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Sidpietersite

A valid IMA mineral species
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About SidpietersiteHide

Formula:
Pb2+4(S2O3)O2(OH)2
Colour:
Colourless, beige
Lustre:
Vitreous, Earthy
Hardness:
1 - 2
Specific Gravity:
6.765 (Calculated)
Crystal System:
Triclinic
Name:
Named after Sidney Pieters (1920-2003), of Windhoek, Namibia for his outstanding contributions to Namibian mineralogy.
One of a relatively small group of thiosulphate minerals.

The thiosulphate analogue of kennygayite.


Unique IdentifiersHide

Mindat ID:
7293
Long-form identifier:
mindat:1:1:7293:5

IMA Classification of SidpietersiteHide

Approved
IMA Formula:
Pb2+4(S6+O3S2-)O2(OH)2
Approval year:
1998

Classification of SidpietersiteHide

7.JA.05

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
J : Thiosulfates
A : Thiosulfates of Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
SdpIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of SidpietersiteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of SidpietersiteHide

Vitreous, Earthy
Transparency:
Transparent, Opaque
Colour:
Colourless, beige
Streak:
Cream-colored, off-white, white
Hardness:
1 - 2 on Mohs scale
Hardness:
VHN25=57 - 67 kg/mm2 - Vickers
Tenacity:
Sectile
Fracture:
Irregular/Uneven
Density:
6.765 g/cm3 (Calculated)

Chemistry of SidpietersiteHide

Mindat Formula:
Pb2+4(S2O3)O2(OH)2
Element Weights:
Element% weight
Pb82.309 %
O11.122 %
S6.369 %
H0.200 %

Calculated from ideal end-member formula.

Crystallography of SidpietersiteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 7.455(2) Å, b = 6.496(2) Å, c = 11.207(4) Å
α = 114. 33(2)°, β = 89.65(2)°, γ = 88.68(2)°
Ratio:
a:b:c = 1.148 : 1 : 1.725
Unit Cell V:
495.60 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Crystals are bladed, elongate [011], with a length-to-width ratio of approximately 4:1. Forms are {001} major, and possible very thin {100} and {01_1} minor.
Twinning:
None observed

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005630SidpietersiteCooper M A, Hawthorne F C (1999) The structure topology of sidpietersite, Pb4(SO3S)O2(OH)2, a novel thiosulfate structure The Canadian Mineralogist 37 1275-128219990293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.13 Å(100)
3.414 Å(100)
3.198 Å(80)
5.93 Å(50)
2.622 Å(40)
4.401 Å(35)
2.889 Å(35)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47b : [Sulfates and sulfites]
Stage 10b: Anthropogenic minerals<10 Ka
56 : Slag and smelter minerals (see also #51 and #55)

Type Occurrence of SidpietersiteHide

General Appearance of Type Material:
Iill-formed, almost warty, nodular masses and crystal groups, as earthy masses and, rarely, as free-standing to radiating bladed-crystal aggregates. Masses, groups and aggregates never exceed 3 mm. Individual subhedral to almost euhedral crystals are bladed, with a length-to-width ratio of approximately 4:1 and not exceeding 0.2 to 0.3 mm in maximum length.
Place of Conservation of Type Material:
The Natural History Museum, London, England, 1998,36.
Canadian Geological Survey, Ottawa, Canada, 68076.
Geological Setting of Type Material:
Oxidation zone, secondary after galena. The last mineral to form, on the galena-sphalerite matrix and on the zincite-coated crystals of smithsonite.
Associated Minerals at Type Locality:

Synonyms of SidpietersiteHide

Other Language Names for SidpietersiteHide

Common AssociatesHide

Associations Based on Photo Data:
5 photos of Sidpietersite associated with GalenaPbS
2 photos of Sidpietersite associated with SpertiniiteCu(OH)2
2 photos of Sidpietersite associated with ElyitePb4Cu(SO4)O2(OH)4 · H2O
2 photos of Sidpietersite associated with CerussitePbCO3
2 photos of Sidpietersite associated with HydrocerussitePb3(CO3)2(OH)2
2 photos of Sidpietersite associated with FluoriteCaF2
1 photo of Sidpietersite associated with Cherokeeite[Pb2Zn(OH)4](SO4) · H2O
1 photo of Sidpietersite associated with SteverustitePb2+5(OH)5[Cu+(S6+O3S2-)3](H2O)2
1 photo of Sidpietersite associated with LanarkitePb2(SO4)O

Related Minerals - Strunz-mindat GroupingHide

7.JA.Hayelasdiite[Pb4O1.5(OH)2.5]2[Cu+5(S2O3)4(S2O2OH)2(H2O)] · 4H2OTric. 1 : P1
7.JA.BoojumitePb8O4(OH)2(S2O3)3Orth. mmm(2/m2/m2/m) : Pnma
7.JA.Finescreekite[Pb4(OH)4](S2O3)2Orth. 222 : P212121
7.JA.BoevskitePb4(TeO3)2(SO4)(S2O3)Orth. mmm(2/m2/m2/m) : Pnma
7.JA.Redmondite[Pb8O2Zn(OH)6](S2O3)4Mon. 2/m : P21/b
7.JA.Hydroredmondite[Pb8O2Zn(OH)6](S2O3)4 · 2H2OMon. 2/m
7.JA.Dinilawiite[Pb4OAl(OH)6]2(S2O3)2 · (S2O3)(H2O)5Mon. 2/m
7.JA.Sulfatoredmondite[Pb8O2Zn(OH)6](SO4)4 · 6H2OMon. 2/m : B2/m
7.JA.Cubothioplumbite[Pb4(OH)4]Pb(S2O3)3Iso. m3(2/m3) : Pa3
7.JA.Hexathioplumbite[Pb2+4(OH)4]Pb2+(S6+O3S2-)3Hex. 6 : P63
7.JA.10SteverustitePb2+5(OH)5[Cu+(S6+O3S2-)3](H2O)2Mon. 2/m : P21/m
7.JA.15FassinaitePb2(S2O3)(CO3)Orth. mmm(2/m2/m2/m) : Pnma
7.JA.20NorthstaritePb6(Te4+O3)5(S6+O3S2-)Hex. 6 : P63

Fluorescence of SidpietersiteHide

Not fluorescent.

Other InformationHide

Notes:
In dilute HCl, there is only an initial effervescence, after which the material turns to a chalky white color over a few minutes.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for SidpietersiteHide

References for SidpietersiteHide

Localities for SidpietersiteHide

Showing 6 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Austria
 
  • Carinthia
    • Sankt Veit an der Glan District
      • Guttaring
        • Waitschach
Program and Abstracts Volume +2 other references
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Breisgau-Hochschwarzwald
        • Badenweiler
EDS-
      • Ortenaukreis
        • Oberwolfach
Schimak et al. (02/2021)
Namibia (TL)
 
  • Oshikoto Region
    • Tsumeb
Am. Mineral. 85 (abs.) +2 other references
UK
 
  • England
    • Derbyshire
      • North East Derbyshire District
        • Ashover
          • Milltown
Steve Rust collection (analysed)
USA
 
  • North Carolina
    • Haywood County
      • Waterville Lake
A. Kampf PXRD 10/2020
 
and/or  
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