Fluorsigaiite
A valid IMA mineral species
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Formula:
Ca2Sr3(PO4)3F
Colour:
colourless to yellowish white
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
3.842 (Calculated)
Crystal System:
Hexagonal
Member of:
The Sr analogue of fluorphosphohedyphane (Pb-dominant). Ca2Sr3-analogue of miyahisaite (Sr2Ba3-dominant).
Chemically similar to two other apatite supergroup species, fluorcaphite and fluorstrophite; also compare 'Strontium-bearing Apatite'.
Ca and Sr dominate at the Ca1 and Ca2 sites, respectively.
Chemically similar to two other apatite supergroup species, fluorcaphite and fluorstrophite; also compare 'Strontium-bearing Apatite'.
Ca and Sr dominate at the Ca1 and Ca2 sites, respectively.
Unique Identifiers
Mindat ID:
56027
Long-form identifier:
mindat:1:1:56027:0
IMA Classification of Fluorsigaiite
Approved
Approval year:
2021
Approval history:
IMA no. 2021-087a
Type description reference:
Wu, Bin, Gu, Xiang-ping, Rao, Can, Wang, Ru-cheng, Xing, Xing-qing, Zhong, Fu-jun, Wan, Jian-jun, Bonnetti, Christophe (2022) Fluorsigaiite, Ca2Sr3(PO4)3F, a new mineral of the apatite supergroup from the Saima alkaline complex, Liaoning Province, China. Mineralogical Magazine, 86 (6) 940-947 doi:10.1180/mgm.2022.96
Classification of Fluorsigaiite
8.BN.
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
N : With only large cations, (OH, etc.):RO4 = 0.33:1
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
N : With only large cations, (OH, etc.):RO4 = 0.33:1
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Fsig | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Fluorsigaiite
Vitreous
Transparency:
Transparent, Translucent
Colour:
Colourless to yellowish white
Hardness:
5 on Mohs scale
Tenacity:
Brittle
Fracture:
Irregular/Uneven
Density:
3.842 g/cm3 (Calculated)
Optical Data of Fluorsigaiite
Type:
Uniaxial (-)
RI values:
nω = 1.64(1) nε = 1.63(1)
Max. Birefringence:
δ = 0.010
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Moderate
Dispersion:
no
Chemistry of Fluorsigaiite
Mindat Formula:
Ca2Sr3(PO4)3F
Element Weights:
Crystallography of Fluorsigaiite
Crystal System:
Hexagonal
Class (H-M):
6/m - Dipyramidal
Space Group:
P63/m
Cell Parameters:
a = 9.6101(2) Å, c = 7.1311(1) Å
Ratio:
a:c = 1 : 0.742
Unit Cell V:
570.35 ų (Calculated from Unit Cell)
Z:
2
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.563 Å | (15) |
| 3.275 Å | (15) |
| 3.144 Å | (19) |
| 2.876 Å | (100) |
| 2.861 Å | (96) |
| 2.772 Å | (27) |
| 1.991 Å | (16) |
| 1.895 Å | (23) |
Reference:
Wu, Bin, Gu, Xiang-ping, Rao, Can, Wang, Ru-cheng, Xing, Xing-qing, Zhong, Fu-jun, Wan, Jian-jun, Bonnetti, Christophe (2022) Fluorsigaiite, Ca2Sr3(PO4)3F, a new mineral of the apatite supergroup from the Saima alkaline complex, Liaoning Province, China. Mineralogical Magazine, 86 (6) 940-947 doi:10.1180/mgm.2022.96
Type Occurrence of Fluorsigaiite
General Appearance of Type Material:
individual, prismatic, columnar and platy crystal, 10-50 μm in size; more rarely: prismatic aggregates in interstices
Place of Conservation of Type Material:
mineralogical collections of the Geological Museum of China, No. 16, Yangrou Hu, Xisi, Beijing 100031, People’s Republic of China, catalogue number M16130
Geological Setting of Type Material:
lujavrite; probably formed from Sr-rich fluids at late-magmatic or hydrothermal stage
Associated Minerals at Type Locality:
Reference:
Wu, Bin, Gu, Xiang-ping, Rao, Can, Wang, Ru-cheng, Xing, Xing-qing, Zhong, Fu-jun, Wan, Jian-jun, Bonnetti, Christophe (2022) Fluorsigaiite, Ca2Sr3(PO4)3F, a new mineral of the apatite supergroup from the Saima alkaline complex, Liaoning Province, China. Mineralogical Magazine, 86 (6) 940-947 doi:10.1180/mgm.2022.96
Synonyms of Fluorsigaiite
Other Language Names for Fluorsigaiite
