Fehrite
A valid IMA mineral species
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About Fehrite
Formula:
MgCu4(SO4)2(OH)6 · 6H2O
Colour:
Turquoise
Lustre:
Vitreous
Specific Gravity:
2.73 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
Named in honour of Karl Thomas Fehr (14 January 1954, Blaichach in Oberallgäu, Germany - 18 March 2014, Munich, Germany), Professor of Mineralogy at the Department of Geo- and Environmental Sciences at the Ludwig-Maximilians-University Munich, Germany.
Isostructural with:
The Mg analogue of ktenasite (isotypic with it) and gobelinite. The only currently known purely Mg-Cu sulfate mineral.
Unique Identifiers
Mindat ID:
54043
Long-form identifier:
mindat:1:1:54043:4
Similar Names
| Ferrite (ceramic) | An artificial material |
| Ferrite (metallurgical) | |
| Ferrite (of English) | A synonym of Native Iron |
| Ferrite (of Johannsen) | |
| Ferrite (of Tieje) | A rock subtype |
| Ferrite (of Vogelsang) | A synonym of 'Limonite' |
| Fiorite | A rock subtype |
| Verite | A synonym of 'Hyalo-olivine-diopside-phlogopite lamproite' |
IMA Classification of Fehrite
Approved
IMA Formula:
MgCu2+4(S6+O4)2(OH)6·6H2O
Approval year:
2019
First published:
2021
Type description reference:
Schlüter, Jochen, Malcherek, Thomas, Mihailova, Boriana, Rewitzer, Christian, Hochleitner, Rupert, Müller, Dirk, Günther, Amanda (2021) Fehrite, MgCu4(SO4)2(OH)6 · 6H2O, the magnesium analogue of ktenasite from the Casualidad mine near Baños de Alhamilla, Almeria, Spain. Neues Jahrbuch für Mineralogie - Abhandlungen, 197 (1). 1-10 doi:10.1127/njma/2020/0218
Classification of Fehrite
7.DD.10
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Feh | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Fehrite
Vitreous
Transparency:
Transparent
Colour:
Turquoise
Streak:
Pale blue-green
Tenacity:
Brittle
Cleavage:
Perfect
on {001}
on {001}
Fracture:
Irregular/Uneven
Density:
2.73 g/cm3 (Calculated)
Chemistry of Fehrite
Mindat Formula:
MgCu4(SO4)2(OH)6 · 6H2O
Element Weights:
Crystallography of Fehrite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 5.6062(8) Å, b = 6.129(1) Å, c = 23.834(3) Å
β = 95.29(1)°
β = 95.29(1)°
Ratio:
a:b:c = 0.915 : 1 : 3.889
Unit Cell V:
815.5 ų
Z:
2
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 11.936 Å | (100) |
| 5.920 Å | (31) |
| 4.845 Å | (11) |
| 3.933 Å | (11) |
| 2.964 Å | (10) |
| 2.775 Å | (9) |
| 2.659 Å | (12) |
| 2.552 Å | (8) |
Reference:
Schlüter, Jochen, Malcherek, Thomas, Mihailova, Boriana, Rewitzer, Christian, Hochleitner, Rupert, Müller, Dirk, Günther, Amanda (2021) Fehrite, MgCu4(SO4)2(OH)6 · 6H2O, the magnesium analogue of ktenasite from the Casualidad mine near Baños de Alhamilla, Almeria, Spain. Neues Jahrbuch für Mineralogie - Abhandlungen, 197 (1). 1-10 doi:10.1127/njma/2020/0218
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47b : [Sulfates and sulfites] |
Type Occurrence of Fehrite
General Appearance of Type Material:
Thin lath-like crystals, up to 200 μm in length, forming radial aggregates.
Place of Conservation of Type Material:
Collections of (1) the Mineralogical Museum, Centrum für Naturkunde, University Hamburg, Grindelallee 48, 20146 Hamburg, Germany, catalogue No. MM1544 (holotype), and (2) the Mineralogische Staatssammlung München, Theresienstrasse 41, 80333 München, Germany, catalogue No. MSM36473 (cotype).
Geological Setting of Type Material:
Oxidation product of primary ore.
