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Sinkankasite

A valid IMA mineral species
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About SinkankasiteHide

08457320017271926733187.jpg
John and Marjory Sinkankas 1988
Formula:
Mn2+Al(PO3OH)2(OH) · 6H2O
Colour:
Colourless
Lustre:
Vitreous, Dull
Hardness:
4
Specific Gravity:
2.27
Crystal System:
Triclinic
Name:
Named in 1984 by Donald R. Peacor, Pete J. Dunn, Willard Lincoln Roberts, Thomas J. Campbell, and William B. Simmons in honor of Captain John Sinkankas [May 15, 1915 Paterson, New Jersey, USA - May 17, 2002 San Diego, California, USA] innovator in faceting gem stones, author of mineralogical and gemological books, rare geoscience book dealer, mineral artist, mineral collector, and associate with Scripps Institute of Oceanography.
This page provides mineralogical data about Sinkankasite.


Unique IdentifiersHide

Mindat ID:
3674
Long-form identifier:
mindat:1:1:3674:6

IMA Classification of SinkankasiteHide

Classification of SinkankasiteHide

8.DB.20

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1
42.7.1.4

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
7 : (AB)2(XO4)Zq·xH2O
19.12.8

19 : Phosphates
12 : Phosphates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
SkaIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of SinkankasiteHide

Vitreous, Dull
Transparency:
Transparent
Comment:
Vitreous on cleavages.
Colour:
Colourless
Hardness:
Tenacity:
Very brittle
Cleavage:
Perfect
{100}
Parting:
Parting along {100} twin boundaries.
Density:
2.27 g/cm3 (Measured)    2.25 g/cm3 (Calculated)

Optical Data of SinkankasiteHide

Type:
Biaxial (-)
RI values:
nα = 1.511(2) nβ = 1.529(2) nγ = 1.544(2)
2V:
Measured: 84° , Calculated: 84°
Max. Birefringence:
δ = 0.033
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
None to Very Low
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r < v, moderate.
Optical Extinction:
Y ∧ c ≃ 11°.
Comments:
Optical measurements are complicated by intrinsic multiple twinning.

Chemistry of SinkankasiteHide

Mindat Formula:
Mn2+Al(PO3OH)2(OH) · 6H2O
Element Weights:
Element% weight
O60.152 %
P15.527 %
Mn13.770 %
Al6.763 %
H3.790 %

Calculated from ideal end-member formula.
O
P
Mn
Al
H

Crystallography of SinkankasiteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 9.590(2) Å, b = 9.818(2) Å, c = 6.860(1) Å
α = 108.04(3)°, β = 99.63(3)°, γ = 98.87(3)°
Ratio:
a:b:c = 0.977 : 1 : 0.699
Unit Cell V:
590.69 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Elongate on [001], tabular on {100} and composed of the forms {100}, {010}, and {001}.
Twinning:
On {100}, common.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0001744SinkankasiteBurns P C, Hawthorne F C (1995) The crystal structure of sinkankasite, a complex heteropolyhedral sheet mineral American Mineralogist 80 620-6271995Barker pegmatite, near Keystone, Pennington County, South Dakota, USA0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Loading XRD data...
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacingIntensity
9.2 Å(100)
5.06 Å(60)
5.41 Å(50)
4.58 Å(40)
2.834 Å(40)
2.701 Å(40)
2.943 Å(30)
Comments:
Barker-Ferguson Mine, South Dakota, USA. Data from the type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
22 : Hydration and low-? subsurface aqueous alteration (see also #23)

Type Occurrence of SinkankasiteHide

General Appearance of Type Material:
Complete pseudomorphs after subhedral to euhedral triphylite and as cavity fillings formed from the partial or complete dissolution of triphylite; ranging in size from <1 to 10 cm3. Also found along fractures that cut quartz, microcline, albite, and muscovite.
Place of Conservation of Type Material:
The Natural History Museum, London, England; National Museum of Natural History, Washington, D.C., USA, 149597.
Geological Setting of Type Material:
Late-stage hydrothermal alteration product of triphylite.
Associated Minerals at Type Locality:

Synonyms of SinkankasiteHide

Other Language Names for SinkankasiteHide

Common AssociatesHide

Associations Based on Photo Data:
6 photos of Sinkankasite associated with HureauliteMn2+5(PO3OH)2(PO4)2 · 4H2O
3 photos of Sinkankasite associated with MuscoviteKAl2(AlSi3O10)(OH)2
2 photos of Sinkankasite associated with 'Carbonate-rich Fluorapatite'Ca5(PO4,CO3)3(F,O)
2 photos of Sinkankasite associated with BarbosaliteFe2+Fe3+2(PO4)2(OH)2
1 photo of Sinkankasite associated with VivianiteFe2+Fe2+2(PO4)2 · 8H2O
1 photo of Sinkankasite associated with QuartzSiO2

