Wilhelmgümbelite
A valid IMA mineral species
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About Wilhelmgümbelite
Formula:
ZnFe2+Fe3+3(PO4)3(OH)4(H2O)5 · 2H2O
Colour:
Light yellow-brown to orange-red
Lustre:
Dull
Specific Gravity:
2.89
Crystal System:
Orthorhombic
Member of:
Name:
The name is for Dr. Carl Wilhelm von Gümbel (11 February 1823, Dannenfels, Germany - 18 June 1898, Munich, Germany). He was appointed to Munich in 1851 by King Maximilian II to lead the geological studies of the kingdom of Bavaria for more than 47 years. Geological mapping of Bavaria became his life’s work, published in a number of comprehensive volumes that were printed between 1861 and 1891. His second volume "Geognostische Beschreibung des Ostbayerischen Grenzgebirges oder des Bayerischen und Oberpfälzer Waldgebirges", published in 1868, became an essential contribution to the mineralogical and geological investigation of pegmatites and their minerals in the eastern parts of Bavaria.
Type Locality:
Isostructural with:
Related to schoonerite - an oxidized form of schoonerite with Mn2+ largely replaced by Fe3+. Chemistry similar to phosphophyllite, plimerite, steinmetzite, zinclipscombite, and zincoberaunite (these minerals have homovalent iron).
Also related to schmidite.
Structural differences from schoonerite: (1) Zn partitioned between two different sites: one 5-coordinated (as in schoonerite), the other tetrahedrally coordinated; (2) partial occupation of one of the Fe sites, probably correlated with the Zn partitioning. The structural formula: [Zn(Mn0.27Fe3+ 0.73)Σ1.0(Zn0.25Fe2+0.15Fe3+0.6)Σ1.0(Zn0.25Fe2+0.45)Σ0.7Fe3+(PO4)3(OH,H2O)9]·2H2O.
Also related to schmidite.
Structural differences from schoonerite: (1) Zn partitioned between two different sites: one 5-coordinated (as in schoonerite), the other tetrahedrally coordinated; (2) partial occupation of one of the Fe sites, probably correlated with the Zn partitioning. The structural formula: [Zn(Mn0.27Fe3+ 0.73)Σ1.0(Zn0.25Fe2+0.15Fe3+0.6)Σ1.0(Zn0.25Fe2+0.45)Σ0.7Fe3+(PO4)3(OH,H2O)9]·2H2O.
Name Encoding
ASCII-7:
Wilhelmgumbelite
Unique Identifiers
Mindat ID:
46972
Long-form identifier:
mindat:1:1:46972:2
IMA Classification of Wilhelmgümbelite
Approved
IMA Formula:
Zn2+Fe2+Fe3+3(PO4)3(OH)4(H2O)5·2H2O
Approval year:
2015
First published:
2017
Type description reference:
Classification of Wilhelmgümbelite
8.DB.07
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Wgü | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Wilhelmgümbelite
Dull
Colour:
Light yellow-brown to orange-red
Streak:
Pale yellow-brown
Tenacity:
Brittle
Cleavage:
Perfect
parallel to {010}
parallel to {010}
Fracture:
Irregular/Uneven
Density:
2.89 g/cm3 (Measured) 2.82 g/cm3 (Calculated)
Optical Data of Wilhelmgümbelite
Type:
Biaxial (+)
RI values:
nα = 1.558 - 1.562 nβ = 1.667 - 1.671 nγ = 1.716 - 1.720
2V:
Measured: 63° (1), Calculated: 65°
Max. Birefringence:
δ = 0.158
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Moderate
Dispersion:
weak (r>v)
Optical Extinction:
Parallel. X = b, Y = c, Z = a.
Pleochroism:
Weak
Comments:
Z = orange-brown, Y = yellow-brown, X = light yellow-brown.
Comments:
Absorption: Z >> Y > X.
Chemistry of Wilhelmgümbelite
Mindat Formula:
ZnFe2+Fe3+3(PO4)3(OH)4(H2O)5 · 2H2O
Element Weights:
Common Impurities:
Mn(II)
Crystallography of Wilhelmgümbelite
Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Cell Parameters:
a = 10.987(3) Å, b = 25.378(13) Å, c = 6.387(6) Å
Ratio:
a:b:c = 0.433 : 1 : 0.252
Unit Cell V:
1,780.87 ų (Calculated from Unit Cell)
Z:
4
Comment:
Space group setting is Pmab
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 12.65 Å | (100) |
| 8.339 Å | (5) |
| 6.421 Å | (14) |
| 6.228 Å | (8) |
| 5.098 Å | (5) |
| 4.223 Å | (30) |
| 3.166 Å | (5) |
| 2.111 Å | (7) |
Reference:
Comments:
Hagendorf South Pegmatite, Bavaria, Germany. Data from the type description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Near-surface Processes | |
| 22 : Hydration and low-? subsurface aqueous alteration (see also #23) | |
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47c : [Carbonates, phosphates, borates, nitrates] |
Type Occurrence of Wilhelmgümbelite
General Appearance of Type Material:
Radiating sprays of needle-like rectangular laths (up to 0.2 mm in length).
