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Chlorite Group

A group of related mineral species
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About Chlorite GroupHide

Colour:
Green to black
Lustre:
Pearly, Dull
Hardness:
2 - 3
Specific Gravity:
2.6 - 3.3
Crystal System:
Monoclinic
Name:
From the Greek chloros (χλωρός), meaning "green", in reference to its color.
A group of mostly monoclinic (also triclinic or orthorhombic) micaceous phyllosilicate minerals with a structure consisting of T-O-T layers with two layers having their silicate tetrahedral apices pointing towards each other, separated by an interlayer that may be simple octahedrally coordinated cations or which may be a brucite-*like* layer of two sheets of closely packed OH groups with the interstices between sheets providing the octahedral coordination site; the T-O-T layers and interlayer are bonded by electrostatic and hydrogen bonding forces; as the "a" and "b" directions of the T-O-T layer may be oriented to the interlayer "a" and "b" directions in twelve different stacking sequences, resulting in twelve different polytype possibilities (not all of which have been found in Nature yet for each species).

The general formula may be stated A5-7T4Z18, where A = Al, Fe2+, Fe3+, Li, Mg, Mn, Cr, Ni, Zn or rarely Na, Ca while T = mostly Si, plus Al, Fe3+, Zn or B, and Z = O and/or OH.

The most common species in the chlorite group are clinochlore and chamosite.

The Árkai index (ÁI; Árkai, 1991) is an index for the estimation of a very low metamorphic grade in rocks, based on the evolution of chlorite. It is often used to complement the Kübler index (KI), earlier called the 'illite crystallinity' for the characterisation of pelites, and can also be applied in metabasites.


Unique IdentifiersHide

Mindat ID:
1016
Long-form identifier:
mindat:1:1:1016:6

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
ChlIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
ChlKretz (1983)Kretz, R. (1983) Symbols of rock-forming minerals. American Mineralogist, 68, 277–279.
ChlSiivolam & Schmid (2007)Siivolam, J. and Schmid, R. (2007) Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: List of mineral abbreviations. Web-version 01.02.07. IUGS Commission on the Systematics in Petrology. download
ChlWhitney & Evans (2010)Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371
ChlThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download
ChlWarr (2020)Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Pronunciation of Chlorite GroupHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of Chlorite GroupHide

Pearly, Dull
Transparency:
Translucent, Opaque
Colour:
Green to black
Streak:
Colorless to pale green
Hardness:
2 - 3 on Mohs scale
Cleavage:
Perfect
Density:
2.6 - 3.3 g/cm3 (Measured)    

Optical Data of Chlorite GroupHide

Type:
Biaxial
Pleochroism:
Visible

Age distributionHide

Recorded ages:
Paleoproterozoic to Quaternary : 2211 Ma to 0 Ma - based on 18 recorded ages.
Sample ages:
Sample IDRecorded ageGeologic TimeDating method
12.588 Ma to present dayPleistoceneFormed in peat.
215.7 ± 0.2 MaMioceneK-Ar
3853 to 837 MaTonianAr-Ar
41034 to 1024 MaStenianAr-Ar
51713 to 1699 MaStatherianAr-Ar
61815 to 1801 MaOrosirianAr-Ar
72068 to 2050 MaRhyacianAr-Ar
82211 to 2193 MaRhyacianAr-Ar
Sample references:
IDLocalityReferenceNotes
1Grieves Siding prospect, Zeehan mineral field, Zeehan mining district, West Coast municipality, Tasmania, Australia
2Tonopah Mining District, San Antonio Mountains, Nye County, Nevada, USA
3Silver Miller Mine, Coleman Township, Cobalt area, Cobalt-Gowganda region, Timiskaming District, Ontario, Canada
4  "  "
5Beaver Mine, Coleman Township, Cobalt area, Cobalt-Gowganda region, Timiskaming District, Ontario, Canada
6  "  "
7  "  "
8  "  "

Chemical AnalysisHide

Oxide wt%:
 123456789
SiO227.8 %26.22 %34.00 %34.81 %34.08 %34.15 %35.49 %34.92 %34.7 %
Al2O311.6 %11.14 %45.06 %45.90 %45.30 %46.35 %44.36 %46.29 %48.4 %
Fe2O319.1 %0.45 %0.72 %0.19 %0.02 %0.12 %0.07 %0.1 %
FeO25.5 %44.83 %0.24 %
MnO1.7 %1.74 %0.13 %
MgO1.4 %1.45 %1.02 %1.32 %0.24 %0.05 %
H2O12.9 %13.49 %14.95 %14.1 %
CaO0.98 %0.04 %0.57 %0.16 %0.26 %0.30 %0.12 %
Na2O0.09 %0.19 %0.52 %0.07 %0.10 %1.12 %0.14 %1.01 %
K2O0.08 %0.14 %0.14 %
Li2O4.02 %3.59 %3.09 %3.18 %2.74 %2.67 %2.45 %
F0.46 %0.13 %0.35 %
H2O+14.87 %14.22 %14.06 %13.84 %14.12 %
TiO20.02 %0.02 %
H2O-0.38 %0.42 %0.55 %0.28 %
B2O30.38 %
BeO1.06 %
Total:100 %100.02 %99.31 %100.54 %98.94 %100.25 %100.18 %99.16 %100.93 %
Sample references:
IDLocalityReferenceNotes
1Tuften, Tvedalen, Larvik Commune, Vestfold, NorwayXRF analysis by A. O. Larsen. Fe2+ by titration. H2O by difference.
2  "  "EMP analysis by M. Erambert. H2O by difference.
3Mount Rubellite Quarries, Mount Rubellite, Hebron, Oxford County, Maine, USAWet chemical analysis from Penfield 1894 from a sample found in a pegmatite cavity. The results from the analysis corresponds well with modern analyses.
4Buckfield, Oxford County, Maine, USAWet chemical analysis by Landes 1925 on cookeite from pegmatite vug, associated with quartz, minor apatite and herderite. The results from the analysis corresponds well with modern analyses.
5Dobrá Voda, Žďár nad Sázavou District, Vysočina Region, Czech RepublicWet chemical analyses, with contamination less than 1%. Sample from cavity lining in pegmatite associated with quartz, apatite, tourmaline and cassiterite
6Muiâne pegmatite, Muiane-Naipa group, Gilé District, Zambezia Province, MozambiqueWet chemical analysis from Sahama et al., 1968. Sample from cavity lining in pegmatite with quartz. No admixtures in the analysed material.
7Lipovka Mine, Lipovsk pegmatite field, Rezhevsky District, Sverdlovsk Oblast, RussiaWet chemical analysis from Ginzburg (1953). Sample form pegmatite.
8Manono-Kitotolo mine, Tanganyika, DR CongoWet chemical analysis from Herman et al. (1961) from pegmatite.
9North Little Rock, Pulaski County, Arkansas, USAAveraged values from a series of wet chemical analyses from Miser and Milton (1964). Samples from a pegmatite.