Associated Minerals at Type Locality:
Reference:
Schlüter, Jochen, Malcherek, Thomas, Mihailova, Boriana, Rewitzer, Christian, Hochleitner, Rupert, Müller, Dirk, Günther, Amanda (2021) Fehrite, MgCu4(SO4)2(OH)6 · 6H2O, the magnesium analogue of ktenasite from the Casualidad mine near Baños de Alhamilla, Almeria, Spain. Neues Jahrbuch für Mineralogie - Abhandlungen, 197 (1). 1-10 doi:10.1127/njma/2020/0218
Other Language Names for Fehrite
Relationship of Fehrite to other Species
Member of:
Other Members of Ktenasite Group:
| Asagiite | NiCu4(SO4)2(OH)6 · 6H2O | Mon. 2/m : P21/b |
| Gobelinite | CoCu4(SO4)2(OH)6 · 6H2O | Mon. 2/m : P21/m |
| Ktenasite | ZnCu4(SO4)2(OH)6 · 6H2O | Mon. 2/m : P21/b |
| 'Unnamed (Zn-analogue of Ktenasite)' | Zn(Zn,Cu)4(SO4)2(OH)6 · 6H2O |
Common Associates
Associations Based on Photo Data:
| 6 photos of Fehrite associated with Devilline | CaCu4(SO4)2(OH)6 · 3H2O |
| 2 photos of Fehrite associated with Gypsum | CaSO4 · 2H2O |
| 1 photo of Fehrite associated with Serpierite | Ca(Cu2+,Zn2+)4(S6+O4)2(OH)6 · 3H2O |
| 1 photo of Fehrite associated with Brochantite | Cu4(SO4)(OH)6 |
Related Minerals - Strunz-mindat Grouping
| 7.DD. | Asagiite | NiCu4(SO4)2(OH)6 · 6H2O |
| 7.DD.05 | Felsőbányaite | Al4(SO4)(OH)10 · 4H2O |
| 7.DD.07 | Llantenesite | Cu6Al[SeO4](OH)12Cl · 3H2O |
| 7.DD.10 | Langite | Cu4(SO4)(OH)6 · 2H2O |
| 7.DD.10 | Posnjakite | Cu4(SO4)(OH)6 · H2O |
| 7.DD.10 | Wroewolfeite | Cu4(SO4)(OH)6 · 2H2O |
| 7.DD.10 | Gobelinite | CoCu4(SO4)2(OH)6 · 6H2O |
| 7.DD.15 | Kobyashevite | Cu5(SO4)2(OH)6 · 4H2O |
| 7.DD.15 | Spangolite | Cu6Al(SO4)(OH)12Cl · 3H2O |
| 7.DD.15 | 'Unnamed (Dimorph of Devilline)' | CaCu4(SO4)2(OH)6 · 3H2O |
| 7.DD.20 | Ktenasite | ZnCu4(SO4)2(OH)6 · 6H2O |
| 7.DD.25 | Christelite | Cu2Zn3(SO4)2(OH)6 · 4H2O |
| 7.DD.30 | Edwardsite | Cu3Cd2(SO4)2(OH)6 · 4H2O |
| 7.DD.30 | Niedermayrite | CdCu4(SO4)2(OH)6 · 4H2O |
| 7.DD.30 | Serpierite | Ca(Cu2+,Zn2+)4(S6+O4)2(OH)6 · 3H2O |
| 7.DD.30 | Campigliaite | Mn2+Cu4(SO4)2(OH)6 · 4H2O |
| 7.DD.30 | Orthoserpierite | Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O |
| 7.DD.30 | Devilline | CaCu4(SO4)2(OH)6 · 3H2O |
| 7.DD.35 | Shigaite | Mn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O |
| 7.DD.35 | Zincaluminite | (Zn1-xAlx)(SO4)x/2(OH)2 · nH2O |
| 7.DD.35 | Zincowoodwardite | Zn1-xAlx(OH)2[SO4]x/2 · nH2O |
| 7.DD.35 | Natroglaucocerinite | Zn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O |
| 7.DD.35 | Hydrowoodwardite | (Cu1-xAlx)(OH)2[SO4]x/2 · nH2O |
| 7.DD.35 | Honessite | (Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2O |
| 7.DD.35 | Carrboydite | (Ni1-xAlx)(SO4)x/2(OH)2 · nH2O |
| 7.DD.35 | Glaucocerinite | (Zn1-xAlx)(OH)2(SO4)x/2 · nH2O |
| 7.DD.35 | Wermlandite | Mg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2O |
