Vote for your favorite mineral in #MinCup26! - Azurite vs. Smithsonite
It's carbonate-vs-carbonate to kick off Mineral Cup 2026 with copper-rich Azurite against zinc-rich Smithsonite.
Log InRegister
Quick Links : The Mindat ManualThe Rock H. Currier Digital LibraryMindat Newsletter [Free Download]
Home PageAbout MindatThe Mindat ManualHistory of MindatCopyright StatusWho We AreContact UsAdvertise on Mindat
Donate to MindatCorporate SponsorshipSponsor a PageSponsored PagesMindat AdvertisersAdvertise on Mindat
Learning CenterWhat is a mineral?The most common minerals on earthInformation for EducatorsMindat ArticlesThe ElementsThe Rock H. Currier Digital LibraryGeologic TimeExplore Fossils
Minerals by PropertiesMinerals by ChemistryMineral Visual ExplorerAdvanced Locality SearchRandom MineralRandom LocalitySearch by minIDLocalities Near MeSearch ArticlesSearch GlossaryMore Search Options
Search For:
Mineral Name:
Locality Name:
Keyword(s):
 
The Mindat ManualAdd a New PhotoRate PhotosLocality Edit ReportCoordinate Completion ReportAdd Glossary Item
Mining CompaniesStatisticsUsersMineral MuseumsClubs & OrganizationsMineral Shows & EventsThe Mindat DirectoryDevice SettingsThe Mineral QuizTime Machine
Photo SearchPhoto GalleriesSearch by ColorPhoto Colour ExplorerNew Photos TodayNew Photos YesterdayMembers' Photo GalleriesPast Photo of the Day GalleryPhotography

Nagashimalite

A valid IMA mineral species
This page is currently not sponsored. Click here to sponsor this page.
09980270017272002046675.jpg
Nagashimalite

Mogurazawa mine, Kiryu City, Gunma Prefecture, Japan
00102550017271980748999.jpg
Nagashimalite

Mogurazawa mine, Kiryu City, Gunma Prefecture, Japan
09984710017523824245755.jpg
Nagashimalite, etc.

Mogurazawa mine, Kiryu City, Gunma Prefecture, Japan
01915690017271925317882.jpg
Nagashimalite

Mogurazawa mine, Kiryu City, Gunma Prefecture, Japan
00102550017271980748999.jpg
Nagashimalite

Mogurazawa mine, Kiryu City, Gunma Prefecture, Japan
07638970017362517139064.jpg
Nagashimalite, etc.

Mogurazawa mine, Kiryu City, Gunma Prefecture, Japan
01915690017271925317882.jpg
Nagashimalite

Mogurazawa mine, Kiryu City, Gunma Prefecture, Japan
00102550017271980748999.jpg
Nagashimalite

Mogurazawa mine, Kiryu City, Gunma Prefecture, Japan
Hide all sections | Show all sections

About NagashimaliteHide

07802050017271925452434.jpg
Otokichi Nagashima
Formula:
Ba4(V,Ti)4B2Si8O27(O,OH)2Cl
Colour:
Greenish-black
Lustre:
Vitreous, Sub-Metallic
Hardness:
6
Specific Gravity:
4.08
Crystal System:
Orthorhombic
Name:
Named in honor of Otokichi Nagashima (長島 乙吉) (2 September 1890 - 4 December 1969), pioneer Japanese amateur mineralogist. The mineral kozoite-(Nd) is named after his mineralogist son, Kozo Nagashima.
This page provides mineralogical data about Nagashimalite.


Unique IdentifiersHide

Mindat ID:
2828
Long-form identifier:
mindat:1:1:2828:4

IMA Classification of NagashimaliteHide

Classification of NagashimaliteHide

Strunz-mindat (2026):
9.CE.20

9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions
Dana 8th ed.:
64.3.1.3

64 : CYCLOSILICATES Rings with Other Anions and Insular Silicate Groups
3 : Rings with Other Anions and Insular Silicate Groups: 4-membered rings with [Si2O7] dimers
Hey's CIM Ref.:
17.5.36

17 : Silicates Containing other Anions
5 : Borosilicates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
NgsIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of NagashimaliteHide