Related Minerals - Strunz-mindat GroupingHide

8.DB.ArangasiteAl2F(PO4)(SO4) · 9H2O Mon. 2/m : P2/b
8.DB.HösliteFe3+3(VO4)2(SO4)(OH)(H2O)4 · 3H2OMon. 2/m : P21/b
8.DB.Camaronesite[Fe3+(H2O)2(PO3OH)]2(SO4) · 1-2H2OTrig. 32 : R32
8.DB.05DestineziteFe3+2(PO4)(SO4)(OH) · 6H2OTric. 1 : P1
8.DB.05Pitticite(Fe, AsO4, H2O) (?)Amor.
8.DB.05DiadochiteFe3+2(PO4)(SO4)(OH) · 6H2OAmor.
8.DB.07WilhelmgümbeliteZnFe2+Fe3+3(PO4)3(OH)4(H2O)5 · 2H2OOrth. mmm(2/m2/m2/m)
8.DB.07Schmidite[Zn2(Fe3+,Mn2+)2Fe3+(PO4)3(OH)3(H2O)6] · 2H2OOrth.
8.DB.07WildenaueriteZn(Fe3+,Mn2+)2MnFe3+(PO4)3(OH)3(H2O)6 · 2H2OOrth. mmm(2/m2/m2/m) : Pbam
8.DB.10VashegyiteAl11(PO4)9(OH)6 · 38H2OOrth. mmm(2/m2/m2/m)
8.DB.15SchooneriteZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2OOrth. mmm(2/m2/m2/m) : Pbam
8.DB.25MitryaevaiteAl6(PO4)((P,S)O3(OH,O))2F2(OH)2 · 14.5H2OTric. 1 : P1
8.DB.30SanjuaniteAl2(PO4)(SO4)(OH) · 9H2OTric.
8.DB.35SarmientiteFe3+2(AsO4)(SO4)(OH) · 5H2OMon. 2/m : P21/b
8.DB.40BukovskýiteFe3+2(AsO4)(SO4)(OH) · 9H2OTric. 1 : P1
8.DB.40ManganflurliteZnMn2+3Fe3+(PO4)3(OH)2(H2O)7 · 2H2OMon. 2/m : P21/m
8.DB.40FlurliteZn3Mn2+Fe3+(PO4)3(OH)2 · 9H2OMon. 2/m : P21/m
8.DB.42BohuslaviteFe3+4(PO4)3(SO4)(OH) · nH2OTric. 1 : P1
8.DB.45ZýkaiteFe3+4(AsO4)3(SO4)(OH) · 15H2OOrth. 222 : P222
8.DB.47LapeyreiteCu3O[AsO3(OH)]2 · 0.75H2OMon. 2/m : B2/m
8.DB.50RossiantoniteAl3(PO4)(SO4)2(OH)2(H2O)14Tric. 1 : P1
8.DB.50GiniiteFe2+Fe3+4(PO4)3(OH)5 · 2H2OMon. 2/m : P2/b
8.DB.52'Arctowskite'Al9(PO4)8(OH)3 · 27H2OOrth.
8.DB.55Sasaite(Al,Fe3+)14(PO4)11(SO4)(OH)7 · 83H2OOrth.
8.DB.60McauslaniteFe3Al2(PO4)3(PO3OH)F · 18H2OTric.
8.DB.65GoldquarryiteCuCd2Al3(PO4)4F2(H2O,F)2 · 10H2OTric. 1 : P1
8.DB.70BirchiteCd2Cu2(PO4)2(SO4) · 5H2OOrth. mmm(2/m2/m2/m) : Pnma
8.DB.75BraithwaiteiteNaCu5(Ti4+Sb5+)(AsO4)4(HAsO4)2O2 · 8H2OTric. 1 : P1

Fluorescence of SinkankasiteHide

Not fluorescent.

Other InformationHide

Notes:
Readily soluble in dilute 1:1 HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for SinkankasiteHide

References for SinkankasiteHide

Localities for SinkankasiteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia
 
  • Sakha
    • Indigirka River Basin
      • Ust'-Nera
Gamyanin et al. (2014) +1 other reference
USA
 
  • New Hampshire
    • Grafton County
      • Groton
Peacor et al. (1984)
  • South Dakota
    • Pennington County
      • Keystone Mining District
        • Keystone
Peacor et al. (1984)
 
and/or  
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