| 7.DD.35 | Nikischerite | Fe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O |
| 7.DD.35 | Hydrohonessite | (Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2O |
| 7.DD.35 | Woodwardite | Cu1-xAlx(OH)2(SO4)x/2 · nH2O |
| 7.DD.35 | Motukoreaite | Mg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2O |
| 7.DD.35 | Mountkeithite | [(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2O |
| 7.DD.40 | Lawsonbauerite | (Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2O |
| 7.DD.40 | Torreyite | (Mg,Mn2+)7◻2Mn2+2Zn4(SO4)2(OH)22 · 8H2O |
| 7.DD.40 | Isselite | Cu6(SO4)(OH)10(H2O)4 · H2O |
| 7.DD.45 | Mooreite | Mg9◻2Mn2Zn4(SO4)2(OH)26 · 8H2O |
| 7.DD.45 | Hodgesmithite | (Cu,Zn)6Zn(SO4)2(OH)10 · 3H2O |
| 7.DD.47 | Lahnsteinite | Zn4(SO4)(OH)6 · 3H2O |
| 7.DD.50 | Namuwite | Zn4(SO4)(OH)6 · 4H2O |
| 7.DD.50 | Minohlite | (Cu,Zn)7(SO4)2(OH)10 · 8H2O |
| 7.DD.52 | Lauraniite | Cu6Cd2(SO4)2(OH)12 · 5H2O |
| 7.DD.55 | Bechererite | Zn7Cu(OH)13[(SiO(OH)3(SO4)] |
| 7.DD.60 | Ramsbeckite | (Cu,Zn)15(SO4)4(OH)22 · 6H2O |
| 7.DD.65 | Vonbezingite | Ca6Cu3(SO4)3(OH)12 · 2H2O |
| 7.DD.70 | Redgillite | Cu6(SO4)(OH)10 · H2O |
| 7.DD.75 | Nickelalumite | NiAl4(SO4)(OH)12(H2O)3 |
| 7.DD.75 | Kyrgyzstanite | ZnAl4(SO4)(OH)12 · 3H2O |
| 7.DD.75 | Chalcoalumite | CuAl4(SO4)(OH)12 · 3H2O |
| 7.DD.80 | Schulenbergite | (Cu,Zn)7(SO4)2(OH)10 · 3H2O |
| 7.DD.80 | 'UM1992-30-SO:CCuHZn' | (Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2O |
| 7.DD.80 | Thérèsemagnanite | NaCo4(SO4)(OH)6Cl · 6H2O |
| 7.DD.80 | Guarinoite | Zn6(SO4)(OH)10 · 5H2O |
| 7.DD.85 | Montetrisaite | Cu6(SO4)(OH)10 · 2H2O |
Fluorescence of Fehrite
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Fehrite
mindat.org URL:
https://www.mindat.org/min-54043.html
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References for Fehrite
Reference List:
Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2019) CNMNC Newsletter 52.New minerals and nomenclature modifications approved in 2019. Mineralogical Magazine, 83 (6) 887-893 doi:10.1180/mgm.2019.73
Schlüter, Jochen, Malcherek, Thomas, Mihailova, Boriana, Rewitzer, Christian, Hochleitner, Rupert, Müller, Dirk, Günther, Amanda (2021) Fehrite, MgCu4(SO4)2(OH)6 · 6H2O, the magnesium analogue of ktenasite from the Casualidad mine near Baños de Alhamilla, Almeria, Spain. Neues Jahrbuch für Mineralogie - Abhandlungen, 197 (1). 1-10 doi:10.1127/njma/2020/0218
Localities for Fehrite
Showing 3 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Germany | |
| Gerhard Möhn collection |
Spain (TL) | |
| Miyawaki et al. (2020) +2 other references |
| Garrido Rufaste +6 other references |
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Mina Casualidad, Baños de Alhamilla, Pechina, Almería, Andalusia, Spain