Lustre:
Vitreous, Sub-Metallic
Transparency:
Transparent, Translucent, Opaque
Colour:
Greenish-black
Streak:
Green
Hardness:
6 on Mohs scale
Hardness:
VHN100=606 - 681 kg/mm2 - Vickers
Cleavage:
None Observed
Density:
4.08 g/cm3 (Measured)    4.14 g/cm3 (Calculated)

Optical Data of NagashimaliteHide

Type:
Biaxial (+)
RI values:
nα = 1.75 nβ = 1.753 nγ = 1.78
2V:
Measured: 30° , Calculated: 38°
Max. Birefringence:
δ = 0.030
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Dispersion:
r > v, strong
Optical Extinction:
X = a; Y = c; Z = b.
Pleochroism:
Strong
Comments:
X = greenish-yellow; Y = green; Z = greenish-brown.
Comments:
Absorption: Z > Y > X.

Chemistry of NagashimaliteHide

Mindat Formula:
Ba4(V,Ti)4B2Si8O27(O,OH)2Cl
Element Weights:
Element% weight
Ba36.650 %
O30.957 %
Si14.991 %
V13.595 %
Cl2.365 %
B1.443 %

Calculated from ideal end-member formula.
Elements listed:
B, Ba, Cl, H, O, Si, Ti, V - search for minerals with similar chemistry
Common Impurities:
Mn,H2O

Crystallography of NagashimaliteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pmmn
Cell Parameters:
a = 13.937(3) Å, b = 12.122(3) Å, c = 7.116(2) Å
Ratio:
a:b:c = 1.15 : 1 : 0.587
Unit Cell V:
1,202.21 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Tabular to elongated crystals, sub=parallel aggregates.

Crystal StructureHide

Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Show
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Display Options
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
View
CIF File    Best | x | y | z | a | b | c
Rotation
Stop | Start
Labels
Console Off | On | Grey | Yellow
IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014423NagashimaliteMatsubara S (1980) The crystal structure of nagashimalite, Ba4(V(3+),Ti)4[(O,OH)2|Cl|Si8B2O27] Mineralogical Journal 10 131-1421980Mogurazawa mine, Kirya City, Gumma Prefecture, Japan0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.020 Å(100)
3.030 Å(60)
2.592 Å(28)
3.854 Å(25)
2.791 Å(20)
3.319 Å(15)
3.273 Å(15)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits

Type Occurrence of NagashimaliteHide

Type Locality:
ⓘ Mogurazawa mine, Kiryu City, Gunma Prefecture, Japan
General Appearance of Type Material:
Crystals up to 15 mm long forming subparallel aggregates in rhodonite ore.
Place of Conservation of Type Material:
National Science Museum, Tokyo, Japan, M21727.
National Museum of Natural History, Washington, D.C., USA, 142987.
Geological Setting of Type Material:
Manganese deposit in bedded chert.
Associated Minerals at Type Locality:
RhodoniteRhodochrositeBaryteQuartzRoscoelite
SuzukiiteAlabanditeDigeniteBorniteTetrahedrite Subgroup
Reference:
Matsubara Satoshi, Kato, Akira (1980) Nagashimalite, Ba4(V3+,Ti)4[(O,OH)2|Cl|Si8B2O27], a new mineral from the Mogurazawa mine, gumma prefecture, Japan. Mineralogical Journal, 10 (3) 122-130 doi:10.2465/minerj.10.122

Synonyms of NagashimaliteHide

Other Language Names for NagashimaliteHide

Simplified Chinese:纤硅钒钡石
Traditional Chinese:纖矽釩鋇石

Common AssociatesHide

Associations Based on Photo Data:
4 photos of Nagashimalite associated with RhodoniteCaMn3Mn[Si5O15]
1 photo of Nagashimalite associated with QuartzSiO2

