Wermlandite
A valid IMA mineral species
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About Wermlandite
Formula:
Mg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2O
May contain some carbonate(?).
Colour:
Green-gray
Lustre:
Waxy
Hardness:
1½
Specific Gravity:
1.932
Crystal System:
Trigonal
Member of:
Name:
Named after its discovery locality, Långban, Värmland (Wermland), Sweden.
This is a genuinely rare species. Almost all specimens labeled "wermlandite" prove to be pyroaurite on analysis.
Unique Identifiers
Mindat ID:
4271
Long-form identifier:
mindat:1:1:4271:6
IMA Classification of Wermlandite
Approved
IMA Formula:
Mg7Al2(OH)18[Ca(H2O)6](S6+O4)2·6H2O
Approval year:
1970
First published:
1971
Classification of Wermlandite
7.DD.35
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
31.3.2.1
31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
3 : (AB)5(XO4)Zq·xH2O
31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
3 : (AB)5(XO4)Zq·xH2O
11.7.10
11 : Carbonates
7 : Carbonates of Al
11 : Carbonates
7 : Carbonates of Al
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Wld | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Wld | Warr (2020) | Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30 |
Physical Properties of Wermlandite
Waxy
Transparency:
Translucent
Colour:
Green-gray
Streak:
White to light gray green
Hardness:
1½ on Mohs scale
Tenacity:
Flexible
Cleavage:
Perfect
Perfect on {0001}
Perfect on {0001}
Fracture:
Micaceous
Density:
1.932 g/cm3 (Measured) 1.96 g/cm3 (Calculated)
Optical Data of Wermlandite
Type:
Uniaxial (-)
RI values:
nω = 1.493 nε = 1.482
2V:
Measured: 2° to 5°
Birefringence:
0.011
Max. Birefringence:
δ = 0.011
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Moderate (negative)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic
(convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis
centred and vertical. The coloured rings are isochromatics, computed with the
same physics as the Michel-Lévy bar above; the dark cross is the isogyre.
For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Optical Extinction:
Parallel
Chemistry of Wermlandite
Mindat Formula:
Mg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2O
May contain some carbonate(?).
May contain some carbonate(?).
Element Weights:
Crystallography of Wermlandite
Crystal System:
Trigonal
Class (H-M):
3m(32/m) - Hexagonal Scalenohedral
Space Group:
P3c1
Setting:
P3c1
Cell Parameters:
a = 9.303(3) Å, c = 22.57(1) Å
Ratio:
a:c = 1 : 2.426
Unit Cell V:
1,691.64 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Thin pseudohexagonal platy crystals
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0010871 | Wermlandite | Rius J, Allmann R (1984) The superstructure of the double layer mineral wermlandite [Mg7(Al0.57,Fe3+0.43)2(OH)18]2+[(Ca0.6,Mg0.4)(SO4)2(H2O)12]2- Zeitschrift fur Kristallographie 168 133-144 | ![]() | 1984 | Langban, Warmland, Sweden | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 11.2 Å | (70) |
| 7.98 Å | (100) |
| 5.62 Å | (40) |
| 4.63 Å | (50) |
| 3.89 Å | (40) |
| 2.61 Å | (40) |
| 1.54 Å | (40) |
| 1.51 Å | (30) |
Comments:
ZK 168:133 (1984)
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-? alteration and/or metamorphism | |
| 32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits | |
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47b : [Sulfates and sulfites] |
Type Occurrence of Wermlandite
General Appearance of Type Material:
Plates up to 1 cm in diameter, with breadth to thickness 20:1, implanted along large calcite crystals.
Place of Conservation of Type Material:
1) Swedish Museum of Natural History, Stockholm, Sweden, 38001.
2) National Museum of Natural History, Washington, D.C., USA, 137023, 149523.
2) National Museum of Natural History, Washington, D.C., USA, 137023, 149523.
Geological Setting of Type Material:
Low temperature vein filling in calcite.
