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Arctite

A valid IMA mineral species
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About ArctiteHide

Formula:
Na2Ca4(PO4)3F
Colour:
Colorless:
Lustre:
Vitreous, Sub-Vitreous, Pearly
Hardness:
5
Specific Gravity:
3.13
Crystal System:
Trigonal
Name:
Named in 1981 by Alexander Petrovich Khomyyakov, A. V. Bykova, and T. A. Kurova for the type locality's area, the Arctic region of Russia.
There is a structural relation to nabimusaite (and thus to nabimusaite-dargaite series): arctite-nabimusaite type triple layers of {[W3B12](TO4)4} composition are mentioned by Galuskin et al. (2016).


Unique IdentifiersHide

Mindat ID:
316
Long-form identifier:
mindat:1:1:316:4

Similar NamesHide

Aragotite(C,H)
ArgutiteA valid IMA mineral speciesGeO2

IMA Classification of ArctiteHide

Classification of ArctiteHide

8.BN.10

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
N : With only large cations, (OH, etc.):RO4 = 0.33:1
41.5.18.1

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
5 : (AB)2(XO4)Zq
22.1.6

22 : Phosphates, Arsenates or Vanadates with other Anions
1 : Phosphates, arsenates or vanadates with fluoride

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
ArcIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ArctiteHide

Vitreous, Sub-Vitreous, Pearly
Transparency:
Transparent, Translucent
Colour:
Colorless:
Streak:
Colorless
Hardness:
Tenacity:
Brittle
Cleavage:
Perfect
{0001}
Density:
3.13 g/cm3 (Measured)    3.19 g/cm3 (Calculated)

Optical Data of ArctiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.578 nε = 1.577
Birefringence:
0.001
Max. Birefringence:
δ = 0.001
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Pleochroism:
Non-pleochroic
Comments:
Anomalously biaxial

Chemistry of ArctiteHide

Mindat Formula:
Na2Ca4(PO4)3F
Element Weights:
Element% weight
O37.631 %
Ca31.421 %
P18.213 %
Na9.012 %
F3.724 %

Calculated from ideal end-member formula.

Chemical AnalysisHide

Oxide wt%:
 1
P2O533.83 %
SiO23.6 %
CaO31.8 %
BaO12 %
Na2O9.72 %
K2O1.64 %
Fe2O30.2 %
ZrO23.25 %
S0.22 %
F5.25 %
H2O0.5 %
Total:102.01 %

Crystallography of ArctiteHide

Crystal System:
Trigonal
Class (H-M):
3m(32/m) - Hexagonal Scalenohedral
Space Group:
R3m
Setting:
R3m
Cell Parameters:
a = 7.078 Å, c = 41.203 Å
Ratio:
a:c = 1 : 5.821
Unit Cell V:
1,787.64 ų (Calculated from Unit Cell)
Z:
6

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012475ArctiteSokolova E V, Yamnova N A, Egorov-Tismenko Y K, Khomyakov A P (1984) The crystal structure of a new phosphate of Na,Ca and Ba: (Na5Ca)Ca6Ba(PO4)6F3 Doklady Akademii Nauk SSSR 274 78-8319840293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
13.80 Å(25)
3.54 Å(21)
3.43 Å(32)
3.06 Å(25)
2.804 Å(25)
2.746 Å(100)
2.719 Å(21)
1.769 Å(20)
Comments:
ICDD 33-1228

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Stage 7: Great Oxidation Event<2.4
45b : [Other oxidized fumarolic minerals]

Type Occurrence of ArctiteHide

General Appearance of Type Material:
Colorless to white masses and rare crystals.
Place of Conservation of Type Material:
Mining Institute, St. Petersburg, Russia, 120/1.
Geology Museum, Kola Branch, Academy of Sciences, Apatity, Russia, 5708/2.
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 82132.
The Natural History Museum, London, England, 1994,2.
Geological Setting of Type Material:
Alkaline massif
Associated Minerals at Type Locality:

Synonyms of ArctiteHide

Other Language Names for ArctiteHide

Dutch:Arctiet
French:Arctite
Norwegian:Arctitt
Russian:Арктит
Spanish:Arctita

Relationship of Arctite to other SpeciesHide

Other Members of Arctite Group:
AriegilatiteBaCa12(SiO4)4(PO4)2F2OTrig. 3m(32/m) : R3m
DargaiteBaCa12(SiO4)4(SO4)2O3Trig. 3m(32/m) : R3m
NabimusaiteKCa12(SiO4)4(SO4)2O2FTrig. 3m(32/m) : R3m

Common AssociatesHide

Associations Based on Photo Data:
6 photos of Arctite associated with NatroliteNa2Al2Si3O10 · 2H2O
5 photos of Arctite associated with AegirineNaFe3+Si2O6
5 photos of Arctite associated with Lamprophyllite(Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2
1 photo of Arctite associated with SodaliteNa4(Si3Al3)O12Cl
1 photo of Arctite associated with VilliaumiteNaF