Related Minerals - Strunz-mindat GroupingHide

9.CE.Dutkevichite-(Ce)NaZnBa2Ce2Ti2Si8O26F · H2OOrth. mm2 : Ama2
9.CE.KataniteBa3NbFe3Si2O14Trig. 32 : P321
9.CE.NiobobaotiteBa4(Ti2.5Fe2+1.5)Nb4Si4O28ClTet. 4/m : I41/a
9.CE.AmaterasuiteSr4Ti6Si4O23(OH)ClOrth. mmm(2/m2/m2/m) : Fddd
9.CE.SteiningeriteBa2Zr2(Si4O12)O2Tet. 4/mmm(4/m2/m2/m) : P4/mbm
9.CE.05PapagoiteCaCu[H3AlSi2O9]Mon. 2/m : B2/m
9.CE.10VerplanckiteBa4Mn2+2Si4O12(OH,H2O)3Cl3Hex. 6/mmm(6/m2/m2/m) : P6/mmm
9.CE.15BaotiteBa4(Ti,Nb,W)8O16(SiO3)4ClTet. 4/m : I41/a
9.CE.20TaramelliteBa4(Fe3+,Ti,Fe2+,Mg)4(B2Si8O27)O2ClxOrth. mmm(2/m2/m2/m) : Pmmn
9.CE.20TitantaramelliteBa4(Ti,Fe3+,Fe2+,Mg)4(B2Si8O27)O2ClxOrth. mmm(2/m2/m2/m)
9.CE.25Bario-orthojoaquinite(Ba,Sr)4Fe2Ti2[Si4O12]2O2 · H2OOrth.
9.CE.25Byelorussite-(Ce)NaBa2Ce2MnTi2[Si4O12]2O2(F,OH) · H2OOrth. mm2 : Ama2
9.CE.25Joaquinite-(Ce)NaBa2Ce2FeTi2[Si4O12]2O2(OH,F) · H2OMon. 2 : B2
9.CE.25Orthojoaquinite-(La)NaBa2La2Fe2+Ti2[Si4O12]2O2(O,OH) · H2OOrth. mmm(2/m2/m2/m)
9.CE.25StrontiojoaquiniteSr2Ba2(Na,Fe)2Ti2[Si4O12]2O2(O,OH)2 · H2OMon.
9.CE.25Orthojoaquinite-(Ce)NaBa2Ce2FeTi2[Si4O12]2O2(O,OH) · H2OOrth.
9.CE.25Strontio-orthojoaquinite(Na,Fe)2Sr2Ba2Ti2[Si4O12]2O2(O,OH)2 · H2OOrth.
9.CE.30eLabuntsovite-MnNa4K4(Ba,K)2Mn2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10-12H2OMon. 2/m : B2/m
9.CE.30bTsepinite-NaNa2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
9.CE.30cGjerdingenite-NaK2Na(Nb,Ti)4(Si4O12)2(OH,O)4 · 5H2OMon. 2/m : B2/m
9.CE.30hAlsakharovite-ZnNaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2OMon. m : Bm
9.CE.30cBurovaite-Ca(Na,K)4Ca2(Ti,Nb)8(Si4O12)4(OH,O)8 · 12H2OMon. 2/m : B2/m
9.CE.30aNenadkevichite(Na,◻)8Nb4(Si4O12)2(O,OH)4 · 8H2OOrth. mmm(2/m2/m2/m) : Pbam
9.CE.30bTsepinite-SrSr(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
9.CE.30cGjerdingenite-MnK2Mn2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30bParatsepinite-Na(Na,Sr,K,Ca)7(Ti,Nb)8(Si4O12)4(O,OH)8 · nH2O n ~ 8Mon. 2/m : B2/m
9.CE.30dLemmleinite-KK2(Ti,Nb)2(Si4O12)(OH,O)2 · 4H2OOrth.
9.CE.30cKarupmøllerite-Ca(Na,Ca,K)2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 7H2OMon. 2/m : B2/m
9.CE.30cLepkhenelmite-Zn(Ba,K)2Zn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2OMon. m : Bm
9.CE.30hGutkovaite-MnK2CaMn(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2OMon. m : Bm
9.CE.30eLabuntsovite-MgNa4K4(Ba,K)2Mg(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2OMon. 2/m : B2/m
9.CE.30eLabuntsovite-FeNa4K4(Ba,K)2Fe2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2OMon. 2/m : B2/m
9.CE.30cKuzmenkoite-ZnK2Zn(Ti,Nb)4(Si4O12)2(OH,O)4 · 6-8H2OMon. m : Bm
9.CE.30fParalabuntsovite-MgNa8K8Mg4Ti16(Si4O12)8(OH,O)16 · 20-24H2OMon. 2/m : B2/m
9.CE.30dLemmleinite-BaNa2K2Ba(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2OMon. 2/m : B2/m
9.CE.30gOrganovaite-MnK2Mn(Nb,Ti)4(Si4O12)2(O,OH)4 · 5-7H2OMon. 2/m : B2/m
9.CE.30gOrganovaite-ZnK2Zn(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30bVuoriyarvite-KK2(Nb,Ti)2(Si4O12)(O,OH)2 · 4H2OMon. m : Bm
9.CE.30cGjerdingenite-FeK2Fe2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30a'Unnamed (Ca-Na-ordered analogue of Korobitsynite)'(Ca,Na)2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2OOrth. 222 : P21212
9.CE.30gParakuzmenkoite-Fe(K,Ba)4Fe(Ti,Nb)8(Si4O12)4(O,OH)8 · 14H2OMon. 2/m : B2/m
9.CE.30aKorobitsynite(Na,◻)4Ti2(Si4O12)(O,OH)2 · 4H2OOrth. mmm(2/m2/m2/m) : Pbam
9.CE.30cKuzmenkoite-MnK2Mn2+(Ti,Nb)4(Si4O12)2(OH,O)4 · 5-6H2OMon. 2/m : B2/m
9.CE.30bTsepinite-KK2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
9.CE.30bParatsepinite-BaBa4(Ti,Nb)8(Si4O12)4(OH,O)8 · 8H2OMon. 2/m : B2/m
9.CE.30hNeskevaaraite-FeK3Na2Fe2+(Ti,Nb)4(Si4O12)2(O,OH)4 · 5-6 H2OMon. m : Bm
9.CE.30cGjerdingenite-CaK2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30bTsepinite-Ca(Ca,K,Na)2-x(Ti,Nb)2(Si4O12)(OH,O)2 · 4H2OMon. 2/m : B2/m
9.CE.45'Natrokomarovite'(Na,Ca,H)2Nb2Si2O10(OH,F)2 · H2OOrth.
9.CE.45Komarovite(Ca,Mn)(Nb,Ti)2[Si2O7](O,F)3 · 3.5H2OOrth. mmm(2/m2/m2/m) : Cmmm

