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Wilhelmgümbelite

A valid IMA mineral species
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About WilhelmgümbeliteHide

08108520017272472595017.jpg
Carl Wilhelm Ritter von Gümbel
Formula:
ZnFe2+Fe3+3(PO4)3(OH)4(H2O)5 · 2H2O
Colour:
Light yellow-brown to orange-red
Lustre:
Dull
Specific Gravity:
2.89
Crystal System:
Orthorhombic
Name:
The name is for Dr. Carl Wilhelm von Gümbel (11 February 1823, Dannenfels, Germany - 18 June 1898, Munich, Germany). He was appointed to Munich in 1851 by King Maximilian II to lead the geological studies of the kingdom of Bavaria for more than 47 years. Geological mapping of Bavaria became his life’s work, published in a number of comprehensive volumes that were printed between 1861 and 1891. His second volume "Geognostische Beschreibung des Ostbayerischen Grenzgebirges oder des Bayerischen und Oberpfälzer Waldgebirges", published in 1868, became an essential contribution to the mineralogical and geological investigation of pegmatites and their minerals in the eastern parts of Bavaria.
Isostructural with:
Related to schoonerite - an oxidized form of schoonerite with Mn2+ largely replaced by Fe3+. Chemistry similar to phosphophyllite, plimerite, steinmetzite, zinclipscombite, and zincoberaunite (these minerals have homovalent iron).
Also related to schmidite.

Structural differences from schoonerite: (1) Zn partitioned between two different sites: one 5-coordinated (as in schoonerite), the other tetrahedrally coordinated; (2) partial occupation of one of the Fe sites, probably correlated with the Zn partitioning. The structural formula: [Zn(Mn0.27Fe3+ 0.73)Σ1.0(Zn0.25Fe2+0.15Fe3+0.6)Σ1.0(Zn0.25Fe2+0.45)Σ0.7Fe3+(PO4)3(OH,H2O)9]·2H2O.


Name EncodingHide

ASCII-7:
Wilhelmgumbelite

Unique IdentifiersHide

Mindat ID:
46972
Long-form identifier:
mindat:1:1:46972:2

IMA Classification of WilhelmgümbeliteHide

Classification of WilhelmgümbeliteHide

8.DB.07

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
WgüIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of WilhelmgümbeliteHide

Colour:
Light yellow-brown to orange-red
Streak:
Pale yellow-brown
Tenacity:
Brittle
Cleavage:
Perfect
parallel to {010}
Fracture:
Irregular/Uneven
Density:
2.89 g/cm3 (Measured)    2.82 g/cm3 (Calculated)

Optical Data of WilhelmgümbeliteHide

Type:
Biaxial (+)
RI values:
nα = 1.558 - 1.562 nβ = 1.667 - 1.671 nγ = 1.716 - 1.720
2V:
Measured: 63° (1), Calculated: 65°
Max. Birefringence:
δ = 0.158
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Dispersion:
weak (r>v)
Optical Extinction:
Parallel. X = b, Y = c, Z = a.
Pleochroism:
Weak
Comments:
Z = orange-brown, Y = yellow-brown, X = light yellow-brown.
Comments:
Absorption: Z >> Y > X.

Chemistry of WilhelmgümbeliteHide

Mindat Formula:
ZnFe2+Fe3+3(PO4)3(OH)4(H2O)5 · 2H2O
Element Weights:
Element% weight
O47.927 %
Fe29.093 %
P12.102 %
Zn8.515 %
H2.363 %

Calculated from ideal end-member formula.
Common Impurities:
Mn(II)

Crystallography of WilhelmgümbeliteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Cell Parameters:
a = 10.987(3) Å, b = 25.378(13) Å, c = 6.387(6) Å
Ratio:
a:b:c = 0.433 : 1 : 0.252
Unit Cell V:
1,780.87 ų (Calculated from Unit Cell)
Z:
4
Comment:
Space group setting is Pmab

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Type Occurrence of WilhelmgümbeliteHide

General Appearance of Type Material:
Radiating sprays of needle-like rectangular laths (up to 0.2 mm in length).
Place of Conservation of Type Material:
Museum Victoria, Melbourne, Australia (registration number M53512)
Geological Setting of Type Material:
Phosphate-bearing granite pegmatite (oxidized zone) likely formed from schoonerite.
Associated Minerals at Type Locality:

