Y)Hide

Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
(Ca,REE)4Y2Al◻2(B4Si4O22)(OH)2
Approval year:
2000
Approval history:
Redefined as hellandite-(Y) by IMA in 2000 (special procedure IMA code 00-F).
Revision of formula: IMA 2017 (CNMNC Newsletter No. 37).

Classification of Hellandite-(Y)Hide

9.DK.20

9 : SILICATES (Germanates)
D : Inosilicates
K : Inosilicates with 5-periodic single chains
54.2.2.1

54 : NESOSILICATES Borosilicates and Some Beryllosilicates
2 : Borosilicates and Some Beryllosilicates with B in [4] coordination
17.5.51

17 : Silicates Containing other Anions
5 : Borosilicates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
Hld-YIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Hellandite-(Y)Hide

Vitreous, Dull
Transparency:
Translucent
Colour:
Nut-brown, brownish red, black, gray, green, yellow, cream, pinkish
Hardness:
4½ - 6½ on Mohs scale
Cleavage:
Poor/Indistinct
Poor on {100}, {010}.
Density:
2.95 - 3.63 g/cm3 (Measured)    3.5(5) g/cm3 (Calculated)

Optical Data of Hellandite-(Y)Hide

Type:
Biaxial (+)
RI values:
nα = 1.64 nβ = 1.65 nγ = 1.66
2V:
Measured: 48° to 86°, Calculated: 88°
Max. Birefringence:
δ = 0.020
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
relatively weak

Chemistry of Hellandite-(Y)Hide

Mindat Formula:
(Ca,REE)4Y2Al◻2(B4Si4O22) (OH)2

In the IMA approved report on hellandites [Am. Mineral.,87 (2002), 745–752], the occupancy at the T sites was given as (Be,Li)2–x, however the value of x was not specified. Actually, it is always x > 1, therefore the T site is vacant in the ideal formula of hellandite-(Y).
Element Weights:
Element% weight
O42.350 %
Y19.611 %
Ca17.681 %
Si12.390 %
B4.769 %
Al2.976 %
H0.222 %

Calculated from ideal end-member formula.

Chemical AnalysisHide

Oxide wt%:
 1
CaO7.65 %
MnO7.71 %
Y2O331.60 %
La2O30.04 %
Ce2O30.29 %
Nd2O30.37 %
Sm2O30.25 %
Gd2O30.19 %
Dy2O30.90 %
Er2O30.93 %
Yb2O32.99 %
Al2O34.85 %
Fe2O30.62 %
SiO224.35 %
B2O315.32 %
ThO20.09 %
H20 (calc)1.83 %
Total:99.98 %
Empirical formulas:
Sample IDEmpirical Formula
1Ca1.34Mn1.07Y2.75Ce0.02Nd0.02Sm0.01Gd0.01Dy0.05Er0.05Yb0.15Al0.94Fe0.08Si3.99B4.33O22.00(OH)2.00

Crystallography of Hellandite-(Y)Hide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P2/b
Setting:
P2/a
Cell Parameters:
a = 18.99(1) Å, b = 7.715(5) Å, c = 10.30(1) Å
β = 111.4(1)°
Ratio:
a:b:c = 2.461 : 1 : 1.335
Unit Cell V:
1,404.99 ų (Calculated from Unit Cell)
Z:
2
Twinning:
Contact and polysynthetic, parallel to {001} and {100}.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0020232Hellandite-(Y)Miyawaki R, Momma K, Yokoyama K, Shigeoka M, Matsubara S, Ito M, Nakai I, Kristiansen R (2015) Mn-bearing hellandite-(Y) from the Heftetjern pegmatite, Tordal, Norway The Canadian Mineralogist 53 345-3562015Heftetjern, Tordal, Telemark, Norway0293
0000557Hellandite-(Y)Mellini M, Merlino S (1977) Hellandite: a new type of silicoborate chain American Mineralogist 62 89-9919770293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.812 Å(100)
4.69 Å(80)
2.635 Å(80)
2.603 Å(80)
3.436 Å(70)
3.198 Å(70)
3.068 Å(70)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites

Type Occurrence of Hellandite-(Y)Hide

Place of Conservation of Type Material:
Mineralogical-Geological Museum, University of Oslo, Oslo, Norway, numbers 21846, various (cotype).
Muséum Nationale d’Histoire Naturelle, Paris, France, number 109732 (type).
Associated Minerals at Type Locality:

