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Chlorocalcite

A valid IMA mineral species - grandfathered
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About ChlorocalciteHide

Formula:
KCaCl3
Colour:
White, violet tinged
Hardness:
2½ - 3
Crystal System:
Orthorhombic
Name:
In allusion to the composition, containing both CHLORine and CALCium.
Isostructural with:
The Ca analogue of javorieite.

Note: possibly isostructural with javorieite (if the synthetic KCaCl3 analogue is indeed structurally identical to chlorocalcite).


Unique IdentifiersHide

Mindat ID:
1020
Long-form identifier:
mindat:1:1:1020:3

IMA Classification of ChlorocalciteHide

Approved, 'Grandfathered' (first described prior to 1959)

Classification of ChlorocalciteHide

3.AA.40

3 : HALIDES
A : Simple halides, without H2O
A : M:X = 1:1, 2:3, 3:5, etc.
11.1.3.1

11 : HALIDE COMPLEXES
1 : AmBX3
8.4.10

8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
4 : Halides of the alkaline earths and Mg

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
CcalIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of ChlorocalciteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of ChlorocalciteHide

Transparency:
Transparent
Colour:
White, violet tinged
Hardness:
2½ - 3 on Mohs scale
Cleavage:
Distinct/Good
Cube-like in two directions, one better than the other.

Optical Data of ChlorocalciteHide

Type:
Biaxial
Dispersion:
not discernible

Chemistry of ChlorocalciteHide

Mindat Formula:
KCaCl3
Element Weights:
Element% weight
Cl57.326 %
Ca21.601 %
K21.073 %

Calculated from ideal end-member formula.

Crystallography of ChlorocalciteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pnma
Setting:
Pnma
Cell Parameters:
a = 7.35 Å, b = 10.44 Å, c = 7.25 Å
Ratio:
a:b:c = 0.704 : 1 : 0.694
Unit Cell V:
556.32 ų (Calculated from Unit Cell)
Morphology:
Cube-like crystals, with octahedral or dodecahedral-like truncations at times. Prismatic with {100}, {010}, and {011} or tabular with {001}, {110}, and {100}.
Comment:
Space group for the synthetic phase

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.612 Å(100)
3.137 Å(35)
3.697 Å(30)
3.119 Å(30)
5.227 Å(25)
2.107 Å(25)
3.058 Å(18)
Comments:
Synthetic. Data from Swanson et al. (1969).

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
25 : Evaporites (prebiotic)
Stage 7: Great Oxidation Event<2.4
45b : [Other oxidized fumarolic minerals]

Type Occurrence of ChlorocalciteHide

Place of Conservation of Type Material:
No defined type material.
Geological Setting of Type Material:
Active volcanic fumaroles.
Associated Minerals at Type Locality:

Synonyms of ChlorocalciteHide

Other Language Names for ChlorocalciteHide

Relationship of Chlorocalcite to other SpeciesHide

Common AssociatesHide

Associations Based on Photo Data:
2 photos of Chlorocalcite associated with SylviteKCl
1 photo of Chlorocalcite associated with HaliteNaCl

Related Minerals - Strunz-mindat GroupingHide

3.AA.Brontesite(NH4)3PbCl5Orth. mmm(2/m2/m2/m) : Pnma
3.AA.05MarshiteCuIIso. 43m : F43m
3.AA.05NantokiteCuClIso. 43m : F43m
3.AA.05'UM1999-11:I:CuS'Cu(I,S)
3.AA.05Miersite(Ag,Cu)IIso. 43m : F43m
3.AA.10Tocornalite(Ag,Hg)I (?)Hex.
3.AA.10IodargyriteAgIHex. 6mm : P6mm
3.AA.15BromargyriteAgBrIso. m3m(4/m32/m) : Fm3m
3.AA.15ChlorargyriteAgClIso. m3m(4/m32/m) : Fm3m
3.AA.20SylviteKClIso. m3m(4/m32/m) : Fm3m
3.AA.20HaliteNaClIso. m3m(4/m32/m) : Fm3m
3.AA.20VilliaumiteNaFIso. m3m(4/m32/m) : Fd3m
3.AA.20CarobbiiteKFIso. m3m(4/m32/m) : Fm3m
3.AA.20GriceiteLiFIso. m3m(4/m32/m) : Fm3m
3.AA.25'UM1998-03-Cl:Tl'TlCl
3.AA.25NataliyamalikiteTlIOrth. mmm(2/m2/m2/m) : Cmcm
3.AA.25LafossaiteTl(Cl,Br)Iso. m3m(4/m32/m) : Pm3m
3.AA.25SalammoniacNH4ClIso. m3m(4/m32/m)
3.AA.30Calomel[Hg2]2+Cl2Tet. 4/mmm(4/m2/m2/m) : I4/mmm
3.AA.30Moschelite[Hg2]2+I2Tet. 4/mmm(4/m2/m2/m) : I4/mmm
3.AA.30KuzminiteHgBrTet. 4/mmm(4/m2/m2/m) : I4/mmm
3.AA.35NeighboriteNaMgF3Orth. mmm(2/m2/m2/m)
3.AA.35ParascandolaiteKMgF3Iso. m3m(4/m32/m) : Pm3m
3.AA.40JavorieiteKFeCl3Orth. mmm(2/m2/m2/m) : Pnma
3.AA.45KolaritePbTeCl2Orth.
3.AA.50RadhakrishnaitePbTe3(Cl,S)2Tet.
3.AA.55ChallacolloiteKPb2Cl5Mon. 2/m : P21/b
3.AA.60HephaistositeTlPb2Cl5Mon. 2/m : P21/b
3.AA.90PseudocotunniteK2PbCl4Orth.

RadioactivityHide

Fluorescence of ChlorocalciteHide

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ChlorocalciteHide

References for ChlorocalciteHide

Reference List:

Localities for ChlorocalciteHide

Showing 6 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
China
 
  • Yunnan
    • Pu'er
      • Jiangcheng County
Li et al. (2015)
Germany
 
  • Lower Saxony
    • Hildesheim District
      • Alfeld
Palache et al. (1951)
Italy (TL)
 
  • Campania
    • Metropolitan City of Naples
Palache et al. (1951) +1 other reference
Pelloux (1927) +3 other references
Russia
 
  • Udmurt Republic
    • Votkinsky District
webmineral.ru (n.d.)
Slovakia
 
  • Banská Bystrica Region
    • Detva District
      • Detva
Kodera et al. (2025)
 
and/or  
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