Dutch:Fluorsigaiiet
German:Fluorsigaiit
Relationship of Fluorsigaiite to other Species
Member of:
Other Members of Hedyphane Group:
| Aiolosite | Na4Bi(SO4)3Cl | Hex. 6/m : P63/m |
| Caracolite | Na3Pb2(SO4)3Cl | Mon. 2/m : P21/m |
| Cesanite | Na3Ca2(SO4)3(OH) | Hex. 6 : P6 |
| Fluorphosphohedyphane | Ca2Pb3(PO4)3F | Hex. 6/m : P63/m |
| Hedyphane | Ca2Pb3(AsO4)3Cl | Hex. 6/mmm(6/m2/m2/m) : P63/mmc |
| Hydroxylhedyphane | Ca2Pb3(AsO4)3(OH) | Trig. 3 : P3 |
| Miyahisaite | (Sr,Ca)2Ba3(PO4)3F | Hex. 6/m : P63/m |
| Morelandite | Ca2Ba3(AsO4)3Cl | Hex. |
| Parafiniukite | Ca2Mn3(PO4)3Cl | Hex. 6/m : P63/m |
| Phosphohedyphane | Ca2Pb3(PO4)3Cl | Hex. 6/m : P63/m |
| 'UM2002-53-PO:CaHPb' | Ca2Pb3(PO4)3(OH,Cl,F) |
Related Minerals - Strunz-mindat Grouping
| 8.BN. | Fluoralforsite | Ba5(PO4)3F |
| 8.BN. | Aradite | BaCa6[(SiO4)(VO4)](VO4)2F |
| 8.BN. | Magganasite | CuFe3+3O(AsO4)3 |
| 8.BN. | Fluorpyromorphite | Pb5(PO4)3F |
| 8.BN.05 | Pieczkaite | Mn5(PO4)3Cl |
| 8.BN.05 | Fluorapatite | Ca5(PO4)3F |
| 8.BN.05 | Fluorcaphite | SrCaCa3(PO4)3F |
| 8.BN.05 | Vanadinite | Pb5(VO4)3Cl |
| 8.BN.05 | Hedyphane | Ca2Pb3(AsO4)3Cl |
| 8.BN.05 | Hydroxylhedyphane | Ca2Pb3(AsO4)3(OH) |
| 8.BN.05 | 'Mimetite-M' | Pb5(AsO4)3Cl |
| 8.BN.05 | Johnbaumite | Ca5(AsO4)3(OH) |
| 8.BN.05 | Pliniusite | Ca5(VO4)3F |
| 8.BN.05 | 'Hydroxylapatite-M' | Ca5(PO4)3OH |
| 8.BN.05 | Hydroxylpyromorphite | Pb5(PO4)3(OH) |
| 8.BN.05 | Miyahisaite | (Sr,Ca)2Ba3(PO4)3F |
| 8.BN.05 | Carlgieseckeite-(Nd) | NaNdCa3(PO4)3F |
| 8.BN.05 | Belovite-(Ce) | NaCeSr3(PO4)3F |
| 8.BN.05 | Kuannersuite-(Ce) | NaCeBa3(PO4)3F0.5Cl0.5 |
| 8.BN.05 | Alforsite | Ba5(PO4)3Cl |
| 8.BN.05 | 'Unnamed (OH-analogue of Mimetite)' | Pb5(AsO4)3(OH) |
| 8.BN.05 | Stronadelphite | Sr5(PO4)3F |
| 8.BN.05 | Parafiniukite | Ca2Mn3(PO4)3Cl |
| 8.BN.05 | Mimetite | Pb5(AsO4)3Cl |
| 8.BN.05 va | 'Germanate-pyromorphite' | Pb5(PO4)2GeO4 |
| 8.BN.05 | Belovite-(La) | NaLaSr3(PO4)3F |
| 8.BN.05 | Fluorphosphohedyphane | Ca2Pb3(PO4)3F |
| 8.BN.05 | Fluorstrophite | SrCaSr3(PO4)3F |
| 8.BN.05 | Hydroxylapatite | Ca5(PO4)3(OH) |
| 8.BN.05 | 'Johnbaumite-M' | Ca5(AsO4)3OH |
| 8.BN.05 | Phosphohedyphane | Ca2Pb3(PO4)3Cl |
| 8.BN.05 | Turneaureite | Ca5(AsO4)3Cl |
| 8.BN.05 | Morelandite | Ca2Ba3(AsO4)3Cl |
| 8.BN.05 | 'Oxypyromorphite' | Pb10(PO4)6O |
| 8.BN.05 | Deloneite | (Na0.5REE0.25Ca0.25)(Ca0.75REE0.25)Sr1.5(CaNa0.25REE0.25)(PO4)3F0.5(OH)0.5 |
| 8.BN.05 | Chlorapatite | Ca5(PO4)3Cl |
| 8.BN.05 | Pyromorphite | Pb5(PO4)3Cl |
| 8.BN.05 | Vanackerite | Pb4Cd(AsO4)3Cl |
| 8.BN.05 | Svabite | Ca5(AsO4)3F |
| 8.BN.10 | Arctite | Na2Ca4(PO4)3F |
| 8.BN.10 | Krügerite | BaCa6(SiO4)2[(P0.5S0.5)O4]2F |
| 8.BN.15 | Goryainovite | Ca2(PO4)Cl |
Fluorescence of Fluorsigaiite
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Fluorsigaiite
mindat.org URL:
https://www.mindat.org/min-56027.html
Please feel free to link to this page.
Please feel free to link to this page.
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External Links:
Mineral Dealers:
References for Fluorsigaiite
Reference List:
Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 67. European Journal of Mineralogy, 34 (3) 359-364 doi:10.5194/ejm-34-359-2022
Wu, Bin, Gu, Xiang-ping, Rao, Can, Wang, Ru-cheng, Xing, Xing-qing, Zhong, Fu-jun, Wan, Jian-jun, Bonnetti, Christophe (2022) Fluorsigaiite, Ca2Sr3(PO4)3F, a new mineral of the apatite supergroup from the Saima alkaline complex, Liaoning Province, China. Mineralogical Magazine, 86 (6) 940-947 doi:10.1180/mgm.2022.96
Localities for Fluorsigaiite
Showing 4 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Australia | |
| Bottrill (2021) |
China (TL) | |
| Miyawaki et al. (2022) |
| Wu et al. (2023) |
Czech Republic | |
| Jirasek et al. (2026) |
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