Sanjuanite
A valid IMA mineral species
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About Sanjuanite
Formula:
Al2(PO4)(SO4)(OH) · 9H2O
Colour:
White
Lustre:
Silky, Dull
Hardness:
3
Specific Gravity:
1.94
Crystal System:
Triclinic
Member of:
Name:
Named after the Province of San Juan, Argentina, the discovery locality.
Unique Identifiers
Mindat ID:
3522
Long-form identifier:
mindat:1:1:3522:0
IMA Classification of Sanjuanite
Approved
Approval year:
1966
First published:
1968
Classification of Sanjuanite
8.DB.30
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1
43.5.1.3
43 : COMPOUND PHOSPHATES, ETC.
5 : Hydrated Compound Phosphates, etc·, Containing Hydroxyl or Halogen
43 : COMPOUND PHOSPHATES, ETC.
5 : Hydrated Compound Phosphates, etc·, Containing Hydroxyl or Halogen
22.3.11
22 : Phosphates, Arsenates or Vanadates with other Anions
3 : Phosphates, arsenates or vanadates with sulphates
22 : Phosphates, Arsenates or Vanadates with other Anions
3 : Phosphates, arsenates or vanadates with sulphates
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Sjn | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Sanjuanite
Silky, Dull
Transparency:
Transparent
Colour:
White
Hardness:
3 on Mohs scale
Fracture:
Irregular/Uneven
Density:
1.94 g/cm3 (Measured) 1.96 g/cm3 (Calculated)
Optical Data of Sanjuanite
Type:
Biaxial
RI values:
nα = 1.484 nγ = 1.499
Max. Birefringence:
δ = 0.015
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.
Surface Relief:
Moderate
Dispersion:
r > v to r < v strong
Chemistry of Sanjuanite
Mindat Formula:
Al2(PO4)(SO4)(OH) · 9H2O
Element Weights:
Crystallography of Sanjuanite
Crystal System:
Triclinic
Cell Parameters:
a = 11.314(11) Å, b = 9.018(9) Å, c = 7.376(7) Å
α = 93°, β = 95°, γ = 105°
α = 93°, β = 95°, γ = 105°
Ratio:
a:b:c = 1.255 : 1 : 0.818
Unit Cell V:
721.96 ų (Calculated from Unit Cell)
Comment:
Questionable
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0018459 | Sanjuanite | Colombo F, Rius J, Pannunzio-Miner E V, Pedregosa J C, Cami G E, Carbonio R E (2011) Sanjuanite: Ab Initio crystal-structure solution from laboratory powder-diffraction data, complemented by FTIR spectroscopy and DT-TG analyses Pocito Department, San Juan Province, Argentina The Canadian Mineralogist 49 835-847 | 2011 | Pensylvanian slates belonging to Los Jejenes Formation at the | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 10.77 Å | (100) |
| 4.13 Å | (55) |
| 5.28 Å | (38) |
| 4.32 Å | (36) |
| 3.450 Å | (35) |
| 8.66 Å | (30) |
| 4.27 Å | (30) |
Comments:
Sierra Chica de Zonda, Argentina. The data are from the type description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47b : [Sulfates and sulfites] | |
| 47c : [Carbonates, phosphates, borates, nitrates] |
Type Occurrence of Sanjuanite
General Appearance of Type Material:
Microscopic laths, parallel to divergent, fibrous, in chalk-like aggregates.
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 149522.
Geological Setting of Type Material:
Dark Carboniferous slate.
