Arupite
A valid IMA mineral species
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About Arupite
Formula:
Ni3(PO4)2 · 8H2O
Colour:
Blue to light blue
Lustre:
Dull, Earthy
Hardness:
1½ - 2
Specific Gravity:
2.85 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
Named in 1990 by Vagn Fabius Buchwald in honor of Hans Henning Arup (4 May 1928 - 19 November 2012), Director of the Danish Corrosion Center, Copenhagen, Denmark.
Unique Identifiers
Mindat ID:
379
Long-form identifier:
mindat:1:1:379:3
IMA Classification of Arupite
Classification of Arupite
8.CE.40
8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
E : With only medium-sized cations, RO4:H2O about 1:2.5
8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
E : With only medium-sized cations, RO4:H2O about 1:2.5
40.3.6.8
40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
3 : A3(XO4)2·xH2O
40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
3 : A3(XO4)2·xH2O
19.15.1
19 : Phosphates
15 : Phosphates of Ni
19 : Phosphates
15 : Phosphates of Ni
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Arp | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Arupite
Dull, Earthy
Transparency:
Translucent
Colour:
Blue to light blue
Streak:
Light blue
Hardness:
1½ - 2 on Mohs scale
Density:
2.85 g/cm3 (Calculated)
Optical Data of Arupite
Type:
Biaxial (+)
RI values:
nα = 1.632 nβ = 1.65 nγ = 1.680
2V:
Measured: 60° to 70°, Calculated: 78°
Birefringence:
0.048
Max. Birefringence:
δ = 0.048
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Moderate
Dispersion:
r < v strong
Pleochroism:
Visible
Comments:
X = blue, Z = colorless
Chemistry of Arupite
Mindat Formula:
Ni3(PO4)2 · 8H2O
Element Weights:
Elements listed:
Common Impurities:
Fe
Crystallography of Arupite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Cell Parameters:
a = 9.889 Å, b = 13.225 Å, c = 4.645 Å
β = 102.41°
β = 102.41°
Ratio:
a:b:c = 0.748 : 1 : 0.351
Unit Cell V:
593.29 ų (Calculated from Unit Cell)
Z:
2
Comment:
I2/m
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0018468 | Arupite | Shouwen J, Wang D, Gao X, Wen X, Zhou J (2008) Poly[octaaquadi-mu-phosphato-tri-nickel(II)] Acta Crystallographica E64 m259-m259 | 2008 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 7.878 Å | (26) |
| 6.624 Å | (100) |
| 4.818 Å | (24) |
| 3.805 Å | (21) |
| 3.152 Å | (24) |
| 2.922 Å | (23) |
| 2.672 Å | (17) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47c : [Carbonates, phosphates, borates, nitrates] | |
| 47i : [Terrestrial weathering of meteorites] |
Type Occurrence of Arupite
General Appearance of Type Material:
Short prismatic blue crystals to 5 microns.
Place of Conservation of Type Material:
Division of Meteorites, National Museum of Natural History, Washington, D.C., USA, numbers 659, 804, 877.
Geological Setting of Type Material:
Weathered meteorite.
Associated Minerals at Type Locality:
Synonyms of Arupite
Other Language Names for Arupite
Relationship of Arupite to other Species
Member of:
Other Members of Vivianite Group:
| Annabergite | Ni3(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
| Babánekite | Cu3(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
| Barićite | (Mg,Fe)3(PO4)2 · 8H2O | Mon. 2/m : B2/m |
| Cabrerite | NiMg2(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
| Erythrite | Co3(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
| Gritsenkoite | CoMg2(AsO4)2(H2O)8 | Mon. 2/m : B2/m |
