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Fluorstrophite

A valid IMA mineral species
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About FluorstrophiteHide

Formula:
SrCaSr3(PO4)3F
Colour:
Green to yellow-green, colourless
Lustre:
Vitreous, Greasy
Hardness:
5
Crystal System:
Hexagonal
Name:
First named strontium-apatite by Efimov et al. in 1962. It was later changed to apatite-(SrOH) (Burke 2008) despite fluorine being dominant over hydroxyl. It was renamed to fluorstrophite by Pasero et al. (2010). The current name reflects the composition, including dominant fluorine, strontium, and phosphate.
This page provides mineralogical data about Fluorstrophite.


Unique IdentifiersHide

Mindat ID:
3757
Long-form identifier:
mindat:1:1:3757:6

IMA Classification of FluorstrophiteHide

Classification of FluorstrophiteHide

8.BN.05

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
N : With only large cations, (OH, etc.):RO4 = 0.33:1
41.8.1.7

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
8 : A5(XO4)3Zq
22.1.18

22 : Phosphates, Arsenates or Vanadates with other Anions
1 : Phosphates, arsenates or vanadates with fluoride

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
FstrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FluorstrophiteHide

Vitreous, Greasy
Transparency:
Transparent, Translucent
Colour:
Green to yellow-green, colourless
Hardness:

Optical Data of FluorstrophiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.651 nε = 1.637
Max. Birefringence:
δ = 0.014
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of FluorstrophiteHide

Mindat Formula:
SrCaSr3(PO4)3F
Element Weights:
Element% weight
Sr50.467 %
O27.646 %
P13.380 %
Ca5.771 %
F2.736 %

Calculated from ideal end-member formula.

Crystallography of FluorstrophiteHide

Crystal System:
Hexagonal
Class (H-M):
6/m - Dipyramidal
Space Group:
P63/m
Cell Parameters:
a = 9.565(8) Å, c = 7.115(3) Å
Ratio:
a:c = 1 : 0.744
Unit Cell V:
563.74 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Crystals short to long hexagonal prisms [0001], with {1010} and {1011} dominant; also thick tabular {0001}, frequently in the crystals of hydrothermal origin in pegmatites and veins, with {1010}, relatively large {0001}, and often also {1011} or low pyramids. Massive, coarse granular to compact.
Comment:
Space group P63/m or P63.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014055FluorstrophiteKlevtsova R F (1964) The crystal structure of strontium-apatite Journal of Structural Chemistry 5 318-32019640293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.89 Å(100)
3.167 Å(70)
2.78 Å(70)
1.909 Å(70)
1.467 Å(60)
2.32 Å(50)
2.147 Å(50)
1.953 Å(40)
1.849 Å(40)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
36 : Carbonatites, kimberlites, and related igneous rocks

Type Occurrence of FluorstrophiteHide

General Appearance of Type Material:
Poorly formed oval crystals 0.2x1 cm in longitudinal section and as small crystals with corroded faces.
Geological Setting of Type Material:
Alkalic pegmatites
Associated Minerals at Type Locality:

Synonyms of FluorstrophiteHide

Other Language Names for FluorstrophiteHide

Relationship of Fluorstrophite to other SpeciesHide

Other Members of Belovite Group:
Belovite-(Ce)NaCeSr3(PO4)3FTrig. 3 : P3
Belovite-(La)NaLaSr3(PO4)3FTrig. 3 : P3
Carlgieseckeite-(Nd)NaNdCa3(PO4)3FTrig. 3 : P3
Deloneite(Na0.5REE0.25Ca0.25)(Ca0.75REE0.25)Sr1.5(CaNa0.25REE0.25)(PO4)3F0.5(OH)0.5Trig. 3 : P3
FluorcaphiteSrCaCa3(PO4)3FHex. 6/m : P63/m
Kuannersuite-(Ce)NaCeBa3(PO4)3F0.5Cl0.5Trig. 3 : P3

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Fluorstrophite associated with Magnesio-arfvedsoniteNaNa2(Mg4Fe3+)(Si8O22)(OH)2
2 photos of Fluorstrophite associated with OrthoclaseK(AlSi3O8)
1 photo of Fluorstrophite associated with SideriteFeCO3
1 photo of Fluorstrophite associated with MarcasiteFeS2
1 photo of Fluorstrophite associated with TitaniteCaTiO(SiO4)
1 photo of Fluorstrophite associated with 'Strontium-bearing Thomsonite'Na(Ca,Sr)2[Al5Si5O20] · 6H2O

Related Minerals - Strunz-mindat GroupingHide

8.BN.FluoralforsiteBa5(PO4)3FHex. 6/m : P6/m
8.BN.AraditeBaCa6[(SiO4)(VO4)](VO4)2FTrig. 3m : R3m
8.BN.MagganasiteCuFe3+3O(AsO4)3Tric. 1 : P1
8.BN.FluorpyromorphitePb5(PO4)3FHex. 6/m : P63/m
8.BN.FluorsigaiiteCa2Sr3(PO4)3FHex. 6/m : P63/m
8.BN.05PieczkaiteMn5(PO4)3ClHex. 6/m : P63/m
8.BN.05FluorapatiteCa5(PO4)3FHex. 6/m : P63/m
8.BN.05FluorcaphiteSrCaCa3(PO4)3FHex. 6/m : P63/m
8.BN.05VanadinitePb5(VO4)3ClHex. 6/m : P63/m
8.BN.05HedyphaneCa2Pb3(AsO4)3ClHex. 6/mmm(6/m2/m2/m) : P63/mmc
8.BN.05HydroxylhedyphaneCa2Pb3(AsO4)3(OH)Trig. 3 : P3
8.BN.05'Mimetite-M'Pb5(AsO4)3ClMon. 2/m : P21/b
8.BN.05JohnbaumiteCa5(AsO4)3(OH)Hex. 6/m : P63/m
8.BN.05PliniusiteCa5(VO4)3FHex. 6/m : P63/m
8.BN.05'Hydroxylapatite-M'Ca5(PO4)3OHMon. 2/m : P21/b
8.BN.05HydroxylpyromorphitePb5(PO4)3(OH)Hex. 6/mmm(6/m2/m2/m) : P63/mcm
8.BN.05Miyahisaite(Sr,Ca)2Ba3(PO4)3F Hex. 6/m : P63/m
8.BN.05Carlgieseckeite-(Nd)NaNdCa3(PO4)3FTrig. 3 : P3
8.BN.05Belovite-(Ce)NaCeSr3(PO4)3FTrig. 3 : P3
8.BN.05Kuannersuite-(Ce)NaCeBa3(PO4)3F0.5Cl0.5Trig. 3 : P3
8.BN.05AlforsiteBa5(PO4)3ClHex. 6/m : P63/m
8.BN.05'Unnamed (OH-analogue of Mimetite)'Pb5(AsO4)3(OH)Hex. 6/m : P63/m
8.BN.05StronadelphiteSr5(PO4)3FHex. 6/m : P63/m
8.BN.05ParafiniukiteCa2Mn3(PO4)3ClHex. 6/m : P63/m
8.BN.05MimetitePb5(AsO4)3ClHex. 6/m : P63/m
8.BN.05 va'Germanate-pyromorphite'Pb5(PO4)2GeO4
8.BN.05Belovite-(La)NaLaSr3(PO4)3FTrig. 3 : P3
8.BN.05FluorphosphohedyphaneCa2Pb3(PO4)3FHex. 6/m : P63/m
8.BN.05HydroxylapatiteCa5(PO4)3(OH)Hex. 6/m : P63/m
8.BN.05'Johnbaumite-M'Ca5(AsO4)3OHMon. 2/m : P21/m
8.BN.05PhosphohedyphaneCa2Pb3(PO4)3ClHex. 6/m : P63/m
8.BN.05TurneaureiteCa5(AsO4)3ClHex. 6/m : P63/m
8.BN.05MorelanditeCa2Ba3(AsO4)3ClHex.
8.BN.05'Oxypyromorphite'Pb10(PO4)6O
8.BN.05Deloneite(Na0.5REE0.25Ca0.25)(Ca0.75REE0.25)Sr1.5(CaNa0.25REE0.25)(PO4)3F0.5(OH)0.5Trig. 3 : P3
8.BN.05ChlorapatiteCa5(PO4)3ClHex. 6/m : P63/m
8.BN.05PyromorphitePb5(PO4)3ClHex. 6/m : P63/m
8.BN.05VanackeritePb4Cd(AsO4)3ClTrig. 3 : P3
8.BN.05SvabiteCa5(AsO4)3FHex. 6/mmm(6/m2/m2/m) : P63/mmc
8.BN.10ArctiteNa2Ca4(PO4)3FTrig. 3m(32/m) : R3m
8.BN.10KrügeriteBaCa6(SiO4)2[(P0.5S0.5)O4]2FTrig. 3m(32/m) : R3m
8.BN.15GoryainoviteCa2(PO4)ClOrth. mmm(2/m2/m2/m) : Pbcm

Other InformationHide

Notes:
Soluble in HCl or in HNO3. Varieties containing CO3 may dissolve with slight effervescence.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FluorstrophiteHide

References for FluorstrophiteHide

Reference List:

Localities for FluorstrophiteHide

Showing 13 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Tasmania
    • Huon Valley municipality
      • Huon-Channel region
        • Cygnet district
Bottrill (2021)
Canada
 
  • Northwest Territories
Anton R. Chakhmouradian and Roger H. Mitchell (2001)
  • Ontario
    • Thunder Bay District
      • O'Meara Township
Platt & Wooley (1990)
Japan
 
  • Niigata Prefecture
Mandarino (2002)
Sakai & Akai (1988)
Mexico
 
  • Guanajuato
    • Guanajuato Municipality
      • Guanajuato
Alejandro Felix Collection
Russia
 
  • Aldan Shield
    • Chara and Tokko Rivers Confluence
Canadian Mineralogist 40:121-136
  • Khabarovsk Krai
    • Ayano-Maysky district
Osipov et al. (2021)
  • Murmansk Oblast
...
  • Sakha
    • Aldan
      • Inagli Massif
Pekov (1998)
South Africa
 
  • North West
    • Bojanala Platinum District Municipality
      • Moses Kotane Local Municipality
Mitchell et al. (2004)
USA
 
  • California
    • San Benito County
      • Picacho Peak
Cooper et al. (2003)
Zambia
 
  • Muchinga Province
    • Isoka District
      • Isoka
 
and/or  
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