Synonyms of WilhelmgümbeliteHide

Other Language Names for WilhelmgümbeliteHide

Relationship of Wilhelmgümbelite to other SpeciesHide

Other Members of Schoonerite Group:
Schmidite[Zn2(Fe3+,Mn2+)2Fe3+(PO4)3(OH)3(H2O)6] · 2H2OOrth.
SchooneriteZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2OOrth. mmm(2/m2/m2/m) : Pbam
WildenaueriteZn(Fe3+,Mn2+)2MnFe3+(PO4)3(OH)3(H2O)6 · 2H2OOrth. mmm(2/m2/m2/m) : Pbam

Related Minerals - Strunz-mindat GroupingHide

8.DB.ArangasiteAl2F(PO4)(SO4) · 9H2O Mon. 2/m : P2/b
8.DB.HösliteFe3+3(VO4)2(SO4)(OH)(H2O)4 · 3H2OMon. 2/m : P21/b
8.DB.Camaronesite[Fe3+(H2O)2(PO3OH)]2(SO4) · 1-2H2OTrig. 32 : R32
8.DB.05DestineziteFe3+2(PO4)(SO4)(OH) · 6H2OTric. 1 : P1
8.DB.05Pitticite(Fe, AsO4, H2O) (?)Amor.
8.DB.05DiadochiteFe3+2(PO4)(SO4)(OH) · 6H2OAmor.
8.DB.07Schmidite[Zn2(Fe3+,Mn2+)2Fe3+(PO4)3(OH)3(H2O)6] · 2H2OOrth.
8.DB.07WildenaueriteZn(Fe3+,Mn2+)2MnFe3+(PO4)3(OH)3(H2O)6 · 2H2OOrth. mmm(2/m2/m2/m) : Pbam
8.DB.10VashegyiteAl11(PO4)9(OH)6 · 38H2OOrth. mmm(2/m2/m2/m)
8.DB.15SchooneriteZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2OOrth. mmm(2/m2/m2/m) : Pbam
8.DB.20SinkankasiteMn2+Al(PO3OH)2(OH) · 6H2OTric. 1 : P1
8.DB.25MitryaevaiteAl6(PO4)((P,S)O3(OH,O))2F2(OH)2 · 14.5H2OTric. 1 : P1
8.DB.30SanjuaniteAl2(PO4)(SO4)(OH) · 9H2OTric.
8.DB.35SarmientiteFe3+2(AsO4)(SO4)(OH) · 5H2OMon. 2/m : P21/b
8.DB.40BukovskýiteFe3+2(AsO4)(SO4)(OH) · 9H2OTric. 1 : P1
8.DB.40ManganflurliteZnMn2+3Fe3+(PO4)3(OH)2(H2O)7 · 2H2OMon. 2/m : P21/m
8.DB.40FlurliteZn3Mn2+Fe3+(PO4)3(OH)2 · 9H2OMon. 2/m : P21/m
8.DB.42BohuslaviteFe3+4(PO4)3(SO4)(OH) · nH2OTric. 1 : P1
8.DB.45ZýkaiteFe3+4(AsO4)3(SO4)(OH) · 15H2OOrth. 222 : P222
8.DB.47LapeyreiteCu3O[AsO3(OH)]2 · 0.75H2OMon. 2/m : B2/m
8.DB.50RossiantoniteAl3(PO4)(SO4)2(OH)2(H2O)14Tric. 1 : P1
8.DB.50GiniiteFe2+Fe3+4(PO4)3(OH)5 · 2H2OMon. 2/m : P2/b
8.DB.52'Arctowskite'Al9(PO4)8(OH)3 · 27H2OOrth.
8.DB.55Sasaite(Al,Fe3+)14(PO4)11(SO4)(OH)7 · 83H2OOrth.
8.DB.60McauslaniteFe3Al2(PO4)3(PO3OH)F · 18H2OTric.
8.DB.65GoldquarryiteCuCd2Al3(PO4)4F2(H2O,F)2 · 10H2OTric. 1 : P1
8.DB.70BirchiteCd2Cu2(PO4)2(SO4) · 5H2OOrth. mmm(2/m2/m2/m) : Pnma
8.DB.75BraithwaiteiteNaCu5(Ti4+Sb5+)(AsO4)4(HAsO4)2O2 · 8H2OTric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for WilhelmgümbeliteHide

References for WilhelmgümbeliteHide

Localities for WilhelmgümbeliteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Germany (TL)
 
  • Bavaria
    • Upper Palatinate
      • Neustadt an der Waldnaab District
        • Waidhaus
          • Hagendorf
Hålenius et al. (2016) +1 other reference
 
and/or  
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