Crystallography of Chlorite GroupHide

Crystal System:
Monoclinic

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0007298ClinochloreZanazzi P F, Comodi P, Nazzareni S, Andreozzi G B (2009) Thermal behaviour of chlorite: an in situ single-crystal and powder diffraction study European Journal of Mineralogy 21 581-5892009Val Malenco, Italy0298
0004250ClinochloreZanazzi P F, Montagnoli M, Nazzareni S, Comodi P (2006) Structural effects of pressure on chlorite: A single-crystal study American Mineralogist 91 1871-18782006Alpe Reguzzolo, Val Malenco, Italy0.0001293
0012235ChamositeWalker J R, Bish D L (1992) Application of Rietveld refinement techniques to a disordered IIb Mg-chamosite Clays and Clay Minerals 40 319-3221992Lebanon, New Hampshire, USA0293
0010543ClinochloreMcMurchy R C (1934) The crystal structure of the chlorite minerals Zeitschrift fur Kristallographie 88 420-4321934Miles City, Montana, USA0293
0007299ClinochloreZanazzi P F, Comodi P, Nazzareni S, Andreozzi G B (2009) Thermal behaviour of chlorite: an in situ single-crystal and powder diffraction study European Journal of Mineralogy 21 581-5892009Val Malenco, Italy0574
0007300ClinochloreZanazzi P F, Comodi P, Nazzareni S, Andreozzi G B (2009) Thermal behaviour of chlorite: an in situ single-crystal and powder diffraction study European Journal of Mineralogy 21 581-5892009Val Malenco, Italy0672
0007301ClinochloreZanazzi P F, Comodi P, Nazzareni S, Andreozzi G B (2009) Thermal behaviour of chlorite: an in situ single-crystal and powder diffraction study European Journal of Mineralogy 21 581-5892009Val Malenco, Italy0775
0004251ClinochloreZanazzi P F, Montagnoli M, Nazzareni S, Comodi P (2006) Structural effects of pressure on chlorite: A single-crystal study American Mineralogist 91 1871-18782006Alpe Reguzzolo, Val Malenco, Italy1.83293
0004252ClinochloreZanazzi P F, Montagnoli M, Nazzareni S, Comodi P (2006) Structural effects of pressure on chlorite: A single-crystal study American Mineralogist 91 1871-18782006Alpe Reguzzolo, Val Malenco, Italy3.14293
0004253ClinochloreZanazzi P F, Montagnoli M, Nazzareni S, Comodi P (2006) Structural effects of pressure on chlorite: A single-crystal study American Mineralogist 91 1871-18782006Alpe Reguzzolo, Val Malenco, Italy4.25293
0004254ClinochloreZanazzi P F, Montagnoli M, Nazzareni S, Comodi P (2006) Structural effects of pressure on chlorite: A single-crystal study American Mineralogist 91 1871-18782006Alpe Reguzzolo, Val Malenco, Italy4.85293
0003597GlagoleviteKrivovichev S V, Armbruster T, Organova N I, Burns P C, Seredkin M V, Chukanov N V (2004) Incorporation of sodium into the chlorite structure: the crystal structure of glagolevite, Na(Mg,Al)6[Si3AlO10](OH,O)8 American Mineralogist 89 1138-114120040293
0002739ClinochloreWelch M D, Marshall W G (2001) High-pressure behaviour of clinochlore American Mineralogist 86 1380-138620010293
0002314ClinochloreGuggenheim S, Zhan W (1999) Crystal structures of two partially dehydrated chlorites: The "modified" chlorite structure American Mineralogist 84 1415-142119990293
0002313ClinochloreGuggenheim S, Zhan W (1999) Crystal structures of two partially dehydrated chlorites: The "modified" chlorite structure American Mineralogist 84 1415-142119990293
0001949CookeiteZheng H, Bailey S W (1997) Refinement of the cookeite "r" structure American Mineralogist 82 1007-101319970293
0001192FranklinfurnaceitePeacor D R, Rouse R C, Bailey S W (1988) Crystal structure of franklinfurnaceite: A tri-dioctahedral zincosilicate intermediate between chlorite and mica American Mineralogist 73 876-88719880293
0000771ClinochlorePhillips T L, Loveless J K, Bailey S W (1980) Cr3+ coordination in chlorites: a structural study of ten chromian chlorites Siskiyou Co., Calif. American Mineralogist 65 112-12219800293
0000770ClinochlorePhillips T L, Loveless J K, Bailey S W (1980) Cr3+ coordination in chlorites: a structural study of ten chromian chlorites Day Book Body, N. C. American Mineralogist 65 112-12219800293
0015561SudoiteAleksandrova V A, Drits V A, Sokolova G V (1973) Crystal structure of ditrioctahedral chlorite Soviet Physics Crystallography 18 50-5319730293
0000155SudoiteEggleton R A, Bailey S W (1967) Structural aspects of dioctahedral chlorite American Mineralogist 52 673-68919670293
0000119ClinochloreBrown B E, Bailey S W (1963) Chlorite polytypism: II. Crystal structure of a one-layer Cr-chlorite American Mineralogist 48 42-6119630293
0001619ClinochloreNelson D O, Guggenheim S (1993) Inferred limitations to the oxidation of Fe in chlorite: a high-temperature single-crystal X-ray study American Mineralogist 78 1197-120719930823
0002740ClinochloreWelch M D, Marshall W G (2001) High-pressure behaviour of clinochlore American Mineralogist 86 1380-138620011.2293
0002741ClinochloreWelch M D, Marshall W G (2001) High-pressure behaviour of clinochlore American Mineralogist 86 1380-138620012.46293
0002742ClinochloreWelch M D, Marshall W G (2001) High-pressure behaviour of clinochlore American Mineralogist 86 1380-138620014.65293
CIF Raw Data - click here to close

