Phosphovanadylite-Ba
A valid IMA mineral species
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Formula:
Ba[V4+4P2O8(OH)8] · 12H2O
Colour:
Light green-blue
Lustre:
Vitreous
Specific Gravity:
2.16
Crystal System:
Isometric
Name:
Named as phosphovanadylite after its composition of phosphate and the vanadyl (V4+O2)2- group. Renamed by IMA in August 2012 as phosphovanadylite-Ba.
This page provides mineralogical data about Phosphovanadylite-Ba.
Unique Identifiers
Mindat ID:
7234
Long-form identifier:
mindat:1:1:7234:8
Similar Names
| Phosphovanadylite-Ca | A valid IMA mineral species | Ca[V44+P2O12(OH)4] · 12H2O |
IMA Classification of Phosphovanadylite-Ba
Approved
IMA status notes:
Renamed by the IMA
IMA Formula:
BaV4+4P2O10(OH)6·12H2O
Approval year:
1996
Approval history:
1996: Approved as phosphovanadylite (IMA1996-037)
2012: Renamed as phosphovanadylite-Ba (IMA 12-A)
2012: Renamed as phosphovanadylite-Ba (IMA 12-A)
Classification of Phosphovanadylite-Ba
8.DM.20
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
M : With large and medium-sized cations, (OH, etc.):RO4 > 2:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
M : With large and medium-sized cations, (OH, etc.):RO4 > 2:1
42.13.15.1
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
13 : Miscellaneous
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
13 : Miscellaneous
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Pvd-Ba | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Phosphovanadylite-Ba
Vitreous
Transparency:
Transparent
Colour:
Light green-blue
Comment:
greenish black on oxidation after long exposure to air
Streak:
Very pale greenish blue
Density:
2.16(3) g/cm3 (Measured) 2.13 g/cm3 (Calculated)
Optical Data of Phosphovanadylite-Ba
Type:
Isotropic
RI values:
n = 1.566(4)
Surface Relief:
Low
Chemistry of Phosphovanadylite-Ba
Mindat Formula:
Ba[V4+4P2O8(OH)8] · 12H2O
Element Weights:
Crystallography of Phosphovanadylite-Ba
Crystal System:
Isometric
Class (H-M):
43m - Hextetrahedral
Space Group:
I43m
Cell Parameters:
a = 15.470(4) Å
Unit Cell V:
3,702.29 ų (Calculated from Unit Cell)
Z:
6
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.164 Å | (100) |
| 2.582 Å | (37) |
| 2.445 Å | (36) |
| 7.73 Å | (34) |
| 10.8 Å | (29) |
| 2.738 Å | (29) |
| 2.827 Å | (28) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47c : [Carbonates, phosphates, borates, nitrates] | |
| 47e : [Vanadates, chromates, manganates] |
Type Occurrence of Phosphovanadylite-Ba
General Appearance of Type Material:
Pseudocubes, to 50 μm,
Geological Setting of Type Material:
organic-rich phosphatic mudstone.
Associated Minerals at Type Locality:
Synonyms of Phosphovanadylite-Ba
Other Language Names for Phosphovanadylite-Ba
Related Minerals - Strunz-mindat Grouping
| 8.DM. | Tomsquarryite | NaMgAl3(PO4)2(OH)6 · 8H2O |
| 8.DM. | Elliottite | NaMgAl3(PO4)2F6 · 9H2O |
| 8.DM. | Betpakdalite-FeFe | [Fe3+2 (H2O)15(OH)2Fe3+(H2O)6][Mo8As2Fe3+3O37] |
| 8.DM. | Penriceite | [Mg(H2O)6][Na(H2O)2Al3(PO4)2F6] · H2O |
| 8.DM. | Betpakdalite-CaMg | [Ca2(H2O)17Mg(H2O)6][Mo8As2Fe3+3O36(OH)] |
| 8.DM. | Chinnerite | [Mg(H2O)6]Na(H2O)2Al3(PO4)2F6 |
| 8.DM. | Sarrochite | [Ca4(H2O)38][Mo8P2Fe3+3O37(OH)] |
| 8.DM.05 | Esperanzaite | NaCa2Al2(AsO4)2(OH)F4 · 2H2O |
| 8.DM.05 | Morinite | NaCa2Al2(PO4)2(OH)F4 · 2H2O |
| 8.DM.10 | Alexshubnikovite | Ca2Cu9(AsO4)4(OH)9Cl(H2O)8 · 2H2O |
| 8.DM.10 | Tangdanite | Ca2Cu9(AsO4)4(SO4)0.5(OH)9 · 9H2O |
| 8.DM.10 | Tyrolite | Ca2Cu9(AsO4)4(CO3)(OH)8 · 11H2O |
| 8.DM.15 | Melkovite | [Ca2(H2O)15Ca(H2O)6][Mo8P2Fe3+3O36(OH)] |
| 8.DM.15 | Betpakdalite-NaCa | [Na2(H2O)17Ca(H2O)6][Mo6+8As5+2Fe3+3O34(OH)3] |
| 8.DM.15 | Betpakdalite-CaCa | [Ca2(H2O)17Ca(H2O)6][Mo6+8As5+2Fe3+3O36(OH)] |
| 8.DM.20 | Phosphovanadylite-Ca | Ca[V4+4P2O12(OH)4] · 12H2O |
| 8.DM.25 | Yukonite | Ca3Fe3+(AsO4)2(OH)3 · 5H2O |
| 8.DM.30 | Uduminelite | Ca3Al8(PO4)2O12 · 2H2O |
| 8.DM.35 | Aldermanite | [Mg(H2O)6][Na(H2O)2Al3(PO4)2(OH,F)6] · H2O |
| 8.DM.35 | 'Azovskite' | Fe3+3(PO4)(OH)6 or near |
| 8.DM.35 | Delvauxite | CaFe4(PO4,SO4)2(OH)8 · 4-6H2O not confirmed |
| 8.DM.40 | Santafeite | (Na,Ca,Sr)12(Mn2+,Fe3+,Al,Mg)8Mn4+8(VO4)16(OH,O)20 · 8H2O |
| 8.DM.55 | Tapiaite | Ca5Al2(AsO4)4(OH)4 · 12H2O |
| 8.DM.60 | Alcantarillaite | [Fe3+0.5(H2O)4][CaAs3+2(Fe3+2.5W6+0.5)(AsO4)2O7] |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Phosphovanadylite-Ba
mindat.org URL:
https://www.mindat.org/min-7234.html
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References for Phosphovanadylite-Ba
Reference List:
Medrano, Marjorie D., Evans, Howard T., Wenk, Hans-Rudolf, Piper, David Z. (1998) Phosphovanadylite; a new vanadium phosphate mineral with a zeolite-type structure. American Mineralogist, 83 (7) 889-895 doi:10.2138/am-1998-7-821
Localities for Phosphovanadylite-Ba
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
USA (TL) | |
| Medrano et al. (1998) |
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