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for NagashimaliteHide

References for NagashimaliteHide

Localities for NagashimaliteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Japan (TL)
 
  • Gunma Prefecture
    • Kiryu City
Matsubara Satoshi et al. (1980) +1 other reference
  • Iwate Prefecture
    • Shimohei District
      • Tanohata
Matsubara et al. (2008) +1 other reference
Matsubara et al. (2010)
Quick NavTopAbout NagashimaliteUnique IdentifiersIMA Classification Classification Mineral SymbolsPhysical Properties Optical Data Chemistry Crystallography Crystal StructureX-Ray Powder DiffractionGeological EnvironmentType Occurrence SynonymsOther LanguagesCommon AssociatesStrunz-MindatOther InformationInternet Links References Localities Locality List
 
and/or  
Mindat.org® is an outreach project of the Hudson Institute of Mineralogy, a 501(c)(3) not-for-profit organization. Mindat® and mindat.org® are registered trademarks of the Hudson Institute of Mineralogy.
Copyright © mindat.org and the Hudson Institute of Mineralogy 1993-2026, except where stated. Most political location boundaries are © OpenStreetMap contributors. Mindat.org relies on the contributions of thousands of members and supporters. Founded in 2000 by Jolyon Ralph and Ida Chau.
Content on this site may not be used to train, fine-tune, or otherwise develop artificial intelligence or machine learning models without prior written permission - see our Terms & Conditions.
To cite: Ralph, J., Von Bargen, D., Martynov, P., Zhang, J., Que, X., Prabhu, A., Morrison, S. M., Li, W., Chen, W., & Ma, X. (2025). Mindat.org: The open access mineralogy database to accelerate data-intensive geoscience research. American Mineralogist, 110(6), 833–844. doi:10.2138/am-2024-9486.
Privacy Policy - Terms & Conditions - Contact Us / DMCA issues - Report a bug/vulnerability Current server date and time: September 1, 2026 16:45:52 Page updated: August 19, 2026 08:01:15
Go to top of page