First Recorded Occurrence of Chlorite GroupHide

Synonyms of Chlorite GroupHide

Other Language Names for Chlorite GroupHide

Esperanto:Kloritoj
German:Chlorit
Helminth
Pseudophit (in part)
Russian:Хлорит
Simplified Chinese:绿泥石族
绿泥石
Spanish:Chlorita

Varieties of Chlorite GroupHide

DelessiteFe-bearing variety of clinochlore (some references also consider it a Mg-rich variety of chamosite).
LeptochloriteA name proposed by Tschermak (1890, 1891) for those members of the chlorite group which have high ferric iron, and commonly occur in fine scales or indistinctly fibrous forms. See also orthochlorite. Considered by Hey (1954) to be mostly an oxidised iron ...
OrthochloriteA name proposed by Tschermak (1890, 1891) for those Mg-rich members of the chlorite group which have low trivalent ions, especially ferric iron. See also leptochlorite.

Also used for any of several chlorites of distinct crystallization —opposed to typi...
OxychloriteObsolete name for altered, oxidised, Fe-rich chlorite.
Also used more recently as a theoretical end-member: for a H-deficient, ferric component, close to tri-trioctahedral, with an O12(OH)6 anionic basis (Masci et al, 2019)
PrasoliteA soft leek-green fibrous mineral from Kilpatrick Hills, Scotland. An aluminosilicate of Mg and Fe, probably a variety of chlorite.
TatarkaiteA hydrated silicate of aluminium, magnesium, etc. from metamorphosed limestone near the Tatarka river, tributary of the Angara river, Siberia. Tatarkaite has been shown to be chlorite near ripidolite.

Relationship of Chlorite Group to other SpeciesHide

Chlorite Group Members:
Baileychlore Zn5Al(AlSi3O10)(OH)8Tric. 1
Borocookeite (LiAl4◻)[BSi3O10](OH)8Mon. m : Bb
Chamosite Fe2+5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
Clinochlore Mg5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
Cookeite (LiAl4◻)[AlSi3O10](OH)8Mon. 2/m
Donbassite Al4.33(AlSi3O10)(OH)8Mon. 2 : B2
Franklinfurnaceite Ca2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8Mon. 2 : B2
Glagolevite Na(Mg,Al)6(AlSi3O10)(OH,O)8Tric. 1 : P1
Gonyerite Mn2+5Fe3+(Fe3+Si3O10)(OH)8Orth.
Nimite Ni5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
Pennantite Mn2+5Al(AlSi3O10)(OH)8Tric.
Sudoite Mg2Al3(AlSi3O10)(OH)8Mon. 2/m : B2/m
Vakhrushevaite Mg5Cr(AlSi3O10)(OH)8Tric. 1
Click on any node to view relationships. Formula-derived relationship network for the group members above. Use Find related species to add formula-neighbour species outside the current group view. Solid links show inferred chemical differences; dashed violet links show same-formula crystallographic differences. Hydration states are not treated as relationship changes. These relationships do not imply any real-world substitution reactions between these species.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Chlorite Group in petrologyHide

Internet Links for Chlorite GroupHide

References for Chlorite GroupHide

Reference List:

Significant localities for Chlorite GroupHide

Showing 32 significant localities out of 22,048 recorded on mindat.org.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Queensland
    • Mareeba Shire
      • Mungana
[Baileychlore] AM 73 (1988) +1 other reference
Czech Republic
 
