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Theophrastite

A valid IMA mineral species
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About TheophrastiteHide

07793310017271927074239.jpg
Theophrastus
Formula:
Ni(OH)2
Colour:
Emerald Green
Lustre:
Silky
Hardness:
Specific Gravity:
4.00
Crystal System:
Trigonal
Member of:
Name:
Named after Theophrastus (ca 371-286 BCE), Greek philosopher and writer, disciple of Aristotle. Although commonly known by his honorary name, his given name was Tyrtamus. Author in about 315 BCE of Περι λιθων, "On Stones" possibly the first mineralogy book.
The nickel analogue of Brucite.


Unique IdentifiersHide

Mindat ID:
3936
Long-form identifier:
mindat:1:1:3936:5

IMA Classification of TheophrastiteHide

Approved
IMA Formula:
Ni2+(OH)2
Approval year:
1980
First published:
1981

Classification of TheophrastiteHide

4.FE.05

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
F : Hydroxides (without V or U)
E : Hydroxides with OH, without H2O; sheets of edge-sharing octahedra
6.2.1.5

6 : HYDROXIDES AND OXIDES CONTAINING HYDROXYL
2 : X(OH)2
7.22.3

7 : Oxides and Hydroxides
22 : Oxides of Ni

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
TphIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TheophrastiteHide

Silky
Transparency:
Translucent
Colour:
Emerald Green
Streak:
Light green
Hardness:
3½ on Mohs scale
Cleavage:
Perfect
on {0001}
Fracture:
Conchoidal
Density:
4.00 g/cm3 (Measured)    3.95 g/cm3 (Calculated)

Optical Data of TheophrastiteHide

Type:
Uniaxial (+)
RI values:
nω = 1.759 - 1.760 nε = 1.759 - 1.760
Birefringence:
Very weak
Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Pleochroism:
Weak

Chemistry of TheophrastiteHide

Mindat Formula:
Ni(OH)2
Element Weights:
Element% weight
Ni63.310 %
O34.516 %
H2.174 %

Calculated from ideal end-member formula.
Ni
O
H

Crystallography of TheophrastiteHide

Crystal System:
Trigonal
Class (H-M):
3m(32/m) - Hexagonal Scalenohedral
Space Group:
P3m1
Cell Parameters:
a = 3.131 Å, c = 4.608 Å
Ratio:
a:c = 1 : 1.472
Unit Cell V:
39.12 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Platy, fibrous, botyroidal crusts.
Comment:
On synthetic

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0009939TheophrastiteRamesh T N, Kamath P V, Shivakumara C (2006) Classification of stacking faults and their stepwise elemination during the disorder -> order transformation of nickel hydroxide Acta Crystallographica B62 530-5362006synthetic0293
0011791TheophrastiteWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 239-44419630293
0018023TheophrastiteCairns R, Ott E (1933) X-ray studies of the system nickel-oxygen-water. I. Nickelous oxide and hydroxide _cod_database_code 1011134 Journal of the American Chemical Society 55 527-53319330293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.335 Å(100)
4.61 Å(95)
1.755 Å(50)
2.708 Å(30)
1.563 Å(25)
1.480 Å(18)
1.336 Å(10)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
7 : Ultramafic igneous rocks
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
Geological Setting:
Chromatites

Type Occurrence of TheophrastiteHide

General Appearance of Type Material:
Small crystals of "0.n" [sic] mm but usually forms thin layers , thickness less than 0.5 cm. In some cases forms successive layers consisting of very fine fibrous crystals aligned perpendicular to the boundaries of vesuvianite or chlorite crystals.
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 148460.
Geological Setting of Type Material:
In cavities and fractures of magnetite-chromite ore in serpentinite.
Associated Minerals at Type Locality:

Synonyms of TheophrastiteHide

Other Language Names for TheophrastiteHide

Relationship of Theophrastite to other SpeciesHide

Member of:
Other Members of Brucite Group:
AmakiniteFe2+(OH)2Trig.
BruciteMg(OH)2Trig. 3m(32/m) : P3m1
PortlanditeCa(OH)2Trig. 3m(32/m) : P3m1
PyrochroiteMn(OH)2Trig. 3m(32/m) : P3m1

Related Minerals - Strunz-mindat GroupingHide

4.FE.NannoniiteAl2(OH)5FMon. 2/m : P21/b
4.FE.05BruciteMg(OH)2Trig. 3m(32/m) : P3m1
4.FE.05AmakiniteFe2+(OH)2Trig.
4.FE.05PortlanditeCa(OH)2Trig. 3m(32/m) : P3m1
4.FE.05PyrochroiteMn(OH)2Trig. 3m(32/m) : P3m1
4.FE.10DoyleiteAl(OH)3Tric. 1 : P1
4.FE.10BayeriteAl(OH)3Mon. 2/m : P21/m
4.FE.10NordstranditeAl(OH)3Tric. 1 : P1
4.FE.10GibbsiteAl(OH)3Mon. 2/m
4.FE.15LepidocrociteFe3+O(OH)Orth. mm2 : Cmc21
4.FE.15BöhmiteAlO(OH)Orth. mmm(2/m2/m2/m)
4.FE.20HeterogeniteCo3+O(OH)Hex.
4.FE.20GrimaldiiteCrO(OH)Trig. 3m : R3m
4.FE.25Lithiophorite(Al,Li)MnO2(OH)2Trig. 3m(32/m) : R3m
4.FE.25FeitknechtiteMn3+O(OH)Trig. 3m(32/m) : P3m1
4.FE.30QuenselitePbMnO2(OH)Mon. 2/m : P2/b
4.FE.35FerrihydriteFe3+10O14(OH)2Trig.
4.FE.40Vernadite(Mn4+,Fe3+,Ca,Na)(O,OH)2 · nH2OMon. 2/m : B2/m
4.FE.40FeroxyhyteFe3+O(OH)Hex.
4.FE.45QuetzalcoatliteZn6Cu3(TeO6)2(OH)6 · AgxPbyClx+2yTrig. 3m(32/m) : P31m
4.FE.50FuettereritePb3Cu2+6Te6+O6(OH)7Cl5 Trig. 3 : R3

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for TheophrastiteHide

References for TheophrastiteHide

Localities for TheophrastiteHide

Showing 7 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Tasmania
    • Waratah-Wynyard municipality
      • Heazlewood district
Henry et al. (1992) +1 other reference
Canada
 
  • Québec
    • Estrie
      • Les Sources RCM
        • Val-des-Sources
Horváth et al. (2013)
Greece (TL)
 
  • Central Macedonia
Marcopoulos et al. (1981) +1 other reference
Italy
 
  • Lombardy
    • Sondrio Province
      • Lanzada
        • Franscia
Bedognè et al. (1993)
Japan
 
  • Ehime Prefecture
    • Shikokuchuo City
Arai +4 other references
Russia
 
  • Chelyabinsk Oblast
    • Verkhny Ufaley
      • Ufaley District (Ufalei District)
Pavel M. Kartashov analytical data (2013)
UK
 
  • Scotland
    • Shetland Islands
      • Unst
Bish et al. (1981) +2 other references
 
and/or  
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