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Garyansellite

A valid IMA mineral species
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About GaryanselliteHide

00678520017271923404475.jpg
H. Gary Ansell
Formula:
Mg2Fe3+(PO4)2(OH) · 2H2O
Colour:
clove-brown
Lustre:
Vitreous
Hardness:
4
Specific Gravity:
3.16
Crystal System:
Orthorhombic
Name:
Named in 1984 by Bozidar Darko Sturman and Pete J. Dunn in honor of Harold Gary Ansell (1943 - 2024), mineralogist with the Canadian Geological Survey. He was curator of the National Mineral Collection from 1972-1997.
Isostructural with:
Forms a series with kryzhanovskite. Structurally close to other members of the phosphoferrite–reddingite series (or phosphoferrite group).

Small (<1 mm) nearly colorless, zones, fringes, or patches in olive phosphosiderite.

The structure is layered, with layers comprising chains formed by edge-sharing M(2)O4(OH)(H2O) octahedra; these octahedra form dimers and these share edges with separate M(1)O4(H2O)2 octahedra. The chains are linked to layers through the common vertices of M(2); octahedra and octaahedral layers are connected via the phosphate tetrahedra.


Unique IdentifiersHide

Mindat ID:
1655
Long-form identifier:
mindat:1:1:1655:7

IMA Classification of GaryanselliteHide

Approved
IMA Formula:
Mg2Fe3+(PO4)2(OH)·2H2O
Approval year:
1981
First published:
1984

Classification of GaryanselliteHide

8.CC.05

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
C : With only medium-sized cations, RO4:H2O = 1:1.5
40.3.2.5

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
3 : A3(XO4)2·xH2O
19.14.12

19 : Phosphates
14 : Phosphates of Fe and other metals

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
GasIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of GaryanselliteHide

Vitreous
Transparency:
Transparent
Comment:
"bronze on cleavages"
Colour:
Clove-brown
Comment:
semitransparent
Streak:
Brown
Hardness:
Cleavage:
Distinct/Good
{001}
Density:
3.16(4) g/cm3 (Measured)    3.154 g/cm3 (Calculated)

Optical Data of GaryanselliteHide

Type:
Biaxial (-)
RI values:
nα = 1.733 nβ = 1.757 nγ = 1.761
2V:
Measured: 55° , Calculated: 42°
Max. Birefringence:
δ = 0.028
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r < v
Comments:
reddish brown (X=Z), yellow (Y)
Comments:
Orientation: X = b, Y = a, Z = c; absorption: Z = X > Y

Chemistry of GaryanselliteHide

Mindat Formula:
Mg2Fe3+(PO4)2(OH) · 2H2O
Element Weights:
Element% weight
O50.655 %
P17.830 %
Fe16.074 %
Mg13.991 %
H1.451 %

Calculated from ideal end-member formula.
O
P
Fe
Mg
H
Common Impurities:
Mn

Crystallography of GaryanselliteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Cell Parameters:
a = 9.45 Å, b = 9.89 Å, c = 8.19 Å
Ratio:
a:b:c = 0.956 : 1 : 0.828
Unit Cell V:
765.44 ų (Calculated from Unit Cell)
Comment:
Space group is Pbna; parameters from Zubkova et al. (2016): a=9.44738, b=9.85976, c=8.14154, V=758.38

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.156 Å(100)
2.705 Å(60)
4.93 Å(50)
3.098 Å(40)
4.26 Å(30)
2.535 Å(30)
2.213 Å(30)
Comments:
Rapid Creek, Yukon, Canada. Data from the type description.

Geological EnvironmentHide

Type Occurrence of GaryanselliteHide

General Appearance of Type Material:
Small colorless patches
Place of Conservation of Type Material:
Royal Ontario Museum, Toronto, Canada (registration no. M37306)
Geological Setting of Type Material:
fractures in a sedimentary iron formation; rare, low-temperature species
Associated Minerals at Type Locality:

Synonyms of GaryanselliteHide

Other Language Names for GaryanselliteHide

Relationship of Garyansellite to other SpeciesHide

Other Members of Reddingite Group:
CorreianevesiteFe2+Mn2+2(PO4)2 · 3H2OOrth. mmm(2/m2/m2/m)
Kryzhanovskite(Fe3+,Mn2+)3(PO4)2(OH,H2O)3Orth. mmm(2/m2/m2/m)
LandesiteMn2+3-xFe3+x(PO4)2(OH)x · (3-x)H2OOrth. mmm(2/m2/m2/m)
Phosphoferrite(Fe2+,Mn2+)3(PO4)2 · 3H2OOrth. mmm(2/m2/m2/m) : Pmna
Reddingite(Mn2+,Fe2+)3(PO4)2 · 3H2OOrth. mmm(2/m2/m2/m) : Pmna
Forms a series with:

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Garyansellite associated with Barićite(Mg,Fe)3(PO4)2 · 8H2O

Related Minerals - Strunz-mindat GroupingHide

8.CC.CorreianevesiteFe2+Mn2+2(PO4)2 · 3H2OOrth. mmm(2/m2/m2/m)
8.CC.05LandesiteMn2+3-xFe3+x(PO4)2(OH)x · (3-x)H2OOrth. mmm(2/m2/m2/m)
8.CC.05Reddingite(Mn2+,Fe2+)3(PO4)2 · 3H2OOrth. mmm(2/m2/m2/m) : Pmna
8.CC.05Phosphoferrite(Fe2+,Mn2+)3(PO4)2 · 3H2OOrth. mmm(2/m2/m2/m) : Pmna
8.CC.05Kryzhanovskite(Fe3+,Mn2+)3(PO4)2(OH,H2O)3Orth. mmm(2/m2/m2/m)
8.CC.10KaatialaiteFe3+[AsO2(OH)2]3 · 5H2OMon. 2/m
8.CC.15LeogangiteCu10(AsO4)4(SO4)(OH)6 · 8H2OMon. 2/m : B2/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for GaryanselliteHide

References for GaryanselliteHide

Localities for GaryanselliteHide

Showing 4 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Yukon
    • Dawson mining district
Robinson et al. (1992)
150-152. +3 other references
        • Kulan Camp (Area A; Area 1)
Tomes et al. (2012)
USA
 
  • South Dakota
    • Pennington County
      • Keystone Mining District
        • Glendale
 
and/or  
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