  • Central Bohemian Region
    • Kutná Hora District
      • Kutná Hora
[Orthochamosite] Am Min 43 (1958)
Germany
 
  • Baden-Württemberg
    • Stuttgart Region
      • Esslingen
        • Plochingen
          • Lützelbach
[Sudoite] von Engelhardt et al. (1962) +1 other reference
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Agios Konstantinos (Kamariza)
          • Mercati mines
[Baileychlore] LAPIS 2010 7/8 (Kristalldruse ad) +2 other references
Mali
 
  • Kayes Region
    • Bafoulabé Cercle
[Clinochlore] Currier et al. (2011)
Poland
 
  • Lower Silesian Voivodeship
    • Świdnica County
[Chamosite] Dana et al. (1892)
[Chamosite] Tomas Praszkier
Russia
 
  • Krasnoyarsk Krai
    • Enisei Range (Yenisei Ridge; Enisei Ridge)
[var: Tatarkaite] Meister A. (1910)
  • Murmansk Oblast
    • Kovdorsky District
      • Kovdor Massif
[Glagolevite] M. V. Seredkin et al.: Zap. Vses. Min. Obshch.:132 (1)
  • Perm Krai
    • Gornozavodskii District
      • Sarany
        • Saranovskii Mine
[Vakhrushevaite] Pekov et al. (2025)
  • Zabaykalsky Krai
    • Krasnochikoysky District
      • Krasnyi Chikoy
        • Malkhan pegmatite field
[Borocookeite] Zagorsky et al. (2003) +2 other references
South Africa
 
  • Mpumalanga
    • Ehlanzeni District Municipality
      • Mbombela Local Municipality
        • Barberton
[Nimite] Hiemstra et al. (1968) +3 other references
Sweden
 
  • Värmland County
    • Filipstad
      • Långban Ore District
[Gonyerite] Frondel (1955) +1 other reference
Switzerland
 
  • Valais
    • Conthey
      • Chamoson
[Chamosite] Berthier (1820) +1 other reference
Turkey
 
  • Erzurum Province
    • Aşkale District
      • Kop Daglari
[Clinochlore var: Chromium-bearing Clinochlore] Dietrich (1978) +2 other references
UK
 
  • Wales
    • Gwynedd
      • Aberdaron
        • Rhiw
[Pennantite] Campbell Smith et al. (1946) +6 other references
Ukraine
 
  • Donetsk Oblast
[Donbassite] Lazarenko (1940)
USA
 
  • California
    • Calaveras County
      • Valley Springs area
Jake Harper: Field work
  • Connecticut
    • Fairfield County
      • Trumbull
        • Long Hill
[Clinochlore] Shannon (1921b) +1 other reference
[Clinochlore] P Cristofono collection
    • Middlesex County
      • Haddam
        • Haddam Neck
[Cookeite] Bowman (1902) +3 other references
      • Portland
        • Collins Hill
          • Strickland pegmatite
[Cookeite] Ralph Lieser of Pappy’s Beryl Shop +3 other references
    • New Haven County
[Clinochlore] Jeremy Zolan Collection
  • Maine
    • Oxford County
      • Buckfield
[Cookeite] King et al. (1991) +1 other reference
      • Hebron
        • Mount Rubellite
[Cookeite] USGS Bull 445 +3 other references
      • Paris
[Cookeite] King et al. (1994) +1 other reference
  • Maryland
    • Baltimore County
      • Holbrook
[Clinochlore var: Chromium-bearing Clinochlore] Stuart Herring Collection
  • New Hampshire
    • Coos County
      • Gorham
[Chamosite] A. Plante collection +3 other references
  • New Jersey
    • Sussex County
      • Franklin
[Franklinfurnaceite] Dunn et al. (1987) +1 other reference
  • New York
    • Putnam County
      • Town of Southeast
[Clinochlore] - (Bridenbaugh, 1873) +1 other reference
  • Pennsylvania
    • Chester County
      • Westtown Township
[Clinochlore] Dana 6:1068 +1 other reference
 
and/or  
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