Associated Minerals at Type Locality:
Synonyms of Wermlandite
Other Language Names for Wermlandite
Relationship of Wermlandite to other Species
Member of:
Other Members of Wermlandite Group:
| Erssonite | Mg7Fe3+2(OH)18[Ca(H2O)6](SO4)2 · 12H2O | Trig. 3m(32/m) : P3c1 |
| Karchevskyite | Mg18Al9(OH)54Sr2(CO3)9(H2O)6(H3O)5 | Trig. |
| Motukoreaite | Mg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2O | Trig. 3m(32/m) : R3m |
| Natroglaucocerinite | Zn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O | Hex. |
| Nikischerite | Fe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O | Trig. 3 : R3 |
| Shigaite | Mn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O | Trig. 3 : R3 |
Common Associates
Related Minerals - Strunz-mindat Grouping
| 7.DD. | Asagiite | NiCu4(SO4)2(OH)6 · 6H2O |
| 7.DD.05 | Felsőbányaite | Al4(SO4)(OH)10 · 4H2O |
| 7.DD.07 | Llantenesite | Cu6Al[SeO4](OH)12Cl · 3H2O |
| 7.DD.10 | Langite | Cu4(SO4)(OH)6 · 2H2O |
| 7.DD.10 | Fehrite | MgCu4(SO4)2(OH)6 · 6H2O |
| 7.DD.10 | Posnjakite | Cu4(SO4)(OH)6 · H2O |
| 7.DD.10 | Wroewolfeite | Cu4(SO4)(OH)6 · 2H2O |
| 7.DD.10 | Gobelinite | CoCu4(SO4)2(OH)6 · 6H2O |
| 7.DD.15 | Kobyashevite | Cu5(SO4)2(OH)6 · 4H2O |
| 7.DD.15 | Spangolite | Cu6Al(SO4)(OH)12Cl · 3H2O |
| 7.DD.15 | 'Unnamed (Dimorph of Devilline)' | CaCu4(SO4)2(OH)6 · 3H2O |
| 7.DD.20 | Ktenasite | ZnCu4(SO4)2(OH)6 · 6H2O |
| 7.DD.25 | Christelite | Cu2Zn3(SO4)2(OH)6 · 4H2O |
| 7.DD.30 | Edwardsite | Cu3Cd2(SO4)2(OH)6 · 4H2O |
| 7.DD.30 | Niedermayrite | CdCu4(SO4)2(OH)6 · 4H2O |
| 7.DD.30 | Serpierite | Ca(Cu2+,Zn2+)4(S6+O4)2(OH)6 · 3H2O |
| 7.DD.30 | Campigliaite | Mn2+Cu4(SO4)2(OH)6 · 4H2O |
| 7.DD.30 | Orthoserpierite | Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O |
| 7.DD.30 | Devilline | CaCu4(SO4)2(OH)6 · 3H2O |
| 7.DD.35 | Shigaite | Mn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O |
| 7.DD.35 | Zincaluminite | (Zn1-xAlx)(SO4)x/2(OH)2 · nH2O |
| 7.DD.35 | Zincowoodwardite | Zn1-xAlx(OH)2[SO4]x/2 · nH2O |
| 7.DD.35 | Natroglaucocerinite | Zn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O |
| 7.DD.35 | Hydrowoodwardite | (Cu1-xAlx)(OH)2[SO4]x/2 · nH2O |
| 7.DD.35 | Honessite | (Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2O |
| 7.DD.35 | Carrboydite | (Ni1-xAlx)(SO4)x/2(OH)2 · nH2O |
| 7.DD.35 | Glaucocerinite | (Zn1-xAlx)(OH)2(SO4)x/2 · nH2O |
| 7.DD.35 | Nikischerite | Fe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O |
| 7.DD.35 | Hydrohonessite | (Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2O |
| 7.DD.35 | Woodwardite | Cu1-xAlx(OH)2(SO4)x/2 · nH2O |
| 7.DD.35 | Motukoreaite | Mg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2O |
| 7.DD.35 | Mountkeithite | [(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2O |
| 7.DD.40 | Lawsonbauerite | (Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2O |
| 7.DD.40 | Torreyite | (Mg,Mn2+)7◻2Mn2+2Zn4(SO4)2(OH)22 · 8H2O |
| 7.DD.40 | Isselite | Cu6(SO4)(OH)10(H2O)4 · H2O |
| 7.DD.45 | Mooreite | Mg9◻2Mn2Zn4(SO4)2(OH)26 · 8H2O |
| 7.DD.45 | Hodgesmithite | (Cu,Zn)6Zn(SO4)2(OH)10 · 3H2O |
| 7.DD.47 | Lahnsteinite | Zn4(SO4)(OH)6 · 3H2O |
| 7.DD.50 | Namuwite | Zn4(SO4)(OH)6 · 4H2O |
| 7.DD.50 | Minohlite | (Cu,Zn)7(SO4)2(OH)10 · 8H2O |
| 7.DD.52 | Lauraniite | Cu6Cd2(SO4)2(OH)12 · 5H2O |
| 7.DD.55 | Bechererite | Zn7Cu(OH)13[(SiO(OH)3(SO4)] |
| 7.DD.60 | Ramsbeckite | (Cu,Zn)15(SO4)4(OH)22 · 6H2O |
| 7.DD.65 | Vonbezingite | Ca6Cu3(SO4)3(OH)12 · 2H2O |
| 7.DD.70 | Redgillite | Cu6(SO4)(OH)10 · H2O |
| 7.DD.75 | Nickelalumite | NiAl4(SO4)(OH)12(H2O)3 |
| 7.DD.75 | Kyrgyzstanite | ZnAl4(SO4)(OH)12 · 3H2O |
| 7.DD.75 | Chalcoalumite | CuAl4(SO4)(OH)12 · 3H2O |
| 7.DD.80 | Schulenbergite | (Cu,Zn)7(SO4)2(OH)10 · 3H2O |
| 7.DD.80 | 'UM1992-30-SO:CCuHZn' | (Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2O |
| 7.DD.80 | Thérèsemagnanite | NaCo4(SO4)(OH)6Cl · 6H2O |
| 7.DD.80 | Guarinoite | Zn6(SO4)(OH)10 · 5H2O |
| 7.DD.85 | Montetrisaite | Cu6(SO4)(OH)10 · 2H2O |
Fluorescence of Wermlandite
Not fluorescent.
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Wermlandite
mindat.org URL:
https://www.mindat.org/min-4271.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Wermlandite
Reference List:
Moore, Paul B (1971) Wermlandite, a new mineral from Långban, Sweden. Lithos, 4 (3) 213-217 doi:10.1016/0024-4937(71)90001-6
Taylor, H. F. W. (1973) Crystal structures of some double hydroxide minerals. Mineralogical Magazine, 39 (304). 377-389 doi:10.1180/minmag.1973.039.304.01
Localities for Wermlandite
Showing 3 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Sweden (TL) | |
| Moore (1971) +2 other references |
| Linden (2002) |
| Östra Värmlands Mineral Society |
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The
Långban Mine, Långban Ore District, Filipstad, Värmland County, Sweden