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Akrochordite

A valid IMA mineral species - grandfathered
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About AkrochorditeHide

Formula:
MnMn2Mn2(AsO4)2(OH)4(H2O)4
Simplified: (Mn2+)5(AsO4)2(OH)4 · 4H2O.
Type material contains some Mg replacing Mn.
Colour:
Yellowish red-brown, pale to dark brown, pale pink,
Lustre:
Sub-Vitreous, Resinous, Dull
Hardness:
Specific Gravity:
3.194 - 3.35
Crystal System:
Monoclinic
Name:
Named by Gustav Flink in 1922 from Greek ακρόχορδον (akrochordon) = "a wart," in allusion to the appearance of its form of aggregation.
Isostructural with:
A rare (Mn,Mg)-arsenate isotypic with Guanacoite.


Unique IdentifiersHide

Mindat ID:
72
Long-form identifier:
mindat:1:1:72:3

IMA Classification of AkrochorditeHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Mn2+Mn2+2Mn2+2(As5+O4)2(OH)4(H2O)4
First published:
1922

Classification of AkrochorditeHide

8.DD.10

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
D : With only medium-sized cations, (OH, etc.):RO4= 2:1
42.4.1.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
4 : (AB)5(XO4)2Zq·xH2O
20.8.11

20 : Arsenates (also arsenates with phosphate, but without other anions)
8 : Arsenates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
AkrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AkrochorditeHide

Sub-Vitreous, Resinous, Dull
Transparency:
Translucent
Colour:
Yellowish red-brown, pale to dark brown, pale pink,
Hardness:
3½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
On {010} , perfect; a second, perpendicular to the first.
Density:
3.194 - 3.35 g/cm3 (Measured)    3.26 g/cm3 (Calculated)

Optical Data of AkrochorditeHide

Type:
Biaxial (+)
RI values:
nα = 1.672 nβ = 1.676 nγ = 1.683
2V:
Measured: 45°
Birefringence:
0.011
Max. Birefringence:
δ = 0.011
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r < v relatively strong
Optical Extinction:
Y^c ~ 45°, X = b
Pleochroism:
Non-pleochroic

Chemistry of AkrochorditeHide

Mindat Formula:
MnMn2Mn2(AsO4)2(OH)4(H2O)4

Simplified: (Mn2+)5(AsO4)2(OH)4 · 4H2O.
Type material contains some Mg replacing Mn.
Element Weights:
Element% weight
Mn39.660 %
O36.960 %
As21.634 %
H1.746 %

Calculated from ideal end-member formula.

Crystallography of AkrochorditeHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 5.682 Å, b = 17.627 Å, c = 6.832 Å
β = 99.5°
Ratio:
a:b:c = 0.322 : 1 : 0.388
Unit Cell V:
674.89 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Crystals are prismatic to lathlike, elongated along [201], generally splayed or tapered, to 2 mm; may be in radial aggregates and subparallel sheaves. Typically as wartlike or spherical aggregates of minute crystals.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0001206AkrochorditeMoore P B, Sen Gupta P K, Schlemper E O (1989) Akrochordite, (Mn,Mg)5(OH)4(H2O)4(AsO4)2: A sheet structure with amphibole walls American Mineralogist 74 256-26219890293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
8.79 Å(80)
5.31 Å(35)
4.40 Å(100)
3.62 Å(40)
3.112 Å(35)
3.062 Å(35)
2.750 Å(50)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits
Geological Setting:
in fractures in a metamorphosed zinc orebody (Sterling Hill, New Jersey, USA).

Type Occurrence of AkrochorditeHide

General Appearance of Type Material:
Small, rounded wartlike aggregates
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 162614, R5396.
Chemical Analysis of Type Material:
P2O50.42 %
As2O533.51 %
MnO38.98 %
Mn2O30.50 %
FeO0.46 %
MgO6.94 %
K2O0.55 %
Na2O1.18 %
CaO0.99 %
H2O16.78 %
Total:100.31 %
Geological Setting of Type Material:
A rare mineral in hausmannite ore from a metamorphosed Fe–Mn orebody
Associated Minerals at Type Locality:

Synonyms of AkrochorditeHide

Other Language Names for AkrochorditeHide

Relationship of Akrochordite to other SpeciesHide

Other Members of Akrochordite Group:
GuanacoiteMgCu2Mg2(AsO4)2(OH)4(H2O)4Mon. 2/m : P21/b
VargiteMnCu2Mn2(AsO4)2(OH)4(H2O)4Mon. 2/m : P21/b