Place of Conservation of Type Material:
Museum Victoria, Melbourne, Australia (registration number M53512)
Geological Setting of Type Material:
Phosphate-bearing granite pegmatite (oxidized zone) likely formed from schoonerite.
Associated Minerals at Type Locality:
Synonyms of Wilhelmgümbelite
Other Language Names for Wilhelmgümbelite
Dutch:Wilhelmgümbeliet
German:Wilhelmgümbelit
Relationship of Wilhelmgümbelite to other Species
Member of:
Other Members of Schoonerite Group:
| Schmidite | [Zn2(Fe3+,Mn2+)2Fe3+(PO4)3(OH)3(H2O)6] · 2H2O | Orth. |
| Schoonerite | ZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2O | Orth. mmm(2/m2/m2/m) : Pbam |
| Wildenauerite | Zn(Fe3+,Mn2+)2MnFe3+(PO4)3(OH)3(H2O)6 · 2H2O | Orth. mmm(2/m2/m2/m) : Pbam |
Related Minerals - Strunz-mindat Grouping
| 8.DB. | Arangasite | Al2F(PO4)(SO4) · 9H2O |
| 8.DB. | Höslite | Fe3+3(VO4)2(SO4)(OH)(H2O)4 · 3H2O |
| 8.DB. | Camaronesite | [Fe3+(H2O)2(PO3OH)]2(SO4) · 1-2H2O |
| 8.DB.05 | Destinezite | Fe3+2(PO4)(SO4)(OH) · 6H2O |
| 8.DB.05 | Pitticite | (Fe, AsO4, H2O) (?) |
| 8.DB.05 | Diadochite | Fe3+2(PO4)(SO4)(OH) · 6H2O |
| 8.DB.07 | Schmidite | [Zn2(Fe3+,Mn2+)2Fe3+(PO4)3(OH)3(H2O)6] · 2H2O |
| 8.DB.07 | Wildenauerite | Zn(Fe3+,Mn2+)2MnFe3+(PO4)3(OH)3(H2O)6 · 2H2O |
| 8.DB.10 | Vashegyite | Al11(PO4)9(OH)6 · 38H2O |
| 8.DB.15 | Schoonerite | ZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2O |
| 8.DB.20 | Sinkankasite | Mn2+Al(PO3OH)2(OH) · 6H2O |
| 8.DB.25 | Mitryaevaite | Al6(PO4)((P,S)O3(OH,O))2F2(OH)2 · 14.5H2O |
| 8.DB.30 | Sanjuanite | Al2(PO4)(SO4)(OH) · 9H2O |
| 8.DB.35 | Sarmientite | Fe3+2(AsO4)(SO4)(OH) · 5H2O |
| 8.DB.40 | Bukovskýite | Fe3+2(AsO4)(SO4)(OH) · 9H2O |
| 8.DB.40 | Manganflurlite | ZnMn2+3Fe3+(PO4)3(OH)2(H2O)7 · 2H2O |
| 8.DB.40 | Flurlite | Zn3Mn2+Fe3+(PO4)3(OH)2 · 9H2O |
| 8.DB.42 | Bohuslavite | Fe3+4(PO4)3(SO4)(OH) · nH2O |
| 8.DB.45 | Zýkaite | Fe3+4(AsO4)3(SO4)(OH) · 15H2O |
| 8.DB.47 | Lapeyreite | Cu3O[AsO3(OH)]2 · 0.75H2O |
| 8.DB.50 | Rossiantonite | Al3(PO4)(SO4)2(OH)2(H2O)14 |
| 8.DB.50 | Giniite | Fe2+Fe3+4(PO4)3(OH)5 · 2H2O |
| 8.DB.52 | 'Arctowskite' | Al9(PO4)8(OH)3 · 27H2O |
| 8.DB.55 | Sasaite | (Al,Fe3+)14(PO4)11(SO4)(OH)7 · 83H2O |
| 8.DB.60 | Mcauslanite | Fe3Al2(PO4)3(PO3OH)F · 18H2O |
| 8.DB.65 | Goldquarryite | CuCd2Al3(PO4)4F2(H2O,F)2 · 10H2O |
| 8.DB.70 | Birchite | Cd2Cu2(PO4)2(SO4) · 5H2O |
| 8.DB.75 | Braithwaiteite | NaCu5(Ti4+Sb5+)(AsO4)4(HAsO4)2O2 · 8H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Wilhelmgümbelite
mindat.org URL:
https://www.mindat.org/min-46972.html
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References for Wilhelmgümbelite
Reference List:
www.nhm.org (2012) http://www.nhm.org/site/research-collections/mineral-sciences/research-studies/anthony-r-kampf
Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2016) New minerals and nomenclature modifications approved in 2015 and 2016, CNMNC Newsletter No 29. Mineralogical Magazine, 80 (1) 199-205 doi:10.1180/minmag.2016.080.080
Localities for Wilhelmgümbelite
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Germany (TL) | |
| Hålenius et al. (2016) +1 other reference |
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The
Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany