Flurlite
A valid IMA mineral species
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About Flurlite
Formula:
Zn3Mn2+Fe3+(PO4)3(OH)2 · 9H2O
Colour:
Bright orange red to dark maroon red
Specific Gravity:
2.89
Crystal System:
Monoclinic
Name:
Named by I.E. Grey, E. Keck, W.G. Mumme, A. Pring and C.M. MacRae in 2014 in honor of Mathias von Flurl (5 February 1756, Straubing, Bavaria - 27 July 1823, Kissingen, Bavaria), the founder of mineralogical and geological studies in Bavaria. He created the first geological map of Bavaria.
Related to schoonerite.
A re-evaluation of the site occupancies in flurlite, using BVS calculations, resulted in a change in the dominant cation in the M1 site from Mn2+ to Zn. Consequently, the end-member formula for flurlite becomes [5]Zn[6]Zn3[6]Fe3+(PO4)3(OH)2(H2O)7·2H2O (CNMNC Newsletter No. 42).
A re-evaluation of the site occupancies in flurlite, using BVS calculations, resulted in a change in the dominant cation in the M1 site from Mn2+ to Zn. Consequently, the end-member formula for flurlite becomes [5]Zn[6]Zn3[6]Fe3+(PO4)3(OH)2(H2O)7·2H2O (CNMNC Newsletter No. 42).
Unique Identifiers
Mindat ID:
46498
Long-form identifier:
mindat:1:1:46498:5
IMA Classification of Flurlite
Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
Zn2+Zn2+3Fe3+(PO4)3(OH)2(H2O)7·2H2O
Approval year:
2014
First published:
2015
Approval history:
2014: Approved by IMA as a new species (IMA 2014-064) with the formula Zn3Mn2+Fe3+(PO4)3(OH)2·9H2O.
2017: Revised end-member formula for flurlite (Proposal 17-I),[5]Zn[6]3[6]Fe3+(PO4)3(OH)2(H2O)7·2H2O.
2017: Revised end-member formula for flurlite (Proposal 17-I),[5]Zn[6]3[6]Fe3+(PO4)3(OH)2(H2O)7·2H2O.
Type description reference:
Grey, I. E., Keck, E., Mumme, W. G., Pring, A., Macrae, C. M., Gable, R. W., Price, J. R. (2015) Flurlite, Zn3Mn2+Fe3+(PO4)3(OH)2·9H2O, a new mineral from the Hagendorf Süd pegmatite, Bavaria, with a schoonerite-related structure. Mineralogical Magazine, 79 (5) 1175-1184 doi:10.1180/minmag.2015.079.5.11
Classification of Flurlite
8.DB.40
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Flu | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Flurlite
Transparency:
Translucent
Colour:
Bright orange red to dark maroon red
Streak:
Buff
Comment:
Hardness not described.
Tenacity:
Brittle
Cleavage:
Perfect
Parallel to (001).
Parallel to (001).
Fracture:
Irregular/Uneven
Density:
2.89 g/cm3 (Measured) 2.84 g/cm3 (Calculated)
Optical Data of Flurlite
Type:
Biaxial (-)
RI values:
nα = 1.60(1) nβ = 1.65(1) nγ = 1.68(1)
2V:
Calculated: 74°
Max. Birefringence:
δ = 0.080
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
Weak
Optical Extinction:
Parallel. X ≈ c, Y ≈ a, Z ≈ b.
Pleochroism:
Weak
Comments:
With colours: X = pale yellow, Y = pale orange, Z = orange brown
Chemistry of Flurlite
Mindat Formula:
Zn3Mn2+Fe3+(PO4)3(OH)2 · 9H2O
Element Weights:
Crystallography of Flurlite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/m
Setting:
P21/m
Cell Parameters:
a = 6.3894(8) Å, b = 11.037(1) Å, c = 13.063(2) Å
β = 99.37(2)°
β = 99.37(2)°
Ratio:
a:b:c = 0.579 : 1 : 1.184
Unit Cell V:
908.91 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Platelets forming twisted accordion-like aggregates.
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 12.900 Å | (100) |
| 8.375 Å | (10) |
| 6.072 Å | (14) |
| 5.567 Å | (8) |
| 5.080 Å | (7) |
| 4.297 Å | (21) |
| 3.221 Å | (7) |
| 2.763 Å | (35) |
Reference:
Grey, I. E., Keck, E., Mumme, W. G., Pring, A., Macrae, C. M., Gable, R. W., Price, J. R. (2015) Flurlite, Zn3Mn2+Fe3+(PO4)3(OH)2·9H2O, a new mineral from the Hagendorf Süd pegmatite, Bavaria, with a schoonerite-related structure. Mineralogical Magazine, 79 (5) 1175-1184 doi:10.1180/minmag.2015.079.5.11
Comments:
From Type Description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Near-surface Processes | |
| 23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47) | |
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites |
Type Occurrence of Flurlite
General Appearance of Type Material:
As ultrathin (<1 μm) translucent platelets that form characteristic twisted accordion-like aggregates, on mitridatite.
Place of Conservation of Type Material:
Type material is deposited in the mineralogical collections of Museum Victoria, Melbourne, Victoria, Australia, registration number M53238.
Geological Setting of Type Material:
Zoned granitic phosphate pegmatite.
Associated Minerals at Type Locality:
Reference:
Grey, I. E., Keck, E., Mumme, W. G., Pring, A., Macrae, C. M., Gable, R. W., Price, J. R. (2015) Flurlite, Zn3Mn2+Fe3+(PO4)3(OH)2·9H2O, a new mineral from the Hagendorf Süd pegmatite, Bavaria, with a schoonerite-related structure. Mineralogical Magazine, 79 (5) 1175-1184 doi:10.1180/minmag.2015.079.5.11
Synonyms of Flurlite
Other Language Names for Flurlite
Common Associates
Associations Based on Photo Data:
| 3 photos of Flurlite associated with Jungite | Ca2Zn4Fe3+8(PO4)9(OH)9 · 16H2O |
| 1 photo of Flurlite associated with Stewartite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
Related Minerals - Strunz-mindat Grouping
| 8.DB. | Arangasite | Al2F(PO4)(SO4) · 9H2O |
| 8.DB. | Höslite | Fe3+3(VO4)2(SO4)(OH)(H2O)4 · 3H2O |
| 8.DB. | Camaronesite | [Fe3+(H2O)2(PO3OH)]2(SO4) · 1-2H2O |
| 8.DB.05 | Destinezite | Fe3+2(PO4)(SO4)(OH) · 6H2O |
| 8.DB.05 | Pitticite | (Fe, AsO4, H2O) (?) |
| 8.DB.05 | Diadochite | Fe3+2(PO4)(SO4)(OH) · 6H2O |
| 8.DB.07 | Wilhelmgümbelite | ZnFe2+Fe3+3(PO4)3(OH)4(H2O)5 · 2H2O |
| 8.DB.07 | Schmidite | [Zn2(Fe3+,Mn2+)2Fe3+(PO4)3(OH)3(H2O)6] · 2H2O |
| 8.DB.07 | Wildenauerite | Zn(Fe3+,Mn2+)2MnFe3+(PO4)3(OH)3(H2O)6 · 2H2O |
| 8.DB.10 | Vashegyite | Al11(PO4)9(OH)6 · 38H2O |
| 8.DB.15 | Schoonerite | ZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2O |
| 8.DB.20 | Sinkankasite | Mn2+Al(PO3OH)2(OH) · 6H2O |
| 8.DB.25 | Mitryaevaite | Al6(PO4)((P,S)O3(OH,O))2F2(OH)2 · 14.5H2O |
| 8.DB.30 | Sanjuanite | Al2(PO4)(SO4)(OH) · 9H2O |
| 8.DB.35 | Sarmientite | Fe3+2(AsO4)(SO4)(OH) · 5H2O |
| 8.DB.40 | Bukovskýite | Fe3+2(AsO4)(SO4)(OH) · 9H2O |
| 8.DB.40 | Manganflurlite | ZnMn2+3Fe3+(PO4)3(OH)2(H2O)7 · 2H2O |
| 8.DB.42 | Bohuslavite | Fe3+4(PO4)3(SO4)(OH) · nH2O |
| 8.DB.45 | Zýkaite | Fe3+4(AsO4)3(SO4)(OH) · 15H2O |
| 8.DB.47 | Lapeyreite | Cu3O[AsO3(OH)]2 · 0.75H2O |
| 8.DB.50 | Rossiantonite | Al3(PO4)(SO4)2(OH)2(H2O)14 |
| 8.DB.50 | Giniite | Fe2+Fe3+4(PO4)3(OH)5 · 2H2O |
| 8.DB.52 | 'Arctowskite' | Al9(PO4)8(OH)3 · 27H2O |
| 8.DB.55 | Sasaite | (Al,Fe3+)14(PO4)11(SO4)(OH)7 · 83H2O |
| 8.DB.60 | Mcauslanite | Fe3Al2(PO4)3(PO3OH)F · 18H2O |
| 8.DB.65 | Goldquarryite | CuCd2Al3(PO4)4F2(H2O,F)2 · 10H2O |
| 8.DB.70 | Birchite | Cd2Cu2(PO4)2(SO4) · 5H2O |
| 8.DB.75 | Braithwaiteite | NaCu5(Ti4+Sb5+)(AsO4)4(HAsO4)2O2 · 8H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Flurlite
mindat.org URL:
https://www.mindat.org/min-46498.html
Please feel free to link to this page.
Please feel free to link to this page.
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External Links:
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References for Flurlite
Reference List:
Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2014 and 2015. Newsletter No 23. Mineralogical Magazine, 79 (1) 51-58 doi:10.1180/minmag.2015.079.1.05
Grey, I. E., Keck, E., Mumme, W. G., Pring, A., Macrae, C. M., Gable, R. W., Price, J. R. (2015) Flurlite, Zn3Mn2+Fe3+(PO4)3(OH)2·9H2O, a new mineral from the Hagendorf Süd pegmatite, Bavaria, with a schoonerite-related structure. Mineralogical Magazine, 79 (5) 1175-1184 doi:10.1180/minmag.2015.079.5.11
Belakovskiy, Dmitriy I.; Cámara, Fernando (2016) New Mineral Names. American Mineralogist, 101 (8). 1920-1924 doi:10.2138/am-2016-nmn101815
Localities for Flurlite
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Germany (TL) | |
| Williams et al. (2015) +1 other reference |
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symbol to view information about a locality.
The
Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany