Pieczkaite
A valid IMA mineral species
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About Pieczkaite
Formula:
Mn5(PO4)3Cl
Colour:
Grey
Hardness:
4 - 5
Specific Gravity:
3.783 (Calculated)
Crystal System:
Hexagonal
Member of:
Name:
After Adam Pieczka (born September 8, 1957, at Wilamowice near Bielsko-Biała, Silesia Province, Poland), Assistant Professor in the Department of Mineralogy, Petrography, and Geochemistry, Faculty of Geology, Geophysics, and Environmental Protection, Kraków, Poland, for his extensive contributions to the crystal chemistry of pegmatite minerals.
Isostructural with:
This page provides mineralogical data about Pieczkaite.
Unique Identifiers
Mindat ID:
46099
Long-form identifier:
mindat:1:1:46099:8
IMA Classification of Pieczkaite
Classification of Pieczkaite
8.BN.05
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
N : With only large cations, (OH, etc.):RO4 = 0.33:1
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
N : With only large cations, (OH, etc.):RO4 = 0.33:1
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Pzk | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Pronunciation of Pieczkaite
Pronunciation:
| Play | Recorded by | Country |
|---|---|---|
| Łukasz Kruszewski | Poland |
Physical Properties of Pieczkaite
Colour:
Grey
Streak:
Grayish-white
Hardness:
4 - 5 on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Parting:
None observed
Fracture:
Irregular/Uneven
Density:
3.783 g/cm3 (Calculated)
Optical Data of Pieczkaite
Type:
Uniaxial (-)
RI values:
nω = 1.694 - 1.698 nε = 1.690 - 1.694
Max. Birefringence:
δ = 0.004
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic
(convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis
centred and vertical. The coloured rings are isochromatics, computed with the
same physics as the Michel-Lévy bar above; the dark cross is the isogyre.
For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Chemistry of Pieczkaite
Mindat Formula:
Mn5(PO4)3Cl
Element Weights:
Elements listed:
Crystallography of Pieczkaite
Crystal System:
Hexagonal
Class (H-M):
6/m - Dipyramidal
Space Group:
P63/m
Setting:
P63/m
Cell Parameters:
a = 9.504(4) Å, c = 6.347(3) Å
Ratio:
a:c = 1 : 0.668
Unit Cell V:
496.5 ų
Z:
2
Morphology:
Narrow veins to ~25 μm in apatite.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0020469 | Pieczkaite | Tait K, Ball N A, Hawthorne F C (2015) Pieczkaite, ideally Mn5(PO4)3Cl, a new apatite-supergroup mineral from Cross Lake, Manitoba, Canada: Description and crystal structure American Mineralogist 100 1047-1052 | 2015 | Cross Lake, Manitoba, Canada | 0 | 293 | |
| 0020231 | Pieczkaite | Engel G, Pretzsch J, Gramlich V, Baur W H (1975) The crystal structure of hydrothermally grown manganese chlorapatite, Mn5(PO4)3Cl0.9(OH)0.1 Acta Crystallographica B31 1854-1860 |  | 1975 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.453 Å | (15) |
| 3.174 Å | (24) |
| 2.794 Å | (100) |
| 2.744 Å | (88) |
| 2.639 Å | (34) |
| 2.514 Å | (25) |
| 1.853 Å | (25) |
| 1.750 Å | (22) |
Comments:
From Type Description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites |
Type Occurrence of Pieczkaite
General Appearance of Type Material:
As small patches and narrow veins in large crystals of apatite and (Mn,Cl)-bearing apatite in phosphate pods in the quartz core of a granitic pegmatite.
Place of Conservation of Type Material:
Type material is deposited in the collections of the Department of Natural History (Mineralogy), Royal Ontario Museum, 100 Queens Park, Toronto, Ontario M5S 2C6, Canada, catalogue number M56483
Geological Setting of Type Material:
Granite pegmatite.
Associated Minerals at Type Locality:
Synonyms of Pieczkaite
Other Language Names for Pieczkaite
Dutch:Pieczkaiet
German:Pieczkait
Relationship of Pieczkaite to other Species
Member of:
Other Members of Apatite Group:
| Alforsite | Ba5(PO4)3Cl | Hex. 6/m : P63/m |
| 'Apatite' | Ca5(PO4)3A | |
| Chlorapatite | Ca5(PO4)3Cl | Hex. 6/m : P63/m |
| Fluoralforsite | Ba5(PO4)3F | Hex. 6/m : P6/m |
| Fluorapatite | Ca5(PO4)3F | Hex. 6/m : P63/m |
| Fluorpyromorphite | Pb5(PO4)3F | Hex. 6/m : P63/m |
| Hydroxylapatite | Ca5(PO4)3(OH) | Hex. 6/m : P63/m |
| Hydroxylpyromorphite | Pb5(PO4)3(OH) | Hex. 6/mmm(6/m2/m2/m) : P63/mcm |
| Johnbaumite | Ca5(AsO4)3(OH) | Hex. 6/m : P63/m |
| Mimetite | Pb5(AsO4)3Cl | Hex. 6/m : P63/m |
| 'Oxypyromorphite' | Pb10(PO4)6O | |
| Pliniusite | Ca5(VO4)3F | Hex. 6/m : P63/m |
| Pyromorphite | Pb5(PO4)3Cl | Hex. 6/m : P63/m |
| Stronadelphite | Sr5(PO4)3F | Hex. 6/m : P63/m |
| Svabite | Ca5(AsO4)3F | Hex. 6/mmm(6/m2/m2/m) : P63/mmc |
| Turneaureite | Ca5(AsO4)3Cl | Hex. 6/m : P63/m |
| 'Unnamed (OH-analogue of Mimetite)' | Pb5(AsO4)3(OH) | Hex. 6/m : P63/m |
| Vanadinite | Pb5(VO4)3Cl | Hex. 6/m : P63/m |
Common Associates
Associations Based on Photo Data:
| 1 photo of Pieczkaite associated with Manitobaite | Na16Mn2+ 25Al8(PO4)30 |
Related Minerals - Strunz-mindat Grouping
| 8.BN. | Fluoralforsite | Ba5(PO4)3F |
| 8.BN. | Aradite | BaCa6[(SiO4)(VO4)](VO4)2F |
| 8.BN. | Magganasite | CuFe3+3O(AsO4)3 |
| 8.BN. | Fluorpyromorphite | Pb5(PO4)3F |
| 8.BN. | Fluorsigaiite | Ca2Sr3(PO4)3F |
| 8.BN.05 | Fluorapatite | Ca5(PO4)3F |
| 8.BN.05 | Fluorcaphite | SrCaCa3(PO4)3F |
| 8.BN.05 | Vanadinite | Pb5(VO4)3Cl |
| 8.BN.05 | Hedyphane | Ca2Pb3(AsO4)3Cl |
| 8.BN.05 | Hydroxylhedyphane | Ca2Pb3(AsO4)3(OH) |
| 8.BN.05 | 'Mimetite-M' | Pb5(AsO4)3Cl |
| 8.BN.05 | Johnbaumite | Ca5(AsO4)3(OH) |
| 8.BN.05 | Pliniusite | Ca5(VO4)3F |
| 8.BN.05 | 'Hydroxylapatite-M' | Ca5(PO4)3OH |
| 8.BN.05 | Hydroxylpyromorphite | Pb5(PO4)3(OH) |
| 8.BN.05 | Miyahisaite | (Sr,Ca)2Ba3(PO4)3F |
| 8.BN.05 | Carlgieseckeite-(Nd) | NaNdCa3(PO4)3F |
| 8.BN.05 | Belovite-(Ce) | NaCeSr3(PO4)3F |
| 8.BN.05 | Kuannersuite-(Ce) | NaCeBa3(PO4)3F0.5Cl0.5 |
| 8.BN.05 | Alforsite | Ba5(PO4)3Cl |
| 8.BN.05 | 'Unnamed (OH-analogue of Mimetite)' | Pb5(AsO4)3(OH) |
| 8.BN.05 | Stronadelphite | Sr5(PO4)3F |
| 8.BN.05 | Parafiniukite | Ca2Mn3(PO4)3Cl |
| 8.BN.05 | Mimetite | Pb5(AsO4)3Cl |
| 8.BN.05 va | 'Germanate-pyromorphite' | Pb5(PO4)2GeO4 |
| 8.BN.05 | Belovite-(La) | NaLaSr3(PO4)3F |
| 8.BN.05 | Fluorphosphohedyphane | Ca2Pb3(PO4)3F |
| 8.BN.05 | Fluorstrophite | SrCaSr3(PO4)3F |
| 8.BN.05 | Hydroxylapatite | Ca5(PO4)3(OH) |
| 8.BN.05 | 'Johnbaumite-M' | Ca5(AsO4)3OH |
| 8.BN.05 | Phosphohedyphane | Ca2Pb3(PO4)3Cl |
| 8.BN.05 | Turneaureite | Ca5(AsO4)3Cl |
| 8.BN.05 | Morelandite | Ca2Ba3(AsO4)3Cl |
| 8.BN.05 | 'Oxypyromorphite' | Pb10(PO4)6O |
| 8.BN.05 | Deloneite | (Na0.5REE0.25Ca0.25)(Ca0.75REE0.25)Sr1.5(CaNa0.25REE0.25)(PO4)3F0.5(OH)0.5 |
| 8.BN.05 | Chlorapatite | Ca5(PO4)3Cl |
| 8.BN.05 | Pyromorphite | Pb5(PO4)3Cl |
| 8.BN.05 | Vanackerite | Pb4Cd(AsO4)3Cl |
| 8.BN.05 | Svabite | Ca5(AsO4)3F |
| 8.BN.10 | Arctite | Na2Ca4(PO4)3F |
| 8.BN.10 | Krügerite | BaCa6(SiO4)2[(P0.5S0.5)O4]2F |
| 8.BN.15 | Goryainovite | Ca2(PO4)Cl |
Fluorescence of Pieczkaite
Does not fluoresce under ultraviolet light
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Pieczkaite
mindat.org URL:
https://www.mindat.org/min-46099.html
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Please feel free to link to this page.
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References for Pieczkaite
Reference List:
Engel, G.; Pretzsch, J.; Gramlich, V.; Baur, W. H. (1975) The crystal structure of hydrothermally grown manganese chlorapatite, Mn5(PO4)3Cl0.9(OH)0.1. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 31 (7). 1854-1860 doi:10.1107/s056774087500636x
Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2014) New minerals and nomenclature modifications approved in 2014, CNMNC Newsletter No 20. Mineralogical Magazine, 78 (3) 549-558 doi:10.1180/minmag.2014.078.3.05
Localities for Pieczkaite
Showing 3 localities.
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Canada (TL) | |
| Williams et al. (2014) +1 other reference |
Poland | |
| Twardak et al. (2018) |
| Pieczka et al. (2015) +2 other references |
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Pegmatite No. 22, North Group, Cross Lake, Manitoba, Canada