Related Minerals - Strunz-mindat GroupingHide

8.BN.FluoralforsiteBa5(PO4)3FHex. 6/m : P6/m
8.BN.AraditeBaCa6[(SiO4)(VO4)](VO4)2FTrig. 3m : R3m
8.BN.MagganasiteCuFe3+3O(AsO4)3Tric. 1 : P1
8.BN.FluorpyromorphitePb5(PO4)3FHex. 6/m : P63/m
8.BN.FluorsigaiiteCa2Sr3(PO4)3FHex. 6/m : P63/m
8.BN.05PieczkaiteMn5(PO4)3ClHex. 6/m : P63/m
8.BN.05FluorapatiteCa5(PO4)3FHex. 6/m : P63/m
8.BN.05FluorcaphiteSrCaCa3(PO4)3FHex. 6/m : P63/m
8.BN.05VanadinitePb5(VO4)3ClHex. 6/m : P63/m
8.BN.05HedyphaneCa2Pb3(AsO4)3ClHex. 6/mmm(6/m2/m2/m) : P63/mmc
8.BN.05HydroxylhedyphaneCa2Pb3(AsO4)3(OH)Trig. 3 : P3
8.BN.05'Mimetite-M'Pb5(AsO4)3ClMon. 2/m : P21/b
8.BN.05JohnbaumiteCa5(AsO4)3(OH)Hex. 6/m : P63/m
8.BN.05PliniusiteCa5(VO4)3FHex. 6/m : P63/m
8.BN.05'Hydroxylapatite-M'Ca5(PO4)3OHMon. 2/m : P21/b
8.BN.05HydroxylpyromorphitePb5(PO4)3(OH)Hex. 6/mmm(6/m2/m2/m) : P63/mcm
8.BN.05Miyahisaite(Sr,Ca)2Ba3(PO4)3F Hex. 6/m : P63/m
8.BN.05Carlgieseckeite-(Nd)NaNdCa3(PO4)3FTrig. 3 : P3
8.BN.05Belovite-(Ce)NaCeSr3(PO4)3FTrig. 3 : P3
8.BN.05Kuannersuite-(Ce)NaCeBa3(PO4)3F0.5Cl0.5Trig. 3 : P3
8.BN.05AlforsiteBa5(PO4)3ClHex. 6/m : P63/m
8.BN.05'Unnamed (OH-analogue of Mimetite)'Pb5(AsO4)3(OH)Hex. 6/m : P63/m
8.BN.05StronadelphiteSr5(PO4)3FHex. 6/m : P63/m
8.BN.05ParafiniukiteCa2Mn3(PO4)3ClHex. 6/m : P63/m
8.BN.05MimetitePb5(AsO4)3ClHex. 6/m : P63/m
8.BN.05 va'Germanate-pyromorphite'Pb5(PO4)2GeO4
8.BN.05Belovite-(La)NaLaSr3(PO4)3FTrig. 3 : P3
8.BN.05FluorphosphohedyphaneCa2Pb3(PO4)3FHex. 6/m : P63/m
8.BN.05FluorstrophiteSrCaSr3(PO4)3FHex. 6/m : P63/m
8.BN.05HydroxylapatiteCa5(PO4)3(OH)Hex. 6/m : P63/m
8.BN.05'Johnbaumite-M'Ca5(AsO4)3OHMon. 2/m : P21/m
8.BN.05PhosphohedyphaneCa2Pb3(PO4)3ClHex. 6/m : P63/m
8.BN.05TurneaureiteCa5(AsO4)3ClHex. 6/m : P63/m
8.BN.05MorelanditeCa2Ba3(AsO4)3ClHex.
8.BN.05'Oxypyromorphite'Pb10(PO4)6O
8.BN.05Deloneite(Na0.5REE0.25Ca0.25)(Ca0.75REE0.25)Sr1.5(CaNa0.25REE0.25)(PO4)3F0.5(OH)0.5Trig. 3 : P3
8.BN.05ChlorapatiteCa5(PO4)3ClHex. 6/m : P63/m
8.BN.05PyromorphitePb5(PO4)3ClHex. 6/m : P63/m
8.BN.05VanackeritePb4Cd(AsO4)3ClTrig. 3 : P3
8.BN.05SvabiteCa5(AsO4)3FHex. 6/mmm(6/m2/m2/m) : P63/mmc
8.BN.10KrügeriteBaCa6(SiO4)2[(P0.5S0.5)O4]2FTrig. 3m(32/m) : R3m
8.BN.15GoryainoviteCa2(PO4)ClOrth. mmm(2/m2/m2/m) : Pbcm

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ArctiteHide

References for ArctiteHide

Localities for ArctiteHide

Showing 6 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia
 
  • Murmansk Oblast
    • Koashva Mt
Arzamastsev et al. (2008)
[World of Stones 95:5-6
Pekov
...
Museum Victoria (Australia)
Khomyakov et al. (1983) +1 other reference
 
and/or  
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