Synonyms of Hellandite-(Y)Hide

Other Language Names for Hellandite-(Y)Hide

Simplified Chinese:硼硅钇钙石
Traditional Chinese:硼矽釔鈣石

Varieties of Hellandite-(Y)Hide

Manganese-bearing Hellandite-(Y)A hellandite-(Y) with greater than 1 apfu Mn. Described from the Sc-rich granite pegmatite at Heftetjern, Tørdal, Telemark, Norway where it occurs as tiny pinkish yellow granular crystals (Miyawaki et al., 2015). It varies from hellandite-(Y) in that Mn...

Relationship of Hellandite-(Y) to other SpeciesHide

Other Members of Hellandite Group:
CiprianiiteCa4[(Th,U),Ca]Σ2Al(Be0.51.5)Σ2[B4Si4O22](OH)2Mon. 2/m : P2/b
Ferri-hellandite-(Ce)(Ca3Ce)Ce2Fe3+2B4Si4O22(OH)2Mon. 2/m : P2/b
Ferri-mottanaite-(Ce)Ca4Ce2Fe3+(Be1.50.5)[Si4B4O22]O2Mon. 2/m : P2/b
Hellandite-(Ce)(Ca,REE)4Ce2Al◻2(B4Si4O22) (OH)2Mon. 2/m
Mottanaite-(Ce)Ca4(Ce,REE)Σ2Al(Be1.50.5)Σ2[B4Si4O22]O2Mon. 2/m
Tadzhikite-(Ce)Ca4Ce3+2Ti◻2(B4Si4O22)(OH)2Mon. 2/m : P2/b
Structurally related to group(s):
Hellandite GroupX4Y2ZT2[B4Si4O22]W2

Common AssociatesHide

Associations Based on Photo Data:
12 photos of Hellandite-(Y) associated with ChamositeFe2+5Al(AlSi3O10)(OH)8
8 photos of Hellandite-(Y) associated with QuartzSiO2
8 photos of Hellandite-(Y) associated with AlbiteNa(AlSi3O8)
6 photos of Hellandite-(Y) associated with SchorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)
3 photos of Hellandite-(Y) associated with Gadolinite-(Y)Y2Fe2+Be2Si2O10
3 photos of Hellandite-(Y) associated with Kainosite-(Y)Ca2Y2(SiO3)4(CO3) · H2O
3 photos of Hellandite-(Y) associated with Fergusonite-(Y)YNbO4
2 photos of Hellandite-(Y) associated with Lokkaite-(Y)Ca(Y,Gd,Nd,Dy)4(CO3)7 · 9H2O
2 photos of Hellandite-(Y) associated with Tengerite-(Y)Y2(CO3)3 · 2-3H2O
2 photos of Hellandite-(Y) associated with Hingganite-(Y)(Y,REE,Ca)2(◻,Fe2+)Be2[SiO4]2(OH)2

Related Minerals - Strunz-mindat GroupingHide

9.DK.FerrorhodoniteCaMn3Fe[Si5O15]Tric. 1 : P1
9.DK.VittinkiiteMnMn3Mn[Si5O15]Tric. 1 : P1
9.DK.Ferri-hellandite-(Ce)(Ca3Ce)Ce2Fe3+2B4Si4O22(OH)2Mon. 2/m : P2/b
9.DK.ShijiangshanitePb3CaAl(Si5O14)(OH)3 · 3H2OTrig. 3m : R3c
9.DK.05NambuliteLiMn2+4Si5O14(OH)Tric.
9.DK.05MarsturiteNaCaMn3Si5O14(OH)Tric. 1 : P1
9.DK.05Natronambulite(Na,Li)(Mn,Ca)4Si5O14OHTric.
9.DK.05RhodoniteCaMn3Mn[Si5O15]Tric. 1
9.DK.05Scandiobabingtonite(Ca,Na)2(Fe2+,Mn)(Sc,Fe3+)Si5O14(OH)Tric.
9.DK.05LithiomarsturiteLiCaMn3Si5O14(OH)Tric. 1 : P1
9.DK.05ManganbabingtoniteCa2Mn2+Fe3+Si5O14(OH)Tric. 1 : P1
9.DK.05Fowlerite(Mn2+,Zn,Ca)SiO3
9.DK.05BabingtoniteCa2Fe2+Fe3+Si5O14(OH)Tric. 1 : P1
9.DK.10SantaclaraiteCaMn4[Si5O14OH](OH) · H2OTric. 1 : P1
9.DK.15SaneroiteNaMn2+5[Si5O14(OH)](VO3)(OH)Tric. 1 : P1
9.DK.20Ferri-mottanaite-(Ce)Ca4Ce2Fe3+(Be1.50.5)[Si4B4O22]O2Mon. 2/m : P2/b
9.DK.20Tadzhikite-(Ce)Ca4Ce3+2Ti◻2(B4Si4O22)(OH)2Mon. 2/m : P2/b
9.DK.20'Hellandite-(Yb)'(Ca,Y)4(Yb,Y)2(Al,Fe3+,Ti4+)(Be,Li)2[B4Si4O22](O,F,OH)2
9.DK.20Mottanaite-(Ce)Ca4(Ce,REE)Σ2Al(Be1.50.5)Σ2[B4Si4O22]O2Mon. 2/m
9.DK.20CiprianiiteCa4[(Th,U),Ca]Σ2Al(Be0.51.5)Σ2[B4Si4O22](OH)2Mon. 2/m : P2/b
9.DK.20Hellandite-(Ce)(Ca,REE)4Ce2Al◻2(B4Si4O22) (OH)2Mon. 2/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Hellandite-(Y)Hide

References for Hellandite-(Y)Hide

Reference List:

Localities for Hellandite-(Y)Hide

Showing 24 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Ontario
    • Nipissing District
      • Murchison Township
Reiner Mielke 2013
  • Québec
    • Nord-du-Québec
      • Jamésie
        • Matagami
PAN et al. (1994) +1 other reference
    • Outaouais
      • Les Collines-de-l'Outaouais RCM
        • Val-des-Monts
          • Saint-Pierre-de-Wakefield
            • Lake Saint-Pierre
Hogarth et al. (1972) +1 other reference
China
 
  • Hebei
    • Baoding
      • Quyang County
Dizhi Xuebao +2 other references
France
 
  • Occitanie
    • Ariège
      • Foix
        • Luzenac
Gatel (1990)
    • Hautes-Pyrénées
      • Bagnères-de-Bigorre
        • Vielle-Aure
Ragu et al. (2025)
Italy
 
  • Piedmont
    • Cuneo Province
      • Bagnolo Piemonte
Flavio G. Taricco collection - Analized by SIUK AMI (Associazione Micromineralogica Italiana)
Flavio G. Taricco collection (material analized by AMI SIUK)
    • Metropolitan City of Turin
Finello et al. (2007)
    • Verbano-Cusio-Ossola Province
      • Baveno
        • Oltrefiume
          • Mount Camoscio
Sergio Varvello collection
  • Sardinia
    • Sassari Province
      • La Maddalena
        • La Maddalena Island
Gamboni (2003)
Japan
 
  • Gifu Prefecture
    • Nakatsugawa City
      • Hirukawa
Miyawaki (1987) +2 other references
  • Miyazaki Prefecture
    • Nobeoka City
      • Ohkueyama (Okueyama)
Okada (2011)
Norway
 
  • Agder
    • Iveland
Müller et al. (2012)
  • Nordland
    • Hamarøy
      • Drag
Husdal (2023)
  • Telemark
    • Bamble
      • Skogstad
Larsen et al. (2016)
    • Drangedal
      • Tørdal
[var: Manganese-bearing Hellandite-(Y)] Raade et al. (2000) +2 other references
    • Kragerø
      • Lindvikskollen-Kalstadgangen pegmatite
Brøgger (1903) +3 other references
Poland
 
  • Lower Silesian Voivodeship
    • Dzierżoniów County
      • Piława Górna
        • DSS Piława Górna Quarry
Pieczka et al. (2015) +1 other reference
Slovakia
 
  • Banská Bystrica Region
    • Brezno District
      • Pohronská Polhora
Ondrejka et al. (2022)
Spain
 
  • Galicia
    • Pontevedra
      • Porriño
Calvo Rebollar et al. (2022)
Tajikistan
 
  • Gorno-Badakhshan
Pavel M. Kartashov (n.d.)
USA
 
  • New Jersey
    • Sussex County
      • Franklin
John Cianciulli +1 other reference
 
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