| Hörnesite | Mg3(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
| Köttigite | Zn3(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
| Manganohörnesite | Mn2+3(AsO4)2 · 8H2O | Mon. 2/m : P2/m |
| Monteneroite | Cu2+Mn2+2(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
| Pakhomovskyite | Co3(PO4)2 · 8H2O | Mon. 2/m : B2/m |
| Parasymplesite | Fe2+3(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
| Vivianite | Fe2+Fe2+2(PO4)2 · 8H2O | Mon. 2/m : B2/m |
| Zincocabrerite | ZnMg2(AsO4)2(H2O)8 | Mon. 2/m : B2/m |
Common Associates
Associations Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
| 8.CE. | Monteneroite | Cu2+Mn2+2(AsO4)2 · 8H2O |
| 8.CE. | Belmonteite | CaMn2(AsO4)2 · 7H2O |
| 8.CE.X | Babánekite | Cu3(AsO4)2 · 8H2O |
| 8.CE.05 | Chudobaite | Mg5(AsO4)2(AsO3OH)2 · 10H2O |
| 8.CE.05 | Geigerite | Mn2+5(AsO4)2(HAsO4)2 · 10H2O |
| 8.CE.10 | Newberyite | Mg(PO3OH) · 3H2O |
| 8.CE.10 | Manganonewberyite | Mn(PO3OH)(H2O)3 |
| 8.CE.15 | Fanguangite | (MoO2)(PO3OH) · 4H2O |
| 8.CE.15 | Brassite | Mg(HAsO4) · 4H2O |
| 8.CE.20 | Phosphorrösslerite | Mg(PO3OH) · 7H2O |
| 8.CE.20 | Rösslerite | Mg(HAsO4) · 7H2O |
| 8.CE.25 | Switzerite | Mn2+3(PO4)2 · 7H2O |
| 8.CE.25 | Metaswitzerite | Mn2+3(PO4)2 · 4H2O |
| 8.CE.30 | Pradetite | CoCu4(AsO4)2(HAsO4)2 · 9H2O |
| 8.CE.30 | Veselovskýite | ZnCu4(AsO4)2(HAsO4)2 · 9H2O |
| 8.CE.30 | Lindackerite | CuCu4(AsO4)2(HAsO4)2 · 9H2O |
| 8.CE.30 | Klajite | MnCu4(AsO4)2(HAsO4)2 · 9-10H2O |
| 8.CE.30 | Hloušekite | (Ni,Co)Cu4(AsO4)2(AsO3OH)2 · 9H2O |
| 8.CE.30 | Ondrušite | CaCu4(AsO4)2(HAsO4)2 · 10H2O |
| 8.CE.35 | Bobierrite | Mg3(PO4)2 · 8H2O |
| 8.CE.40 | Barićite | (Mg,Fe)3(PO4)2 · 8H2O |
| 8.CE.40 | Parasymplesite | Fe2+3(AsO4)2 · 8H2O |
| 8.CE.40 | Gritsenkoite | CoMg2(AsO4)2(H2O)8 |
| 8.CE.40 | Cabrerite | NiMg2(AsO4)2 · 8H2O |
| 8.CE.40 | Pakhomovskyite | Co3(PO4)2 · 8H2O |
| 8.CE.40 | Vivianite | Fe2+Fe2+2(PO4)2 · 8H2O |
| 8.CE.40 | Erythrite | Co3(AsO4)2 · 8H2O |
| 8.CE.40 | Hörnesite | Mg3(AsO4)2 · 8H2O |
| 8.CE.40 | Manganohörnesite | Mn2+3(AsO4)2 · 8H2O |
| 8.CE.40 | Köttigite | Zn3(AsO4)2 · 8H2O |
| 8.CE.40 | Ferrisymplesite | Fe3+3(AsO4)2(OH)3 · 5H2O |
| 8.CE.40 | Annabergite | Ni3(AsO4)2 · 8H2O |
| 8.CE.45 | Symplesite | Fe2+3(AsO4)2 · 8H2O |
| 8.CE.50 | Cattiite | Mg3(PO4)2 · 22H2O |
| 8.CE.55 | Koninckite | Fe3+PO4 · 3H2O |
| 8.CE.60 | Kaňkite | FeAsO4 · 3.5H2O |
| 8.CE.60 | Hilarionite | Fe3+2(SO4)(AsO4)(OH) · 6H2O |
| 8.CE.65 | Steigerite | Al(VO4) · 3H2O |
| 8.CE.70 | Metaschoderite | Al2(PO4)(VO4) · 6H2O |
| 8.CE.70 | Schoderite | Al2(PO4)(VO4) · 8H2O |
| 8.CE.75 | Zigrasite | MgZr(PO4)2 · 4H2O |
| 8.CE.75 | 'UM2009-11-PO:CaHZr' | CaZr[PO4]2 · 4H2O |
| 8.CE.75 | Malhmoodite | FeZr(PO4)2 · 4H2O |
| 8.CE.80 | Santabarbaraite | Fe3+3(PO4)2(OH)3 · 5H2O |
| 8.CE.85 | Metaköttigite | (Zn,Fe,Fe)3(AsO4)2 · 8(H2O,OH) |
| 8.CE.90 | Slavkovite | Cu13(AsO4)6(AsO3OH)4 · 23H2O |
Fluorescence of Arupite
Not fluorescent.
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Arupite
mindat.org URL:
https://www.mindat.org/min-379.html
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References for Arupite
Localities for Arupite
Showing 2 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Brazil (TL) | |
| Buchwald (1990) +1 other reference |
Japan | |
| The Mineral Species of Japan (5th ed) +1 other reference |
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Santa Catharina meteorite, Morro do Rócio, São Francisco do Sul, Santa Catarina, Brazil