Associated Minerals at Type Locality:
Synonyms of Sanjuanite
Other Language Names for Sanjuanite
Relationship of Sanjuanite to other Species
Member of:
Other Members of Sanjuanite-Destinezite Group:
| Destinezite | Fe3+2(PO4)(SO4)(OH) · 6H2O | Tric. 1 : P1 |
| Sarmientite | Fe3+2(AsO4)(SO4)(OH) · 5H2O | Mon. 2/m : P21/b |
| Zýkaite | Fe3+4(AsO4)3(SO4)(OH) · 15H2O | Orth. 2 2 2 : P2 2 2 |
Related Minerals - Strunz-mindat Grouping
| 8.DB. | Arangasite | Al2F(PO4)(SO4) · 9H2O |
| 8.DB. | Höslite | Fe3+3(VO4)2(SO4)(OH)(H2O)4 · 3H2O |
| 8.DB. | Camaronesite | [Fe3+(H2O)2(PO3OH)]2(SO4) · 1-2H2O |
| 8.DB.05 | Destinezite | Fe3+2(PO4)(SO4)(OH) · 6H2O |
| 8.DB.05 | Pitticite | (Fe, AsO4, H2O) (?) |
| 8.DB.05 | Diadochite | Fe3+2(PO4)(SO4)(OH) · 6H2O |
| 8.DB.07 | Wilhelmgümbelite | ZnFe2+Fe3+3(PO4)3(OH)4(H2O)5 · 2H2O |
| 8.DB.07 | Schmidite | [Zn2(Fe3+,Mn2+)2Fe3+(PO4)3(OH)3(H2O)6] · 2H2O |
| 8.DB.07 | Wildenauerite | Zn(Fe3+,Mn2+)2MnFe3+(PO4)3(OH)3(H2O)6 · 2H2O |
| 8.DB.10 | Vashegyite | Al11(PO4)9(OH)6 · 38H2O |
| 8.DB.15 | Schoonerite | ZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2O |
| 8.DB.20 | Sinkankasite | Mn2+Al(PO3OH)2(OH) · 6H2O |
| 8.DB.25 | Mitryaevaite | Al6(PO4)((P,S)O3(OH,O))2F2(OH)2 · 14.5H2O |
| 8.DB.35 | Sarmientite | Fe3+2(AsO4)(SO4)(OH) · 5H2O |
| 8.DB.40 | Bukovskýite | Fe3+2(AsO4)(SO4)(OH) · 9H2O |
| 8.DB.40 | Manganflurlite | ZnMn2+3Fe3+(PO4)3(OH)2(H2O)7 · 2H2O |
| 8.DB.40 | Flurlite | Zn3Mn2+Fe3+(PO4)3(OH)2 · 9H2O |
| 8.DB.42 | Bohuslavite | Fe3+4(PO4)3(SO4)(OH) · nH2O |
| 8.DB.45 | Zýkaite | Fe3+4(AsO4)3(SO4)(OH) · 15H2O |
| 8.DB.47 | Lapeyreite | Cu3O[AsO3(OH)]2 · 0.75H2O |
| 8.DB.50 | Rossiantonite | Al3(PO4)(SO4)2(OH)2(H2O)14 |
| 8.DB.50 | Giniite | Fe2+Fe3+4(PO4)3(OH)5 · 2H2O |
| 8.DB.52 | 'Arctowskite' | Al9(PO4)8(OH)3 · 27H2O |
| 8.DB.55 | Sasaite | (Al,Fe3+)14(PO4)11(SO4)(OH)7 · 83H2O |
| 8.DB.60 | Mcauslanite | Fe3Al2(PO4)3(PO3OH)F · 18H2O |
| 8.DB.65 | Goldquarryite | CuCd2Al3(PO4)4F2(H2O,F)2 · 10H2O |
| 8.DB.70 | Birchite | Cd2Cu2(PO4)2(SO4) · 5H2O |
| 8.DB.75 | Braithwaiteite | NaCu5(Ti4+Sb5+)(AsO4)4(HAsO4)2O2 · 8H2O |
Other Information
Thermal Behaviour:
Heated in a closed tube, it gives of a high proportion of acid water.
Notes:
Readily soluble in warm mineral acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Sanjuanite
mindat.org URL:
https://www.mindat.org/min-3522.html
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Please feel free to link to this page.
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References for Sanjuanite
Reference List:
de Abeledo, M. E. J., Angelelli, V., de Benyacar, M. A. R., Gordillo, C. (1968) Sanjuanite, a new hydrated basic sulfate-phosphate of aluminum. American Mineralogist, 53 (1-2) 1-8
De Bruiyn, H., Beukes, G. J., Van Der Westhuizen, W. A., Tordiffe, E. A. W. (1989) Unit cell dimensions of the hydrated aluminium phosphate–sulphate minerals sanjuanite, kribergite, and hotsonite. Mineralogical Magazine, 53 (371) 385-386 doi:10.1180/minmag.1989.053.371.17
Colombo, F., Rius, J., Pannunzio-Miner, E. V., Pedregosa, J. C., Cami, G. E., Carbonio, R. E. (2011) Sanjuanite: Ab Initio crystal-structure solution from laboratory powder-diffraction data, complemented by FTIR spectroscopy and DT-TG analyses. The Canadian Mineralogist, 49 (3) 835-847 doi:10.3749/canmin.49.3.835
Localities for Sanjuanite
Showing 4 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Argentina (TL) | |
| de Abeledo et al. (1968) +2 other references |
Poland | |
| Cu +2 other references |
Venezuela | |
| Sauro et al. (2013) |
| Galli et al. (2013) |
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The
Sierra Chica de Zonda, Pocito Department, San Juan Province, Argentina