Common AssociatesHide

Associations Based on Photo Data:
8 photos of Akrochordite associated with EveiteMn2+2(AsO4)(OH)
4 photos of Akrochordite associated with PyrochroiteMn(OH)2
4 photos of Akrochordite associated with SarkiniteMn2+2(AsO4)(OH)
4 photos of Akrochordite associated with SussexiteMn2+BO2(OH)
4 photos of Akrochordite associated with KraissliteZn3(Mn,Mg)25(Fe3+,Al)(As3+O3)2[(Si,As5+)O4]10(OH)16
4 photos of Akrochordite associated with WillemiteZn2SiO4
3 photos of Akrochordite associated with FrankliniteZn2+Fe3+2O4
2 photos of Akrochordite associated with ManganohörnesiteMn2+3(AsO4)2 · 8H2O
1 photo of Akrochordite associated with Hematolite(Mn,Mg,Al,Fe3+)15(As5+O4)2(As3+O3)(OH)23
1 photo of Akrochordite associated with LångbanshyttanitePb2Mn2Mg(AsO4)2(OH)4 · 6H2O

Related Minerals - Strunz-mindat GroupingHide

8.DD.Penberthycroftite[Al6(AsO4)3(OH)9(H2O)5] · 8H2OMon. 2/m : P21/b
8.DD.Bettertonite[Al6(AsO4)3(OH)9(H2O)5] · 11H2OMon. 2/m : P21/b
8.DD.VargiteMnCu2Mn2(AsO4)2(OH)4(H2O)4Mon. 2/m : P21/b
8.DD.GaleaclolusiteAl6(AsO4)3(OH)9(H2O)4 · 8H2OOrth. mmm(2/m2/m2/m) : Pnma
8.DD.05LuetheiteCu2Al2(AsO4)2(OH)4Mon. 2/m : P21/m
8.DD.05ChenevixiteCu2Fe3+2(AsO4)2(OH)4Mon. 2/m : P21/m
8.DD.10GuanacoiteMgCu2Mg2(AsO4)2(OH)4(H2O)4Mon. 2/m : P21/b
8.DD.15'UM1981-32-PO:FeH'Fe2+Fe3+6(PO4)4-x[PO3(OH)]x(OH)8 · 4H2O
8.DD.15AfmiteAl3(OH)4(H2O)3(PO4)(PO3OH) · H2OTric. 1 : P1
8.DD.15Aheylite(Fe2+,Zn)Al6(PO4)4(OH)8 · 4H2OTric. 1 : P1
8.DD.15'Coeruleolactite'Tric. 1 : P1
8.DD.15FaustiteZnAl6(PO4)4(OH)8 · 4H2OTric. 1 : P1
8.DD.15PlaneriteAl6(PO4)2(PO3OH)2(OH)8 · 4H2OTric. 1 : P1
8.DD.15ChalcosideriteCuFe3+6(PO4)4(OH)8 · 4H2OTric. 1 : P1
8.DD.15TurquoiseCuAl6(PO4)4(OH)8 · 4H2OTric. 1 : P1
8.DD.20EosphoriteMn2+Al(PO4)(OH)2 · H2OOrth. mmm(2/m2/m2/m) : Cmca
8.DD.20Ernstite(Mn2+,Fe3+)Al(PO4)(OH,O)2 · H2OMon.
8.DD.20LefontiteFe2Al2Be(PO4)2(OH)6Orth. mmm(2/m2/m2/m) : Cmca
8.DD.20ChildreniteFe2+Al(PO4)(OH)2 · H2OOrth. mm2 : Ccc2
8.DD.25KobokoboiteAl6(PO4)4(OH)6 · 11H2O Tric.
8.DD.30SmamiteCa2Sb(OH)4[H(AsO4)2] · 6H2OTric. 1 : P1
8.DD.35'Gutsevichite'Al3(PO4)2(OH)3 · 8H2OIso.
8.DD.40'Laubmannite (of Moore)'(Fe3+,Fe2+,M)8+x(OH,H2O)9(H2O)2(PO4)5, M = Fe3+, Cu2+ or other metal cation, x ~ 0.1.Orth. mmm(2/m2/m2/m) : Pbcm

Fluorescence of AkrochorditeHide

Not fluorescent

Other InformationHide

Notes:
Readily soluble in dilute H2SO4, yielding a purple (lilac) solution.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for AkrochorditeHide

References for AkrochorditeHide

Reference List:

Localities for AkrochorditeHide

Showing 5 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Germany
 
  • Lower Saxony
    • Göttingen District
      • Bad Grund
        • Bergstadt Bad Grund
Haack et al. (1987)
Sweden (TL)
 
  • Värmland County
    • Filipstad
      • Långban Ore District
Palache et al. (1951) +2 other references
Flink (1922)
      • Nordmark Odal Field
Langhof (2003)
USA
 
  • New Jersey
    • Sussex County
      • Ogdensburg
        • Sterling Hill
Dunn (1981) +1 other reference
 
and/or  
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